Rare earth element fractionation in magmatic Ca-rich garnets

Abstract Igneous garnets have the potential to strongly fractionate rare earth elements (REE). Yet informations on partition coefficients are very scant, and criteria for distinguishing between hydrothermal and magmatic garnets are ambiguous. To fill this gap, we present trace element and isotopic d...
Ausführliche Beschreibung

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Autor*in:	Scheibner, Birgit [verfasserIn] Wörner, Gerhard Civetta, Lucia Stosch, Heinz-Günter Simon, Klaus Kronz, Andreas

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2007

Schlagwörter:	Grandite Ca-rich garnets Andradite Rare earth elements Mt. Somma-Vesuvius Fractionation Partition coefficient Skarn Hydrothermal Magma chamber Phonolite

Anmerkung:	© Springer-Verlag 2007

Übergeordnetes Werk:	Enthalten in: Contributions to mineralogy and petrology - Berlin : Springer, 1947, 154(2007), 1 vom: 23. Feb., Seite 55-74
Übergeordnetes Werk:	volume:154 ; year:2007 ; number:1 ; day:23 ; month:02 ; pages:55-74

Links:	Volltext

DOI / URN:	10.1007/s00410-006-0179-z

Katalog-ID:	SPR005246350

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245	1	0	\|a Rare earth element fractionation in magmatic Ca-rich garnets
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520			\|a Abstract Igneous garnets have the potential to strongly fractionate rare earth elements (REE). Yet informations on partition coefficients are very scant, and criteria for distinguishing between hydrothermal and magmatic garnets are ambiguous. To fill this gap, we present trace element and isotopic data for two types of Ca-rich garnets from phonolites (Mt. Somma-Vesuvius). Both Ca-garnet populations are different in their style and dynamics of fractionation: one population is progressively strongly depleted in HREE from core to rim, reflecting REE fractionation in the host phonolite via earlier-crystallized garnets. Such examples for extreme changes in HREE in garnets are only known for hydrothermal grandites by REE-bearing fluids. The second garnet population is homogeneous and formed in a closed system. Near-flat patterns between Sm and Lu confirm experimental data indicating lower D(Sm)/D(Lu) for Ca-rich garnets than for e.g. pyrope-rich garnets. It follows: DGrt/PhMelt for La = 0.5, Sm = 48 and Yb = 110.
650		4	\|a Grandite \|7 (dpeaa)DE-He213
650		4	\|a Ca-rich garnets \|7 (dpeaa)DE-He213
650		4	\|a Andradite \|7 (dpeaa)DE-He213
650		4	\|a Rare earth elements \|7 (dpeaa)DE-He213
650		4	\|a Mt. Somma-Vesuvius \|7 (dpeaa)DE-He213
650		4	\|a Fractionation \|7 (dpeaa)DE-He213
650		4	\|a Partition coefficient \|7 (dpeaa)DE-He213
650		4	\|a Skarn \|7 (dpeaa)DE-He213
650		4	\|a Hydrothermal \|7 (dpeaa)DE-He213
650		4	\|a Magma chamber \|7 (dpeaa)DE-He213
650		4	\|a Phonolite \|7 (dpeaa)DE-He213
700	1		\|a Wörner, Gerhard \|4 aut
700	1		\|a Civetta, Lucia \|4 aut
700	1		\|a Stosch, Heinz-Günter \|4 aut
700	1		\|a Simon, Klaus \|4 aut
700	1		\|a Kronz, Andreas \|4 aut
773	0	8	\|i Enthalten in \|t Contributions to mineralogy and petrology \|d Berlin : Springer, 1947 \|g 154(2007), 1 vom: 23. Feb., Seite 55-74 \|w (DE-627)25372208X \|w (DE-600)1458979-5 \|x 1432-0967 \|7 nnns
773	1	8	\|g volume:154 \|g year:2007 \|g number:1 \|g day:23 \|g month:02 \|g pages:55-74
856	4	0	\|u https://dx.doi.org/10.1007/s00410-006-0179-z \|z lizenzpflichtig \|3 Volltext
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912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_206
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_267
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_381
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
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912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
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912			\|a GBV_ILN_2031
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912			\|a GBV_ILN_2037
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912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
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912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
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952			\|d 154 \|j 2007 \|e 1 \|b 23 \|c 02 \|h 55-74

