Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $
Abstract The experiments show that the alloying liquid In with only (0.1–0.5) at% Ti dramatically reduces the equilibrium contact angle Θ∞ formed by In on the surface of $ CaF_{2} $. The aim of this paper is to clarify whether this practically important and conceptually challenging effect can be exp...
Ausführliche Beschreibung
Autor*in: |
Glickman, E. [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2011 |
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Schlagwörter: |
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Anmerkung: |
© Springer-Verlag 2011 |
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Übergeordnetes Werk: |
Enthalten in: Applied physics - Berlin : Springer, 1973, 106(2011), 1 vom: 28. Aug., Seite 181-189 |
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Übergeordnetes Werk: |
volume:106 ; year:2011 ; number:1 ; day:28 ; month:08 ; pages:181-189 |
Links: |
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DOI / URN: |
10.1007/s00339-011-6546-2 |
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Katalog-ID: |
SPR004123336 |
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520 | |a Abstract The experiments show that the alloying liquid In with only (0.1–0.5) at% Ti dramatically reduces the equilibrium contact angle Θ∞ formed by In on the surface of $ CaF_{2} $. The aim of this paper is to clarify whether this practically important and conceptually challenging effect can be explained solely by Ti adsorption at the F-terminated solid–liquid interface without resorting to any other Ti-induced effect. The combination of ab initio calculations and regular solution approximation was proposed for finding the binding energy, ΔETi of Ti adatom with the interface “$ CaF_{2} $/liquid solutions In–Ti.” With thus obtained ΔETi=1.16 eV, we calculated from the Shishkovsky isotherm the reduction in the solid–liquid interface energy, ΔγSL induced by Ti adsorption from liquid In with various Ti concentration, C. It was found that ΔγSL(C) dependence demonstrated close inverse correspondence with Θ∞(C) and that the theory fitted very well all available experimental data on the concentration and temperature dependence of ΔγSL. It was concluded that the Ti adsorption effect is large enough to account for the observed wetting improvement. The proposed multiscale modeling approach to the role of adsorption in wetting can be applied also to other nonreactive systems “liquid metal–ceramics” where the substrate determines the surface density of the adsorption sites for the active element. | ||
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700 | 1 | |a Frage, N. |4 aut | |
700 | 1 | |a Barzilai, S. |4 aut | |
700 | 1 | |a Froumin, N. |4 aut | |
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10.1007/s00339-011-6546-2 doi (DE-627)SPR004123336 (SPR)s00339-011-6546-2-e DE-627 ger DE-627 rakwb eng Glickman, E. verfasserin aut Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $ 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2011 Abstract The experiments show that the alloying liquid In with only (0.1–0.5) at% Ti dramatically reduces the equilibrium contact angle Θ∞ formed by In on the surface of $ CaF_{2} $. The aim of this paper is to clarify whether this practically important and conceptually challenging effect can be explained solely by Ti adsorption at the F-terminated solid–liquid interface without resorting to any other Ti-induced effect. The combination of ab initio calculations and regular solution approximation was proposed for finding the binding energy, ΔETi of Ti adatom with the interface “$ CaF_{2} $/liquid solutions In–Ti.” With thus obtained ΔETi=1.16 eV, we calculated from the Shishkovsky isotherm the reduction in the solid–liquid interface energy, ΔγSL induced by Ti adsorption from liquid In with various Ti concentration, C. It was found that ΔγSL(C) dependence demonstrated close inverse correspondence with Θ∞(C) and that the theory fitted very well all available experimental data on the concentration and temperature dependence of ΔγSL. It was concluded that the Ti adsorption effect is large enough to account for the observed wetting improvement. The proposed multiscale modeling approach to the role of adsorption in wetting can be applied also to other nonreactive systems “liquid metal–ceramics” where the substrate determines the surface density of the adsorption sites for the active element. Triple Line (dpeaa)DE-He213 Equilibrium Contact Angle (dpeaa)DE-He213 Regular Solution Approximation (dpeaa)DE-He213 Multiscale Modeling Approach (dpeaa)DE-He213 Equilibrium Surface Coverage (dpeaa)DE-He213 Fuks, D. aut Frage, N. aut Barzilai, S. aut Froumin, N. aut Enthalten in Applied physics Berlin : Springer, 1973 106(2011), 1 vom: 28. Aug., Seite 181-189 (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:106 year:2011 number:1 day:28 month:08 pages:181-189 https://dx.doi.org/10.1007/s00339-011-6546-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 106 2011 1 28 08 181-189 |
