Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry
Abstract An analytical strategy based on a hybrid quadrupole-Orbitrap mass spectrometry was proposed for the simultaneous screening of known destruxins and characterization of potential members of this class of secondary metabolites, in order to evaluate the metabolite production of entomopathogenic...
Ausführliche Beschreibung
Autor*in: |
Arroyo-Manzanares, Natalia [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2017 |
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Schlagwörter: |
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Anmerkung: |
© Springer-Verlag Berlin Heidelberg 2017 |
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Übergeordnetes Werk: |
Enthalten in: Analytical and bioanalytical chemistry - Berlin : Springer, 2002, 409(2017), 13 vom: 09. März, Seite 3347-3357 |
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Übergeordnetes Werk: |
volume:409 ; year:2017 ; number:13 ; day:09 ; month:03 ; pages:3347-3357 |
Links: |
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DOI / URN: |
10.1007/s00216-017-0276-z |
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Katalog-ID: |
SPR002252880 |
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100 | 1 | |a Arroyo-Manzanares, Natalia |e verfasserin |4 aut | |
245 | 1 | 0 | |a Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry |
264 | 1 | |c 2017 | |
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520 | |a Abstract An analytical strategy based on a hybrid quadrupole-Orbitrap mass spectrometry was proposed for the simultaneous screening of known destruxins and characterization of potential members of this class of secondary metabolites, in order to evaluate the metabolite production of entomopathogenic fungi used as biocontrol agents. Initially, the fragmentation pathway of the known and commercially available destruxin A was established combining high resolution mass spectrometry (HRMS) and multiple stage MS data in order to obtain the strategy for the characterization of other destruxins for which reference standards were not available. Nineteen known destruxins including A, B, C, D, Ed, F, $ A_{1} $, $ B_{1} $, $ Ed_{1} $, $ A_{2} $, $ B_{2} $, $ D_{2} $, $ A_{3} $, DesmA, DesmB, DesmC, $ DesmB_{2} $, and two chloro-derivatives (Cl and $ E_{2} $ chlorohydrin) were unequivocally identified in Metarhizium brunneum using the proposed strategy. In addition, four unknown destruxins, namely $ C_{1} $, $ Ed_{2} $, G, and $ G_{1} $, were structurally elucidated and characterized for the first time in this fungal strain. | ||
650 | 4 | |a Destruxins identification |7 (dpeaa)DE-He213 | |
650 | 4 | |a Untargeted analysis |7 (dpeaa)DE-He213 | |
650 | 4 | |a Hybrid quadrupole-Orbitrap |7 (dpeaa)DE-He213 | |
650 | 4 | |a Fragmentation pathway |7 (dpeaa)DE-He213 | |
700 | 1 | |a Diana Di Mavungu, José |4 aut | |
700 | 1 | |a Garrido-Jurado, Inmaculada |4 aut | |
700 | 1 | |a Arce, Lourdes |4 aut | |
700 | 1 | |a Vanhaecke, Lynn |4 aut | |
700 | 1 | |a Quesada-Moraga, Enrique |4 aut | |
700 | 1 | |a De Saeger, Sarah |4 aut | |
773 | 0 | 8 | |i Enthalten in |t Analytical and bioanalytical chemistry |d Berlin : Springer, 2002 |g 409(2017), 13 vom: 09. März, Seite 3347-3357 |w (DE-627)25372337X |w (DE-600)1459122-4 |x 1618-2650 |7 nnns |
773 | 1 | 8 | |g volume:409 |g year:2017 |g number:13 |g day:09 |g month:03 |g pages:3347-3357 |
856 | 4 | 0 | |u https://dx.doi.org/10.1007/s00216-017-0276-z |z lizenzpflichtig |3 Volltext |
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912 | |a GBV_ILN_2122 | ||
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912 | |a GBV_ILN_2148 | ||
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912 | |a GBV_ILN_2232 | ||
912 | |a GBV_ILN_2336 | ||
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10.1007/s00216-017-0276-z doi (DE-627)SPR002252880 (SPR)s00216-017-0276-z-e DE-627 ger DE-627 rakwb eng Arroyo-Manzanares, Natalia verfasserin aut Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2017 Abstract An analytical strategy based on a hybrid quadrupole-Orbitrap mass spectrometry was proposed for the simultaneous screening of known destruxins and characterization of potential members of this class of secondary metabolites, in order to evaluate the metabolite production of entomopathogenic fungi used as biocontrol agents. Initially, the fragmentation pathway of the known and commercially available destruxin A was established combining high resolution mass spectrometry (HRMS) and