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publishDate	2007
allfields	10.1007/s00410-006-0179-z doi (DE-627)SPR005246350 (SPR)s00410-006-0179-z-e DE-627 ger DE-627 rakwb eng Scheibner, Birgit verfasserin aut Rare earth element fractionation in magmatic Ca-rich garnets 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2007 Abstract Igneous garnets have the potential to strongly fractionate rare earth elements (REE). Yet informations on partition coefficients are very scant, and criteria for distinguishing between hydrothermal and magmatic garnets are ambiguous. To fill this gap, we present trace element and isotopic data for two types of Ca-rich garnets from phonolites (Mt. Somma-Vesuvius). Both Ca-garnet populations are different in their style and dynamics of fractionation: one population is progressively strongly depleted in HREE from core to rim, reflecting REE fractionation in the host phonolite via earlier-crystallized garnets. Such examples for extreme changes in HREE in garnets are only known for hydrothermal grandites by REE-bearing fluids. The second garnet population is homogeneous and formed in a closed system. Near-flat patterns between Sm and Lu confirm experimental data indicating lower D(Sm)/D(Lu) for Ca-rich garnets than for e.g. pyrope-rich garnets. It follows: DGrt/PhMelt for La = 0.5, Sm = 48 and Yb = 110. Grandite (dpeaa)DE-He213 Ca-rich garnets (dpeaa)DE-He213 Andradite (dpeaa)DE-He213 Rare earth elements (dpeaa)DE-He213 Mt. Somma-Vesuvius (dpeaa)DE-He213 Fractionation (dpeaa)DE-He213 Partition coefficient (dpeaa)DE-He213 Skarn (dpeaa)DE-He213 Hydrothermal (dpeaa)DE-He213 Magma chamber (dpeaa)DE-He213 Phonolite (dpeaa)DE-He213 Wörner, Gerhard aut Civetta, Lucia aut Stosch, Heinz-Günter aut Simon, Klaus aut Kronz, Andreas aut Enthalten in Contributions to mineralogy and petrology Berlin : Springer, 1947 154(2007), 1 vom: 23. Feb., Seite 55-74 (DE-627)25372208X (DE-600)1458979-5 1432-0967 nnns volume:154 year:2007 number:1 day:23 month:02 pages:55-74 https://dx.doi.org/10.1007/s00410-006-0179-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 154 2007 1 23 02 55-74
spelling	10.1007/s00410-006-0179-z doi (DE-627)SPR005246350 (SPR)s00410-006-0179-z-e DE-627 ger DE-627 rakwb eng Scheibner, Birgit verfasserin aut Rare earth element fractionation in magmatic Ca-rich garnets 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2007 Abstract Igneous garnets have the potential to strongly fractionate rare earth elements (REE). Yet informations on partition coefficients are very scant, and criteria for distinguishing between hydrothermal and magmatic garnets are ambiguous. To fill this gap, we present trace element and isotopic data for two types of Ca-rich garnets from phonolites (Mt. Somma-Vesuvius). Both Ca-garnet populations are different in their style and dynamics of fractionation: one population is progressively strongly depleted in HREE from core to rim, reflecting REE fractionation in the host phonolite via earlier-crystallized garnets. Such examples for extreme changes in HREE in garnets are only known for hydrothermal grandites by REE-bearing fluids. The second garnet population is homogeneous and formed in a closed system. Near-flat patterns between Sm and Lu confirm experimental data indicating lower D(Sm)/D(Lu) for Ca-rich garnets than for e.g. pyrope-rich garnets. It follows: DGrt/PhMelt for La = 0.5, Sm = 48 and Yb = 110. Grandite (dpeaa)DE-He213 Ca-rich garnets (dpeaa)DE-He213 Andradite (dpeaa)DE-He213 