Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers
Abstract Well defined ABA triblock copolymer comprising a biodegradable poly(ε-caprolactone) (PCL) middle block and two pH responsive poly(acrylic acid) (PAA) outer blocks was synthesized by atom transfer radical polymerization of tert-butyl acrylate, initiated by PCL-based macroinitiator, followed...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Kamenova, Katya [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer-Verlag Berlin Heidelberg 2016 |
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| Übergeordnetes Werk: |
Enthalten in: Polymer bulletin - Berlin : Springer, 1978, 74(2016), 3 vom: 01. Juli, Seite 707-720 |
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| Übergeordnetes Werk: |
volume:74 ; year:2016 ; number:3 ; day:01 ; month:07 ; pages:707-720 |
| Links: |
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| DOI / URN: |
10.1007/s00289-016-1741-0 |
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| Katalog-ID: |
SPR003762866 |
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| 245 | 1 | 0 | |a Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers |
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| 520 | |a Abstract Well defined ABA triblock copolymer comprising a biodegradable poly(ε-caprolactone) (PCL) middle block and two pH responsive poly(acrylic acid) (PAA) outer blocks was synthesized by atom transfer radical polymerization of tert-butyl acrylate, initiated by PCL-based macroinitiator, followed by selective hydrolysis of the poly(tert-butyl acrylate) blocks. The cooperative self-assembly of the synthesized poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) ($ PAA_{22} %$ PCL_{26} %$ PAA_{22} $) copolymer with a temperature-responsive poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) ($ PEO_{26} %$ PPO_{40} %$ PEO_{26} $, Pluronic P85) triblock copolymer at different compositions in aqueous media was investigated. Based on experimental data, copolymer properties and composition, formation of nano-sized aggregates comprising a mixed PCL/PPO core and a mixed PEO/PAA corona is suggested. The binary mixture of $ PAA_{22} %$ PCL_{26} %$ PAA_{22} $:$ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ copolymers at molar ratio 3:1 favors the formation of mixed aggregates only, while at higher $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ content the aggregates coexist with pure $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ micelles. | ||
| 650 | 4 | |a Amphiphilic copolymers |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Double stimuli responsive aggregates |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a ATRP |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Trzebicka, Barbara |4 aut | |
| 700 | 1 | |a Momekova, Denitsa |4 aut | |
| 700 | 1 | |a Petrov, Petar |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Polymer bulletin |d Berlin : Springer, 1978 |g 74(2016), 3 vom: 01. Juli, Seite 707-720 |w (DE-627)268761833 |w (DE-600)1473175-7 |x 1436-2449 |7 nnns |
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10.1007/s00289-016-1741-0 doi (DE-627)SPR003762866 (SPR)s00289-016-1741-0-e DE-627 ger DE-627 rakwb eng Kamenova, Katya verfasserin aut Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract Well defined ABA triblock copolymer comprising a biodegradable poly(ε-caprolactone) (PCL) middle block and two pH responsive poly(acrylic acid) (PAA) outer blocks was synthesized by atom transfer radical polymerization of tert-butyl acrylate, initiated by PCL-based macroinitiator, followed by selective hydrolysis of the poly(tert-butyl acrylate) blocks. The cooperative self-assembly of the synthesized poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) ($ PAA_{22} %$ PCL_{26} %$ PAA_{22} $) copolymer with a temperature-responsive poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) ($ PEO_{26} %$ PPO_{40} %$ PEO_{26} $, Pluronic P85) triblock copolymer at different compositions in aqueous media was investigated. Based on experimental data, copolymer properties and composition, formation of nano-sized aggregates comprising a mixed PCL/PPO core and a mixed PEO/PAA corona is suggested. The binary mixture of $ PAA_{22} %$ PCL_{26} %$ PAA_{22} $:$ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ copolymers at molar ratio 3:1 favors the formation of mixed aggregates only, while at higher $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ content the aggregates coexist with pure $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ micelles. Amphiphilic copolymers (dpeaa)DE-He213 Double stimuli responsive aggregates (dpeaa)DE-He213 ATRP (dpeaa)DE-He213 Trzebicka, Barbara aut Momekova, Denitsa aut Petrov, Petar aut Enthalten in Polymer bulletin Berlin : Springer, 1978 74(2016), 3 vom: 01. Juli, Seite 707-720 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:74 year:2016 number:3 day:01 month:07 pages:707-720 https://dx.doi.org/10.1007/s00289-016-1741-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 74 2016 3 01 07 707-720 |
