The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide

Abstract In the context of derivatisation studies of the pentaamine ligand 2,6-$ C_{5} $$ H_{3} $N[CMe($ CH_{2} $$ NH_{2} $)2]2 (2-(6-(1,3-diamino-2-methylpropan-2-yl)pyridin-2-yl)-2-methylpropane-1,3-diamine, 1), we explored its zinc(II) coordination chemistry. With $ ZnBr_{2} $ in hot aqueous etha...
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Autor*in:	Pitarch López, Jesús [verfasserIn] Heinemann, Frank W. Grohmann, Andreas

Format:	Artikel
Sprache:	Englisch

Erschienen:	2004

Systematik:	VA 8360

Anmerkung:	© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Übergeordnetes Werk:	Enthalten in: Zeitschrift für Naturforschung. B, Chemical sciences - Verlag der Zeitschrift für Naturforschung, 1947, 59(2004), 11-12 vom: 01. Dez., Seite 1600-1604
Übergeordnetes Werk:	volume:59 ; year:2004 ; number:11-12 ; day:01 ; month:12 ; pages:1600-1604

Links:	Volltext

DOI / URN:	10.1515/znb-2004-11-1233

Katalog-ID:	OLC214056930X

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520			\|a Abstract In the context of derivatisation studies of the pentaamine ligand 2,6-$ C_{5} $$ H_{3} $N[CMe($ CH_{2} $$ NH_{2} $)2]2 (2-(6-(1,3-diamino-2-methylpropan-2-yl)pyridin-2-yl)-2-methylpropane-1,3-diamine, 1), we explored its zinc(II) coordination chemistry. With $ ZnBr_{2} $ in hot aqueous ethanol, in the absence of Lewis acid, the aqua complex [Zn(1)($ H_{2} $O)]$ Br_{2} $ (2) is obtained, in which the pentaamine ligand acts as a square-pyramidal coordination cap. Single crystal structure data for the dihydrate of 2 are reported. In methanol solution, the complex is reactive towards carbon dioxide, and spectroscopic data (IR, 13C NMR) indicate the reversible formation of the dinuclear methyl carbonate complex [(Zn(1))2($ μ_{2} $-($ η^{1} $-O,$ η^{1} $-O)$ O_{2} $$ COCH_{3} $)]$ Br_{3} $.
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allfields	10.1515/znb-2004-11-1233 doi (DE-627)OLC214056930X (DE-B1597)znb-2004-11-1233-p DE-627 ger DE-627 rakwb eng 540 VZ 540 VZ VA 8360 VZ rvk Pitarch López, Jesús verfasserin aut The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide 2004 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract In the context of derivatisation studies of the pentaamine ligand 2,6-$ C_{5} $$ H_{3} $N[CMe($ CH_{2} $$ NH_{2} $)2]2 (2-(6-(1,3-diamino-2-methylpropan-2-yl)pyridin-2-yl)-2-methylpropane-1,3-diamine, 1), we explored its zinc(II) coordination chemistry. With $ ZnBr_{2} $ in hot aqueous ethanol, in the absence of Lewis acid, the aqua complex [Zn(1)($ H_{2} $O)]$ Br_{2} $ (2) is obtained, in which the pentaamine ligand acts as a square-pyramidal coordination cap. Single crystal structure data for the dihydrate of 2 are reported. In methanol solution, the complex is reactive towards carbon dioxide, and spectroscopic data (IR, 13C NMR) indicate the reversible formation of the dinuclear methyl carbonate complex [(Zn(1))2($ μ_{2} $-($ η^{1} $-O,$ η^{1} $-O)$ O_{2} $$ COCH_{3} $)]$ Br_{3} $. Heinemann, Frank W. aut Grohmann, Andreas aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 59(2004), 11-12 vom: 01. Dez., Seite 1600-1604 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:59 year:2004 number:11-12 day:01 month:12 pages:1600-1604 https://doi.org/10.1515/znb-2004-11-1233 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_120 GBV_ILN_121 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2185 GBV_ILN_2279 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4310 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 GBV_ILN_4323 VA 8360 AR 59 2004 11-12 01 12 1600-1604
