Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging
Abstract Metal organic chemical vapor deposition grown films consisting of $ Mg_{x} %$ Zn_{1-x} $O (4% < x < 5%) nanorod arrays ($ MgZnO_{nano} $) were functionalized with 11-azidoundecanoic acid (1). The $ MgZnO_{nano} $ was used instead of pure ZnO to take advantage of the etching resistance...
Ausführliche Beschreibung
Autor*in: |
Chen, Yuan [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2017 |
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Anmerkung: |
© Springer-Verlag GmbH Germany 2017 |
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Übergeordnetes Werk: |
Enthalten in: Analytical and bioanalytical chemistry - Berlin : Springer, 2002, 409(2017), 27 vom: 24. Aug., Seite 6379-6386 |
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Übergeordnetes Werk: |
volume:409 ; year:2017 ; number:27 ; day:24 ; month:08 ; pages:6379-6386 |
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DOI / URN: |
10.1007/s00216-017-0577-2 |
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Katalog-ID: |
SPR002256029 |
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520 | |a Abstract Metal organic chemical vapor deposition grown films consisting of $ Mg_{x} %$ Zn_{1-x} $O (4% < x < 5%) nanorod arrays ($ MgZnO_{nano} $) were functionalized with 11-azidoundecanoic acid (1). The $ MgZnO_{nano} $ was used instead of pure ZnO to take advantage of the etching resistance of the $ MgZnO_{nano} $ during the binding and subsequent sensing device fabrication processes of sensor devices, while the low Mg composition level ensures that selected ZnO properties useful for sensors development, such as piezoelectricity, are retained. Compound 1 was bound to the $ MgZnO_{nano} $ surface through the carboxylic acid group, leaving the azido group available for click chemistry and as a convenient infrared spectroscopy (IR) probe. The progress of the functionalization with 1 was characterized by FTIR microscopic imaging as a function of binding time, solvents employed, and $ MgZnO_{nano} $ morphology. Binding of 1 was most stable in solutions of 3-methoxypropionitrile (MPN), a non-protic polar solvent. This occurred first in μm-scale islands, then expanded to form a rather uniform layer after 22 h. Binding in alcohols resulted in less homogenous coverage, but the 1/$ MgZnO_{nano} $ films prepared from MPN were stable upon treatment with alcohols at room temperature. The binding behavior was significantly dependent on the surface morphology of $ MgZnO_{nano} $. Graphical abstractThe functionalization of MgZnO nanorod films with a click-ready linker and its dependence on bidning conditions and morphology has been studied by FTIR microscopic imaging using the azido group as the IR tag | ||
650 | 4 | |a Zinc oxide |7 (dpeaa)DE-He213 | |
650 | 4 | |a Magnesium zinc oxide |7 (dpeaa)DE-He213 | |
650 | 4 | |a Surface functionalization |7 (dpeaa)DE-He213 | |
650 | 4 | |a FTIR microscopic imaging |7 (dpeaa)DE-He213 | |
700 | 1 | |a Zhang, Qihong |4 aut | |
700 | 1 | |a Flach, Carol |4 aut | |
700 | 1 | |a Mendelsohn, Richard |4 aut | |
700 | 1 | |a Galoppini, Elena |4 aut | |
700 | 1 | |a Reyes, Pavel Ivanoff |4 aut | |
700 | 1 | |a Yang, Keyang |4 aut | |
700 | 1 | |a Li, Rui |4 aut | |
700 | 1 | |a Li, Guangyuan |4 aut | |
700 | 1 | |a Lu, Yicheng |4 aut | |
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10.1007/s00216-017-0577-2 doi (DE-627)SPR002256029 (SPR)s00216-017-0577-2-e DE-627 ger DE-627 rakwb eng Chen, Yuan verfasserin aut Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag GmbH Germany 2017 Abstract Metal organic chemical vapor deposition grown films consisting of $ Mg_{x} %$ Zn_{1-x} $O (4% < x < 5%) nanorod arrays ($ MgZnO_{nano} $) were functionalized with 11-azidoundecanoic acid (1). The $ MgZnO_{nano} $ was used instead of pure ZnO to take advantage of the etching resistance of the $ MgZnO_{nano} $ during the binding and subsequent sensing device fabrication processes of sensor devices, while the low Mg composition level ensures that selected ZnO properties useful for sensors development, such as piezoelectricity, are retained. Compound 1 was bound to the $ MgZnO_{nano} $ surface through the carboxylic acid group, leaving the azido group available for click chemistry and as a convenient infrared spectroscopy (IR) probe. The progress of the functionalization with 1 was characterized by FTIR microscopic imaging as a function of binding time, solvents employed, and $ MgZnO_{nano} $ morphology. Binding of 1 was most