Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)2(dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl)

Abstract The salt [Rh(III)(phpy)2(dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type...
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Gespeichert in:

Autor*in:	Vogler, Arnd [verfasserIn] Bodensteiner, Michael

Format:	Artikel
Sprache:	Englisch

Erschienen:	2019

Systematik:	VA 8360

Anmerkung:	©2019 Walter de Gruyter GmbH, Berlin/Boston

Übergeordnetes Werk:	Enthalten in: Zeitschrift für Naturforschung. B, Chemical sciences - De Gruyter, 1947, 74(2019), 5 vom: 05. Apr., Seite 405-408
Übergeordnetes Werk:	volume:74 ; year:2019 ; number:5 ; day:05 ; month:04 ; pages:405-408

Links:	Volltext

DOI / URN:	10.1515/znb-2018-0242

Katalog-ID:	OLC2141768551

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520			\|a Abstract The salt [Rh(III)(phpy)2(dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at λmax = 607 nm with φϕ = $ 10^{−3} $ and τ = 3.7 ns in $ CH_{2} $$ Cl_{2} $.
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allfields	10.1515/znb-2018-0242 doi (DE-627)OLC2141768551 (DE-B1597)znb-2018-0242-p DE-627 ger DE-627 rakwb eng 540 VZ 540 VZ VA 8360 VZ rvk Vogler, Arnd verfasserin aut Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)2(dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl) 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier ©2019 Walter de Gruyter GmbH, Berlin/Boston Abstract The salt [Rh(III)(phpy)2(dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at λmax = 607 nm with φϕ = $ 10^{−3} $ and τ = 3.7 ns in $ CH_{2} $$ Cl_{2} $. Bodensteiner, Michael aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences De Gruyter, 1947 74(2019), 5 vom: 05. Apr., Seite 405-408 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:74 year:2019 number:5 day:05 month:04 pages:405-408 https://doi.org/10.1515/znb-2018-0242 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_24 GBV_ILN_59 GBV_ILN_70 GBV_ILN_121 GBV_ILN_267 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_4012 GBV_ILN_4125 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4320 VA 8360 AR 74 2019 5 05 04 405-408
spelling	10.1515/znb-2018-0242 doi (DE-627)OLC2141768551 (DE-B1597)znb-2018-0242-p DE-627 ger DE-627 rakwb eng 540 VZ 540 VZ VA 8360 VZ rvk Vogler, Arnd verfasserin aut Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)2(dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl) 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier ©2019 Walter de Gruyter GmbH, Berlin/Boston Abstract The salt [Rh(III)(phpy)2(dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at λmax = 607 nm with φϕ = $ 10^{−3} $ and τ = 3.7 ns in $ CH_{2} $$ Cl_{2} $. Bodensteiner, Michael aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences De Gruyter, 1947 74(2019), 5 vom: 05. Apr., Seite 405-408 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:74 year:2019 number:5 day:05 month:04 pages:405-408 https://doi.org/10.1515/znb-2018-0242 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_24 GBV_ILN_59 GBV_ILN_70 GBV_ILN_121 GBV_ILN_267 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_4012 GBV_ILN_4125 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4320 VA 8360 AR 74 2019 5 05 04 405-408
allfields_unstemmed	10.1515/znb-2018-0242 doi (DE-627)OLC2141768551 (DE-B1597)znb-2018-0242-p DE-627 ger DE-627 rakwb eng 540 VZ 540 VZ VA 8360 VZ rvk Vogler, Arnd verfasserin aut Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)2(dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl) 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier ©2019 Walter de Gruyter GmbH, Berlin/Boston Abstract The salt [Rh(III)(phpy)2(dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at λmax = 607 nm with φϕ = $ 10^{−3} $ and τ = 3.7 ns in $ CH_{2} $$ Cl_{2} $. Bodensteiner, Michael aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences De Gruyter, 1947 74(2019), 5 vom: 05. Apr., Seite 405-408 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:74 year:2019 number:5 day:05 month:04 pages:405-408 https://doi.org/10.1515/znb-2018-0242 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_24 GBV_ILN_59 GBV_ILN_70 GBV_ILN_121 GBV_ILN_267 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_4012 GBV_ILN_4125 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4320 VA 8360 AR 74 2019 5 05 04 405-408