spelling	10.1515/znb-2004-11-1233 doi (DE-627)OLC214056930X (DE-B1597)znb-2004-11-1233-p DE-627 ger DE-627 rakwb eng 540 VZ 540 VZ VA 8360 VZ rvk Pitarch López, Jesús verfasserin aut The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide 2004 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract In the context of derivatisation studies of the pentaamine ligand 2,6-$ C_{5} $$ H_{3} $N[CMe($ CH_{2} $$ NH_{2} $)2]2 (2-(6-(1,3-diamino-2-methylpropan-2-yl)pyridin-2-yl)-2-methylpropane-1,3-diamine, 1), we explored its zinc(II) coordination chemistry. With $ ZnBr_{2} $ in hot aqueous ethanol, in the absence of Lewis acid, the aqua complex [Zn(1)($ H_{2} $O)]$ Br_{2} $ (2) is obtained, in which the pentaamine ligand acts as a square-pyramidal coordination cap. Single crystal structure data for the dihydrate of 2 are reported. In methanol solution, the complex is reactive towards carbon dioxide, and spectroscopic data (IR, 13C NMR) indicate the reversible formation of the dinuclear methyl carbonate complex [(Zn(1))2($ μ_{2} $-($ η^{1} $-O,$ η^{1} $-O)$ O_{2} $$ COCH_{3} $)]$ Br_{3} $. Heinemann, Frank W. aut Grohmann, Andreas aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 59(2004), 11-12 vom: 01. Dez., Seite 1600-1604 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:59 year:2004 number:11-12 day:01 month:12 pages:1600-1604 https://doi.org/10.1515/znb-2004-11-1233 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_120 GBV_ILN_121 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2185 GBV_ILN_2279 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4310 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 GBV_ILN_4323 VA 8360 AR 59 2004 11-12 01 12 1600-1604
allfields_unstemmed	10.1515/znb-2004-11-1233 doi (DE-627)OLC214056930X (DE-B1597)znb-2004-11-1233-p DE-627 ger DE-627 rakwb eng 540 VZ 540 VZ VA 8360 VZ rvk Pitarch López, Jesús verfasserin aut The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide 2004 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract In the context of derivatisation studies of the pentaamine ligand 2,6-$ C_{5} $$ H_{3} $N[CMe($ CH_{2} $$ NH_{2} $)2]2 (2-(6-(1,3-diamino-2-methylpropan-2-yl)pyridin-2-yl)-2-methylpropane-1,3-diamine, 1), we explored its zinc(II) coordination chemistry. With $ ZnBr_{2} $ in hot aqueous ethanol, in the absence of Lewis acid, the aqua complex [Zn(1)($ H_{2} $O)]$ Br_{2} $ (2) is obtained, in which the pentaamine ligand acts as a square-pyramidal coordination cap. Single crystal structure data for the dihydrate of 2 are reported. In methanol solution, the complex is reactive towards carbon dioxide, and spectroscopic data (IR, 13C NMR) indicate the reversible formation of the dinuclear methyl carbonate complex [(Zn(1))2($ μ_{2} $-($ η^{1} $-O,$ η^{1} $-O)$ O_{2} $$ COCH_{3} $)]$ Br_{3} $. Heinemann, Frank W. aut Grohmann, Andreas aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 59(2004), 11-12 vom: 01. Dez., Seite 1600-1604 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:59 year:2004 number:11-12 day:01 month:12 pages:1600-1604 https://doi.org/10.1515/znb-2004-11-1233 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_120 GBV_ILN_121 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2185 GBV_ILN_2279 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4310 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 GBV_ILN_4323 VA 8360 AR 59 2004 11-12 01 12 1600-1604