stable in solutions of 3-methoxypropionitrile (MPN), a non-protic polar solvent. This occurred first in μm-scale islands, then expanded to form a rather uniform layer after 22 h. Binding in alcohols resulted in less homogenous coverage, but the 1/$ MgZnO_{nano} $ films prepared from MPN were stable upon treatment with alcohols at room temperature. The binding behavior was significantly dependent on the surface morphology of $ MgZnO_{nano} $. Graphical abstractThe functionalization of MgZnO nanorod films with a click-ready linker and its dependence on bidning conditions and morphology has been studied by FTIR microscopic imaging using the azido group as the IR tag Zinc oxide (dpeaa)DE-He213 Magnesium zinc oxide (dpeaa)DE-He213 Surface functionalization (dpeaa)DE-He213 FTIR microscopic imaging (dpeaa)DE-He213 Zhang, Qihong aut Flach, Carol aut Mendelsohn, Richard aut Galoppini, Elena aut Reyes, Pavel Ivanoff aut Yang, Keyang aut Li, Rui aut Li, Guangyuan aut Lu, Yicheng aut Enthalten in Analytical and bioanalytical chemistry Berlin : Springer, 2002 409(2017), 27 vom: 24. Aug., Seite 6379-6386 (DE-627)25372337X (DE-600)1459122-4 1618-2650 nnns volume:409 year:2017 number:27 day:24 month:08 pages:6379-6386 https://dx.doi.org/10.1007/s00216-017-0577-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 409 2017 27 24 08 6379-6386 |
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10.1007/s00216-017-0577-2 doi (DE-627)SPR002256029 (SPR)s00216-017-0577-2-e DE-627 ger DE-627 rakwb eng Chen, Yuan verfasserin aut Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag GmbH Germany 2017 Abstract Metal organic chemical vapor deposition grown films consisting of $ Mg_{x} %$ Zn_{1-x} $O (4% < x < 5%) nanorod arrays ($ MgZnO_{nano} $) were functionalized with 11-azidoundecanoic acid (1). The $ MgZnO_{nano} $ was used instead of pure ZnO to take advantage of the etching resistance of the $ MgZnO_{nano} $ during the binding and subsequent sensing device fabrication processes of sensor devices, while the low Mg composition level ensures that selected ZnO properties useful for sensors development, such as piezoelectricity, are retained. Compound 1 was bound to the $ MgZnO_{nano} $ surface through the carboxylic acid group, leaving the azido group available for click chemistry and as a convenient infrared spectroscopy (IR) probe. The progress of the functionalization with 1 was characterized by FTIR microscopic imaging as a function of binding time, solvents employed, and $ MgZnO_{nano} $ morphology. Binding of 1 was most stable in solutions of 3-methoxypropionitrile (MPN), a non-protic polar solvent. This occurred first in μm-scale islands, then expanded to form a rather uniform layer after 22 h. Binding in alcohols resulted in less homogenous coverage, but the 1/$ MgZnO_{nano} $ films prepared from MPN were stable upon treatment with alcohols at room temperature. The binding behavior was significantly dependent on the surface morphology of $ MgZnO_{nano} $. Graphical abstractThe functionalization of MgZnO nanorod films with a click-ready linker and its dependence on bidning conditions and morphology has been studied by FTIR microscopic imaging using the azido group as the IR tag Zinc oxide (dpeaa)DE-He213 Magnesium zinc oxide (dpeaa)DE-He213 Surface functionalization (dpeaa)DE-He213 FTIR microscopic imaging (dpeaa)DE-He213 Zhang, Qihong aut Flach, Carol aut Mendelsohn, Richard aut Galoppini, Elena aut Reyes, Pavel Ivanoff aut Yang, Keyang aut Li, Rui aut Li, Guangyuan aut Lu, Yicheng aut Enthalten in Analytical and bioanalytical chemistry Berlin : Springer, 2002 409(2017), 27 vom: 24. Aug., Seite 6379-6386 (DE-627)25372337X (DE-600)1459122-4 1618-2650 nnns volume:409 year:2017 number:27 day:24 month:08 pages:6379-6386 https://dx.doi.org/10.1007/s00216-017-0577-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 409 2017 27 24 08 6379-6386 |
