Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions

Abstract Polypyrrole–polycaprolactone (PPy-PCL) composites were synthesized by emulsion polymerization to improve their mechanical and electrical properties by forming conducting polymer composites and hence enhance the electrorheological (ER) response. Various PPy-PCL composite particles were synth...
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Gespeichert in:

Autor*in:	Kim, Young Dae [verfasserIn] Kim, Jun Ho [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2007

Schlagwörter:	Electrorheology Conducting polymer composite Conducting polymer Suspension Polypyrrole

Übergeordnetes Werk:	Enthalten in: Colloid & polymer science - Berlin : Springer, 1906, 286(2007), 6-7 vom: 03. Dez., Seite 631-637
Übergeordnetes Werk:	volume:286 ; year:2007 ; number:6-7 ; day:03 ; month:12 ; pages:631-637

Links:	Volltext

DOI / URN:	10.1007/s00396-007-1802-x

Katalog-ID:	SPR004928628

Internformat


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520			\|a Abstract Polypyrrole–polycaprolactone (PPy-PCL) composites were synthesized by emulsion polymerization to improve their mechanical and electrical properties by forming conducting polymer composites and hence enhance the electrorheological (ER) response. Various PPy-PCL composite particles were synthesized by controlling the amount of PCL. The ER response increased with increasing electric field strength and particle volume fraction. A power-law dependence, τ = KφmEn, showed a good fit to the yield stresses when m = 2 and n = 1.5. The dependence of E1.5 is consistent with the conduction model and the dependence of φ2 appears to be related to structural changes with the electric field, which leads to many-body interactions between the particles. The ER response also increased with increasing amount of PCL, but the dielectric properties and dc conductivities of the PPy-PCL composite particles and the dielectric properties of the PPy-PCL composite suspensions were not consistent with the ER behavior. However, the particle diameter increased with the increasing amount of PCL, which is consistent with the ER behavior. The ER behavior of various amounts of PCL fits τ = 85.12d4E3/2 quite well. The proportionality of d4 appears to be due to the many-body interactions between the particles.
650		4	\|a Electrorheology \|7 (dpeaa)DE-He213
650		4	\|a Conducting polymer composite \|7 (dpeaa)DE-He213
650		4	\|a Conducting polymer \|7 (dpeaa)DE-He213
650		4	\|a Suspension \|7 (dpeaa)DE-He213
650		4	\|a Polypyrrole \|7 (dpeaa)DE-He213
700	1		\|a Kim, Jun Ho \|e verfasserin \|4 aut
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912			\|a GBV_ILN_187
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912			\|a GBV_ILN_250
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912			\|a GBV_ILN_285
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912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2009
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matchkey_str	article:14351536:2007----::yteioplproeoyarlcoeopstsymlinoyeiainntelcrrel
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allfields	10.1007/s00396-007-1802-x doi (DE-627)SPR004928628 (SPR)s00396-007-1802-x-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Kim, Young Dae verfasserin aut Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Polypyrrole–polycaprolactone (PPy-PCL) composites were synthesized by emulsion polymerization to improve their mechanical and electrical properties by forming conducting polymer composites and hence enhance the electrorheological (ER) response. Various PPy-PCL composite particles were synthesized by controlling the amount of PCL. The ER response increased with increasing electric field strength and particle volume fraction. A power-law dependence, τ = KφmEn, showed a good fit to the yield stresses when m = 2 and n = 1.5. The dependence of E1.5 is consistent with the conduction model and the dependence of φ2 appears to be related to structural changes with the electric field, which leads to many-body interactions between the particles. The ER response also increased with increasing amount of PCL, but the dielectric properties and dc conductivities of the PPy-PCL composite particles and the dielectric properties of the PPy-PCL composite suspensions were not consistent with the ER behavior. However, the particle diameter increased with the increasing amount of PCL, which is consistent with the ER behavior. The ER behavior of various amounts of PCL fits τ = 85.12d4E3/2 quite well. The proportionality of d4 appears to be due to the many-body interactions between the particles. Electrorheology (dpeaa)DE-He213 Conducting polymer composite (dpeaa)DE-He213 Conducting polymer (dpeaa)DE-He213 Suspension (dpeaa)DE-He213 Polypyrrole (dpeaa)DE-He213 Kim, Jun Ho verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 286(2007), 6-7 vom: 03. Dez., Seite 631-637 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:286 year:2007 number:6-7 day:03 month:12 pages:631-637 https://dx.doi.org/10.1007/s00396-007-1802-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 286 2007 6-7 03 12 631-637
