Effect of Sub- and Supercritical Water on the Transformation of High-Molecular-Mass Components of High-Carbon Rocks from Unconventional Formations (A Review)

Abstract State-of-the-art in the field of recovering high-molecular-mass hydrocarbon components of bituminous and shale rocks by intrastratum transformation into readily recoverable forms using sub- and supercritical water is analyzed. The phase composition of water and its properties in the critica...
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Autor*in:	Nasyrova, Z. R. [verfasserIn] Kayukova, G. P. Kosachev, I. P. Vakhin, A. V.

Format:	Artikel
Sprache:	Englisch

Erschienen:	2023

Anmerkung:	© Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 145–179.

Übergeordnetes Werk:	Enthalten in: Petroleum chemistry - Pleiades Publishing, 1962, 63(2023), 4 vom: Apr., Seite 365-393
Übergeordnetes Werk:	volume:63 ; year:2023 ; number:4 ; month:04 ; pages:365-393

Links:	Volltext

DOI / URN:	10.1134/S0965544123030209

Katalog-ID:	OLC2145651160

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allfields	10.1134/S0965544123030209 doi (DE-627)OLC2145651160 (DE-He213)S0965544123030209-p DE-627 ger DE-627 rakwb eng 690 VZ Nasyrova, Z. R. verfasserin (orcid)0000-0002-1110-9752 aut Effect of Sub- and Supercritical Water on the Transformation of High-Molecular-Mass Components of High-Carbon Rocks from Unconventional Formations (A Review) 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 145–179. Abstract State-of-the-art in the field of recovering high-molecular-mass hydrocarbon components of bituminous and shale rocks by intrastratum transformation into readily recoverable forms using sub- and supercritical water is analyzed. The phase composition of water and its properties in the critical state and the transformations of a number of substances in subcritical (SBW) and supercritical (SCW) water are discussed. The substances under consideration include model polycyclic and heteroatomic compounds containing nitrogen, sulfur, and oxygen, metal porphyrin complexes, asphaltenes, oil sands, and heavy oils and organic matter (OM) of kerogen-containing shale rocks. The preventing effect of hydrogen donors and catalysts for hydrogenation and oxidative cracking on the coking in the course of transformation of heavy hydrocarbons in SCW is compared. The catalytic effect of the mineral matrix of rocks in the course of generation of oil fractions from them is analyzed in detail. The published data concerning the possibility of using SBW and SCW for the transformation of high-molecular-mass components of high-carbon dense rocks from unconventional formations demonstrate high potential of hydrothermal and supercritical fluid technologies. Kayukova, G. P. (orcid)0000-0002-5707-7370 aut Kosachev, I. P. (orcid)0000-0003-2384-3310 aut Vakhin, A. V. (orcid)0000-0002-5168-7063 aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 63(2023), 4 vom: Apr., Seite 365-393 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:63 year:2023 number:4 month:04 pages:365-393 https://doi.org/10.1134/S0965544123030209 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC AR 63 2023 4 04 365-393
spelling	10.1134/S0965544123030209 doi (DE-627)OLC2145651160 (DE-He213)S0965544123030209-p DE-627 ger DE-627 rakwb eng 690 VZ Nasyrova, Z. R. verfasserin (orcid)0000-0002-1110-9752 aut Effect of Sub- and Supercritical Water on the Transformation of High-Molecular-Mass Components of High-Carbon Rocks from Unconventional Formations (A Review) 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 145–179. Abstract State-of-the-art in the field of recovering high-molecular-mass hydrocarbon components of bituminous and shale rocks by intrastratum transformation into readily recoverable forms using sub- and supercritical water is analyzed. The phase composition of water and its properties in the critical state and the transformations of a number of substances in subcritical (SBW) and supercritical (SCW) water are discussed. The substances under consideration include model polycyclic and heteroatomic compounds containing nitrogen, sulfur, and oxygen, metal porphyrin complexes, asphaltenes, oil sands, and heavy oils and organic matter (OM) of kerogen-containing shale rocks. The preventing effect of hydrogen donors and catalysts for hydrogenation and oxidative cracking on the coking in the course of transformation of heavy hydrocarbons in SCW is compared. The catalytic effect of the mineral matrix of rocks in the course of generation of oil fractions from them is analyzed in detail. The published data concerning the possibility of using SBW and SCW for the transformation of high-molecular-mass components of high-carbon dense rocks from unconventional formations demonstrate high potential of hydrothermal and supercritical fluid technologies. Kayukova, G. P. (orcid)0000-0002-5707-7370 aut Kosachev, I. P. (orcid)0000-0003-2384-3310 aut Vakhin, A. V. (orcid)0000-0002-5168-7063 aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 63(2023), 4 vom: Apr., Seite 365-393 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:63 year:2023 number:4 month:04 pages:365-393 https://doi.org/10.1134/S0965544123030209 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC AR 63 2023 4 04 365-393