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10.1007/s00216-017-0577-2 doi (DE-627)SPR002256029 (SPR)s00216-017-0577-2-e DE-627 ger DE-627 rakwb eng Chen, Yuan verfasserin aut Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag GmbH Germany 2017 Abstract Metal organic chemical vapor deposition grown films consisting of $ Mg_{x} %$ Zn_{1-x} $O (4% < x < 5%) nanorod arrays ($ MgZnO_{nano} $) were functionalized with 11-azidoundecanoic acid (1). The $ MgZnO_{nano} $ was used instead of pure ZnO to take advantage of the etching resistance of the $ MgZnO_{nano} $ during the binding and subsequent sensing device fabrication processes of sensor devices, while the low Mg composition level ensures that selected ZnO properties useful for sensors development, such as piezoelectricity, are retained. Compound 1 was bound to the $ MgZnO_{nano} $ surface through the carboxylic acid group, leaving the azido group available for click chemistry and as a convenient infrared spectroscopy (IR) probe. The progress of the functionalization with 1 was characterized by FTIR microscopic imaging as a function of binding time, solvents employed, and $ MgZnO_{nano} $ morphology. Binding of 1 was most stable in solutions of 3-methoxypropionitrile (MPN), a non-protic polar solvent. This occurred first in μm-scale islands, then expanded to form a rather uniform layer after 22 h. Binding in alcohols resulted in less homogenous coverage, but the 1/$ MgZnO_{nano} $ films prepared from MPN were stable upon treatment with alcohols at room temperature. The binding behavior was significantly dependent on the surface morphology of $ MgZnO_{nano} $. Graphical abstractThe functionalization of MgZnO nanorod films with a click-ready linker and its dependence on bidning conditions and morphology has been studied by FTIR microscopic imaging using the azido group as the IR tag Zinc oxide (dpeaa)DE-He213 Magnesium zinc oxide (dpeaa)DE-He213 Surface functionalization (dpeaa)DE-He213 FTIR microscopic imaging (dpeaa)DE-He213 Zhang, Qihong aut Flach, Carol aut Mendelsohn, Richard aut Galoppini, Elena aut Reyes, Pavel Ivanoff aut Yang, Keyang aut Li, Rui aut Li, Guangyuan aut Lu, Yicheng aut Enthalten in Analytical and bioanalytical chemistry Berlin : Springer, 2002 409(2017), 27 vom: 24. Aug., Seite 6379-6386 (DE-627)25372337X (DE-600)1459122-4 1618-2650 nnns volume:409 year:2017 number:27 day:24 month:08 pages:6379-6386 https://dx.doi.org/10.1007/s00216-017-0577-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 409 2017 27 24 08 6379-6386 |
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10.1007/s00216-017-0577-2 doi (DE-627)SPR002256029 (SPR)s00216-017-0577-2-e DE-627 ger DE-627 rakwb eng Chen, Yuan verfasserin aut Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag GmbH Germany 2017 Abstract Metal organic chemical vapor deposition grown films consisting of $ Mg_{x} %$ Zn_{1-x} $O (4% < x < 5%) nanorod arrays ($ MgZnO_{nano} $) were functionalized with 11-azidoundecanoic acid (1). The $ MgZnO_{nano} $ was used instead of pure ZnO to take advantage of the etching resistance of the $ MgZnO_{nano} $ during the binding and subsequent sensing device fabrication processes of sensor devices, while the low Mg composition level ensures that selected ZnO properties useful for sensors development, such as piezoelectricity, are retained. Compound 1 was bound to the $ MgZnO_{nano} $ surface through the carboxylic acid group, leaving the azido group available for click chemistry and as a convenient infrared spectroscopy (IR) probe. The progress of the functionalization with 1 was characterized by FTIR microscopic imaging as a function of binding time, solvents employed, and $ MgZnO_{nano} $ morphology. Binding of 1 was most stable in solutions of 3-methoxypropionitrile (MPN), a non-protic polar solvent. This occurred first in μm-scale islands, then expanded to form a rather uniform layer after 22 h. Binding in alcohols resulted in less homogenous coverage, but the 1/$ MgZnO_{nano} $ films prepared from MPN were stable upon treatment with alcohols at room temperature. The binding behavior was significantly dependent on the surface morphology of $ MgZnO_{nano} $. Graphical abstractThe functionalization of MgZnO nanorod films with a click-ready linker and its dependence on bidning conditions and morphology has been studied by FTIR microscopic imaging using the azido group as the IR tag Zinc oxide (dpeaa)DE-He213 Magnesium zinc oxide (dpeaa)DE-He213 Surface functionalization (dpeaa)DE-He213 FTIR microscopic imaging (dpeaa)DE-He213 Zhang, Qihong aut Flach, Carol aut Mendelsohn, Richard aut Galoppini, Elena aut Reyes, Pavel Ivanoff aut Yang, Keyang aut Li, Rui aut Li, Guangyuan aut Lu, Yicheng aut Enthalten in Analytical and bioanalytical chemistry Berlin : Springer, 2002 409(2017), 27 vom: 24. Aug., Seite 6379-6386 (DE-627)25372337X (DE-600)1459122-4 1618-2650 nnns volume:409 year:2017 number:27 day:24 month:08 pages:6379-6386 https://dx.doi.org/10.1007/s00216-017-0577-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 409 2017 27 24 08 6379-6386 |
allfieldsSound |