multiple stage MS data in order to obtain the strategy for the characterization of other destruxins for which reference standards were not available. Nineteen known destruxins including A, B, C, D, Ed, F, $ A_{1} $, $ B_{1} $, $ Ed_{1} $, $ A_{2} $, $ B_{2} $, $ D_{2} $, $ A_{3} $, DesmA, DesmB, DesmC, $ DesmB_{2} $, and two chloro-derivatives (Cl and $ E_{2} $ chlorohydrin) were unequivocally identified in Metarhizium brunneum using the proposed strategy. In addition, four unknown destruxins, namely $ C_{1} $, $ Ed_{2} $, G, and $ G_{1} $, were structurally elucidated and characterized for the first time in this fungal strain. Destruxins identification (dpeaa)DE-He213 Untargeted analysis (dpeaa)DE-He213 Hybrid quadrupole-Orbitrap (dpeaa)DE-He213 Fragmentation pathway (dpeaa)DE-He213 Diana Di Mavungu, José aut Garrido-Jurado, Inmaculada aut Arce, Lourdes aut Vanhaecke, Lynn aut Quesada-Moraga, Enrique aut De Saeger, Sarah aut Enthalten in Analytical and bioanalytical chemistry Berlin : Springer, 2002 409(2017), 13 vom: 09. März, Seite 3347-3357 (DE-627)25372337X (DE-600)1459122-4 1618-2650 nnns volume:409 year:2017 number:13 day:09 month:03 pages:3347-3357 https://dx.doi.org/10.1007/s00216-017-0276-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 409 2017 13 09 03 3347-3357 |
spelling |
10.1007/s00216-017-0276-z doi (DE-627)SPR002252880 (SPR)s00216-017-0276-z-e DE-627 ger DE-627 rakwb eng Arroyo-Manzanares, Natalia verfasserin aut Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2017 Abstract An analytical strategy based on a hybrid quadrupole-Orbitrap mass spectrometry was proposed for the simultaneous screening of known destruxins and characterization of potential members of this class of secondary metabolites, in order to evaluate the metabolite production of entomopathogenic fungi used as biocontrol agents. Initially, the fragmentation pathway of the known and commercially available destruxin A was established combining high resolution mass spectrometry (HRMS) and multiple stage MS data in order to obtain the strategy for the characterization of other destruxins for which reference standards were not available. Nineteen known destruxins including A, B, C, D, Ed, F, $ A_{1} $, $ B_{1} $, $ Ed_{1} $, $ A_{2} $, $ B_{2} $, $ D_{2} $, $ A_{3} $, DesmA, DesmB, DesmC, $ DesmB_{2} $, and two chloro-derivatives (Cl and $ E_{2} $ chlorohydrin) were unequivocally identified in Metarhizium brunneum using the proposed strategy. In addition, four unknown destruxins, namely $ C_{1} $, $ Ed_{2} $, G, and $ G_{1} $, were structurally elucidated and characterized for the first time in this fungal strain. Destruxins identification (dpeaa)DE-He213 Untargeted analysis (dpeaa)DE-He213 Hybrid quadrupole-Orbitrap (dpeaa)DE-He213 Fragmentation pathway (dpeaa)DE-He213 Diana Di Mavungu, José aut Garrido-Jurado, Inmaculada aut Arce, Lourdes aut Vanhaecke, Lynn aut Quesada-Moraga, Enrique aut De Saeger, Sarah aut Enthalten in Analytical and bioanalytical chemistry Berlin : Springer, 2002 409(2017), 13 vom: 09. März, Seite 3347-3357 (DE-627)25372337X (DE-600)1459122-4 1618-2650 nnns volume:409 year:2017 number:13 day:09 month:03 pages:3347-3357 https://dx.doi.org/10.1007/s00216-017-0276-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 409 2017 13 09 03 3347-3357 |
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10.1007/s00216-017-0276-z doi (DE-627)SPR002252880 (SPR)s00216-017-0276-z-e DE-627 ger DE-627 rakwb eng Arroyo-Manzanares, Natalia verfasserin aut Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2017 Abstract An analytical strategy based on a hybrid quadrupole-Orbitrap mass spectrometry was proposed for the simultaneous screening of known destruxins and characterization of potential members of this class of secondary metabolites, in order to evaluate the metabolite production of entomopathogenic fungi used as biocontrol agents. Initially, the fragmentation pathway of the known and commercially available destruxin A was established combining high resolution mass spectrometry (HRMS) and multiple stage MS data in order to obtain the strategy for the characterization of other destruxins for which reference standards were not available. Nineteen known destruxins including A, B, C, D, Ed, F, $ A_{1} $, $ B_{1} $, $ Ed_{1} $, $ A_{2} $, $ B_{2} $, $ D_{2} $, $ A_{3} $, DesmA, DesmB, DesmC, $ DesmB_{2} $, and two chloro-derivatives (Cl and $ E_{2} $ chlorohydrin) were unequivocally identified in Metarhizium brunneum using the proposed strategy. In