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allfieldsGer	10.1134/S0965544123030209 doi (DE-627)OLC2145651160 (DE-He213)S0965544123030209-p DE-627 ger DE-627 rakwb eng 690 VZ Nasyrova, Z. R. verfasserin (orcid)0000-0002-1110-9752 aut Effect of Sub- and Supercritical Water on the Transformation of High-Molecular-Mass Components of High-Carbon Rocks from Unconventional Formations (A Review) 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 145–179. Abstract State-of-the-art in the field of recovering high-molecular-mass hydrocarbon components of bituminous and shale rocks by intrastratum transformation into readily recoverable forms using sub- and supercritical water is analyzed. The phase composition of water and its properties in the critical state and the transformations of a number of substances in subcritical (SBW) and supercritical (SCW) water are discussed. The substances under consideration include model polycyclic and heteroatomic compounds containing nitrogen, sulfur, and oxygen, metal porphyrin complexes, asphaltenes, oil sands, and heavy oils and organic matter (OM) of kerogen-containing shale rocks. The preventing effect of hydrogen donors and catalysts for hydrogenation and oxidative cracking on the coking in the course of transformation of heavy hydrocarbons in SCW is compared. The catalytic effect of the mineral matrix of rocks in the course of generation of oil fractions from them is analyzed in detail. The published data concerning the possibility of using SBW and SCW for the transformation of high-molecular-mass components of high-carbon dense rocks from unconventional formations demonstrate high potential of hydrothermal and supercritical fluid technologies. Kayukova, G. P. (orcid)0000-0002-5707-7370 aut Kosachev, I. P. (orcid)0000-0003-2384-3310 aut Vakhin, A. V. (orcid)0000-0002-5168-7063 aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 63(2023), 4 vom: Apr., Seite 365-393 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:63 year:2023 number:4 month:04 pages:365-393 https://doi.org/10.1134/S0965544123030209 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC AR 63 2023 4 04 365-393
allfieldsSound	10.1134/S0965544123030209 doi (DE-627)OLC2145651160 (DE-He213)S0965544123030209-p DE-627 ger DE-627 rakwb eng 690 VZ Nasyrova, Z. R. verfasserin (orcid)0000-0002-1110-9752 aut Effect of Sub- and Supercritical Water on the Transformation of High-Molecular-Mass Components of High-Carbon Rocks from Unconventional Formations (A Review) 2023 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 145–179. Abstract State-of-the-art in the field of recovering high-molecular-mass hydrocarbon components of bituminous and shale rocks by intrastratum transformation into readily recoverable forms using sub- and supercritical water is analyzed. The phase composition of water and its properties in the critical state and the transformations of a number of substances in subcritical (SBW) and supercritical (SCW) water are discussed. The substances under consideration include model polycyclic and heteroatomic compounds containing nitrogen, sulfur, and oxygen, metal porphyrin complexes, asphaltenes, oil sands, and heavy oils and organic matter (OM) of kerogen-containing shale rocks. The preventing effect of hydrogen donors and catalysts for hydrogenation and oxidative cracking on the coking in the course of transformation of heavy hydrocarbons in SCW is compared. The catalytic effect of the mineral matrix of rocks in the course of generation of oil fractions from them is analyzed in detail. The published data concerning the possibility of using SBW and SCW for the transformation of high-molecular-mass components of high-carbon dense rocks from unconventional formations demonstrate high potential of hydrothermal and supercritical fluid technologies. Kayukova, G. P. (orcid)0000-0002-5707-7370 aut Kosachev, I. P. (orcid)0000-0003-2384-3310 aut Vakhin, A. V. (orcid)0000-0002-5168-7063 aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 63(2023), 4 vom: Apr., Seite 365-393 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:63 year:2023 number:4 month:04 pages:365-393 https://doi.org/10.1134/S0965544123030209 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC AR 63 2023 4 04 365-393
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title_sort	effect of sub- and supercritical water on the transformation of high-molecular-mass components of high-carbon rocks from unconventional formations (a review)