10.1007/s00216-017-0577-2 doi (DE-627)SPR002256029 (SPR)s00216-017-0577-2-e DE-627 ger DE-627 rakwb eng Chen, Yuan verfasserin aut Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag GmbH Germany 2017 Abstract Metal organic chemical vapor deposition grown films consisting of $ Mg_{x} %$ Zn_{1-x} $O (4% < x < 5%) nanorod arrays ($ MgZnO_{nano} $) were functionalized with 11-azidoundecanoic acid (1). The $ MgZnO_{nano} $ was used instead of pure ZnO to take advantage of the etching resistance of the $ MgZnO_{nano} $ during the binding and subsequent sensing device fabrication processes of sensor devices, while the low Mg composition level ensures that selected ZnO properties useful for sensors development, such as piezoelectricity, are retained. Compound 1 was bound to the $ MgZnO_{nano} $ surface through the carboxylic acid group, leaving the azido group available for click chemistry and as a convenient infrared spectroscopy (IR) probe. The progress of the functionalization with 1 was characterized by FTIR microscopic imaging as a function of binding time, solvents employed, and $ MgZnO_{nano} $ morphology. Binding of 1 was most stable in solutions of 3-methoxypropionitrile (MPN), a non-protic polar solvent. This occurred first in μm-scale islands, then expanded to form a rather uniform layer after 22 h. Binding in alcohols resulted in less homogenous coverage, but the 1/$ MgZnO_{nano} $ films prepared from MPN were stable upon treatment with alcohols at room temperature. The binding behavior was significantly dependent on the surface morphology of $ MgZnO_{nano} $. Graphical abstractThe functionalization of MgZnO nanorod films with a click-ready linker and its dependence on bidning conditions and morphology has been studied by FTIR microscopic imaging using the azido group as the IR tag Zinc oxide (dpeaa)DE-He213 Magnesium zinc oxide (dpeaa)DE-He213 Surface functionalization (dpeaa)DE-He213 FTIR microscopic imaging (dpeaa)DE-He213 Zhang, Qihong aut Flach, Carol aut Mendelsohn, Richard aut Galoppini, Elena aut Reyes, Pavel Ivanoff aut Yang, Keyang aut Li, Rui aut Li, Guangyuan aut Lu, Yicheng aut Enthalten in Analytical and bioanalytical chemistry Berlin : Springer, 2002 409(2017), 27 vom: 24. Aug., Seite 6379-6386 (DE-627)25372337X (DE-600)1459122-4 1618-2650 nnns volume:409 year:2017 number:27 day:24 month:08 pages:6379-6386 https://dx.doi.org/10.1007/s00216-017-0577-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 409 2017 27 24 08 6379-6386 |
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English |
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Enthalten in Analytical and bioanalytical chemistry 409(2017), 27 vom: 24. Aug., Seite 6379-6386 volume:409 year:2017 number:27 day:24 month:08 pages:6379-6386 |
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Enthalten in Analytical and bioanalytical chemistry 409(2017), 27 vom: 24. Aug., Seite 6379-6386 volume:409 year:2017 number:27 day:24 month:08 pages:6379-6386 |
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Zinc oxide Magnesium zinc oxide Surface functionalization FTIR microscopic imaging |
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Analytical and bioanalytical chemistry |
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Chen, Yuan @@aut@@ Zhang, Qihong @@aut@@ Flach, Carol @@aut@@ Mendelsohn, Richard @@aut@@ Galoppini, Elena @@aut@@ Reyes, Pavel Ivanoff @@aut@@ Yang, Keyang @@aut@@ Li, Rui @@aut@@ Li, Guangyuan @@aut@@ Lu, Yicheng @@aut@@ |
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2017-08-24T00:00:00Z |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR002256029</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519084524.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201001s2017 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s00216-017-0577-2</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR002256029</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s00216-017-0577-2-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Chen, Yuan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer-Verlag GmbH Germany 2017</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Metal organic chemical vapor deposition grown films consisting of $ Mg_{x} %$ Zn_{1-x} $O (4% < x < 5%) nanorod arrays ($ MgZnO_{nano} $) were functionalized with 11-azidoundecanoic acid (1). The $ MgZnO_{nano} $ was used instead of pure ZnO to take advantage of the etching resistance of the $ MgZnO_{nano} $ during the binding and subsequent sensing device fabrication processes of sensor devices, while the low Mg composition level ensures that selected ZnO properties useful for sensors development, such