Features of Cl K-edge XANES Spectra of Transition Metal Complexes {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt)
Abstract Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orb...
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| Autor*in: |
Fedorenko, A. D. [verfasserIn] |
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Artikel |
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Englisch |
| Erschienen: |
2023 |
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© Allerton Press, Inc. 2023. ISSN 1062-8738, Bulletin of the Russian Academy of Sciences: Physics, 2023, Vol. 87, No. 5, pp. 654–661. © Allerton Press, Inc., 2023. Russian Text © The Author(s), 2023, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2023, Vol. 87, No. 5, pp. 738–746. |
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Enthalten in: Bulletin of the Russian Academy of Sciences: Physics - Pleiades Publishing, 1992, 87(2023), 5 vom: Mai, Seite 654-661 |
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volume:87 ; year:2023 ; number:5 ; month:05 ; pages:654-661 |
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10.3103/S1062873822701805 |
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| 520 | |a Abstract Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes. | ||
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10.3103/S1062873822701805 doi (DE-627)OLC2143924364 (DE-He213)S1062873822701805-p DE-627 ger DE-627 rakwb eng 530 VZ Fedorenko, A. D. verfasserin aut Features of Cl K-edge XANES Spectra of Transition Metal Complexes {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Allerton Press, Inc. 2023. ISSN 1062-8738, Bulletin of the Russian Academy of Sciences: Physics, 2023, Vol. 87, No. 5, pp. 654–661. © Allerton Press, Inc., 2023. Russian Text © The Author(s), 2023, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2023, Vol. 87, No. 5, pp. 738–746. Abstract Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes. Asanov, I. P. aut Asanova, T. I. aut Vasil’chenko, D. B. aut Nikolenko, A. D. aut Piminov, P. A. aut Karyukina, K. Yu. aut Enthalten in Bulletin of the Russian Academy of Sciences: Physics Pleiades Publishing, 1992 87(2023), 5 vom: Mai, Seite 654-661 (DE-627)131135384 (DE-600)1124898-1 (DE-576)032854463 1062-8738 nnns volume:87 year:2023 number:5 month:05 pages:654-661 https://doi.org/10.3103/S1062873822701805 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-OEU SSG-OLC-HIS AR 87 2023 5 05 654-661 |
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10.3103/S1062873822701805 doi (DE-627)OLC2143924364 (DE-He213)S1062873822701805-p DE-627 ger DE-627 rakwb eng 530 VZ Fedorenko, A. D. verfasserin aut Features of Cl K-edge XANES Spectra of Transition Metal Complexes {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Allerton Press, Inc. 2023. ISSN 1062-8738, Bulletin of the Russian Academy of Sciences: Physics, 2023, Vol. 87, No. 5, pp. 654–661. © Allerton Press, Inc., 2023. Russian Text © The Author(s), 2023, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2023, Vol. 87, No. 5, pp. 738–746. Abstract Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes. Asanov, I. P. aut Asanova, T. I. aut Vasil’chenko, D. B. aut Nikolenko, A. D. aut Piminov, P. A. aut Karyukina, K. Yu. aut Enthalten in Bulletin of the Russian Academy of Sciences: Physics Pleiades Publishing, 1992 87(2023), 5 vom: Mai, Seite 654-661 (DE-627)131135384 (DE-600)1124898-1 (DE-576)032854463 1062-8738 nnns volume:87 year:2023 number:5 month:05 pages:654-661 https://doi.org/10.3103/S1062873822701805 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-OEU SSG-OLC-HIS AR 87 2023 5 05 654-661 |