Rare earth elements (dpeaa)DE-He213 Mt. Somma-Vesuvius (dpeaa)DE-He213 Fractionation (dpeaa)DE-He213 Partition coefficient (dpeaa)DE-He213 Skarn (dpeaa)DE-He213 Hydrothermal (dpeaa)DE-He213 Magma chamber (dpeaa)DE-He213 Phonolite (dpeaa)DE-He213 Wörner, Gerhard aut Civetta, Lucia aut Stosch, Heinz-Günter aut Simon, Klaus aut Kronz, Andreas aut Enthalten in Contributions to mineralogy and petrology Berlin : Springer, 1947 154(2007), 1 vom: 23. Feb., Seite 55-74 (DE-627)25372208X (DE-600)1458979-5 1432-0967 nnns volume:154 year:2007 number:1 day:23 month:02 pages:55-74 https://dx.doi.org/10.1007/s00410-006-0179-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 154 2007 1 23 02 55-74
allfields_unstemmed	10.1007/s00410-006-0179-z doi (DE-627)SPR005246350 (SPR)s00410-006-0179-z-e DE-627 ger DE-627 rakwb eng Scheibner, Birgit verfasserin aut Rare earth element fractionation in magmatic Ca-rich garnets 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2007 Abstract Igneous garnets have the potential to strongly fractionate rare earth elements (REE). Yet informations on partition coefficients are very scant, and criteria for distinguishing between hydrothermal and magmatic garnets are ambiguous. To fill this gap, we present trace element and isotopic data for two types of Ca-rich garnets from phonolites (Mt. Somma-Vesuvius). Both Ca-garnet populations are different in their style and dynamics of fractionation: one population is progressively strongly depleted in HREE from core to rim, reflecting REE fractionation in the host phonolite via earlier-crystallized garnets. Such examples for extreme changes in HREE in garnets are only known for hydrothermal grandites by REE-bearing fluids. The second garnet population is homogeneous and formed in a closed system. Near-flat patterns between Sm and Lu confirm experimental data indicating lower D(Sm)/D(Lu) for Ca-rich garnets than for e.g. pyrope-rich garnets. It follows: DGrt/PhMelt for La = 0.5, Sm = 48 and Yb = 110. Grandite (dpeaa)DE-He213 Ca-rich garnets (dpeaa)DE-He213 Andradite (dpeaa)DE-He213 Rare earth elements (dpeaa)DE-He213 Mt. Somma-Vesuvius (dpeaa)DE-He213 Fractionation (dpeaa)DE-He213 Partition coefficient (dpeaa)DE-He213 Skarn (dpeaa)DE-He213 Hydrothermal (dpeaa)DE-He213 Magma chamber (dpeaa)DE-He213 Phonolite (dpeaa)DE-He213 Wörner, Gerhard aut Civetta, Lucia aut Stosch, Heinz-Günter aut Simon, Klaus aut Kronz, Andreas aut Enthalten in Contributions to mineralogy and petrology Berlin : Springer, 1947 154(2007), 1 vom: 23. Feb., Seite 55-74 (DE-627)25372208X (DE-600)1458979-5 1432-0967 nnns volume:154 year:2007 number:1 day:23 month:02 pages:55-74 https://dx.doi.org/10.1007/s00410-006-0179-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 154 2007 1 23 02 55-74
allfieldsGer	10.1007/s00410-006-0179-z doi (DE-627)SPR005246350 (SPR)s00410-006-0179-z-e DE-627 ger DE-627 rakwb eng Scheibner, Birgit verfasserin aut Rare earth element fractionation in magmatic Ca-rich garnets 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2007 Abstract Igneous garnets have the potential to strongly fractionate rare earth elements (REE). Yet informations on partition coefficients are very scant, and criteria for distinguishing between hydrothermal and magmatic garnets are ambiguous. To fill this gap, we present trace element and isotopic data for two types of Ca-rich garnets from phonolites (Mt. Somma-Vesuvius). Both Ca-garnet populations are different in their style and dynamics of fractionation: one population is progressively strongly depleted in HREE from core to rim, reflecting REE fractionation in the host phonolite via earlier-crystallized garnets. Such examples for extreme changes in HREE in garnets are only known for hydrothermal grandites by REE-bearing fluids. The second garnet population is homogeneous and formed in a closed system. Near-flat patterns between Sm and Lu confirm experimental data indicating lower D(Sm)/D(Lu) for Ca-rich garnets than for e.g. pyrope-rich garnets. It follows: DGrt/PhMelt for La = 0.5, Sm = 48 and Yb = 110. Grandite (dpeaa)DE-He213 Ca-rich garnets (dpeaa)DE-He213 Andradite (dpeaa)DE-He213 Rare earth elements (dpeaa)DE-He213 Mt. Somma-Vesuvius (dpeaa)DE-He213 Fractionation (dpeaa)DE-He213 Partition coefficient (dpeaa)DE-He213 Skarn (dpeaa)DE-He213 Hydrothermal (dpeaa)DE-He213 Magma chamber (dpeaa)DE-He213 Phonolite (dpeaa)DE-He213 Wörner, Gerhard aut Civetta, Lucia aut Stosch, Heinz-Günter aut Simon, Klaus aut Kronz, Andreas aut Enthalten in Contributions to mineralogy and petrology Berlin : Springer, 1947 154(2007), 1 vom: 23. Feb., Seite 55-74 (DE-627)25372208X (DE-600)1458979-5 1432-0967 nnns volume:154 year:2007 number:1 day:23 month:02 pages:55-74 https://dx.doi.org/10.1007/s00410-006-0179-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 154 2007 1 23 02 55-74
allfieldsSound	10.1007/s00410-006-0179-z doi (DE-627)SPR005246350 (SPR)s00410-006-0179-z-e DE-627 ger DE-627 rakwb eng Scheibner, Birgit verfasserin aut Rare earth element fractionation in magmatic Ca-rich garnets 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2007 Abstract Igneous garnets have the potential to strongly fractionate rare earth elements (REE). Yet informations on partition coefficients are very scant, and criteria for distinguishing between hydrothermal and magmatic garnets are ambiguous. To fill this gap, we present trace element and isotopic data for two types of Ca-rich garnets from phonolites (Mt. Somma-Vesuvius). Both Ca-garnet populations are different in their style and dynamics of fractionation: one population is progressively strongly depleted in HREE from core to rim, reflecting REE fractionation in the host phonolite via earlier-crystallized garnets. Such examples for extreme changes in HREE in garnets are only known for hydrothermal grandites by REE-bearing fluids. The second garnet population is homogeneous and formed in a closed system. Near-flat patterns between Sm and Lu confirm experimental data indicating lower D(Sm)/D(Lu) for Ca-rich garnets than for e.g. pyrope-rich garnets. It follows: DGrt/PhMelt for La = 0.5, Sm = 48 and Yb = 110. Grandite (dpeaa)DE-He213 Ca-rich garnets (dpeaa)DE-He213 Andradite (dpeaa)DE-He213 Rare earth elements (dpeaa)DE-He213 Mt. Somma-Vesuvius (dpeaa)DE-He213 Fractionation (dpeaa)DE-He213 Partition coefficient (dpeaa)DE-He213 Skarn (dpeaa)DE-He213 Hydrothermal (dpeaa)DE-He213 Magma chamber (dpeaa)DE-He213 Phonolite (dpeaa)DE-He213 Wörner, Gerhard aut Civetta, Lucia aut Stosch, Heinz-Günter aut Simon, Klaus aut Kronz, Andreas aut Enthalten in Contributions to mineralogy and petrology Berlin : Springer, 1947 154(2007), 1 vom: 23. Feb., Seite 55-74 (DE-627)25372208X (DE-600)1458979-5 1432-0967 nnns volume:154 year:2007 number:1 day:23 month:02 pages:55-74 https://dx.doi.org/10.1007/s00410-006-0179-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 154 2007 1 23 02 55-74
language	English
source	Enthalten in Contributions to mineralogy and petrology 154(2007), 1 vom: 23. Feb., Seite 55-74 volume:154 year:2007 number:1 day:23 month:02 pages:55-74