spelling	10.1007/s00396-007-1802-x doi (DE-627)SPR004928628 (SPR)s00396-007-1802-x-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Kim, Young Dae verfasserin aut Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Polypyrrole–polycaprolactone (PPy-PCL) composites were synthesized by emulsion polymerization to improve their mechanical and electrical properties by forming conducting polymer composites and hence enhance the electrorheological (ER) response. Various PPy-PCL composite particles were synthesized by controlling the amount of PCL. The ER response increased with increasing electric field strength and particle volume fraction. A power-law dependence, τ = KφmEn, showed a good fit to the yield stresses when m = 2 and n = 1.5. The dependence of E1.5 is consistent with the conduction model and the dependence of φ2 appears to be related to structural changes with the electric field, which leads to many-body interactions between the particles. The ER response also increased with increasing amount of PCL, but the dielectric properties and dc conductivities of the PPy-PCL composite particles and the dielectric properties of the PPy-PCL composite suspensions were not consistent with the ER behavior. However, the particle diameter increased with the increasing amount of PCL, which is consistent with the ER behavior. The ER behavior of various amounts of PCL fits τ = 85.12d4E3/2 quite well. The proportionality of d4 appears to be due to the many-body interactions between the particles. Electrorheology (dpeaa)DE-He213 Conducting polymer composite (dpeaa)DE-He213 Conducting polymer (dpeaa)DE-He213 Suspension (dpeaa)DE-He213 Polypyrrole (dpeaa)DE-He213 Kim, Jun Ho verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 286(2007), 6-7 vom: 03. Dez., Seite 631-637 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:286 year:2007 number:6-7 day:03 month:12 pages:631-637 https://dx.doi.org/10.1007/s00396-007-1802-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 286 2007 6-7 03 12 631-637
allfields_unstemmed	10.1007/s00396-007-1802-x doi (DE-627)SPR004928628 (SPR)s00396-007-1802-x-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Kim, Young Dae verfasserin aut Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Polypyrrole–polycaprolactone (PPy-PCL) composites were synthesized by emulsion polymerization to improve their mechanical and electrical properties by forming conducting polymer composites and hence enhance the electrorheological (ER) response. Various PPy-PCL composite particles were synthesized by controlling the amount of PCL. The ER response increased with increasing electric field strength and particle volume fraction. A power-law dependence, τ = KφmEn, showed a good fit to the yield stresses when m = 2 and n = 1.5. The dependence of E1.5 is consistent with the conduction model and the dependence of φ2 appears to be related to structural changes with the electric field, which leads to many-body interactions between the particles. The ER response also increased with increasing amount of PCL, but the dielectric properties and dc conductivities of the PPy-PCL composite particles and the dielectric properties of the PPy-PCL composite suspensions were not consistent with the ER behavior. However, the particle diameter increased with the increasing amount of PCL, which is consistent with the ER behavior. The ER behavior of various amounts of PCL fits τ = 85.12d4E3/2 quite well. The proportionality of d4 appears to be due to the many-body interactions between the particles. Electrorheology (dpeaa)DE-He213 Conducting polymer composite (dpeaa)DE-He213 Conducting polymer (dpeaa)DE-He213 Suspension (dpeaa)DE-He213 Polypyrrole (dpeaa)DE-He213 Kim, Jun Ho verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 286(2007), 6-7 vom: 03. Dez., Seite 631-637 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:286 year:2007 number:6-7 day:03 month:12 pages:631-637 https://dx.doi.org/10.1007/s00396-007-1802-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 286 2007 6-7 03 12 631-637
allfieldsGer	10.1007/s00396-007-1802-x doi (DE-627)SPR004928628 (SPR)s00396-007-1802-x-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Kim, Young Dae verfasserin aut Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Polypyrrole–polycaprolactone (PPy-PCL) composites were synthesized by emulsion polymerization to improve their mechanical and electrical properties by forming conducting polymer composites and hence enhance the electrorheological (ER) response. Various PPy-PCL composite particles were synthesized by controlling the amount of PCL. The ER response increased with increasing electric field strength and particle volume fraction. A power-law dependence, τ = KφmEn, showed a good fit to the yield stresses when m = 2 and n = 1.5. The dependence of E1.5 is consistent with the conduction model and the dependence of φ2 appears to be related to structural changes with the electric field, which leads to many-body interactions between the particles. The ER response also increased with increasing amount of PCL, but the dielectric properties and dc conductivities of the PPy-PCL composite particles and the dielectric properties of the PPy-PCL composite suspensions were not consistent with the ER behavior. However, the particle diameter increased with the increasing amount of PCL, which is consistent with the ER behavior. The ER behavior of various amounts of PCL fits τ = 85.12d4E3/2 quite well. The proportionality of d4 appears to be due to the many-body interactions between the particles. Electrorheology (dpeaa)DE-He213 Conducting polymer composite (dpeaa)DE-He213 Conducting polymer (dpeaa)DE-He213 Suspension (dpeaa)DE-He213 Polypyrrole (dpeaa)DE-He213 Kim, Jun Ho verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 286(2007), 6-7 vom: 03. Dez., Seite 631-637 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:286 year:2007 number:6-7 day:03 month:12 pages:631-637 https://dx.doi.org/10.1007/s00396-007-1802-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 286 2007 6-7 03 12 631-637