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10.3103/S1062873822701805 doi (DE-627)OLC2143924364 (DE-He213)S1062873822701805-p DE-627 ger DE-627 rakwb eng 530 VZ Fedorenko, A. D. verfasserin aut Features of Cl K-edge XANES Spectra of Transition Metal Complexes {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Allerton Press, Inc. 2023. ISSN 1062-8738, Bulletin of the Russian Academy of Sciences: Physics, 2023, Vol. 87, No. 5, pp. 654–661. © Allerton Press, Inc., 2023. Russian Text © The Author(s), 2023, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2023, Vol. 87, No. 5, pp. 738–746. Abstract Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes. Asanov, I. P. aut Asanova, T. I. aut Vasil’chenko, D. B. aut Nikolenko, A. D. aut Piminov, P. A. aut Karyukina, K. Yu. aut Enthalten in Bulletin of the Russian Academy of Sciences: Physics Pleiades Publishing, 1992 87(2023), 5 vom: Mai, Seite 654-661 (DE-627)131135384 (DE-600)1124898-1 (DE-576)032854463 1062-8738 nnns volume:87 year:2023 number:5 month:05 pages:654-661 https://doi.org/10.3103/S1062873822701805 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-OEU SSG-OLC-HIS AR 87 2023 5 05 654-661 |
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10.3103/S1062873822701805 doi (DE-627)OLC2143924364 (DE-He213)S1062873822701805-p DE-627 ger DE-627 rakwb eng 530 VZ Fedorenko, A. D. verfasserin aut Features of Cl K-edge XANES Spectra of Transition Metal Complexes {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Allerton Press, Inc. 2023. ISSN 1062-8738, Bulletin of the Russian Academy of Sciences: Physics, 2023, Vol. 87, No. 5, pp. 654–661. © Allerton Press, Inc., 2023. Russian Text © The Author(s), 2023, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2023, Vol. 87, No. 5, pp. 738–746. Abstract Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes. Asanov, I. P. aut Asanova, T. I. aut Vasil’chenko, D. B. aut Nikolenko, A. D. aut Piminov, P. A. aut Karyukina, K. Yu. aut Enthalten in Bulletin of the Russian Academy of Sciences: Physics Pleiades Publishing, 1992 87(2023), 5 vom: Mai, Seite 654-661 (DE-627)131135384 (DE-600)1124898-1 (DE-576)032854463 1062-8738 nnns volume:87 year:2023 number:5 month:05 pages:654-661 https://doi.org/10.3103/S1062873822701805 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-OEU SSG-OLC-HIS AR 87 2023 5 05 654-661 |
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features of cl k-edge xanes spectra of transition metal complexes {$ mcl_{6} $}n− (m = rh, pd, re, os, ir, pt) |
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Features of Cl K-edge XANES Spectra of Transition Metal Complexes {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) |
| abstract |
Abstract Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes. © Allerton Press, Inc. 2023. ISSN 1062-8738, Bulletin of the Russian Academy of Sciences: Physics, 2023, Vol. 87, No. 5, pp. 654–661. © Allerton Press, Inc., 2023. Russian Text © The Author(s), 2023, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2023, Vol. 87, No. 5, pp. 738–746. |
| abstractGer |
Abstract Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes. © Allerton Press, Inc. 2023. ISSN 1062-8738, Bulletin of the Russian Academy of Sciences: Physics, 2023, Vol. 87, No. 5, pp. 654–661. © Allerton Press, Inc., 2023. Russian Text © The Author(s), 2023, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2023, Vol. 87, No. 5, pp. 738–746. |
| abstract_unstemmed |
Abstract Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes. © Allerton Press, Inc. 2023. ISSN 1062-8738, Bulletin of the Russian Academy of Sciences: Physics, 2023, Vol. 87, No. 5, pp. 654–661. © Allerton Press, Inc., 2023. Russian Text © The Author(s), 2023, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2023, Vol. 87, No. 5, pp. 738–746. |
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| title_short |
Features of Cl K-edge XANES Spectra of Transition Metal Complexes {$ MCl_{6} $}n− (M = Rh, Pd, Re, Os, Ir, Pt) |
| url |
https://doi.org/10.3103/S1062873822701805 |
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| author2 |
Asanov, I. P. Asanova, T. I. Vasil’chenko, D. B. Nikolenko, A. D. Piminov, P. A. Karyukina, K. Yu |
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Asanov, I. P. Asanova, T. I. Vasil’chenko, D. B. Nikolenko, A. D. Piminov, P. A. Karyukina, K. Yu |
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