allfieldsGer	10.1515/znb-2004-11-1233 doi (DE-627)OLC214056930X (DE-B1597)znb-2004-11-1233-p DE-627 ger DE-627 rakwb eng 540 VZ 540 VZ VA 8360 VZ rvk Pitarch López, Jesús verfasserin aut The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide 2004 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract In the context of derivatisation studies of the pentaamine ligand 2,6-$ C_{5} $$ H_{3} $N[CMe($ CH_{2} $$ NH_{2} $)2]2 (2-(6-(1,3-diamino-2-methylpropan-2-yl)pyridin-2-yl)-2-methylpropane-1,3-diamine, 1), we explored its zinc(II) coordination chemistry. With $ ZnBr_{2} $ in hot aqueous ethanol, in the absence of Lewis acid, the aqua complex [Zn(1)($ H_{2} $O)]$ Br_{2} $ (2) is obtained, in which the pentaamine ligand acts as a square-pyramidal coordination cap. Single crystal structure data for the dihydrate of 2 are reported. In methanol solution, the complex is reactive towards carbon dioxide, and spectroscopic data (IR, 13C NMR) indicate the reversible formation of the dinuclear methyl carbonate complex [(Zn(1))2($ μ_{2} $-($ η^{1} $-O,$ η^{1} $-O)$ O_{2} $$ COCH_{3} $)]$ Br_{3} $. Heinemann, Frank W. aut Grohmann, Andreas aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 59(2004), 11-12 vom: 01. Dez., Seite 1600-1604 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:59 year:2004 number:11-12 day:01 month:12 pages:1600-1604 https://doi.org/10.1515/znb-2004-11-1233 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_120 GBV_ILN_121 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2185 GBV_ILN_2279 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4310 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 GBV_ILN_4323 VA 8360 AR 59 2004 11-12 01 12 1600-1604
allfieldsSound	10.1515/znb-2004-11-1233 doi (DE-627)OLC214056930X (DE-B1597)znb-2004-11-1233-p DE-627 ger DE-627 rakwb eng 540 VZ 540 VZ VA 8360 VZ rvk Pitarch López, Jesús verfasserin aut The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide 2004 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © 1946 – 2014: Verlag der Zeitschrift für Naturforschung Abstract In the context of derivatisation studies of the pentaamine ligand 2,6-$ C_{5} $$ H_{3} $N[CMe($ CH_{2} $$ NH_{2} $)2]2 (2-(6-(1,3-diamino-2-methylpropan-2-yl)pyridin-2-yl)-2-methylpropane-1,3-diamine, 1), we explored its zinc(II) coordination chemistry. With $ ZnBr_{2} $ in hot aqueous ethanol, in the absence of Lewis acid, the aqua complex [Zn(1)($ H_{2} $O)]$ Br_{2} $ (2) is obtained, in which the pentaamine ligand acts as a square-pyramidal coordination cap. Single crystal structure data for the dihydrate of 2 are reported. In methanol solution, the complex is reactive towards carbon dioxide, and spectroscopic data (IR, 13C NMR) indicate the reversible formation of the dinuclear methyl carbonate complex [(Zn(1))2($ μ_{2} $-($ η^{1} $-O,$ η^{1} $-O)$ O_{2} $$ COCH_{3} $)]$ Br_{3} $. Heinemann, Frank W. aut Grohmann, Andreas aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Verlag der Zeitschrift für Naturforschung, 1947 59(2004), 11-12 vom: 01. Dez., Seite 1600-1604 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:59 year:2004 number:11-12 day:01 month:12 pages:1600-1604 https://doi.org/10.1515/znb-2004-11-1233 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_22 GBV_ILN_24 GBV_ILN_30 GBV_ILN_40 GBV_ILN_59 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_120 GBV_ILN_121 GBV_ILN_267 GBV_ILN_285 GBV_ILN_2001 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2026 GBV_ILN_2185 GBV_ILN_2279 GBV_ILN_2409 GBV_ILN_4012 GBV_ILN_4027 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4116 GBV_ILN_4125 GBV_ILN_4266 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4310 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 GBV_ILN_4323 VA 8360 AR 59 2004 11-12 01 12 1600-1604
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source	Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences 59(2004), 11-12 vom: 01. Dez., Seite 1600-1604 volume:59 year:2004 number:11-12 day:01 month:12 pages:1600-1604
sourceStr	Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences 59(2004), 11-12 vom: 01. Dez., Seite 1600-1604 volume:59 year:2004 number:11-12 day:01 month:12 pages:1600-1604
