Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide)
Abstract Some physical properties of high molecular weight linear poly(N-isopropylacrylamide)s (PNIPAM) having different isotacticities (m, meso dyad = 47, 62, 68, 81, and 88 %) have been studied. The solubility of these polymers in different solvents varied with their isotacticity. Thermal degradat...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Biswas, Chandra Sekhar [verfasserIn] Mitra, Kheyanath [verfasserIn] Singh, Shikha [verfasserIn] Ramesh, Kalyan [verfasserIn] Misra, Nira [verfasserIn] Maiti, Biswajit [verfasserIn] Panda, Amiya Kumar [verfasserIn] Maiti, Pralay [verfasserIn] Kamigaito, Masami [verfasserIn] Okamoto, Yoshio [verfasserIn] Ray, Biswajit [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Colloid & polymer science - Berlin : Springer, 1906, 293(2015), 6 vom: 24. März, Seite 1749-1757 |
|---|---|
| Übergeordnetes Werk: |
volume:293 ; year:2015 ; number:6 ; day:24 ; month:03 ; pages:1749-1757 |
| Links: |
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| DOI / URN: |
10.1007/s00396-015-3562-3 |
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| Katalog-ID: |
SPR00494805X |
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| 520 | |a Abstract Some physical properties of high molecular weight linear poly(N-isopropylacrylamide)s (PNIPAM) having different isotacticities (m, meso dyad = 47, 62, 68, 81, and 88 %) have been studied. The solubility of these polymers in different solvents varied with their isotacticity. Thermal degradation of higher isotactic polymer started slightly earlier. Cloud point of these polymers in water gradually decreased with increase in m up to 68 %. Surface tension of these polymers in N,N-dimethylformamide (DMF) was slightly lower than DMF and almost independent of their isotacticity in the temperature range of 20–60 °C. But it decreased linearly with the increase in temperature. Moreover, for all polymers, it decreased very slightly with the increase in their concentrations in the range of 0.001–0.01 % (w/v). Viscosity of these polymers in DMF increased with (i) the increase in the concentration range of 1–5 % (w/v), (ii) the increase in their m values, and (iii) the decrease in the temperature in the range of 20–60 oC. | ||
| 650 | 4 | |a Isotactic PNIPAM |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Solubility |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Thermogravimetry |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Powder XRD |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Cloud point |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Surface tension |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Viscosity |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Mitra, Kheyanath |e verfasserin |4 aut | |
| 700 | 1 | |a Singh, Shikha |e verfasserin |4 aut | |
| 700 | 1 | |a Ramesh, Kalyan |e verfasserin |4 aut | |
| 700 | 1 | |a Misra, Nira |e verfasserin |4 aut | |
| 700 | 1 | |a Maiti, Biswajit |e verfasserin |4 aut | |
| 700 | 1 | |a Panda, Amiya Kumar |e verfasserin |4 aut | |
| 700 | 1 | |a Maiti, Pralay |e verfasserin |4 aut | |
| 700 | 1 | |a Kamigaito, Masami |e verfasserin |4 aut | |
| 700 | 1 | |a Okamoto, Yoshio |e verfasserin |4 aut | |
| 700 | 1 | |a Ray, Biswajit |e verfasserin |4 aut | |
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10.1007/s00396-015-3562-3 doi (DE-627)SPR00494805X (SPR)s00396-015-3562-3-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Biswas, Chandra Sekhar verfasserin aut Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide) 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Some physical properties of high molecular weight linear poly(N-isopropylacrylamide)s (PNIPAM) having different isotacticities (m, meso dyad = 47, 62, 68, 81, and 88 %) have been studied. The solubility of these polymers in different solvents varied with their isotacticity. Thermal degradation of higher isotactic polymer started slightly earlier. Cloud point of these polymers in water gradually decreased with increase in m up to 68 %. Surface tension of these polymers in N,N-dimethylformamide (DMF) was slightly lower than DMF and almost independent of their isotacticity in the temperature range of 20–60 °C. But it decreased linearly with the increase in temperature. Moreover, for all polymers, it decreased very slightly with the