allfieldsGer	10.1515/znb-2018-0242 doi (DE-627)OLC2141768551 (DE-B1597)znb-2018-0242-p DE-627 ger DE-627 rakwb eng 540 VZ 540 VZ VA 8360 VZ rvk Vogler, Arnd verfasserin aut Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)2(dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl) 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier ©2019 Walter de Gruyter GmbH, Berlin/Boston Abstract The salt [Rh(III)(phpy)2(dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at λmax = 607 nm with φϕ = $ 10^{−3} $ and τ = 3.7 ns in $ CH_{2} $$ Cl_{2} $. Bodensteiner, Michael aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences De Gruyter, 1947 74(2019), 5 vom: 05. Apr., Seite 405-408 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:74 year:2019 number:5 day:05 month:04 pages:405-408 https://doi.org/10.1515/znb-2018-0242 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_24 GBV_ILN_59 GBV_ILN_70 GBV_ILN_121 GBV_ILN_267 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_4012 GBV_ILN_4125 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4320 VA 8360 AR 74 2019 5 05 04 405-408
allfieldsSound	10.1515/znb-2018-0242 doi (DE-627)OLC2141768551 (DE-B1597)znb-2018-0242-p DE-627 ger DE-627 rakwb eng 540 VZ 540 VZ VA 8360 VZ rvk Vogler, Arnd verfasserin aut Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)2(dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl) 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier ©2019 Walter de Gruyter GmbH, Berlin/Boston Abstract The salt [Rh(III)(phpy)2(dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at λmax = 607 nm with φϕ = $ 10^{−3} $ and τ = 3.7 ns in $ CH_{2} $$ Cl_{2} $. Bodensteiner, Michael aut Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences De Gruyter, 1947 74(2019), 5 vom: 05. Apr., Seite 405-408 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:74 year:2019 number:5 day:05 month:04 pages:405-408 https://doi.org/10.1515/znb-2018-0242 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OPC-FOR GBV_ILN_24 GBV_ILN_59 GBV_ILN_70 GBV_ILN_121 GBV_ILN_267 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_4012 GBV_ILN_4125 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4320 VA 8360 AR 74 2019 5 05 04 405-408
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title	Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)2(dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl)
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title_sort	synthesis, crystal structure and photoluminescence of [rh(iii)(phpy)2(dithiooxamide)]cl (phpy = 2-(2-pyridyl)phenyl)
title_auth	Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)2(dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl)
abstract	Abstract The salt [Rh(III)(phpy)2(dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at λmax = 607 nm with φϕ = $ 10^{−3} $ and τ = 3.7 ns in $ CH_{2} $$ Cl_{2} $. ©2019 Walter de Gruyter GmbH, Berlin/Boston
abstractGer	Abstract The salt [Rh(III)(phpy)2(dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at λmax = 607 nm with φϕ = $ 10^{−3} $ and τ = 3.7 ns in $ CH_{2} $$ Cl_{2} $. ©2019 Walter de Gruyter GmbH, Berlin/Boston
abstract_unstemmed	Abstract The salt [Rh(III)(phpy)2(dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at λmax = 607 nm with φϕ = $ 10^{−3} $ and τ = 3.7 ns in $ CH_{2} $$ Cl_{2} $. ©2019 Walter de Gruyter GmbH, Berlin/Boston
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container_issue	5
title_short	Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)2(dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl)
url	https://doi.org/10.1515/znb-2018-0242
remote_bool	false
author2	Bodensteiner, Michael
author2Str	Bodensteiner, Michael
ppnlink	129307386
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isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1515/znb-2018-0242
up_date	2024-07-04T02:52:14.100Z
_version_	1803615243190927360
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Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)2(dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl)

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