allfieldsSound	10.1007/s00396-007-1802-x doi (DE-627)SPR004928628 (SPR)s00396-007-1802-x-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Kim, Young Dae verfasserin aut Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Polypyrrole–polycaprolactone (PPy-PCL) composites were synthesized by emulsion polymerization to improve their mechanical and electrical properties by forming conducting polymer composites and hence enhance the electrorheological (ER) response. Various PPy-PCL composite particles were synthesized by controlling the amount of PCL. The ER response increased with increasing electric field strength and particle volume fraction. A power-law dependence, τ = KφmEn, showed a good fit to the yield stresses when m = 2 and n = 1.5. The dependence of E1.5 is consistent with the conduction model and the dependence of φ2 appears to be related to structural changes with the electric field, which leads to many-body interactions between the particles. The ER response also increased with increasing amount of PCL, but the dielectric properties and dc conductivities of the PPy-PCL composite particles and the dielectric properties of the PPy-PCL composite suspensions were not consistent with the ER behavior. However, the particle diameter increased with the increasing amount of PCL, which is consistent with the ER behavior. The ER behavior of various amounts of PCL fits τ = 85.12d4E3/2 quite well. The proportionality of d4 appears to be due to the many-body interactions between the particles. Electrorheology (dpeaa)DE-He213 Conducting polymer composite (dpeaa)DE-He213 Conducting polymer (dpeaa)DE-He213 Suspension (dpeaa)DE-He213 Polypyrrole (dpeaa)DE-He213 Kim, Jun Ho verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 286(2007), 6-7 vom: 03. Dez., Seite 631-637 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:286 year:2007 number:6-7 day:03 month:12 pages:631-637 https://dx.doi.org/10.1007/s00396-007-1802-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 286 2007 6-7 03 12 631-637
language	English
source	Enthalten in Colloid & polymer science 286(2007), 6-7 vom: 03. Dez., Seite 631-637 volume:286 year:2007 number:6-7 day:03 month:12 pages:631-637
sourceStr	Enthalten in Colloid & polymer science 286(2007), 6-7 vom: 03. Dez., Seite 631-637 volume:286 year:2007 number:6-7 day:03 month:12 pages:631-637
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Electrorheology Conducting polymer composite Conducting polymer Suspension Polypyrrole
dewey-raw	540
isfreeaccess_bool	false
container_title	Colloid & polymer science
authorswithroles_txt_mv	Kim, Young Dae @@aut@@ Kim, Jun Ho @@aut@@
publishDateDaySort_date	2007-12-03T00:00:00Z
hierarchy_top_id	254629849
dewey-sort	3540
id	SPR004928628
language_de	englisch
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author	Kim, Young Dae
spellingShingle	Kim, Young Dae ddc 540 bkl 35.18 misc Electrorheology misc Conducting polymer composite misc Conducting polymer misc Suspension misc Polypyrrole Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions
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topic_title	540 ASE 35.18 bkl Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions Electrorheology (dpeaa)DE-He213 Conducting polymer composite (dpeaa)DE-He213 Conducting polymer (dpeaa)DE-He213 Suspension (dpeaa)DE-He213 Polypyrrole (dpeaa)DE-He213
topic	ddc 540 bkl 35.18 misc Electrorheology misc Conducting polymer composite misc Conducting polymer misc Suspension misc Polypyrrole
topic_unstemmed	ddc 540 bkl 35.18 misc Electrorheology misc Conducting polymer composite misc Conducting polymer misc Suspension misc Polypyrrole
topic_browse	ddc 540 bkl 35.18 misc Electrorheology misc Conducting polymer composite misc Conducting polymer misc Suspension misc Polypyrrole
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title	Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions
ctrlnum	(DE-627)SPR004928628 (SPR)s00396-007-1802-x-e
title_full	Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions
author_sort	Kim, Young Dae
journal	Colloid & polymer science
journalStr	Colloid & polymer science
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author_browse	Kim, Young Dae Kim, Jun Ho
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title_sort	synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions
title_auth	Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions
abstract	Abstract Polypyrrole–polycaprolactone (PPy-PCL) composites were synthesized by emulsion polymerization to improve their mechanical and electrical properties by forming conducting polymer composites and hence enhance the electrorheological (ER) response. Various PPy-PCL composite particles were synthesized by controlling the amount of PCL. The ER response increased with increasing electric field strength and particle volume fraction. A power-law dependence, τ = KφmEn, showed a good fit to the yield stresses when m = 2 and n = 1.5. The dependence of E1.5 is consistent with the conduction model and the dependence of φ2 appears to be related to structural changes with the electric field, which leads to many-body interactions between the particles. The ER response also increased with increasing amount of PCL, but the dielectric properties and dc conductivities of the PPy-PCL composite particles and the dielectric properties of the PPy-PCL composite suspensions were not consistent with the ER behavior. However, the particle diameter increased with the increasing amount of PCL, which is consistent with the ER behavior. The ER behavior of various amounts of PCL fits τ = 85.12d4E3/2 quite well. The proportionality of d4 appears to be due to the many-body interactions between the particles.
abstractGer	Abstract Polypyrrole–polycaprolactone (PPy-PCL) composites were synthesized by emulsion polymerization to improve their mechanical and electrical properties by forming conducting polymer composites and hence enhance the electrorheological (ER) response. Various PPy-PCL composite particles were synthesized by controlling the amount of PCL. The ER response increased with increasing electric field strength and particle volume fraction. A power-law dependence, τ = KφmEn, showed a good fit to the yield stresses when m = 2 and n = 1.5. The dependence of E1.5 is consistent with the conduction model and the dependence of φ2 appears to be related to structural changes with the electric field, which leads to many-body interactions between the particles. The ER response also increased with increasing amount of PCL, but the dielectric properties and dc conductivities of the PPy-PCL composite particles and the dielectric properties of the PPy-PCL composite suspensions were not consistent with the ER behavior. However, the particle diameter increased with the increasing amount of PCL, which is consistent with the ER behavior. The ER behavior of various amounts of PCL fits τ = 85.12d4E3/2 quite well. The proportionality of d4 appears to be due to the many-body interactions between the particles.
abstract_unstemmed	Abstract Polypyrrole–polycaprolactone (PPy-PCL) composites were synthesized by emulsion polymerization to improve their mechanical and electrical properties by forming conducting polymer composites and hence enhance the electrorheological (ER) response. Various PPy-PCL composite particles were synthesized by controlling the amount of PCL. The ER response increased with increasing electric field strength and particle volume fraction. A power-law dependence, τ = KφmEn, showed a good fit to the yield stresses when m = 2 and n = 1.5. The dependence of E1.5 is consistent with the conduction model and the dependence of φ2 appears to be related to structural changes with the electric field, which leads to many-body interactions between the particles. The ER response also increased with increasing amount of PCL, but the dielectric properties and dc conductivities of the PPy-PCL composite particles and the dielectric properties of the PPy-PCL composite suspensions were not consistent with the ER behavior. However, the particle diameter increased with the increasing amount of PCL, which is consistent with the ER behavior. The ER behavior of various amounts of PCL fits τ = 85.12d4E3/2 quite well. The proportionality of d4 appears to be due to the many-body interactions between the particles.
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title_short	Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions
url	https://dx.doi.org/10.1007/s00396-007-1802-x
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doi_str	10.1007/s00396-007-1802-x
up_date	2024-07-04T03:04:24.384Z
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Various PPy-PCL composite particles were synthesized by controlling the amount of PCL. The ER response increased with increasing electric field strength and particle volume fraction. A power-law dependence, τ = KφmEn, showed a good fit to the yield stresses when m = 2 and n = 1.5. The dependence of E1.5 is consistent with the conduction model and the dependence of φ2 appears to be related to structural changes with the electric field, which leads to many-body interactions between the particles. The ER response also increased with increasing amount of PCL, but the dielectric properties and dc conductivities of the PPy-PCL composite particles and the dielectric properties of the PPy-PCL composite suspensions were not consistent with the ER behavior. However, the particle diameter increased with the increasing amount of PCL, which is consistent with the ER behavior. The ER behavior of various amounts of PCL fits τ = 85.12d4E3/2 quite well. 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Synthesis of polypyrrole–polycaprolactone composites by emulsion polymerization and the electrorheological behavior of their suspensions

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