increase in their concentrations in the range of 0.001–0.01 % (w/v). Viscosity of these polymers in DMF increased with (i) the increase in the concentration range of 1–5 % (w/v), (ii) the increase in their m values, and (iii) the decrease in the temperature in the range of 20–60 oC. Isotactic PNIPAM (dpeaa)DE-He213 Solubility (dpeaa)DE-He213 Thermogravimetry (dpeaa)DE-He213 Powder XRD (dpeaa)DE-He213 Cloud point (dpeaa)DE-He213 Surface tension (dpeaa)DE-He213 Viscosity (dpeaa)DE-He213 Mitra, Kheyanath verfasserin aut Singh, Shikha verfasserin aut Ramesh, Kalyan verfasserin aut Misra, Nira verfasserin aut Maiti, Biswajit verfasserin aut Panda, Amiya Kumar verfasserin aut Maiti, Pralay verfasserin aut Kamigaito, Masami verfasserin aut Okamoto, Yoshio verfasserin aut Ray, Biswajit verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 293(2015), 6 vom: 24. März, Seite 1749-1757 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:293 year:2015 number:6 day:24 month:03 pages:1749-1757 https://dx.doi.org/10.1007/s00396-015-3562-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 293 2015 6 24 03 1749-1757 |
| spelling |
10.1007/s00396-015-3562-3 doi (DE-627)SPR00494805X (SPR)s00396-015-3562-3-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Biswas, Chandra Sekhar verfasserin aut Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide) 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Some physical properties of high molecular weight linear poly(N-isopropylacrylamide)s (PNIPAM) having different isotacticities (m, meso dyad = 47, 62, 68, 81, and 88 %) have been studied. The solubility of these polymers in different solvents varied with their isotacticity. Thermal degradation of higher isotactic polymer started slightly earlier. Cloud point of these polymers in water gradually decreased with increase in m up to 68 %. Surface tension of these polymers in N,N-dimethylformamide (DMF) was slightly lower than DMF and almost independent of their isotacticity in the temperature range of 20–60 °C. But it decreased linearly with the increase in temperature. Moreover, for all polymers, it decreased very slightly with the increase in their concentrations in the range of 0.001–0.01 % (w/v). Viscosity of these polymers in DMF increased with (i) the increase in the concentration range of 1–5 % (w/v), (ii) the increase in their m values, and (iii) the decrease in the temperature in the range of 20–60 oC. Isotactic PNIPAM (dpeaa)DE-He213 Solubility (dpeaa)DE-He213 Thermogravimetry (dpeaa)DE-He213 Powder XRD (dpeaa)DE-He213 Cloud point (dpeaa)DE-He213 Surface tension (dpeaa)DE-He213 Viscosity (dpeaa)DE-He213 Mitra, Kheyanath verfasserin aut Singh, Shikha verfasserin aut Ramesh, Kalyan verfasserin aut Misra, Nira verfasserin aut Maiti, Biswajit verfasserin aut Panda, Amiya Kumar verfasserin aut Maiti, Pralay verfasserin aut Kamigaito, Masami verfasserin aut Okamoto, Yoshio verfasserin aut Ray, Biswajit verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 293(2015), 6 vom: 24. März, Seite 1749-1757 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:293 year:2015 number:6 day:24 month:03 pages:1749-1757 https://dx.doi.org/10.1007/s00396-015-3562-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 293 2015 6 24 03 1749-1757 |
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10.1007/s00396-015-3562-3 doi (DE-627)SPR00494805X (SPR)s00396-015-3562-3-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Biswas, Chandra Sekhar verfasserin aut Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide) 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Some physical properties of high molecular weight linear poly(N-isopropylacrylamide)s (PNIPAM) having different isotacticities (m, meso dyad = 47, 62, 68, 81, and 88 %) have been studied. The solubility of these polymers in different solvents varied with their isotacticity. Thermal degradation of higher isotactic polymer started slightly earlier. Cloud point of these polymers in water gradually decreased with increase in m up to 68 %. Surface tension of these polymers in N,N-dimethylformamide (DMF) was slightly lower than DMF and almost independent of their isotacticity in the temperature range of 20–60 °C. But it decreased linearly with the increase in temperature. Moreover, for all polymers, it decreased very slightly with the increase in their concentrations in the range of 