as piezoelectricity, are retained. Compound 1 was bound to the $ MgZnO_{nano} $ surface through the carboxylic acid group, leaving the azido group available for click chemistry and as a convenient infrared spectroscopy (IR) probe. The progress of the functionalization with 1 was characterized by FTIR microscopic imaging as a function of binding time, solvents employed, and $ MgZnO_{nano} $ morphology. Binding of 1 was most stable in solutions of 3-methoxypropionitrile (MPN), a non-protic polar solvent. This occurred first in μm-scale islands, then expanded to form a rather uniform layer after 22 h. Binding in alcohols resulted in less homogenous coverage, but the 1/$ MgZnO_{nano} $ films prepared from MPN were stable upon treatment with alcohols at room temperature. The binding behavior was significantly dependent on the surface morphology of $ MgZnO_{nano} $. Graphical abstractThe functionalization of MgZnO nanorod films with a click-ready linker and its dependence on bidning conditions and morphology has been studied by FTIR microscopic imaging using the azido group as the IR tag</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Zinc oxide</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Magnesium zinc oxide</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Surface functionalization</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">FTIR microscopic imaging</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Qihong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Flach, Carol</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mendelsohn, Richard</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Galoppini, Elena</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Reyes, Pavel Ivanoff</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yang, Keyang</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Rui</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Guangyuan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lu, Yicheng</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Analytical and bioanalytical chemistry</subfield><subfield code="d">Berlin : Springer, 2002</subfield><subfield code="g">409(2017), 27 vom: 24. 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Chen, Yuan |
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Chen, Yuan misc Zinc oxide misc Magnesium zinc oxide misc Surface functionalization misc FTIR microscopic imaging Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging |
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Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging Zinc oxide (dpeaa)DE-He213 Magnesium zinc oxide (dpeaa)DE-He213 Surface functionalization (dpeaa)DE-He213 FTIR microscopic imaging (dpeaa)DE-He213 |
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Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging |
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Chen, Yuan Zhang, Qihong Flach, Carol Mendelsohn, Richard Galoppini, Elena Reyes, Pavel Ivanoff Yang, Keyang Li, Rui Li, Guangyuan Lu, Yicheng |
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functionalization of mgzno nanorod films and characterization by ftir microscopic imaging |
title_auth |
Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging |
abstract |
Abstract Metal organic chemical vapor deposition grown films consisting of $ Mg_{x} %$ Zn_{1-x} $O (4% < x < 5%) nanorod arrays ($ MgZnO_{nano} $) were functionalized with 11-azidoundecanoic acid (1). The $ MgZnO_{nano} $ was used instead of pure ZnO to take advantage of the etching resistance of the $ MgZnO_{nano} $ during the binding and subsequent sensing device fabrication processes of sensor devices, while the low Mg composition level ensures that selected ZnO properties useful for sensors development, such as piezoelectricity, are retained. Compound 1 was bound to the $ MgZnO_{nano} $ surface through the carboxylic acid group, leaving the azido group available for click chemistry and as a convenient infrared spectroscopy (IR) probe. The progress of the functionalization with 1 was characterized by FTIR microscopic imaging as a function of binding time, solvents employed, and $ MgZnO_{nano} $ morphology. Binding of 1 was most stable in solutions of 3-methoxypropionitrile (MPN), a non-protic polar solvent. This occurred first in μm-scale islands, then expanded to form a rather uniform layer after 22 h. Binding in alcohols resulted in less homogenous coverage, but the 1/$ MgZnO_{nano} $ films prepared from MPN were stable upon treatment with alcohols at room temperature. The binding behavior was significantly dependent on the surface morphology of $ MgZnO_{nano} $. Graphical abstractThe functionalization of MgZnO nanorod films with a click-ready linker and its dependence on bidning conditions and morphology has been studied by FTIR microscopic imaging using the azido group as the IR tag © Springer-Verlag GmbH Germany 2017 |
