Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes
Summary The gas permeability of three substituted polyacetylenes, poly(1-chloro-2-phenylacetylene) (PClPA), poly[1-phenyl-2-(4-trimethylsilyl)phenylacetylene] (PTMSDPA), and poly[1-(trimethylsilyl)-1-propyne] (PTMSP), increased systematically with increasing content of nonporous fumed silica (FS) na...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Kono, Toshiki [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2006 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer-Verlag 2006 |
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| Übergeordnetes Werk: |
Enthalten in: Polymer bulletin - Berlin : Springer, 1978, 58(2006), 5-6 vom: 23. Dez., Seite 995-1003 |
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| Übergeordnetes Werk: |
volume:58 ; year:2006 ; number:5-6 ; day:23 ; month:12 ; pages:995-1003 |
| Links: |
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| DOI / URN: |
10.1007/s00289-006-0720-2 |
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| Katalog-ID: |
SPR003739864 |
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| 041 | |a eng | ||
| 100 | 1 | |a Kono, Toshiki |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes |
| 264 | 1 | |c 2006 | |
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| 520 | |a Summary The gas permeability of three substituted polyacetylenes, poly(1-chloro-2-phenylacetylene) (PClPA), poly[1-phenyl-2-(4-trimethylsilyl)phenylacetylene] (PTMSDPA), and poly[1-(trimethylsilyl)-1-propyne] (PTMSP), increased systematically with increasing content of nonporous fumed silica (FS) nanoparticles. For instance, the oxygen permeability coefficient ($ PO_{2} $) of PClPA containing 30 wt % FS was 86 barrers, which was 10 times higher than that of the unfilled polymer ($ PO_{2} $=8.6 barrers). The extent of permeability increase with the addition of FS was smaller when the permeability of the original polymer was higher. The order of the permeability increase in FS-filled polymers was as follows: PClPA > PTMSDPA > PTMSP. The addition of FS resulted in the decrease of $ O_{2} $/$ N_{2} $ permselectivity of these polymers. The $ H_{2} $/$ CH_{4} $ permselectivity largely decreased with increasing FS content in PClPA, while it hardly changed with FS loading in PTMSP. The gas solubility of PClPA was practically independent of FS content, and the increase in gas permeability in filled PClPA resulted from an increase in diffusivity with the addition of FS. | ||
| 650 | 4 | |a Fumed Silica |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Phenylacetylene |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Propyne |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Permeability Enhancement |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Fumed Silica Nanoparticles |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Hu, Yanming |4 aut | |
| 700 | 1 | |a Masuda, Toshio |4 aut | |
| 700 | 1 | |a Tanaka, Katsuchisa |4 aut | |
| 700 | 1 | |a Priestley, Rodney D. |4 aut | |
| 700 | 1 | |a Freeman, Benny D. |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Polymer bulletin |d Berlin : Springer, 1978 |g 58(2006), 5-6 vom: 23. Dez., Seite 995-1003 |w (DE-627)268761833 |w (DE-600)1473175-7 |x 1436-2449 |7 nnns |
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| 856 | 4 | 0 | |u https://dx.doi.org/10.1007/s00289-006-0720-2 |z lizenzpflichtig |3 Volltext |
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| 912 | |a GBV_ILN_2031 | ||
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| 912 | |a GBV_ILN_2055 | ||
| 912 | |a GBV_ILN_2057 | ||
| 912 | |a GBV_ILN_2059 | ||
| 912 | |a GBV_ILN_2061 | ||
| 912 | |a GBV_ILN_2064 | ||
| 912 | |a GBV_ILN_2065 | ||
| 912 | |a GBV_ILN_2068 | ||
| 912 | |a GBV_ILN_2070 | ||
| 912 | |a GBV_ILN_2086 | ||
| 912 | |a GBV_ILN_2088 | ||
| 912 | |a GBV_ILN_2093 | ||
| 912 | |a GBV_ILN_2106 | ||
| 912 | |a GBV_ILN_2107 | ||
| 912 | |a GBV_ILN_2108 | ||
| 912 | |a GBV_ILN_2110 | ||
| 912 | |a GBV_ILN_2111 | ||
| 912 | |a GBV_ILN_2112 | ||
| 912 | |a GBV_ILN_2113 | ||
| 912 | |a GBV_ILN_2116 | ||
| 912 | |a GBV_ILN_2118 | ||
| 912 | |a GBV_ILN_2119 | ||
| 912 | |a GBV_ILN_2122 | ||
| 912 | |a GBV_ILN_2129 | ||
| 912 | |a GBV_ILN_2143 | ||
| 912 | |a GBV_ILN_2144 | ||
| 912 | |a GBV_ILN_2147 | ||
| 912 | |a GBV_ILN_2148 | ||
| 912 | |a GBV_ILN_2152 | ||
| 912 | |a GBV_ILN_2153 | ||