addition, four unknown destruxins, namely $ C_{1} $, $ Ed_{2} $, G, and $ G_{1} $, were structurally elucidated and characterized for the first time in this fungal strain. Destruxins identification (dpeaa)DE-He213 Untargeted analysis (dpeaa)DE-He213 Hybrid quadrupole-Orbitrap (dpeaa)DE-He213 Fragmentation pathway (dpeaa)DE-He213 Diana Di Mavungu, José aut Garrido-Jurado, Inmaculada aut Arce, Lourdes aut Vanhaecke, Lynn aut Quesada-Moraga, Enrique aut De Saeger, Sarah aut Enthalten in Analytical and bioanalytical chemistry Berlin : Springer, 2002 409(2017), 13 vom: 09. März, Seite 3347-3357 (DE-627)25372337X (DE-600)1459122-4 1618-2650 nnns volume:409 year:2017 number:13 day:09 month:03 pages:3347-3357 https://dx.doi.org/10.1007/s00216-017-0276-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 409 2017 13 09 03 3347-3357 |
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10.1007/s00216-017-0276-z doi (DE-627)SPR002252880 (SPR)s00216-017-0276-z-e DE-627 ger DE-627 rakwb eng Arroyo-Manzanares, Natalia verfasserin aut Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2017 Abstract An analytical strategy based on a hybrid quadrupole-Orbitrap mass spectrometry was proposed for the simultaneous screening of known destruxins and characterization of potential members of this class of secondary metabolites, in order to evaluate the metabolite production of entomopathogenic fungi used as biocontrol agents. Initially, the fragmentation pathway of the known and commercially available destruxin A was established combining high resolution mass spectrometry (HRMS) and multiple stage MS data in order to obtain the strategy for the characterization of other destruxins for which reference standards were not available. Nineteen known destruxins including A, B, C, D, Ed, F, $ A_{1} $, $ B_{1} $, $ Ed_{1} $, $ A_{2} $, $ B_{2} $, $ D_{2} $, $ A_{3} $, DesmA, DesmB, DesmC, $ DesmB_{2} $, and two chloro-derivatives (Cl and $ E_{2} $ chlorohydrin) were unequivocally identified in Metarhizium brunneum using the proposed strategy. In addition, four unknown destruxins, namely $ C_{1} $, $ Ed_{2} $, G, and $ G_{1} $, were structurally elucidated and characterized for the first time in this fungal strain. Destruxins identification (dpeaa)DE-He213 Untargeted analysis (dpeaa)DE-He213 Hybrid quadrupole-Orbitrap (dpeaa)DE-He213 Fragmentation pathway (dpeaa)DE-He213 Diana Di Mavungu, José aut Garrido-Jurado, Inmaculada aut Arce, Lourdes aut Vanhaecke, Lynn aut Quesada-Moraga, Enrique aut De Saeger, Sarah aut Enthalten in Analytical and bioanalytical chemistry Berlin : Springer, 2002 409(2017), 13 vom: 09. März, Seite 3347-3357 (DE-627)25372337X (DE-600)1459122-4 1618-2650 nnns volume:409 year:2017 number:13 day:09 month:03 pages:3347-3357 https://dx.doi.org/10.1007/s00216-017-0276-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 409 2017 13 09 03 3347-3357 |
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10.1007/s00216-017-0276-z doi (DE-627)SPR002252880 (SPR)s00216-017-0276-z-e DE-627 ger DE-627 rakwb eng Arroyo-Manzanares, Natalia verfasserin aut Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2017 Abstract An analytical strategy based on a hybrid quadrupole-Orbitrap mass spectrometry was proposed for the simultaneous screening of known destruxins and characterization of potential members of this class of secondary metabolites, in order to evaluate the metabolite production of entomopathogenic fungi used as biocontrol agents. Initially, the fragmentation pathway of the known and commercially available destruxin A was established combining high resolution mass spectrometry (HRMS) and multiple stage MS data in order to obtain the strategy for the characterization of other destruxins for which reference standards were not available. Nineteen known destruxins including A, B, C, D, Ed, F, $ A_{1} $, $ B_{1} $, $ Ed_{1} $, $ A_{2} $, $ B_{2} $, $ D_{2} $, $ A_{3} $, DesmA, DesmB, DesmC, $ DesmB_{2} $, and two chloro-derivatives (Cl and $ E_{2} $ chlorohydrin) were unequivocally identified in Metarhizium brunneum using the proposed strategy. In addition, four unknown destruxins, namely $ C_{1} $, $ Ed_{2} $, G, and $ G_{1} $, were structurally elucidated and characterized for the first time in this fungal strain. Destruxins identification (dpeaa)DE-He213 Untargeted analysis (dpeaa)DE-He213 Hybrid quadrupole-Orbitrap (dpeaa)DE-He213 Fragmentation pathway (dpeaa)DE-He213 Diana Di Mavungu, José aut Garrido-Jurado, Inmaculada aut Arce, Lourdes aut Vanhaecke, Lynn aut Quesada-Moraga, Enrique aut De Saeger, Sarah aut Enthalten in Analytical and bioanalytical chemistry Berlin : Springer, 2002 409(2017), 13 vom: 09. März, Seite 3347-3357 (DE-627)25372337X (DE-600)1459122-4 1618-2650 nnns volume:409 year:2017 number:13 day:09 month:03 pages:3347-3357 https://dx.doi.org/10.1007/s00216-017-0276-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 409 2017 13 09 03 3347-3357 |