sourceStr	Enthalten in Contributions to mineralogy and petrology 154(2007), 1 vom: 23. Feb., Seite 55-74 volume:154 year:2007 number:1 day:23 month:02 pages:55-74
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Grandite Ca-rich garnets Andradite Rare earth elements Mt. Somma-Vesuvius Fractionation Partition coefficient Skarn Hydrothermal Magma chamber Phonolite
isfreeaccess_bool	false
container_title	Contributions to mineralogy and petrology
authorswithroles_txt_mv	Scheibner, Birgit @@aut@@ Wörner, Gerhard @@aut@@ Civetta, Lucia @@aut@@ Stosch, Heinz-Günter @@aut@@ Simon, Klaus @@aut@@ Kronz, Andreas @@aut@@
publishDateDaySort_date	2007-02-23T00:00:00Z
hierarchy_top_id	25372208X
id	SPR005246350
language_de	englisch
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author	Scheibner, Birgit
spellingShingle	Scheibner, Birgit misc Grandite misc Ca-rich garnets misc Andradite misc Rare earth elements misc Mt. Somma-Vesuvius misc Fractionation misc Partition coefficient misc Skarn misc Hydrothermal misc Magma chamber misc Phonolite Rare earth element fractionation in magmatic Ca-rich garnets
authorStr	Scheibner, Birgit
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topic_title	Rare earth element fractionation in magmatic Ca-rich garnets Grandite (dpeaa)DE-He213 Ca-rich garnets (dpeaa)DE-He213 Andradite (dpeaa)DE-He213 Rare earth elements (dpeaa)DE-He213 Mt. Somma-Vesuvius (dpeaa)DE-He213 Fractionation (dpeaa)DE-He213 Partition coefficient (dpeaa)DE-He213 Skarn (dpeaa)DE-He213 Hydrothermal (dpeaa)DE-He213 Magma chamber (dpeaa)DE-He213 Phonolite (dpeaa)DE-He213
topic	misc Grandite misc Ca-rich garnets misc Andradite misc Rare earth elements misc Mt. Somma-Vesuvius misc Fractionation misc Partition coefficient misc Skarn misc Hydrothermal misc Magma chamber misc Phonolite
topic_unstemmed	misc Grandite misc Ca-rich garnets misc Andradite misc Rare earth elements misc Mt. Somma-Vesuvius misc Fractionation misc Partition coefficient misc Skarn misc Hydrothermal misc Magma chamber misc Phonolite
topic_browse	misc Grandite misc Ca-rich garnets misc Andradite misc Rare earth elements misc Mt. Somma-Vesuvius misc Fractionation misc Partition coefficient misc Skarn misc Hydrothermal misc Magma chamber misc Phonolite
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title	Rare earth element fractionation in magmatic Ca-rich garnets
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title_full	Rare earth element fractionation in magmatic Ca-rich garnets
author_sort	Scheibner, Birgit
journal	Contributions to mineralogy and petrology
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author_browse	Scheibner, Birgit Wörner, Gerhard Civetta, Lucia Stosch, Heinz-Günter Simon, Klaus Kronz, Andreas
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format_se	Elektronische Aufsätze
author-letter	Scheibner, Birgit
doi_str_mv	10.1007/s00410-006-0179-z
title_sort	rare earth element fractionation in magmatic ca-rich garnets
title_auth	Rare earth element fractionation in magmatic Ca-rich garnets