| 912 | |a GBV_ILN_2188 | ||
| 912 | |a GBV_ILN_2190 | ||
| 912 | |a GBV_ILN_2232 | ||
| 912 | |a GBV_ILN_2336 | ||
| 912 | |a GBV_ILN_2411 | ||
| 912 | |a GBV_ILN_2446 | ||
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| 912 | |a GBV_ILN_2507 | ||
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| 912 | |a GBV_ILN_4125 | ||
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| 912 | |a GBV_ILN_4242 | ||
| 912 | |a GBV_ILN_4246 | ||
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| 912 | |a GBV_ILN_4251 | ||
| 912 | |a GBV_ILN_4305 | ||
| 912 | |a GBV_ILN_4306 | ||
| 912 | |a GBV_ILN_4307 | ||
| 912 | |a GBV_ILN_4313 | ||
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| 912 | |a GBV_ILN_4324 | ||
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| 912 | |a GBV_ILN_4334 | ||
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10.1007/s00289-006-0720-2 doi (DE-627)SPR003739864 (SPR)s00289-006-0720-2-e DE-627 ger DE-627 rakwb eng Kono, Toshiki verfasserin aut Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2006 Summary The gas permeability of three substituted polyacetylenes, poly(1-chloro-2-phenylacetylene) (PClPA), poly[1-phenyl-2-(4-trimethylsilyl)phenylacetylene] (PTMSDPA), and poly[1-(trimethylsilyl)-1-propyne] (PTMSP), increased systematically with increasing content of nonporous fumed silica (FS) nanoparticles. For instance, the oxygen permeability coefficient ($ PO_{2} $) of PClPA containing 30 wt % FS was 86 barrers, which was 10 times higher than that of the unfilled polymer ($ PO_{2} $=8.6 barrers). The extent of permeability increase with the addition of FS was smaller when the permeability of the original polymer was higher. The order of the permeability increase in FS-filled polymers was as follows: PClPA > PTMSDPA > PTMSP. The addition of FS resulted in the decrease of $ O_{2} $/$ N_{2} $ permselectivity of these polymers. The $ H_{2} $/$ CH_{4} $ permselectivity largely decreased with increasing FS content in PClPA, while it hardly changed with FS loading in PTMSP. The gas solubility of PClPA was practically independent of FS content, and the increase in gas permeability in filled PClPA resulted from an increase in diffusivity with the addition of FS. Fumed Silica (dpeaa)DE-He213 Phenylacetylene (dpeaa)DE-He213 Propyne (dpeaa)DE-He213 Permeability Enhancement (dpeaa)DE-He213 Fumed Silica Nanoparticles (dpeaa)DE-He213 Hu, Yanming aut Masuda, Toshio aut Tanaka, Katsuchisa aut Priestley, Rodney D. aut Freeman, Benny D. aut Enthalten in Polymer bulletin Berlin : Springer, 1978 58(2006), 5-6 vom: 23. Dez., Seite 995-1003 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:58 year:2006 number:5-6 day:23 month:12 pages:995-1003 https://dx.doi.org/10.1007/s00289-006-0720-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 58 2006 5-6 23 12 995-1003 |
| spelling |
10.1007/s00289-006-0720-2 doi (DE-627)SPR003739864 (SPR)s00289-006-0720-2-e DE-627 ger DE-627 rakwb eng Kono, Toshiki verfasserin aut Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2006 Summary The gas permeability of three substituted polyacetylenes, poly(1-chloro-2-phenylacetylene) (PClPA), poly[1-phenyl-2-(4-trimethylsilyl)phenylacetylene] (PTMSDPA), and poly[1-(trimethylsilyl)-1-propyne] (PTMSP), increased systematically with increasing content of nonporous fumed silica (FS) nanoparticles. For instance, the oxygen permeability coefficient ($ PO_{2} $) of PClPA containing 30 wt % FS was 86 barrers, which was 10 times higher than that of the unfilled polymer ($ PO_{2} $=8.6 barrers). The extent of permeability increase with the addition of FS was smaller when the permeability of the original polymer was higher. The order of the permeability increase in FS-filled polymers was as follows: PClPA > PTMSDPA > PTMSP. The addition of FS resulted in the decrease of $ O_{2} $/$ N_{2} $ permselectivity of these polymers. The $ H_{2} $/$ CH_{4} $ permselectivity largely decreased with increasing FS content in PClPA, while it hardly changed with FS loading in PTMSP. The gas solubility of PClPA was practically independent of FS content, and the increase in gas permeability in filled PClPA resulted from an increase in diffusivity with the addition of FS. Fumed Silica (dpeaa)DE-He213 Phenylacetylene (dpeaa)DE-He213 Propyne (dpeaa)DE-He213 Permeability Enhancement (dpeaa)DE-He213 Fumed Silica Nanoparticles (dpeaa)DE-He213 Hu, Yanming aut Masuda, Toshio aut Tanaka, Katsuchisa aut Priestley, Rodney D. aut Freeman, Benny D. aut Enthalten in Polymer bulletin Berlin : Springer, 1978 58(2006), 5-6 vom: 23. Dez., Seite 995-1003 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:58 year:2006 number:5-6 day:23 month:12 pages:995-1003 https://dx.doi.org/10.1007/s00289-006-0720-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 58 2006 5-6 23 12 995-1003 |