language |
English |
source |
Enthalten in Analytical and bioanalytical chemistry 409(2017), 13 vom: 09. März, Seite 3347-3357 volume:409 year:2017 number:13 day:09 month:03 pages:3347-3357 |
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Enthalten in Analytical and bioanalytical chemistry 409(2017), 13 vom: 09. März, Seite 3347-3357 volume:409 year:2017 number:13 day:09 month:03 pages:3347-3357 |
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Article |
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topic_facet |
Destruxins identification Untargeted analysis Hybrid quadrupole-Orbitrap Fragmentation pathway |
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container_title |
Analytical and bioanalytical chemistry |
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Arroyo-Manzanares, Natalia @@aut@@ Diana Di Mavungu, José @@aut@@ Garrido-Jurado, Inmaculada @@aut@@ Arce, Lourdes @@aut@@ Vanhaecke, Lynn @@aut@@ Quesada-Moraga, Enrique @@aut@@ De Saeger, Sarah @@aut@@ |
publishDateDaySort_date |
2017-03-09T00:00:00Z |
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Initially, the fragmentation pathway of the known and commercially available destruxin A was established combining high resolution mass spectrometry (HRMS) and multiple stage MS data in order to obtain the strategy for the characterization of other destruxins for which reference standards were not available. Nineteen known destruxins including A, B, C, D, Ed, F, $ A_{1} $, $ B_{1} $, $ Ed_{1} $, $ A_{2} $, $ B_{2} $, $ D_{2} $, $ A_{3} $, DesmA, DesmB, DesmC, $ DesmB_{2} $, and two chloro-derivatives (Cl and $ E_{2} $ chlorohydrin) were unequivocally identified in Metarhizium brunneum using the proposed strategy. In addition, four unknown destruxins, namely $ C_{1} $, $ Ed_{2} $, G, and $ G_{1} $, were structurally elucidated and characterized for the first time in this fungal strain.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Destruxins identification</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Untargeted analysis</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hybrid quadrupole-Orbitrap</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fragmentation pathway</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Diana Di Mavungu, José</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Garrido-Jurado, Inmaculada</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Arce, Lourdes</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Vanhaecke, Lynn</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Quesada-Moraga, Enrique</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">De Saeger, Sarah</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Analytical and bioanalytical chemistry</subfield><subfield code="d">Berlin : Springer, 2002</subfield><subfield code="g">409(2017), 13 vom: 09. 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Arroyo-Manzanares, Natalia |
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Arroyo-Manzanares, Natalia misc Destruxins identification misc Untargeted analysis misc Hybrid quadrupole-Orbitrap misc Fragmentation pathway Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry |
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Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry Destruxins identification (dpeaa)DE-He213 Untargeted analysis (dpeaa)DE-He213 Hybrid quadrupole-Orbitrap (dpeaa)DE-He213 Fragmentation pathway (dpeaa)DE-He213 |
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Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry |
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Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry |
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Arroyo-Manzanares, Natalia |
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Arroyo-Manzanares, Natalia Diana Di Mavungu, José Garrido-Jurado, Inmaculada Arce, Lourdes Vanhaecke, Lynn Quesada-Moraga, Enrique De Saeger, Sarah |
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title_sort |
analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-orbitrap high-resolution mass spectrometry |