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10.1007/s00339-011-6546-2 doi (DE-627)SPR004123336 (SPR)s00339-011-6546-2-e DE-627 ger DE-627 rakwb eng Glickman, E. verfasserin aut Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $ 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2011 Abstract The experiments show that the alloying liquid In with only (0.1–0.5) at% Ti dramatically reduces the equilibrium contact angle Θ∞ formed by In on the surface of $ CaF_{2} $. The aim of this paper is to clarify whether this practically important and conceptually challenging effect can be explained solely by Ti adsorption at the F-terminated solid–liquid interface without resorting to any other Ti-induced effect. The combination of ab initio calculations and regular solution approximation was proposed for finding the binding energy, ΔETi of Ti adatom with the interface “$ CaF_{2} $/liquid solutions In–Ti.” With thus obtained ΔETi=1.16 eV, we calculated from the Shishkovsky isotherm the reduction in the solid–liquid interface energy, ΔγSL induced by Ti adsorption from liquid In with various Ti concentration, C. It was found that ΔγSL(C) dependence demonstrated close inverse correspondence with Θ∞(C) and that the theory fitted very well all available experimental data on the concentration and temperature dependence of ΔγSL. It was concluded that the Ti adsorption effect is large enough to account for the observed wetting improvement. The proposed multiscale modeling approach to the role of adsorption in wetting can be applied also to other nonreactive systems “liquid metal–ceramics” where the substrate determines the surface density of the adsorption sites for the active element. Triple Line (dpeaa)DE-He213 Equilibrium Contact Angle (dpeaa)DE-He213 Regular Solution Approximation (dpeaa)DE-He213 Multiscale Modeling Approach (dpeaa)DE-He213 Equilibrium Surface Coverage (dpeaa)DE-He213 Fuks, D. aut Frage, N. aut Barzilai, S. aut Froumin, N. aut Enthalten in Applied physics Berlin : Springer, 1973 106(2011), 1 vom: 28. Aug., Seite 181-189 (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:106 year:2011 number:1 day:28 month:08 pages:181-189 https://dx.doi.org/10.1007/s00339-011-6546-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 106 2011 1 28 08 181-189 |
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10.1007/s00339-011-6546-2 doi (DE-627)SPR004123336 (SPR)s00339-011-6546-2-e DE-627 ger DE-627 rakwb eng Glickman, E. verfasserin aut Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $ 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2011 Abstract The experiments show that the alloying liquid In with only (0.1–0.5) at% Ti dramatically reduces the equilibrium contact angle Θ∞ formed by In on the surface of $ CaF_{2} $. The aim of this paper is to clarify whether this practically important and conceptually challenging effect can be explained solely by Ti adsorption at the F-terminated solid–liquid interface without resorting to any other Ti-induced effect. The combination of ab initio calculations and regular solution approximation was proposed for finding the binding energy, ΔETi of Ti adatom with the interface “$ CaF_{2} $/liquid solutions In–Ti.” With thus obtained ΔETi=1.16 eV, we calculated from the Shishkovsky isotherm the reduction in the solid–liquid interface energy, ΔγSL induced by Ti adsorption from liquid In with various Ti concentration, C. It was found that ΔγSL(C) dependence demonstrated close inverse correspondence with Θ∞(C) and that the theory fitted very well all available experimental data on the concentration and temperature dependence of ΔγSL. It was concluded that the Ti adsorption effect is large enough to account for the observed wetting improvement. The proposed multiscale modeling approach to the role of adsorption in wetting can be applied also to other nonreactive systems “liquid metal–ceramics” where the substrate determines the surface density of the adsorption sites for the active element. Triple Line (dpeaa)DE-He213 Equilibrium Contact Angle (dpeaa)DE-He213 Regular Solution Approximation (dpeaa)DE-He213 Multiscale Modeling Approach (dpeaa)DE-He213 Equilibrium Surface Coverage (dpeaa)DE-He213 Fuks, D. aut Frage, N. aut Barzilai, S. aut Froumin, N. aut Enthalten in Applied physics Berlin : Springer, 1973 106(2011), 1 vom: 28. Aug., Seite 181-189 (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:106 year:2011 number:1 day:28 month:08 pages:181-189 https://dx.doi.org/10.1007/s00339-011-6546-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 106 2011 1 28 08 181-189 |