abstractGer |
Abstract Metal organic chemical vapor deposition grown films consisting of $ Mg_{x} %$ Zn_{1-x} $O (4% < x < 5%) nanorod arrays ($ MgZnO_{nano} $) were functionalized with 11-azidoundecanoic acid (1). The $ MgZnO_{nano} $ was used instead of pure ZnO to take advantage of the etching resistance of the $ MgZnO_{nano} $ during the binding and subsequent sensing device fabrication processes of sensor devices, while the low Mg composition level ensures that selected ZnO properties useful for sensors development, such as piezoelectricity, are retained. Compound 1 was bound to the $ MgZnO_{nano} $ surface through the carboxylic acid group, leaving the azido group available for click chemistry and as a convenient infrared spectroscopy (IR) probe. The progress of the functionalization with 1 was characterized by FTIR microscopic imaging as a function of binding time, solvents employed, and $ MgZnO_{nano} $ morphology. Binding of 1 was most stable in solutions of 3-methoxypropionitrile (MPN), a non-protic polar solvent. This occurred first in μm-scale islands, then expanded to form a rather uniform layer after 22 h. Binding in alcohols resulted in less homogenous coverage, but the 1/$ MgZnO_{nano} $ films prepared from MPN were stable upon treatment with alcohols at room temperature. The binding behavior was significantly dependent on the surface morphology of $ MgZnO_{nano} $. Graphical abstractThe functionalization of MgZnO nanorod films with a click-ready linker and its dependence on bidning conditions and morphology has been studied by FTIR microscopic imaging using the azido group as the IR tag © Springer-Verlag GmbH Germany 2017 |
abstract_unstemmed |
Abstract Metal organic chemical vapor deposition grown films consisting of $ Mg_{x} %$ Zn_{1-x} $O (4% < x < 5%) nanorod arrays ($ MgZnO_{nano} $) were functionalized with 11-azidoundecanoic acid (1). The $ MgZnO_{nano} $ was used instead of pure ZnO to take advantage of the etching resistance of the $ MgZnO_{nano} $ during the binding and subsequent sensing device fabrication processes of sensor devices, while the low Mg composition level ensures that selected ZnO properties useful for sensors development, such as piezoelectricity, are retained. Compound 1 was bound to the $ MgZnO_{nano} $ surface through the carboxylic acid group, leaving the azido group available for click chemistry and as a convenient infrared spectroscopy (IR) probe. The progress of the functionalization with 1 was characterized by FTIR microscopic imaging as a function of binding time, solvents employed, and $ MgZnO_{nano} $ morphology. Binding of 1 was most stable in solutions of 3-methoxypropionitrile (MPN), a non-protic polar solvent. This occurred first in μm-scale islands, then expanded to form a rather uniform layer after 22 h. Binding in alcohols resulted in less homogenous coverage, but the 1/$ MgZnO_{nano} $ films prepared from MPN were stable upon treatment with alcohols at room temperature. The binding behavior was significantly dependent on the surface morphology of $ MgZnO_{nano} $. Graphical abstractThe functionalization of MgZnO nanorod films with a click-ready linker and its dependence on bidning conditions and morphology has been studied by FTIR microscopic imaging using the azido group as the IR tag © Springer-Verlag GmbH Germany 2017 |
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container_issue |
27 |
title_short |
Functionalization of MgZnO nanorod films and characterization by FTIR microscopic imaging |
url |
https://dx.doi.org/10.1007/s00216-017-0577-2 |
remote_bool |
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author2 |
Zhang, Qihong Flach, Carol Mendelsohn, Richard Galoppini, Elena Reyes, Pavel Ivanoff Yang, Keyang Li, Rui Li, Guangyuan Lu, Yicheng |
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Zhang, Qihong Flach, Carol Mendelsohn, Richard Galoppini, Elena Reyes, Pavel Ivanoff Yang, Keyang Li, Rui Li, Guangyuan Lu, Yicheng |
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doi_str |
10.1007/s00216-017-0577-2 |
up_date |
2024-07-04T02:23:15.351Z |
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score |
7.398299 |