Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid
Abstract The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of $ C_{tr} $ was defined...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Grigoreva, Alexandra [verfasserIn] Polozov, Egor [verfasserIn] Zaitsev, Sergey [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Colloid & polymer science - Berlin : Springer, 1906, 297(2019), 11-12 vom: 13. Sept., Seite 1423-1435 |
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| Übergeordnetes Werk: |
volume:297 ; year:2019 ; number:11-12 ; day:13 ; month:09 ; pages:1423-1435 |
| Links: |
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| DOI / URN: |
10.1007/s00396-019-04559-6 |
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| Katalog-ID: |
SPR00495677X |
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| 245 | 1 | 0 | |a Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid |
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| 520 | |a Abstract The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of $ C_{tr} $ was defined using the size-exclusion chromatography measurements. Copolymers of acrylic acid and OFPA with different microstructure were synthesized by three methods: block copolymerization, copolymerization of acrylic acid and OFPA, and chemical modification of copolymer of tert-butyl acrylate and OFPA. Copolymerization of abovementioned monomer pairs was studied. The reactivity ratios were calculated by using the Fineman–Ross and Kelen–Tudos models, as well as the method of least squares. Aggregation behavior of the obtained amphiphilic copolymers at the air/water interface was defined by the Langmuir monolayer technique. Monomolecular films of amphiphilic copolymers were studied using atomic force microscopy. The effect of the chain microstructure, the acrylic acid content in the copolymer, and subphase pH on the isotherm curves were shown. Graphical abstract | ||
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| 650 | 4 | |a Fluorinated poly(meth)acrylate |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Amphiphiles |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Copolymers |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Self-assembly |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Polozov, Egor |e verfasserin |4 aut | |
| 700 | 1 | |a Zaitsev, Sergey |e verfasserin |4 aut | |
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10.1007/s00396-019-04559-6 doi (DE-627)SPR00495677X (SPR)s00396-019-04559-6-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Grigoreva, Alexandra verfasserin aut Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of $ C_{tr} $ was defined using the size-exclusion chromatography measurements. Copolymers of acrylic acid and OFPA with different microstructure were synthesized by three methods: block copolymerization, copolymerization of acrylic acid and OFPA, and chemical modification of copolymer of tert-butyl acrylate and OFPA. Copolymerization of abovementioned monomer pairs was studied. The reactivity ratios were calculated by using the Fineman–Ross and Kelen–Tudos models, as well as the method of least squares. Aggregation behavior of the obtained amphiphilic copolymers at the air/water interface was defined by the Langmuir monolayer technique. Monomolecular films of amphiphilic copolymers were studied using atomic force microscopy. The effect of the chain microstructure, the acrylic acid content in the copolymer, and subphase pH on the isotherm curves were shown. Graphical abstract RAFT polymerization (dpeaa)DE-He213 Fluorinated poly(meth)acrylate (dpeaa)DE-He213 Amphiphiles (dpeaa)DE-He213 Copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 Polozov, Egor verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 297(2019), 11-12 vom: 13. Sept., Seite 1423-1435 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:297 year:2019 number:11-12 day:13 month:09 pages:1423-1435 https://dx.doi.org/10.1007/s00396-019-04559-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 297 2019 11-12 13 09 1423-1435 |
| spelling |
10.1007/s00396-019-04559-6 doi (DE-627)SPR00495677X (SPR)s00396-019-04559-6-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Grigoreva, Alexandra verfasserin aut Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of $ C_{tr} $ was defined using the size-exclusion chromatography measurements. Copolymers of acrylic acid and OFPA with different microstructure were synthesized by three methods: block copolymerization, copolymerization of acrylic acid and OFPA, and chemical modification of copolymer of tert-butyl acrylate and OFPA. Copolymerization of abovementioned monomer pairs was studied. The reactivity ratios were calculated by using the Fineman–Ross and Kelen–Tudos models, as well as the method of least squares. Aggregation behavior of the obtained amphiphilic copolymers at the air/water interface was defined by the Langmuir monolayer technique. Monomolecular films of amphiphilic copolymers were studied using atomic force microscopy. The effect of the chain microstructure, the acrylic acid content in the copolymer, and subphase pH on the isotherm curves were shown. Graphical abstract RAFT polymerization (dpeaa)DE-He213 Fluorinated poly(meth)acrylate (dpeaa)DE-He213 Amphiphiles (dpeaa)DE-He213 Copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 Polozov, Egor verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 297(2019), 11-12 vom: 13. Sept., Seite 1423-1435 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:297 year:2019 number:11-12 day:13 month:09 pages:1423-1435 https://dx.doi.org/10.1007/s00396-019-04559-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 297 2019 11-12 13 09 1423-1435 |