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10.1007/s00339-011-6546-2 doi (DE-627)SPR004123336 (SPR)s00339-011-6546-2-e DE-627 ger DE-627 rakwb eng Glickman, E. verfasserin aut Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $ 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2011 Abstract The experiments show that the alloying liquid In with only (0.1–0.5) at% Ti dramatically reduces the equilibrium contact angle Θ∞ formed by In on the surface of $ CaF_{2} $. The aim of this paper is to clarify whether this practically important and conceptually challenging effect can be explained solely by Ti adsorption at the F-terminated solid–liquid interface without resorting to any other Ti-induced effect. The combination of ab initio calculations and regular solution approximation was proposed for finding the binding energy, ΔETi of Ti adatom with the interface “$ CaF_{2} $/liquid solutions In–Ti.” With thus obtained ΔETi=1.16 eV, we calculated from the Shishkovsky isotherm the reduction in the solid–liquid interface energy, ΔγSL induced by Ti adsorption from liquid In with various Ti concentration, C. It was found that ΔγSL(C) dependence demonstrated close inverse correspondence with Θ∞(C) and that the theory fitted very well all available experimental data on the concentration and temperature dependence of ΔγSL. It was concluded that the Ti adsorption effect is large enough to account for the observed wetting improvement. The proposed multiscale modeling approach to the role of adsorption in wetting can be applied also to other nonreactive systems “liquid metal–ceramics” where the substrate determines the surface density of the adsorption sites for the active element. Triple Line (dpeaa)DE-He213 Equilibrium Contact Angle (dpeaa)DE-He213 Regular Solution Approximation (dpeaa)DE-He213 Multiscale Modeling Approach (dpeaa)DE-He213 Equilibrium Surface Coverage (dpeaa)DE-He213 Fuks, D. aut Frage, N. aut Barzilai, S. aut Froumin, N. aut Enthalten in Applied physics Berlin : Springer, 1973 106(2011), 1 vom: 28. Aug., Seite 181-189 (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:106 year:2011 number:1 day:28 month:08 pages:181-189 https://dx.doi.org/10.1007/s00339-011-6546-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 106 2011 1 28 08 181-189 |
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10.1007/s00339-011-6546-2 doi (DE-627)SPR004123336 (SPR)s00339-011-6546-2-e DE-627 ger DE-627 rakwb eng Glickman, E. verfasserin aut Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $ 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2011 Abstract The experiments show that the alloying liquid In with only (0.1–0.5) at% Ti dramatically reduces the equilibrium contact angle Θ∞ formed by In on the surface of $ CaF_{2} $. The aim of this paper is to clarify whether this practically important and conceptually challenging effect can be explained solely by Ti adsorption at the F-terminated solid–liquid interface without resorting to any other Ti-induced effect. The combination of ab initio calculations and regular solution approximation was proposed for finding the binding energy, ΔETi of Ti adatom with the interface “$ CaF_{2} $/liquid solutions In–Ti.” With thus obtained ΔETi=1.16 eV, we calculated from the Shishkovsky isotherm the reduction in the solid–liquid interface energy, ΔγSL induced by Ti adsorption from liquid In with various Ti concentration, C. It was found that ΔγSL(C) dependence demonstrated close inverse correspondence with Θ∞(C) and that the theory fitted very well all available experimental data on the concentration and temperature dependence of ΔγSL. It was concluded that the Ti adsorption effect is large enough to account for the observed wetting improvement. The proposed multiscale modeling approach to the role of adsorption in wetting can be applied also to other nonreactive systems “liquid metal–ceramics” where the substrate determines the surface density of the adsorption sites for the active element. Triple Line (dpeaa)DE-He213 Equilibrium Contact Angle (dpeaa)DE-He213 Regular Solution Approximation (dpeaa)DE-He213 Multiscale Modeling Approach (dpeaa)DE-He213 Equilibrium Surface Coverage (dpeaa)DE-He213 Fuks, D. aut Frage, N. aut Barzilai, S. aut Froumin, N. aut Enthalten in Applied physics Berlin : Springer, 1973 106(2011), 1 vom: 28. Aug., Seite 181-189 (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:106 year:2011 number:1 day:28 month:08 pages:181-189 https://dx.doi.org/10.1007/s00339-011-6546-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 106 2011 1 28 08 181-189 |