title_auth |
Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry |
abstract |
Abstract An analytical strategy based on a hybrid quadrupole-Orbitrap mass spectrometry was proposed for the simultaneous screening of known destruxins and characterization of potential members of this class of secondary metabolites, in order to evaluate the metabolite production of entomopathogenic fungi used as biocontrol agents. Initially, the fragmentation pathway of the known and commercially available destruxin A was established combining high resolution mass spectrometry (HRMS) and multiple stage MS data in order to obtain the strategy for the characterization of other destruxins for which reference standards were not available. Nineteen known destruxins including A, B, C, D, Ed, F, $ A_{1} $, $ B_{1} $, $ Ed_{1} $, $ A_{2} $, $ B_{2} $, $ D_{2} $, $ A_{3} $, DesmA, DesmB, DesmC, $ DesmB_{2} $, and two chloro-derivatives (Cl and $ E_{2} $ chlorohydrin) were unequivocally identified in Metarhizium brunneum using the proposed strategy. In addition, four unknown destruxins, namely $ C_{1} $, $ Ed_{2} $, G, and $ G_{1} $, were structurally elucidated and characterized for the first time in this fungal strain. © Springer-Verlag Berlin Heidelberg 2017 |
abstractGer |
Abstract An analytical strategy based on a hybrid quadrupole-Orbitrap mass spectrometry was proposed for the simultaneous screening of known destruxins and characterization of potential members of this class of secondary metabolites, in order to evaluate the metabolite production of entomopathogenic fungi used as biocontrol agents. Initially, the fragmentation pathway of the known and commercially available destruxin A was established combining high resolution mass spectrometry (HRMS) and multiple stage MS data in order to obtain the strategy for the characterization of other destruxins for which reference standards were not available. Nineteen known destruxins including A, B, C, D, Ed, F, $ A_{1} $, $ B_{1} $, $ Ed_{1} $, $ A_{2} $, $ B_{2} $, $ D_{2} $, $ A_{3} $, DesmA, DesmB, DesmC, $ DesmB_{2} $, and two chloro-derivatives (Cl and $ E_{2} $ chlorohydrin) were unequivocally identified in Metarhizium brunneum using the proposed strategy. In addition, four unknown destruxins, namely $ C_{1} $, $ Ed_{2} $, G, and $ G_{1} $, were structurally elucidated and characterized for the first time in this fungal strain. © Springer-Verlag Berlin Heidelberg 2017 |
abstract_unstemmed |
Abstract An analytical strategy based on a hybrid quadrupole-Orbitrap mass spectrometry was proposed for the simultaneous screening of known destruxins and characterization of potential members of this class of secondary metabolites, in order to evaluate the metabolite production of entomopathogenic fungi used as biocontrol agents. Initially, the fragmentation pathway of the known and commercially available destruxin A was established combining high resolution mass spectrometry (HRMS) and multiple stage MS data in order to obtain the strategy for the characterization of other destruxins for which reference standards were not available. Nineteen known destruxins including A, B, C, D, Ed, F, $ A_{1} $, $ B_{1} $, $ Ed_{1} $, $ A_{2} $, $ B_{2} $, $ D_{2} $, $ A_{3} $, DesmA, DesmB, DesmC, $ DesmB_{2} $, and two chloro-derivatives (Cl and $ E_{2} $ chlorohydrin) were unequivocally identified in Metarhizium brunneum using the proposed strategy. In addition, four unknown destruxins, namely $ C_{1} $, $ Ed_{2} $, G, and $ G_{1} $, were structurally elucidated and characterized for the first time in this fungal strain. © Springer-Verlag Berlin Heidelberg 2017 |
collection_details |
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container_issue |
13 |
title_short |
Analytical strategy for determination of known and unknown destruxins using hybrid quadrupole-Orbitrap high-resolution mass spectrometry |
url |
https://dx.doi.org/10.1007/s00216-017-0276-z |
remote_bool |
true |
author2 |
Diana Di Mavungu, José Garrido-Jurado, Inmaculada Arce, Lourdes Vanhaecke, Lynn Quesada-Moraga, Enrique De Saeger, Sarah |
author2Str |
Diana Di Mavungu, José Garrido-Jurado, Inmaculada Arce, Lourdes Vanhaecke, Lynn Quesada-Moraga, Enrique De Saeger, Sarah |
ppnlink |
25372337X |
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hochschulschrift_bool |
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doi_str |
10.1007/s00216-017-0276-z |
up_date |
2024-07-04T02:22:27.168Z |
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score |
7.3996477 |