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10.1007/s00396-019-04559-6 doi (DE-627)SPR00495677X (SPR)s00396-019-04559-6-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Grigoreva, Alexandra verfasserin aut Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of $ C_{tr} $ was defined using the size-exclusion chromatography measurements. Copolymers of acrylic acid and OFPA with different microstructure were synthesized by three methods: block copolymerization, copolymerization of acrylic acid and OFPA, and chemical modification of copolymer of tert-butyl acrylate and OFPA. Copolymerization of abovementioned monomer pairs was studied. The reactivity ratios were calculated by using the Fineman–Ross and Kelen–Tudos models, as well as the method of least squares. Aggregation behavior of the obtained amphiphilic copolymers at the air/water interface was defined by the Langmuir monolayer technique. Monomolecular films of amphiphilic copolymers were studied using atomic force microscopy. The effect of the chain microstructure, the acrylic acid content in the copolymer, and subphase pH on the isotherm curves were shown. Graphical abstract RAFT polymerization (dpeaa)DE-He213 Fluorinated poly(meth)acrylate (dpeaa)DE-He213 Amphiphiles (dpeaa)DE-He213 Copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 Polozov, Egor verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 297(2019), 11-12 vom: 13. Sept., Seite 1423-1435 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:297 year:2019 number:11-12 day:13 month:09 pages:1423-1435 https://dx.doi.org/10.1007/s00396-019-04559-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 297 2019 11-12 13 09 1423-1435 |
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10.1007/s00396-019-04559-6 doi (DE-627)SPR00495677X (SPR)s00396-019-04559-6-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Grigoreva, Alexandra verfasserin aut Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of $ C_{tr} $ was defined using the size-exclusion chromatography measurements. Copolymers of acrylic acid and OFPA with different microstructure were synthesized by three methods: block copolymerization, copolymerization of acrylic acid and OFPA, and chemical modification of copolymer of tert-butyl acrylate and OFPA. Copolymerization of abovementioned monomer pairs was studied. The reactivity ratios were calculated by using the Fineman–Ross and Kelen–Tudos models, as well as the method of least squares. Aggregation behavior of the obtained amphiphilic copolymers at the air/water interface was defined by the Langmuir monolayer technique. Monomolecular films of amphiphilic copolymers were studied using atomic force microscopy. The effect of the chain microstructure, the acrylic acid content in the copolymer, and subphase pH on the isotherm curves were shown. Graphical abstract RAFT polymerization (dpeaa)DE-He213 Fluorinated poly(meth)acrylate (dpeaa)DE-He213 Amphiphiles (dpeaa)DE-He213 Copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 Polozov, Egor verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 297(2019), 11-12 vom: 13. Sept., Seite 1423-1435 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:297 year:2019 number:11-12 day:13 month:09 pages:1423-1435 https://dx.doi.org/10.1007/s00396-019-04559-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 297 2019 11-12 13 09 1423-1435 |
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10.1007/s00396-019-04559-6 doi (DE-627)SPR00495677X (SPR)s00396-019-04559-6-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Grigoreva, Alexandra verfasserin aut Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of $ C_{tr} $ was defined using the size-exclusion chromatography measurements. Copolymers of acrylic acid and OFPA with different microstructure were synthesized by three methods: block copolymerization, copolymerization of acrylic acid and OFPA, and chemical modification of copolymer of tert-butyl acrylate and OFPA. Copolymerization of abovementioned monomer pairs was studied. The reactivity ratios were calculated by using the Fineman–Ross and Kelen–Tudos models, as well as the method of least squares. Aggregation behavior of the obtained amphiphilic copolymers at the air/water interface was defined by the Langmuir monolayer technique. Monomolecular films of amphiphilic copolymers were studied using atomic force microscopy. The effect of the chain microstructure, the acrylic acid content in the copolymer, and subphase pH on the isotherm curves were shown. Graphical abstract RAFT polymerization (dpeaa)DE-He213 Fluorinated poly(meth)acrylate (dpeaa)DE-He213 Amphiphiles (dpeaa)DE-He213 Copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 Polozov, Egor verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 297(2019), 11-12 vom: 13. Sept., Seite 1423-1435 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:297 year:2019 number:11-12 day:13 month:09 pages:1423-1435 https://dx.doi.org/10.1007/s00396-019-04559-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 297 2019 11-12 13 09 1423-1435 |
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Enthalten in Colloid & polymer science 297(2019), 11-12 vom: 13. Sept., Seite 1423-1435 volume:297 year:2019 number:11-12 day:13 month:09 pages:1423-1435 |
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Enthalten in Colloid & polymer science 297(2019), 11-12 vom: 13. Sept., Seite 1423-1435 volume:297 year:2019 number:11-12 day:13 month:09 pages:1423-1435 |
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RAFT polymerization Fluorinated poly(meth)acrylate Amphiphiles Copolymers Self-assembly |
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Grigoreva, Alexandra @@aut@@ Polozov, Egor @@aut@@ Zaitsev, Sergey @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR00495677X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519154135.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201001s2019 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s00396-019-04559-6</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR00495677X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s00396-019-04559-6-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.18</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Grigoreva, Alexandra</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of $ C_{tr} $ was defined using the size-exclusion chromatography measurements. Copolymers of acrylic acid and OFPA with different microstructure were synthesized by three methods: block copolymerization, copolymerization of acrylic acid and OFPA, and chemical modification of copolymer of tert-butyl acrylate and OFPA. Copolymerization of abovementioned monomer pairs was studied. The reactivity ratios were calculated by using the Fineman–Ross and Kelen–Tudos models, as well as the method of least squares. Aggregation behavior of the obtained amphiphilic copolymers at the air/water interface was defined by the Langmuir monolayer technique. Monomolecular films of amphiphilic copolymers were studied using atomic force microscopy. The effect of the chain microstructure, the acrylic acid content in the copolymer, and subphase pH on the isotherm curves were shown. 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|