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Enthalten in Applied physics 106(2011), 1 vom: 28. Aug., Seite 181-189 volume:106 year:2011 number:1 day:28 month:08 pages:181-189 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR004123336</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230328161538.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201001s2011 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s00339-011-6546-2</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR004123336</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s00339-011-6546-2-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Glickman, E.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2011</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer-Verlag 2011</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The experiments show that the alloying liquid In with only (0.1–0.5) at% Ti dramatically reduces the equilibrium contact angle Θ∞ formed by In on the surface of $ CaF_{2} $. The aim of this paper is to clarify whether this practically important and conceptually challenging effect can be explained solely by Ti adsorption at the F-terminated solid–liquid interface without resorting to any other Ti-induced effect. The combination of ab initio calculations and regular solution approximation was proposed for finding the binding energy, ΔETi of Ti adatom with the interface “$ CaF_{2} $/liquid solutions In–Ti.” With thus obtained ΔETi=1.16 eV, we calculated from the Shishkovsky isotherm the reduction in the solid–liquid interface energy, ΔγSL induced by Ti adsorption from liquid In with various Ti concentration, C. It was found that ΔγSL(C) dependence demonstrated close inverse correspondence with Θ∞(C) and that the theory fitted very well all available experimental data on the concentration and temperature dependence of ΔγSL. It was concluded that the Ti adsorption effect is large enough to account for the observed wetting improvement. The proposed multiscale modeling approach to the role of adsorption in wetting can be applied also to other nonreactive systems “liquid metal–ceramics” where the substrate determines the surface density of the adsorption sites for the active element.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Triple Line</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Equilibrium Contact Angle</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Regular Solution Approximation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Multiscale Modeling Approach</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Equilibrium Surface Coverage</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Fuks, D.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Frage, N.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Barzilai, S.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Froumin, N.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Applied physics</subfield><subfield code="d">Berlin : Springer, 1973</subfield><subfield code="g">106(2011), 1 vom: 28. 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Glickman, E. |
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Glickman, E. misc Triple Line misc Equilibrium Contact Angle misc Regular Solution Approximation misc Multiscale Modeling Approach misc Equilibrium Surface Coverage Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $ |
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Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $ Triple Line (dpeaa)DE-He213 Equilibrium Contact Angle (dpeaa)DE-He213 Regular Solution Approximation (dpeaa)DE-He213 Multiscale Modeling Approach (dpeaa)DE-He213 Equilibrium Surface Coverage (dpeaa)DE-He213 |
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Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $ |
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adsorption effect in non-reaction wetting: in–ti on $ caf_{2} $ |
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Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $ |
abstract |
