Temporal variability of phosphorus fractions in Irish karst springs
Abstract Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs f...
Ausführliche Beschreibung
Autor*in: |
Kilroy, Garrett [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2004 |
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Anmerkung: |
© Springer-Verlag 2004 |
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Übergeordnetes Werk: |
Enthalten in: Environmental geology - Berlin : Springer, 1975, 47(2004), 3 vom: 20. Okt., Seite 421-430 |
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Übergeordnetes Werk: |
volume:47 ; year:2004 ; number:3 ; day:20 ; month:10 ; pages:421-430 |
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DOI / URN: |
10.1007/s00254-004-1171-4 |
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Katalog-ID: |
SPR003047849 |
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520 | |a Abstract Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg $ l^{−1} $) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg $ l^{−1} $)and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg $ l^{−1} $), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg $ l^{−1} $ due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge. | ||
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10.1007/s00254-004-1171-4 doi (DE-627)SPR003047849 (SPR)s00254-004-1171-4-e DE-627 ger DE-627 rakwb eng Kilroy, Garrett verfasserin aut Temporal variability of phosphorus fractions in Irish karst springs 2004 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2004 Abstract Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg $ l^{−1} $) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg $ l^{−1} $)and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg $ l^{−1} $), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg $ l^{−1} $ due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge. Phosphorus (dpeaa)DE-He213 Karst aquifer (dpeaa)DE-He213 Temporal variability (dpeaa)DE-He213 Groundwater (dpeaa)DE-He213 Coxon, Catherine aut Enthalten in Environmental geology Berlin : Springer, 1975 47(2004), 3 vom: 20. Okt., Seite 421-430 (DE-627)253722586 (DE-600)1459034-7 1432-0495 nnns volume:47 year:2004 number:3 day:20 month:10 pages:421-430 https://dx.doi.org/10.1007/s00254-004-1171-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_24 GBV_ILN_31 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_110 GBV_ILN_120 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_267 GBV_ILN_285 GBV_ILN_293 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4338 AR 47 2004 3 20 10 421-430 |
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10.1007/s00254-004-1171-4 doi (DE-627)SPR003047849 (SPR)s00254-004-1171-4-e DE-627 ger DE-627 rakwb eng Kilroy, Garrett verfasserin aut Temporal variability of phosphorus fractions in Irish karst springs 2004 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2004 Abstract Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg $ l^{−1} $) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg $ l^{−1} $)and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg $ l^{−1} $), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg $ l^{−1} $ due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge. Phosphorus (dpeaa)DE-He213 Karst aquifer (dpeaa)DE-He213 Temporal variability (dpeaa)DE-He213 Groundwater (dpeaa)DE-He213 Coxon, Catherine aut Enthalten in Environmental geology Berlin : Springer, 1975 47(2004), 3 vom: 20. Okt., Seite 421-430 (DE-627)253722586 (DE-600)1459034-7 1432-0495 nnns volume:47 year:2004 number:3 day:20 month:10 pages:421-430 https://dx.doi.org/10.1007/s00254-004-1171-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_24 GBV_ILN_31 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_110 GBV_ILN_120 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_267 GBV_ILN_285 GBV_ILN_293 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4338 AR 47 2004 3 20 10 421-430 |
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10.1007/s00254-004-1171-4 doi (DE-627)SPR003047849 (SPR)s00254-004-1171-4-e DE-627 ger DE-627 rakwb eng Kilroy, Garrett verfasserin aut Temporal variability of phosphorus fractions in Irish karst springs 2004 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2004 Abstract Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg $ l^{−1} $) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg $ l^{−1} $)and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg $ l^{−1} $), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg $ l^{−1} $ due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge. Phosphorus (dpeaa)DE-He213 Karst aquifer (dpeaa)DE-He213 Temporal variability (dpeaa)DE-He213 Groundwater (dpeaa)DE-He213 Coxon, Catherine aut Enthalten in Environmental geology Berlin : Springer, 1975 47(2004), 3 vom: 20. Okt., Seite 421-430 (DE-627)253722586 (DE-600)1459034-7 1432-0495 nnns volume:47 year:2004 number:3 day:20 month:10 pages:421-430 https://dx.doi.org/10.1007/s00254-004-1171-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_24 GBV_ILN_31 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_110 GBV_ILN_120 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_267 GBV_ILN_285 GBV_ILN_293 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4338 AR 47 2004 3 20 10 421-430 |