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Grigoreva, Alexandra |
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Grigoreva, Alexandra ddc 540 bkl 35.18 misc RAFT polymerization misc Fluorinated poly(meth)acrylate misc Amphiphiles misc Copolymers misc Self-assembly Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid |
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540 ASE 35.18 bkl Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid RAFT polymerization (dpeaa)DE-He213 Fluorinated poly(meth)acrylate (dpeaa)DE-He213 Amphiphiles (dpeaa)DE-He213 Copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 |
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ddc 540 bkl 35.18 misc RAFT polymerization misc Fluorinated poly(meth)acrylate misc Amphiphiles misc Copolymers misc Self-assembly |
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ddc 540 bkl 35.18 misc RAFT polymerization misc Fluorinated poly(meth)acrylate misc Amphiphiles misc Copolymers misc Self-assembly |
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ddc 540 bkl 35.18 misc RAFT polymerization misc Fluorinated poly(meth)acrylate misc Amphiphiles misc Copolymers misc Self-assembly |
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Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid |
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(DE-627)SPR00495677X (SPR)s00396-019-04559-6-e |
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Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid |
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Grigoreva, Alexandra |
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Grigoreva, Alexandra Polozov, Egor Zaitsev, Sergey |
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Elektronische Aufsätze |
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Grigoreva, Alexandra |
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10.1007/s00396-019-04559-6 |
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verfasserin |
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controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid |
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Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid |
| abstract |
Abstract The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of $ C_{tr} $ was defined using the size-exclusion chromatography measurements. Copolymers of acrylic acid and OFPA with different microstructure were synthesized by three methods: block copolymerization, copolymerization of acrylic acid and OFPA, and chemical modification of copolymer of tert-butyl acrylate and OFPA. Copolymerization of abovementioned monomer pairs was studied. The reactivity ratios were calculated by using the Fineman–Ross and Kelen–Tudos models, as well as the method of least squares. Aggregation behavior of the obtained amphiphilic copolymers at the air/water interface was defined by the Langmuir monolayer technique. Monomolecular films of amphiphilic copolymers were studied using atomic force microscopy. The effect of the chain microstructure, the acrylic acid content in the copolymer, and subphase pH on the isotherm curves were shown. Graphical abstract |
| abstractGer |
Abstract The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of $ C_{tr} $ was defined using the size-exclusion chromatography measurements. Copolymers of acrylic acid and OFPA with different microstructure were synthesized by three methods: block copolymerization, copolymerization of acrylic acid and OFPA, and chemical modification of copolymer of tert-butyl acrylate and OFPA. Copolymerization of abovementioned monomer pairs was studied. The reactivity ratios were calculated by using the Fineman–Ross and Kelen–Tudos models, as well as the method of least squares. Aggregation behavior of the obtained amphiphilic copolymers at the air/water interface was defined by the Langmuir monolayer technique. Monomolecular films of amphiphilic copolymers were studied using atomic force microscopy. The effect of the chain microstructure, the acrylic acid content in the copolymer, and subphase pH on the isotherm curves were shown. Graphical abstract |
| abstract_unstemmed |
Abstract The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of $ C_{tr} $ was defined using the size-exclusion chromatography measurements. Copolymers of acrylic acid and OFPA with different microstructure were synthesized by three methods: block copolymerization, copolymerization of acrylic acid and OFPA, and chemical modification of copolymer of tert-butyl acrylate and OFPA. Copolymerization of abovementioned monomer pairs was studied. The reactivity ratios were calculated by using the Fineman–Ross and Kelen–Tudos models, as well as the method of least squares. Aggregation behavior of the obtained amphiphilic copolymers at the air/water interface was defined by the Langmuir monolayer technique. Monomolecular films of amphiphilic copolymers were studied using atomic force microscopy. The effect of the chain microstructure, the acrylic acid content in the copolymer, and subphase pH on the isotherm curves were shown. Graphical abstract |
| collection_details |
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| container_issue |
11-12 |
| title_short |
Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid |
| url |
https://dx.doi.org/10.1007/s00396-019-04559-6 |
| remote_bool |
true |
| author2 |
Polozov, Egor Zaitsev, Sergey |
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Polozov, Egor Zaitsev, Sergey |
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| doi_str |
10.1007/s00396-019-04559-6 |
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2024-07-04T03:10:39.646Z |
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1803616402439929856 |
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| score |
7.3986635 |