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10.1007/s00289-006-0720-2 doi (DE-627)SPR003739864 (SPR)s00289-006-0720-2-e DE-627 ger DE-627 rakwb eng Kono, Toshiki verfasserin aut Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2006 Summary The gas permeability of three substituted polyacetylenes, poly(1-chloro-2-phenylacetylene) (PClPA), poly[1-phenyl-2-(4-trimethylsilyl)phenylacetylene] (PTMSDPA), and poly[1-(trimethylsilyl)-1-propyne] (PTMSP), increased systematically with increasing content of nonporous fumed silica (FS) nanoparticles. For instance, the oxygen permeability coefficient ($ PO_{2} $) of PClPA containing 30 wt % FS was 86 barrers, which was 10 times higher than that of the unfilled polymer ($ PO_{2} $=8.6 barrers). The extent of permeability increase with the addition of FS was smaller when the permeability of the original polymer was higher. The order of the permeability increase in FS-filled polymers was as follows: PClPA > PTMSDPA > PTMSP. The addition of FS resulted in the decrease of $ O_{2} $/$ N_{2} $ permselectivity of these polymers. The $ H_{2} $/$ CH_{4} $ permselectivity largely decreased with increasing FS content in PClPA, while it hardly changed with FS loading in PTMSP. The gas solubility of PClPA was practically independent of FS content, and the increase in gas permeability in filled PClPA resulted from an increase in diffusivity with the addition of FS. Fumed Silica (dpeaa)DE-He213 Phenylacetylene (dpeaa)DE-He213 Propyne (dpeaa)DE-He213 Permeability Enhancement (dpeaa)DE-He213 Fumed Silica Nanoparticles (dpeaa)DE-He213 Hu, Yanming aut Masuda, Toshio aut Tanaka, Katsuchisa aut Priestley, Rodney D. aut Freeman, Benny D. aut Enthalten in Polymer bulletin Berlin : Springer, 1978 58(2006), 5-6 vom: 23. Dez., Seite 995-1003 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:58 year:2006 number:5-6 day:23 month:12 pages:995-1003 https://dx.doi.org/10.1007/s00289-006-0720-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 58 2006 5-6 23 12 995-1003 |
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10.1007/s00289-006-0720-2 doi (DE-627)SPR003739864 (SPR)s00289-006-0720-2-e DE-627 ger DE-627 rakwb eng Kono, Toshiki verfasserin aut Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2006 Summary The gas permeability of three substituted polyacetylenes, poly(1-chloro-2-phenylacetylene) (PClPA), poly[1-phenyl-2-(4-trimethylsilyl)phenylacetylene] (PTMSDPA), and poly[1-(trimethylsilyl)-1-propyne] (PTMSP), increased systematically with increasing content of nonporous fumed silica (FS) nanoparticles. For instance, the oxygen permeability coefficient ($ PO_{2} $) of PClPA containing 30 wt % FS was 86 barrers, which was 10 times higher than that of the unfilled polymer ($ PO_{2} $=8.6 barrers). The extent of permeability increase with the addition of FS was smaller when the permeability of the original polymer was higher. The order of the permeability increase in FS-filled polymers was as follows: PClPA > PTMSDPA > PTMSP. The addition of FS resulted in the decrease of $ O_{2} $/$ N_{2} $ permselectivity of these polymers. The $ H_{2} $/$ CH_{4} $ permselectivity largely decreased with increasing FS content in PClPA, while it hardly changed with FS loading in PTMSP. The gas solubility of PClPA was practically independent of FS content, and the increase in gas permeability in filled PClPA resulted from an increase in diffusivity with the addition of FS. Fumed Silica (dpeaa)DE-He213 Phenylacetylene (dpeaa)DE-He213 Propyne (dpeaa)DE-He213 Permeability Enhancement (dpeaa)DE-He213 Fumed Silica Nanoparticles (dpeaa)DE-He213 Hu, Yanming aut Masuda, Toshio aut Tanaka, Katsuchisa aut Priestley, Rodney D. aut Freeman, Benny D. aut Enthalten in Polymer bulletin Berlin : Springer, 1978 58(2006), 5-6 vom: 23. Dez., Seite 995-1003 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:58 year:2006 number:5-6 day:23 month:12 pages:995-1003 https://dx.doi.org/10.1007/s00289-006-0720-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 58 2006 5-6 23 12 995-1003 |