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10.1007/s00289-016-1741-0 doi (DE-627)SPR003762866 (SPR)s00289-016-1741-0-e DE-627 ger DE-627 rakwb eng Kamenova, Katya verfasserin aut Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract Well defined ABA triblock copolymer comprising a biodegradable poly(ε-caprolactone) (PCL) middle block and two pH responsive poly(acrylic acid) (PAA) outer blocks was synthesized by atom transfer radical polymerization of tert-butyl acrylate, initiated by PCL-based macroinitiator, followed by selective hydrolysis of the poly(tert-butyl acrylate) blocks. The cooperative self-assembly of the synthesized poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) ($ PAA_{22} %$ PCL_{26} %$ PAA_{22} $) copolymer with a temperature-responsive poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) ($ PEO_{26} %$ PPO_{40} %$ PEO_{26} $, Pluronic P85) triblock copolymer at different compositions in aqueous media was investigated. Based on experimental data, copolymer properties and composition, formation of nano-sized aggregates comprising a mixed PCL/PPO core and a mixed PEO/PAA corona is suggested. The binary mixture of $ PAA_{22} %$ PCL_{26} %$ PAA_{22} $:$ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ copolymers at molar ratio 3:1 favors the formation of mixed aggregates only, while at higher $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ content the aggregates coexist with pure $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ micelles. Amphiphilic copolymers (dpeaa)DE-He213 Double stimuli responsive aggregates (dpeaa)DE-He213 ATRP (dpeaa)DE-He213 Trzebicka, Barbara aut Momekova, Denitsa aut Petrov, Petar aut Enthalten in Polymer bulletin Berlin : Springer, 1978 74(2016), 3 vom: 01. Juli, Seite 707-720 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:74 year:2016 number:3 day:01 month:07 pages:707-720 https://dx.doi.org/10.1007/s00289-016-1741-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 74 2016 3 01 07 707-720 |
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10.1007/s00289-016-1741-0 doi (DE-627)SPR003762866 (SPR)s00289-016-1741-0-e DE-627 ger DE-627 rakwb eng Kamenova, Katya verfasserin aut Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract Well defined ABA triblock copolymer comprising a biodegradable poly(ε-caprolactone) (PCL) middle block and two pH responsive poly(acrylic acid) (PAA) outer blocks was synthesized by atom transfer radical polymerization of tert-butyl acrylate, initiated by PCL-based macroinitiator, followed by selective hydrolysis of the poly(tert-butyl acrylate) blocks. The cooperative self-assembly of the synthesized poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) ($ PAA_{22} %$ PCL_{26} %$ PAA_{22} $) copolymer with a temperature-responsive poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) ($ PEO_{26} %$ PPO_{40} %$ PEO_{26} $, Pluronic P85) triblock copolymer at different compositions in aqueous media was investigated. Based on experimental data, copolymer properties and composition, formation of nano-sized aggregates comprising a mixed PCL/PPO core and a mixed PEO/PAA corona is suggested. The binary mixture of $ PAA_{22} %$ PCL_{26} %$ PAA_{22} $:$ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ copolymers at molar ratio 3:1 favors the formation of mixed aggregates only, while at higher $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ content the aggregates coexist with pure $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ micelles. Amphiphilic copolymers (dpeaa)DE-He213 Double stimuli responsive aggregates (dpeaa)DE-He213 ATRP (dpeaa)DE-He213 Trzebicka, Barbara aut Momekova, Denitsa aut Petrov, Petar aut Enthalten in Polymer bulletin Berlin : Springer, 1978 74(2016), 3 vom: 01. Juli, Seite 707-720 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:74 year:2016 number:3 day:01 month:07 pages:707-720 https://dx.doi.org/10.1007/s00289-016-1741-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 74 2016 3 01 07 707-720 |