0.001–0.01 % (w/v). Viscosity of these polymers in DMF increased with (i) the increase in the concentration range of 1–5 % (w/v), (ii) the increase in their m values, and (iii) the decrease in the temperature in the range of 20–60 oC. Isotactic PNIPAM (dpeaa)DE-He213 Solubility (dpeaa)DE-He213 Thermogravimetry (dpeaa)DE-He213 Powder XRD (dpeaa)DE-He213 Cloud point (dpeaa)DE-He213 Surface tension (dpeaa)DE-He213 Viscosity (dpeaa)DE-He213 Mitra, Kheyanath verfasserin aut Singh, Shikha verfasserin aut Ramesh, Kalyan verfasserin aut Misra, Nira verfasserin aut Maiti, Biswajit verfasserin aut Panda, Amiya Kumar verfasserin aut Maiti, Pralay verfasserin aut Kamigaito, Masami verfasserin aut Okamoto, Yoshio verfasserin aut Ray, Biswajit verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 293(2015), 6 vom: 24. März, Seite 1749-1757 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:293 year:2015 number:6 day:24 month:03 pages:1749-1757 https://dx.doi.org/10.1007/s00396-015-3562-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 293 2015 6 24 03 1749-1757 |
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10.1007/s00396-015-3562-3 doi (DE-627)SPR00494805X (SPR)s00396-015-3562-3-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Biswas, Chandra Sekhar verfasserin aut Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide) 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Some physical properties of high molecular weight linear poly(N-isopropylacrylamide)s (PNIPAM) having different isotacticities (m, meso dyad = 47, 62, 68, 81, and 88 %) have been studied. The solubility of these polymers in different solvents varied with their isotacticity. Thermal degradation of higher isotactic polymer started slightly earlier. Cloud point of these polymers in water gradually decreased with increase in m up to 68 %. Surface tension of these polymers in N,N-dimethylformamide (DMF) was slightly lower than DMF and almost independent of their isotacticity in the temperature range of 20–60 °C. But it decreased linearly with the increase in temperature. Moreover, for all polymers, it decreased very slightly with the increase in their concentrations in the range of 0.001–0.01 % (w/v). Viscosity of these polymers in DMF increased with (i) the increase in the concentration range of 1–5 % (w/v), (ii) the increase in their m values, and (iii) the decrease in the temperature in the range of 20–60 oC. Isotactic PNIPAM (dpeaa)DE-He213 Solubility (dpeaa)DE-He213 Thermogravimetry (dpeaa)DE-He213 Powder XRD (dpeaa)DE-He213 Cloud point (dpeaa)DE-He213 Surface tension (dpeaa)DE-He213 Viscosity (dpeaa)DE-He213 Mitra, Kheyanath verfasserin aut Singh, Shikha verfasserin aut Ramesh, Kalyan verfasserin aut Misra, Nira verfasserin aut Maiti, Biswajit verfasserin aut Panda, Amiya Kumar verfasserin aut Maiti, Pralay verfasserin aut Kamigaito, Masami verfasserin aut Okamoto, Yoshio verfasserin aut Ray, Biswajit verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 293(2015), 6 vom: 24. März, Seite 1749-1757 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:293 year:2015 number:6 day:24 month:03 pages:1749-1757 https://dx.doi.org/10.1007/s00396-015-3562-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 293 2015 6 24 03 1749-1757 |
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10.1007/s00396-015-3562-3 doi (DE-627)SPR00494805X (SPR)s00396-015-3562-3-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Biswas, Chandra Sekhar verfasserin aut Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide) 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Some physical properties of high molecular weight linear poly(N-isopropylacrylamide)s (PNIPAM) having different isotacticities (m, meso dyad = 47, 62, 68, 81, and 88 %) have been studied. The solubility of these polymers in different solvents varied with their isotacticity. Thermal degradation of higher isotactic polymer started slightly earlier. Cloud point of these polymers in water gradually decreased with increase in m up to 68 %. Surface tension of these polymers in N,N-dimethylformamide (DMF) was slightly lower than DMF and almost independent of their isotacticity in the temperature range of 20–60 °C. But it decreased linearly with the increase in temperature. Moreover, for all polymers, it decreased very slightly with the increase in their concentrations in the range of 0.001–0.01 % (w/v). Viscosity of these polymers in DMF increased with (i) the increase in the concentration range of 1–5 % (w/v), (ii) the increase in their m values, and (iii) the decrease in the temperature in the range of 20–60 oC. Isotactic PNIPAM (dpeaa)DE-He213 Solubility (dpeaa)DE-He213 Thermogravimetry (dpeaa)DE-He213 Powder XRD (dpeaa)DE-He213 Cloud point (dpeaa)DE-He213 Surface tension (dpeaa)DE-He213 Viscosity (dpeaa)DE-He213 Mitra, Kheyanath verfasserin aut Singh, Shikha verfasserin aut Ramesh, Kalyan verfasserin aut Misra, Nira verfasserin aut Maiti, Biswajit verfasserin aut Panda, Amiya Kumar verfasserin aut Maiti, Pralay verfasserin aut Kamigaito, Masami verfasserin aut Okamoto, Yoshio verfasserin aut Ray, Biswajit verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 293(2015), 6 vom: 24. März, Seite 1749-1757 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:293 year:2015 number:6 day:24 month:03 pages:1749-1757 https://dx.doi.org/10.1007/s00396-015-3562-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 293 2015 6 24 03 1749-1757 |
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Enthalten in Colloid & polymer science 293(2015), 6 vom: 24. März, Seite 1749-1757 volume:293 year:2015 number:6 day:24 month:03 pages:1749-1757 |
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Isotactic PNIPAM Solubility Thermogravimetry Powder XRD Cloud point Surface tension Viscosity |
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Biswas, Chandra Sekhar @@aut@@ Mitra, Kheyanath @@aut@@ Singh, Shikha @@aut@@ Ramesh, Kalyan @@aut@@ Misra, Nira @@aut@@ Maiti, Biswajit @@aut@@ Panda, Amiya Kumar @@aut@@ Maiti, Pralay @@aut@@ Kamigaito, Masami @@aut@@ Okamoto, Yoshio @@aut@@ Ray, Biswajit @@aut@@ |
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The solubility of these polymers in different solvents varied with their isotacticity. Thermal degradation of higher isotactic polymer started slightly earlier. Cloud point of these polymers in water gradually decreased with increase in m up to 68 %. Surface tension of these polymers in N,N-dimethylformamide (DMF) was slightly lower than DMF and almost independent of their isotacticity in the temperature range of 20–60 °C. But it decreased linearly with the increase in temperature. Moreover, for all polymers, it decreased very slightly with the increase in their concentrations in the range of 0.001–0.01 % (w/v). 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|
| author |
Biswas, Chandra Sekhar |
| spellingShingle |
Biswas, Chandra Sekhar ddc 540 bkl 35.18 misc Isotactic PNIPAM misc Solubility misc Thermogravimetry misc Powder XRD misc Cloud point misc Surface tension misc Viscosity Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide) |
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Biswas, Chandra Sekhar |
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electronic Article |
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540 - Chemistry & allied sciences |
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springer |
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Not Illustrated |
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1435-1536 |
| topic_title |
540 ASE 35.18 bkl Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide) Isotactic PNIPAM (dpeaa)DE-He213 Solubility (dpeaa)DE-He213 Thermogravimetry (dpeaa)DE-He213 Powder XRD (dpeaa)DE-He213 Cloud point (dpeaa)DE-He213 Surface tension (dpeaa)DE-He213 Viscosity (dpeaa)DE-He213 |
| topic |
ddc 540 bkl 35.18 misc Isotactic PNIPAM misc Solubility misc Thermogravimetry misc Powder XRD misc Cloud point misc Surface tension misc Viscosity |
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ddc 540 bkl 35.18 misc Isotactic PNIPAM misc Solubility misc Thermogravimetry misc Powder XRD misc Cloud point misc Surface tension misc Viscosity |
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ddc 540 bkl 35.18 misc Isotactic PNIPAM misc Solubility misc Thermogravimetry misc Powder XRD misc Cloud point misc Surface tension misc Viscosity |
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Elektronische Aufsätze Aufsätze Elektronische Ressource |
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Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide) |
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Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide) |