title_auth	Effect of Sub- and Supercritical Water on the Transformation of High-Molecular-Mass Components of High-Carbon Rocks from Unconventional Formations (A Review)
abstract	Abstract State-of-the-art in the field of recovering high-molecular-mass hydrocarbon components of bituminous and shale rocks by intrastratum transformation into readily recoverable forms using sub- and supercritical water is analyzed. The phase composition of water and its properties in the critical state and the transformations of a number of substances in subcritical (SBW) and supercritical (SCW) water are discussed. The substances under consideration include model polycyclic and heteroatomic compounds containing nitrogen, sulfur, and oxygen, metal porphyrin complexes, asphaltenes, oil sands, and heavy oils and organic matter (OM) of kerogen-containing shale rocks. The preventing effect of hydrogen donors and catalysts for hydrogenation and oxidative cracking on the coking in the course of transformation of heavy hydrocarbons in SCW is compared. The catalytic effect of the mineral matrix of rocks in the course of generation of oil fractions from them is analyzed in detail. The published data concerning the possibility of using SBW and SCW for the transformation of high-molecular-mass components of high-carbon dense rocks from unconventional formations demonstrate high potential of hydrothermal and supercritical fluid technologies. © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 145–179.
abstractGer	Abstract State-of-the-art in the field of recovering high-molecular-mass hydrocarbon components of bituminous and shale rocks by intrastratum transformation into readily recoverable forms using sub- and supercritical water is analyzed. The phase composition of water and its properties in the critical state and the transformations of a number of substances in subcritical (SBW) and supercritical (SCW) water are discussed. The substances under consideration include model polycyclic and heteroatomic compounds containing nitrogen, sulfur, and oxygen, metal porphyrin complexes, asphaltenes, oil sands, and heavy oils and organic matter (OM) of kerogen-containing shale rocks. The preventing effect of hydrogen donors and catalysts for hydrogenation and oxidative cracking on the coking in the course of transformation of heavy hydrocarbons in SCW is compared. The catalytic effect of the mineral matrix of rocks in the course of generation of oil fractions from them is analyzed in detail. The published data concerning the possibility of using SBW and SCW for the transformation of high-molecular-mass components of high-carbon dense rocks from unconventional formations demonstrate high potential of hydrothermal and supercritical fluid technologies. © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 145–179.
abstract_unstemmed	Abstract State-of-the-art in the field of recovering high-molecular-mass hydrocarbon components of bituminous and shale rocks by intrastratum transformation into readily recoverable forms using sub- and supercritical water is analyzed. The phase composition of water and its properties in the critical state and the transformations of a number of substances in subcritical (SBW) and supercritical (SCW) water are discussed. The substances under consideration include model polycyclic and heteroatomic compounds containing nitrogen, sulfur, and oxygen, metal porphyrin complexes, asphaltenes, oil sands, and heavy oils and organic matter (OM) of kerogen-containing shale rocks. The preventing effect of hydrogen donors and catalysts for hydrogenation and oxidative cracking on the coking in the course of transformation of heavy hydrocarbons in SCW is compared. The catalytic effect of the mineral matrix of rocks in the course of generation of oil fractions from them is analyzed in detail. The published data concerning the possibility of using SBW and SCW for the transformation of high-molecular-mass components of high-carbon dense rocks from unconventional formations demonstrate high potential of hydrothermal and supercritical fluid technologies. © Pleiades Publishing, Ltd. 2023. Russian Text © The Author(s), 2023, published in Neftekhimiya, 2023, Vol. 63, No. 2, pp. 145–179.
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title_short	Effect of Sub- and Supercritical Water on the Transformation of High-Molecular-Mass Components of High-Carbon Rocks from Unconventional Formations (A Review)
url	https://doi.org/10.1134/S0965544123030209
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author2	Kayukova, G. P. Kosachev, I. P. Vakhin, A. V.
author2Str	Kayukova, G. P. Kosachev, I. P. Vakhin, A. V.
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doi_str	10.1134/S0965544123030209
up_date	2024-07-04T03:55:12.336Z
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