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10.1007/s00289-016-1741-0 doi (DE-627)SPR003762866 (SPR)s00289-016-1741-0-e DE-627 ger DE-627 rakwb eng Kamenova, Katya verfasserin aut Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract Well defined ABA triblock copolymer comprising a biodegradable poly(ε-caprolactone) (PCL) middle block and two pH responsive poly(acrylic acid) (PAA) outer blocks was synthesized by atom transfer radical polymerization of tert-butyl acrylate, initiated by PCL-based macroinitiator, followed by selective hydrolysis of the poly(tert-butyl acrylate) blocks. The cooperative self-assembly of the synthesized poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) ($ PAA_{22} %$ PCL_{26} %$ PAA_{22} $) copolymer with a temperature-responsive poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) ($ PEO_{26} %$ PPO_{40} %$ PEO_{26} $, Pluronic P85) triblock copolymer at different compositions in aqueous media was investigated. Based on experimental data, copolymer properties and composition, formation of nano-sized aggregates comprising a mixed PCL/PPO core and a mixed PEO/PAA corona is suggested. The binary mixture of $ PAA_{22} %$ PCL_{26} %$ PAA_{22} $:$ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ copolymers at molar ratio 3:1 favors the formation of mixed aggregates only, while at higher $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ content the aggregates coexist with pure $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ micelles. Amphiphilic copolymers (dpeaa)DE-He213 Double stimuli responsive aggregates (dpeaa)DE-He213 ATRP (dpeaa)DE-He213 Trzebicka, Barbara aut Momekova, Denitsa aut Petrov, Petar aut Enthalten in Polymer bulletin Berlin : Springer, 1978 74(2016), 3 vom: 01. Juli, Seite 707-720 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:74 year:2016 number:3 day:01 month:07 pages:707-720 https://dx.doi.org/10.1007/s00289-016-1741-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 74 2016 3 01 07 707-720 |
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10.1007/s00289-016-1741-0 doi (DE-627)SPR003762866 (SPR)s00289-016-1741-0-e DE-627 ger DE-627 rakwb eng Kamenova, Katya verfasserin aut Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract Well defined ABA triblock copolymer comprising a biodegradable poly(ε-caprolactone) (PCL) middle block and two pH responsive poly(acrylic acid) (PAA) outer blocks was synthesized by atom transfer radical polymerization of tert-butyl acrylate, initiated by PCL-based macroinitiator, followed by selective hydrolysis of the poly(tert-butyl acrylate) blocks. The cooperative self-assembly of the synthesized poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) ($ PAA_{22} %$ PCL_{26} %$ PAA_{22} $) copolymer with a temperature-responsive poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) ($ PEO_{26} %$ PPO_{40} %$ PEO_{26} $, Pluronic P85) triblock copolymer at different compositions in aqueous media was investigated. Based on experimental data, copolymer properties and composition, formation of nano-sized aggregates comprising a mixed PCL/PPO core and a mixed PEO/PAA corona is suggested. The binary mixture of $ PAA_{22} %$ PCL_{26} %$ PAA_{22} $:$ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ copolymers at molar ratio 3:1 favors the formation of mixed aggregates only, while at higher $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ content the aggregates coexist with pure $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ micelles. Amphiphilic copolymers (dpeaa)DE-He213 Double stimuli responsive aggregates (dpeaa)DE-He213 ATRP (dpeaa)DE-He213 Trzebicka, Barbara aut Momekova, Denitsa aut Petrov, Petar aut Enthalten in Polymer bulletin Berlin : Springer, 1978 74(2016), 3 vom: 01. Juli, Seite 707-720 (DE-627)268761833 (DE-600)1473175-7 1436-2449 nnns volume:74 year:2016 number:3 day:01 month:07 pages:707-720 https://dx.doi.org/10.1007/s00289-016-1741-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 74 2016 3 01 07 707-720 |
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Enthalten in Polymer bulletin 74(2016), 3 vom: 01. Juli, Seite 707-720 volume:74 year:2016 number:3 day:01 month:07 pages:707-720 |
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Kamenova, Katya @@aut@@ Trzebicka, Barbara @@aut@@ Momekova, Denitsa @@aut@@ Petrov, Petar @@aut@@ |
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The cooperative self-assembly of the synthesized poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) ($ PAA_{22} %$ PCL_{26} %$ PAA_{22} $) copolymer with a temperature-responsive poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) ($ PEO_{26} %$ PPO_{40} %$ PEO_{26} $, Pluronic P85) triblock copolymer at different compositions in aqueous media was investigated. Based on experimental data, copolymer properties and composition, formation of nano-sized aggregates comprising a mixed PCL/PPO core and a mixed PEO/PAA corona is suggested. 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Kamenova, Katya |
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Kamenova, Katya misc Amphiphilic copolymers misc Double stimuli responsive aggregates misc ATRP Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers |
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Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers Amphiphilic copolymers (dpeaa)DE-He213 Double stimuli responsive aggregates (dpeaa)DE-He213 ATRP (dpeaa)DE-He213 |
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Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers |
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Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers |
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double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers |
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Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers |
| abstract |
Abstract Well defined ABA triblock copolymer comprising a biodegradable poly(ε-caprolactone) (PCL) middle block and two pH responsive poly(acrylic acid) (PAA) outer blocks was synthesized by atom transfer radical polymerization of tert-butyl acrylate, initiated by PCL-based macroinitiator, followed by selective hydrolysis of the poly(tert-butyl acrylate) blocks. The cooperative self-assembly of the synthesized poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) ($ PAA_{22} %$ PCL_{26} %$ PAA_{22} $) copolymer with a temperature-responsive poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) ($ PEO_{26} %$ PPO_{40} %$ PEO_{26} $, Pluronic P85) triblock copolymer at different compositions in aqueous media was investigated. Based on experimental data, copolymer properties and composition, formation of nano-sized aggregates comprising a mixed PCL/PPO core and a mixed PEO/PAA corona is suggested. The binary mixture of $ PAA_{22} %$ PCL_{26} %$ PAA_{22} $:$ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ copolymers at molar ratio 3:1 favors the formation of mixed aggregates only, while at higher $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ content the aggregates coexist with pure $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ micelles. © Springer-Verlag Berlin Heidelberg 2016 |
| abstractGer |
Abstract Well defined ABA triblock copolymer comprising a biodegradable poly(ε-caprolactone) (PCL) middle block and two pH responsive poly(acrylic acid) (PAA) outer blocks was synthesized by atom transfer radical polymerization of tert-butyl acrylate, initiated by PCL-based macroinitiator, followed by selective hydrolysis of the poly(tert-butyl acrylate) blocks. The cooperative self-assembly of the synthesized poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) ($ PAA_{22} %$ PCL_{26} %$ PAA_{22} $) copolymer with a temperature-responsive poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) ($ PEO_{26} %$ PPO_{40} %$ PEO_{26} $, Pluronic P85) triblock copolymer at different compositions in aqueous media was investigated. Based on experimental data, copolymer properties and composition, formation of nano-sized aggregates comprising a mixed PCL/PPO core and a mixed PEO/PAA corona is suggested. The binary mixture of $ PAA_{22} %$ PCL_{26} %$ PAA_{22} $:$ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ copolymers at molar ratio 3:1 favors the formation of mixed aggregates only, while at higher $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ content the aggregates coexist with pure $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ micelles. © Springer-Verlag Berlin Heidelberg 2016 |
| abstract_unstemmed |
Abstract Well defined ABA triblock copolymer comprising a biodegradable poly(ε-caprolactone) (PCL) middle block and two pH responsive poly(acrylic acid) (PAA) outer blocks was synthesized by atom transfer radical polymerization of tert-butyl acrylate, initiated by PCL-based macroinitiator, followed by selective hydrolysis of the poly(tert-butyl acrylate) blocks. The cooperative self-assembly of the synthesized poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) ($ PAA_{22} %$ PCL_{26} %$ PAA_{22} $) copolymer with a temperature-responsive poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) ($ PEO_{26} %$ PPO_{40} %$ PEO_{26} $, Pluronic P85) triblock copolymer at different compositions in aqueous media was investigated. Based on experimental data, copolymer properties and composition, formation of nano-sized aggregates comprising a mixed PCL/PPO core and a mixed PEO/PAA corona is suggested. The binary mixture of $ PAA_{22} %$ PCL_{26} %$ PAA_{22} $:$ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ copolymers at molar ratio 3:1 favors the formation of mixed aggregates only, while at higher $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ content the aggregates coexist with pure $ PEO_{26} %$ PPO_{40} %$ PEO_{26} $ micelles. © Springer-Verlag Berlin Heidelberg 2016 |
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3 |
| title_short |
Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers |
| url |
https://dx.doi.org/10.1007/s00289-016-1741-0 |
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| author2 |
Trzebicka, Barbara Momekova, Denitsa Petrov, Petar |
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Trzebicka, Barbara Momekova, Denitsa Petrov, Petar |
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| doi_str |
10.1007/s00289-016-1741-0 |
| up_date |
2024-07-03T21:30:53.620Z |
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| score |
7.4006367 |