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Biswas, Chandra Sekhar |
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Colloid & polymer science |
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Colloid & polymer science |
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Biswas, Chandra Sekhar Mitra, Kheyanath Singh, Shikha Ramesh, Kalyan Misra, Nira Maiti, Biswajit Panda, Amiya Kumar Maiti, Pralay Kamigaito, Masami Okamoto, Yoshio Ray, Biswajit |
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10.1007/s00396-015-3562-3 |
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study of the effect of isotacticity on some physical properties of poly(n-isopropylacrylamide) |
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Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide) |
| abstract |
Abstract Some physical properties of high molecular weight linear poly(N-isopropylacrylamide)s (PNIPAM) having different isotacticities (m, meso dyad = 47, 62, 68, 81, and 88 %) have been studied. The solubility of these polymers in different solvents varied with their isotacticity. Thermal degradation of higher isotactic polymer started slightly earlier. Cloud point of these polymers in water gradually decreased with increase in m up to 68 %. Surface tension of these polymers in N,N-dimethylformamide (DMF) was slightly lower than DMF and almost independent of their isotacticity in the temperature range of 20–60 °C. But it decreased linearly with the increase in temperature. Moreover, for all polymers, it decreased very slightly with the increase in their concentrations in the range of 0.001–0.01 % (w/v). Viscosity of these polymers in DMF increased with (i) the increase in the concentration range of 1–5 % (w/v), (ii) the increase in their m values, and (iii) the decrease in the temperature in the range of 20–60 oC. |
| abstractGer |
Abstract Some physical properties of high molecular weight linear poly(N-isopropylacrylamide)s (PNIPAM) having different isotacticities (m, meso dyad = 47, 62, 68, 81, and 88 %) have been studied. The solubility of these polymers in different solvents varied with their isotacticity. Thermal degradation of higher isotactic polymer started slightly earlier. Cloud point of these polymers in water gradually decreased with increase in m up to 68 %. Surface tension of these polymers in N,N-dimethylformamide (DMF) was slightly lower than DMF and almost independent of their isotacticity in the temperature range of 20–60 °C. But it decreased linearly with the increase in temperature. Moreover, for all polymers, it decreased very slightly with the increase in their concentrations in the range of 0.001–0.01 % (w/v). Viscosity of these polymers in DMF increased with (i) the increase in the concentration range of 1–5 % (w/v), (ii) the increase in their m values, and (iii) the decrease in the temperature in the range of 20–60 oC. |
| abstract_unstemmed |
Abstract Some physical properties of high molecular weight linear poly(N-isopropylacrylamide)s (PNIPAM) having different isotacticities (m, meso dyad = 47, 62, 68, 81, and 88 %) have been studied. The solubility of these polymers in different solvents varied with their isotacticity. Thermal degradation of higher isotactic polymer started slightly earlier. Cloud point of these polymers in water gradually decreased with increase in m up to 68 %. Surface tension of these polymers in N,N-dimethylformamide (DMF) was slightly lower than DMF and almost independent of their isotacticity in the temperature range of 20–60 °C. But it decreased linearly with the increase in temperature. Moreover, for all polymers, it decreased very slightly with the increase in their concentrations in the range of 0.001–0.01 % (w/v). Viscosity of these polymers in DMF increased with (i) the increase in the concentration range of 1–5 % (w/v), (ii) the increase in their m values, and (iii) the decrease in the temperature in the range of 20–60 oC. |
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Study of the effect of isotacticity on some physical properties of poly(N-isopropylacrylamide) |
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Mitra, Kheyanath Singh, Shikha Ramesh, Kalyan Misra, Nira Maiti, Biswajit Panda, Amiya Kumar Maiti, Pralay Kamigaito, Masami Okamoto, Yoshio Ray, Biswajit |
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| score |
7.3998175 |