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author	Pitarch López, Jesús
spellingShingle	Pitarch López, Jesús ddc 540 rvk VA 8360 The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide
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title	The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide
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title_full	The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide
author_sort	Pitarch López, Jesús
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author_browse	Pitarch López, Jesús Heinemann, Frank W. Grohmann, Andreas
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title_sort	the zinc aqua complex of a tetrapodal pentaamine ligand and its reactivity towards carbon dioxide
title_auth	The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide
abstract	Abstract In the context of derivatisation studies of the pentaamine ligand 2,6-$ C_{5} $$ H_{3} $N[CMe($ CH_{2} $$ NH_{2} $)2]2 (2-(6-(1,3-diamino-2-methylpropan-2-yl)pyridin-2-yl)-2-methylpropane-1,3-diamine, 1), we explored its zinc(II) coordination chemistry. With $ ZnBr_{2} $ in hot aqueous ethanol, in the absence of Lewis acid, the aqua complex [Zn(1)($ H_{2} $O)]$ Br_{2} $ (2) is obtained, in which the pentaamine ligand acts as a square-pyramidal coordination cap. Single crystal structure data for the dihydrate of 2 are reported. In methanol solution, the complex is reactive towards carbon dioxide, and spectroscopic data (IR, 13C NMR) indicate the reversible formation of the dinuclear methyl carbonate complex [(Zn(1))2($ μ_{2} $-($ η^{1} $-O,$ η^{1} $-O)$ O_{2} $$ COCH_{3} $)]$ Br_{3} $. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
abstractGer	Abstract In the context of derivatisation studies of the pentaamine ligand 2,6-$ C_{5} $$ H_{3} $N[CMe($ CH_{2} $$ NH_{2} $)2]2 (2-(6-(1,3-diamino-2-methylpropan-2-yl)pyridin-2-yl)-2-methylpropane-1,3-diamine, 1), we explored its zinc(II) coordination chemistry. With $ ZnBr_{2} $ in hot aqueous ethanol, in the absence of Lewis acid, the aqua complex [Zn(1)($ H_{2} $O)]$ Br_{2} $ (2) is obtained, in which the pentaamine ligand acts as a square-pyramidal coordination cap. Single crystal structure data for the dihydrate of 2 are reported. In methanol solution, the complex is reactive towards carbon dioxide, and spectroscopic data (IR, 13C NMR) indicate the reversible formation of the dinuclear methyl carbonate complex [(Zn(1))2($ μ_{2} $-($ η^{1} $-O,$ η^{1} $-O)$ O_{2} $$ COCH_{3} $)]$ Br_{3} $. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
abstract_unstemmed	Abstract In the context of derivatisation studies of the pentaamine ligand 2,6-$ C_{5} $$ H_{3} $N[CMe($ CH_{2} $$ NH_{2} $)2]2 (2-(6-(1,3-diamino-2-methylpropan-2-yl)pyridin-2-yl)-2-methylpropane-1,3-diamine, 1), we explored its zinc(II) coordination chemistry. With $ ZnBr_{2} $ in hot aqueous ethanol, in the absence of Lewis acid, the aqua complex [Zn(1)($ H_{2} $O)]$ Br_{2} $ (2) is obtained, in which the pentaamine ligand acts as a square-pyramidal coordination cap. Single crystal structure data for the dihydrate of 2 are reported. In methanol solution, the complex is reactive towards carbon dioxide, and spectroscopic data (IR, 13C NMR) indicate the reversible formation of the dinuclear methyl carbonate complex [(Zn(1))2($ μ_{2} $-($ η^{1} $-O,$ η^{1} $-O)$ O_{2} $$ COCH_{3} $)]$ Br_{3} $. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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title_short	The Zinc Aqua Complex of a Tetrapodal Pentaamine Ligand and its Reactivity towards Carbon Dioxide
url	https://doi.org/10.1515/znb-2004-11-1233
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up_date	2024-07-03T23:53:55.179Z
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