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10.1007/s00289-006-0720-2 doi (DE-627)SPR003739864 (SPR)s00289-006-0720-2-e DE-627 ger DE-627 rakwb eng Kono, Toshiki verfasserin aut Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2006 Summary The gas permeability of three substituted polyacetylenes, poly(1-chloro-2-phenylacetylene) (PClPA), poly[1-phenyl-2-(4-trimethylsilyl)phenylacetylene] (PTMSDPA), and poly[1-(trimethylsilyl)-1-propyne] (PTMSP), increased systematically with increasing content of nonporous fumed silica (FS) nanoparticles. For instance, the oxygen permeability coefficient ($ PO_{2} $) of PClPA containing 30 wt % FS was 86 barrers, which was 10 times higher than that of the unfilled polymer ($ PO_{2} $=8.6 barrers). The extent of permeability increase with the addition of FS was smaller when the permeability of the original polymer was higher. The order of the permeability increase in FS-filled polymers was as follows: PClPA > PTMSDPA > PTMSP. The addition of FS resulted in the decrease of $ O_{2} $/$ N_{2} $ permselectivity of these polymers. The $ H_{2} $/$ CH_{4} $ permselectivity largely decreased with increasing FS content in PClPA, while it hardly changed with FS loading in PTMSP. The gas solubility of PClPA was practically independent of FS content, and the increase in gas permeability in filled PClPA resulted from an increase in diffusivity with the addition of FS. Fumed Silica (dpeaa)DE-He213 Phenylacetylene (dpeaa)DE-He213 Propyne (dpeaa)DE-He213 Permeability Enhancement (dpeaa)DE-He213 Fumed Silica Nanoparticles (dpeaa)DE-He213 Hu, Yanming aut Masuda, Toshio aut Tanaka, Katsuchisa aut Priestley, Rodney D. aut Freeman, Benny D. aut Enthalten in Polymer bulletin Berlin : Springer, 1978 58(2006), 5-6 vom: 23. Dez., Seite 995-1003 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:58 year:2006 number:5-6 day:23 month:12 pages:995-1003 https://dx.doi.org/10.1007/s00289-006-0720-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 58 2006 5-6 23 12 995-1003 |
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Enthalten in Polymer bulletin 58(2006), 5-6 vom: 23. Dez., Seite 995-1003 volume:58 year:2006 number:5-6 day:23 month:12 pages:995-1003 |
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Fumed Silica Phenylacetylene Propyne Permeability Enhancement Fumed Silica Nanoparticles |
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Kono, Toshiki @@aut@@ Hu, Yanming @@aut@@ Masuda, Toshio @@aut@@ Tanaka, Katsuchisa @@aut@@ Priestley, Rodney D. @@aut@@ Freeman, Benny D. @@aut@@ |
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|
| author |
Kono, Toshiki |
| spellingShingle |
Kono, Toshiki misc Fumed Silica misc Phenylacetylene misc Propyne misc Permeability Enhancement misc Fumed Silica Nanoparticles Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes |
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Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes Fumed Silica (dpeaa)DE-He213 Phenylacetylene (dpeaa)DE-He213 Propyne (dpeaa)DE-He213 Permeability Enhancement (dpeaa)DE-He213 Fumed Silica Nanoparticles (dpeaa)DE-He213 |
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misc Fumed Silica misc Phenylacetylene misc Propyne misc Permeability Enhancement misc Fumed Silica Nanoparticles |
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misc Fumed Silica misc Phenylacetylene misc Propyne misc Permeability Enhancement misc Fumed Silica Nanoparticles |
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Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes |
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Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes |
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Kono, Toshiki |
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Kono, Toshiki Hu, Yanming Masuda, Toshio Tanaka, Katsuchisa Priestley, Rodney D. Freeman, Benny D. |
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Kono, Toshiki |
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10.1007/s00289-006-0720-2 |
| title_sort |
effect of fumed silica nanoparticles on the gas permeation properties of substituted polyacetylene membranes |
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Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes |
| abstract |