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10.1007/s00254-004-1171-4 doi (DE-627)SPR003047849 (SPR)s00254-004-1171-4-e DE-627 ger DE-627 rakwb eng Kilroy, Garrett verfasserin aut Temporal variability of phosphorus fractions in Irish karst springs 2004 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2004 Abstract Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg $ l^{−1} $) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg $ l^{−1} $)and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg $ l^{−1} $), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg $ l^{−1} $ due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge. Phosphorus (dpeaa)DE-He213 Karst aquifer (dpeaa)DE-He213 Temporal variability (dpeaa)DE-He213 Groundwater (dpeaa)DE-He213 Coxon, Catherine aut Enthalten in Environmental geology Berlin : Springer, 1975 47(2004), 3 vom: 20. Okt., Seite 421-430 (DE-627)253722586 (DE-600)1459034-7 1432-0495 nnns volume:47 year:2004 number:3 day:20 month:10 pages:421-430 https://dx.doi.org/10.1007/s00254-004-1171-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_24 GBV_ILN_31 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_110 GBV_ILN_120 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_267 GBV_ILN_285 GBV_ILN_293 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4338 AR 47 2004 3 20 10 421-430 |
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10.1007/s00254-004-1171-4 doi (DE-627)SPR003047849 (SPR)s00254-004-1171-4-e DE-627 ger DE-627 rakwb eng Kilroy, Garrett verfasserin aut Temporal variability of phosphorus fractions in Irish karst springs 2004 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2004 Abstract Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg $ l^{−1} $) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg $ l^{−1} $)and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg $ l^{−1} $), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg $ l^{−1} $ due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge. Phosphorus (dpeaa)DE-He213 Karst aquifer (dpeaa)DE-He213 Temporal variability (dpeaa)DE-He213 Groundwater (dpeaa)DE-He213 Coxon, Catherine aut Enthalten in Environmental geology Berlin : Springer, 1975 47(2004), 3 vom: 20. Okt., Seite 421-430 (DE-627)253722586 (DE-600)1459034-7 1432-0495 nnns volume:47 year:2004 number:3 day:20 month:10 pages:421-430 https://dx.doi.org/10.1007/s00254-004-1171-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_24 GBV_ILN_31 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_110 GBV_ILN_120 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_267 GBV_ILN_285 GBV_ILN_293 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4338 AR 47 2004 3 20 10 421-430 |
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Temporal variability of phosphorus fractions in Irish karst springs |
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Kilroy, Garrett Coxon, Catherine |
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10.1007/s00254-004-1171-4 |
title_sort |
temporal variability of phosphorus fractions in irish karst springs |
title_auth |
Temporal variability of phosphorus fractions in Irish karst springs |
abstract |
Abstract Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg $ l^{−1} $) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg $ l^{−1} $)and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg $ l^{−1} $), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg $ l^{−1} $ due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge. © Springer-Verlag 2004 |
abstractGer |
Abstract Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg $ l^{−1} $) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg $ l^{−1} $)and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg $ l^{−1} $), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg $ l^{−1} $ due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge. © Springer-Verlag 2004 |
abstract_unstemmed |
Abstract Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg $ l^{−1} $) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg $ l^{−1} $)and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg $ l^{−1} $), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg $ l^{−1} $ due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge. © Springer-Verlag 2004 |
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title_short |
Temporal variability of phosphorus fractions in Irish karst springs |
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