Abstract The experiments show that the alloying liquid In with only (0.1–0.5) at% Ti dramatically reduces the equilibrium contact angle Θ∞ formed by In on the surface of $ CaF_{2} $. The aim of this paper is to clarify whether this practically important and conceptually challenging effect can be explained solely by Ti adsorption at the F-terminated solid–liquid interface without resorting to any other Ti-induced effect. The combination of ab initio calculations and regular solution approximation was proposed for finding the binding energy, ΔETi of Ti adatom with the interface “$ CaF_{2} $/liquid solutions In–Ti.” With thus obtained ΔETi=1.16 eV, we calculated from the Shishkovsky isotherm the reduction in the solid–liquid interface energy, ΔγSL induced by Ti adsorption from liquid In with various Ti concentration, C. It was found that ΔγSL(C) dependence demonstrated close inverse correspondence with Θ∞(C) and that the theory fitted very well all available experimental data on the concentration and temperature dependence of ΔγSL. It was concluded that the Ti adsorption effect is large enough to account for the observed wetting improvement. The proposed multiscale modeling approach to the role of adsorption in wetting can be applied also to other nonreactive systems “liquid metal–ceramics” where the substrate determines the surface density of the adsorption sites for the active element. © Springer-Verlag 2011 |
abstractGer |
Abstract The experiments show that the alloying liquid In with only (0.1–0.5) at% Ti dramatically reduces the equilibrium contact angle Θ∞ formed by In on the surface of $ CaF_{2} $. The aim of this paper is to clarify whether this practically important and conceptually challenging effect can be explained solely by Ti adsorption at the F-terminated solid–liquid interface without resorting to any other Ti-induced effect. The combination of ab initio calculations and regular solution approximation was proposed for finding the binding energy, ΔETi of Ti adatom with the interface “$ CaF_{2} $/liquid solutions In–Ti.” With thus obtained ΔETi=1.16 eV, we calculated from the Shishkovsky isotherm the reduction in the solid–liquid interface energy, ΔγSL induced by Ti adsorption from liquid In with various Ti concentration, C. It was found that ΔγSL(C) dependence demonstrated close inverse correspondence with Θ∞(C) and that the theory fitted very well all available experimental data on the concentration and temperature dependence of ΔγSL. It was concluded that the Ti adsorption effect is large enough to account for the observed wetting improvement. The proposed multiscale modeling approach to the role of adsorption in wetting can be applied also to other nonreactive systems “liquid metal–ceramics” where the substrate determines the surface density of the adsorption sites for the active element. © Springer-Verlag 2011 |
abstract_unstemmed |
Abstract The experiments show that the alloying liquid In with only (0.1–0.5) at% Ti dramatically reduces the equilibrium contact angle Θ∞ formed by In on the surface of $ CaF_{2} $. The aim of this paper is to clarify whether this practically important and conceptually challenging effect can be explained solely by Ti adsorption at the F-terminated solid–liquid interface without resorting to any other Ti-induced effect. The combination of ab initio calculations and regular solution approximation was proposed for finding the binding energy, ΔETi of Ti adatom with the interface “$ CaF_{2} $/liquid solutions In–Ti.” With thus obtained ΔETi=1.16 eV, we calculated from the Shishkovsky isotherm the reduction in the solid–liquid interface energy, ΔγSL induced by Ti adsorption from liquid In with various Ti concentration, C. It was found that ΔγSL(C) dependence demonstrated close inverse correspondence with Θ∞(C) and that the theory fitted very well all available experimental data on the concentration and temperature dependence of ΔγSL. It was concluded that the Ti adsorption effect is large enough to account for the observed wetting improvement. The proposed multiscale modeling approach to the role of adsorption in wetting can be applied also to other nonreactive systems “liquid metal–ceramics” where the substrate determines the surface density of the adsorption sites for the active element. © Springer-Verlag 2011 |
collection_details |
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container_issue |
1 |
title_short |
Adsorption effect in non-reaction wetting: In–Ti on $ CaF_{2} $ |
url |
https://dx.doi.org/10.1007/s00339-011-6546-2 |
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author2 |
Fuks, D. Frage, N. Barzilai, S. Froumin, N. |
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Fuks, D. Frage, N. Barzilai, S. Froumin, N. |
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doi_str |
10.1007/s00339-011-6546-2 |
up_date |
2024-07-03T23:43:36.526Z |
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|
score |
7.398695 |