abstract	Abstract Igneous garnets have the potential to strongly fractionate rare earth elements (REE). Yet informations on partition coefficients are very scant, and criteria for distinguishing between hydrothermal and magmatic garnets are ambiguous. To fill this gap, we present trace element and isotopic data for two types of Ca-rich garnets from phonolites (Mt. Somma-Vesuvius). Both Ca-garnet populations are different in their style and dynamics of fractionation: one population is progressively strongly depleted in HREE from core to rim, reflecting REE fractionation in the host phonolite via earlier-crystallized garnets. Such examples for extreme changes in HREE in garnets are only known for hydrothermal grandites by REE-bearing fluids. The second garnet population is homogeneous and formed in a closed system. Near-flat patterns between Sm and Lu confirm experimental data indicating lower D(Sm)/D(Lu) for Ca-rich garnets than for e.g. pyrope-rich garnets. It follows: DGrt/PhMelt for La = 0.5, Sm = 48 and Yb = 110. © Springer-Verlag 2007
abstractGer	Abstract Igneous garnets have the potential to strongly fractionate rare earth elements (REE). Yet informations on partition coefficients are very scant, and criteria for distinguishing between hydrothermal and magmatic garnets are ambiguous. To fill this gap, we present trace element and isotopic data for two types of Ca-rich garnets from phonolites (Mt. Somma-Vesuvius). Both Ca-garnet populations are different in their style and dynamics of fractionation: one population is progressively strongly depleted in HREE from core to rim, reflecting REE fractionation in the host phonolite via earlier-crystallized garnets. Such examples for extreme changes in HREE in garnets are only known for hydrothermal grandites by REE-bearing fluids. The second garnet population is homogeneous and formed in a closed system. Near-flat patterns between Sm and Lu confirm experimental data indicating lower D(Sm)/D(Lu) for Ca-rich garnets than for e.g. pyrope-rich garnets. It follows: DGrt/PhMelt for La = 0.5, Sm = 48 and Yb = 110. © Springer-Verlag 2007
abstract_unstemmed	Abstract Igneous garnets have the potential to strongly fractionate rare earth elements (REE). Yet informations on partition coefficients are very scant, and criteria for distinguishing between hydrothermal and magmatic garnets are ambiguous. To fill this gap, we present trace element and isotopic data for two types of Ca-rich garnets from phonolites (Mt. Somma-Vesuvius). Both Ca-garnet populations are different in their style and dynamics of fractionation: one population is progressively strongly depleted in HREE from core to rim, reflecting REE fractionation in the host phonolite via earlier-crystallized garnets. Such examples for extreme changes in HREE in garnets are only known for hydrothermal grandites by REE-bearing fluids. The second garnet population is homogeneous and formed in a closed system. Near-flat patterns between Sm and Lu confirm experimental data indicating lower D(Sm)/D(Lu) for Ca-rich garnets than for e.g. pyrope-rich garnets. It follows: DGrt/PhMelt for La = 0.5, Sm = 48 and Yb = 110. © Springer-Verlag 2007
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container_issue	1
title_short	Rare earth element fractionation in magmatic Ca-rich garnets
url	https://dx.doi.org/10.1007/s00410-006-0179-z
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author2	Wörner, Gerhard Civetta, Lucia Stosch, Heinz-Günter Simon, Klaus Kronz, Andreas
author2Str	Wörner, Gerhard Civetta, Lucia Stosch, Heinz-Günter Simon, Klaus Kronz, Andreas
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doi_str	10.1007/s00410-006-0179-z
up_date	2024-07-03T15:00:28.270Z
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Rare earth element fractionation in magmatic Ca-rich garnets

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