Summary The gas permeability of three substituted polyacetylenes, poly(1-chloro-2-phenylacetylene) (PClPA), poly[1-phenyl-2-(4-trimethylsilyl)phenylacetylene] (PTMSDPA), and poly[1-(trimethylsilyl)-1-propyne] (PTMSP), increased systematically with increasing content of nonporous fumed silica (FS) nanoparticles. For instance, the oxygen permeability coefficient ($ PO_{2} $) of PClPA containing 30 wt % FS was 86 barrers, which was 10 times higher than that of the unfilled polymer ($ PO_{2} $=8.6 barrers). The extent of permeability increase with the addition of FS was smaller when the permeability of the original polymer was higher. The order of the permeability increase in FS-filled polymers was as follows: PClPA > PTMSDPA > PTMSP. The addition of FS resulted in the decrease of $ O_{2} $/$ N_{2} $ permselectivity of these polymers. The $ H_{2} $/$ CH_{4} $ permselectivity largely decreased with increasing FS content in PClPA, while it hardly changed with FS loading in PTMSP. The gas solubility of PClPA was practically independent of FS content, and the increase in gas permeability in filled PClPA resulted from an increase in diffusivity with the addition of FS. © Springer-Verlag 2006 |
| abstractGer |
Summary The gas permeability of three substituted polyacetylenes, poly(1-chloro-2-phenylacetylene) (PClPA), poly[1-phenyl-2-(4-trimethylsilyl)phenylacetylene] (PTMSDPA), and poly[1-(trimethylsilyl)-1-propyne] (PTMSP), increased systematically with increasing content of nonporous fumed silica (FS) nanoparticles. For instance, the oxygen permeability coefficient ($ PO_{2} $) of PClPA containing 30 wt % FS was 86 barrers, which was 10 times higher than that of the unfilled polymer ($ PO_{2} $=8.6 barrers). The extent of permeability increase with the addition of FS was smaller when the permeability of the original polymer was higher. The order of the permeability increase in FS-filled polymers was as follows: PClPA > PTMSDPA > PTMSP. The addition of FS resulted in the decrease of $ O_{2} $/$ N_{2} $ permselectivity of these polymers. The $ H_{2} $/$ CH_{4} $ permselectivity largely decreased with increasing FS content in PClPA, while it hardly changed with FS loading in PTMSP. The gas solubility of PClPA was practically independent of FS content, and the increase in gas permeability in filled PClPA resulted from an increase in diffusivity with the addition of FS. © Springer-Verlag 2006 |
| abstract_unstemmed |
Summary The gas permeability of three substituted polyacetylenes, poly(1-chloro-2-phenylacetylene) (PClPA), poly[1-phenyl-2-(4-trimethylsilyl)phenylacetylene] (PTMSDPA), and poly[1-(trimethylsilyl)-1-propyne] (PTMSP), increased systematically with increasing content of nonporous fumed silica (FS) nanoparticles. For instance, the oxygen permeability coefficient ($ PO_{2} $) of PClPA containing 30 wt % FS was 86 barrers, which was 10 times higher than that of the unfilled polymer ($ PO_{2} $=8.6 barrers). The extent of permeability increase with the addition of FS was smaller when the permeability of the original polymer was higher. The order of the permeability increase in FS-filled polymers was as follows: PClPA > PTMSDPA > PTMSP. The addition of FS resulted in the decrease of $ O_{2} $/$ N_{2} $ permselectivity of these polymers. The $ H_{2} $/$ CH_{4} $ permselectivity largely decreased with increasing FS content in PClPA, while it hardly changed with FS loading in PTMSP. The gas solubility of PClPA was practically independent of FS content, and the increase in gas permeability in filled PClPA resulted from an increase in diffusivity with the addition of FS. © Springer-Verlag 2006 |
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5-6 |
| title_short |
Effect of Fumed Silica Nanoparticles on the Gas Permeation Properties of Substituted Polyacetylene Membranes |
| url |
https://dx.doi.org/10.1007/s00289-006-0720-2 |
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| author2 |
Hu, Yanming Masuda, Toshio Tanaka, Katsuchisa Priestley, Rodney D. Freeman, Benny D. |
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Hu, Yanming Masuda, Toshio Tanaka, Katsuchisa Priestley, Rodney D. Freeman, Benny D. |
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| doi_str |
10.1007/s00289-006-0720-2 |
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2024-07-03T21:21:57.454Z |
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| score |
7.3996267 |