Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures
Abstract The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.$ 0^{2.6} $]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.$ 0^{2,6} $.$ 0^{8,10} $]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investiga...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Kazakov, A. I. [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Anmerkung: |
© Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 268–276. |
|---|
| Übergeordnetes Werk: |
Enthalten in: Petroleum chemistry - Pleiades Publishing, 1962, 63(2023), 4 vom: Apr., Seite 468-476 |
|---|---|
| Übergeordnetes Werk: |
volume:63 ; year:2023 ; number:4 ; month:04 ; pages:468-476 |
| Links: |
|---|
| DOI / URN: |
10.1134/S0965544123030118 |
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OLC2145651020 |
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| 520 | |a Abstract The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.$ 0^{2.6} $]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.$ 0^{2,6} $.$ 0^{8,10} $]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified. | ||
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10.1134/S0965544123030118 doi (DE-627)OLC2145651020 (DE-He213)S0965544123030118-p DE-627 ger DE-627 rakwb eng 690 VZ Kazakov, A. I. verfasserin (orcid)0000-0002-3760-7514 aut Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 268–276. Abstract The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.$ 0^{2.6} $]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.$ 0^{2,6} $.$ 0^{8,10} $]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified. Yanovskiy, L. S. (orcid)0000-0002-2603-6795 aut Tomilov, Yu. V. (orcid)0000-0002-3433-7571 aut Molokanov, A. A. (orcid)0000-0001-7913-2732 aut Plishkin, N. A. (orcid)0009-0005-9786-3340 aut Lempert, D. B. (orcid)0000-0002-0219-1571 aut Varlamova, N. I. (orcid)0009-0003-6432-4629 aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 63(2023), 4 vom: Apr., Seite 468-476 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:63 year:2023 number:4 month:04 pages:468-476 https://doi.org/10.1134/S0965544123030118 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC AR 63 2023 4 04 468-476 |
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10.1134/S0965544123030118 doi (DE-627)OLC2145651020 (DE-He213)S0965544123030118-p DE-627 ger DE-627 rakwb eng 690 VZ Kazakov, A. I. verfasserin (orcid)0000-0002-3760-7514 aut Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 268–276. Abstract The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.$ 0^{2.6} $]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.$ 0^{2,6} $.$ 0^{8,10} $]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified. Yanovskiy, L. S. (orcid)0000-0002-2603-6795 aut Tomilov, Yu. V. (orcid)0000-0002-3433-7571 aut Molokanov, A. A. (orcid)0000-0001-7913-2732 aut Plishkin, N. A. (orcid)0009-0005-9786-3340 aut Lempert, D. B. (orcid)0000-0002-0219-1571 aut Varlamova, N. I. (orcid)0009-0003-6432-4629 aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 63(2023), 4 vom: Apr., Seite 468-476 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:63 year:2023 number:4 month:04 pages:468-476 https://doi.org/10.1134/S0965544123030118 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC AR 63 2023 4 04 468-476 |
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10.1134/S0965544123030118 doi (DE-627)OLC2145651020 (DE-He213)S0965544123030118-p DE-627 ger DE-627 rakwb eng 690 VZ Kazakov, A. I. verfasserin (orcid)0000-0002-3760-7514 aut Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 268–276. Abstract The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.$ 0^{2.6} $]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.$ 0^{2,6} $.$ 0^{8,10} $]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified. Yanovskiy, L. S. (orcid)0000-0002-2603-6795 aut Tomilov, Yu. V. (orcid)0000-0002-3433-7571 aut Molokanov, A. A. (orcid)0000-0001-7913-2732 aut Plishkin, N. A. (orcid)0009-0005-9786-3340 aut Lempert, D. B. (orcid)0000-0002-0219-1571 aut Varlamova, N. I. (orcid)0009-0003-6432-4629 aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 63(2023), 4 vom: Apr., Seite 468-476 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:63 year:2023 number:4 month:04 pages:468-476 https://doi.org/10.1134/S0965544123030118 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC AR 63 2023 4 04 468-476 |
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10.1134/S0965544123030118 doi (DE-627)OLC2145651020 (DE-He213)S0965544123030118-p DE-627 ger DE-627 rakwb eng 690 VZ Kazakov, A. I. verfasserin (orcid)0000-0002-3760-7514 aut Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 268–276. Abstract The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.$ 0^{2.6} $]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.$ 0^{2,6} $.$ 0^{8,10} $]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified. Yanovskiy, L. S. (orcid)0000-0002-2603-6795 aut Tomilov, Yu. V. (orcid)0000-0002-3433-7571 aut Molokanov, A. A. (orcid)0000-0001-7913-2732 aut Plishkin, N. A. (orcid)0009-0005-9786-3340 aut Lempert, D. B. (orcid)0000-0002-0219-1571 aut Varlamova, N. I. (orcid)0009-0003-6432-4629 aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 63(2023), 4 vom: Apr., Seite 468-476 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:63 year:2023 number:4 month:04 pages:468-476 https://doi.org/10.1134/S0965544123030118 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC AR 63 2023 4 04 468-476 |
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10.1134/S0965544123030118 doi (DE-627)OLC2145651020 (DE-He213)S0965544123030118-p DE-627 ger DE-627 rakwb eng 690 VZ Kazakov, A. I. verfasserin (orcid)0000-0002-3760-7514 aut Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 268–276. Abstract The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.$ 0^{2.6} $]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.$ 0^{2,6} $.$ 0^{8,10} $]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified. Yanovskiy, L. S. (orcid)0000-0002-2603-6795 aut Tomilov, Yu. V. (orcid)0000-0002-3433-7571 aut Molokanov, A. A. (orcid)0000-0001-7913-2732 aut Plishkin, N. A. (orcid)0009-0005-9786-3340 aut Lempert, D. B. (orcid)0000-0002-0219-1571 aut Varlamova, N. I. (orcid)0009-0003-6432-4629 aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 63(2023), 4 vom: Apr., Seite 468-476 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:63 year:2023 number:4 month:04 pages:468-476 https://doi.org/10.1134/S0965544123030118 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC AR 63 2023 4 04 468-476 |
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690 |
| title_sort |
thermal decomposition of synthetic cage hydrocarbons and their mixtures |
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Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures |
| abstract |
Abstract The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.$ 0^{2.6} $]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.$ 0^{2,6} $.$ 0^{8,10} $]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified. © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 268–276. |
| abstractGer |
Abstract The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.$ 0^{2.6} $]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.$ 0^{2,6} $.$ 0^{8,10} $]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified. © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 268–276. |
| abstract_unstemmed |
Abstract The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.$ 0^{2.6} $]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.$ 0^{2,6} $.$ 0^{8,10} $]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified. © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 268–276. |
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| title_short |
Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures |
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https://doi.org/10.1134/S0965544123030118 |
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| author2 |
Yanovskiy, L. S. Tomilov, Yu. V. Molokanov, A. A. Plishkin, N. A. Lempert, D. B. Varlamova, N. I. |
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Yanovskiy, L. S. Tomilov, Yu. V. Molokanov, A. A. Plishkin, N. A. Lempert, D. B. Varlamova, N. I. |
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2024-07-04T03:55:10.759Z |
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