Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy)
Abstract Fluids are considered a fundamental agent for chemical exchanges between different rock types in the subduction system. Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. The Monviso ophiolitic sequence is compo...
Ausführliche Beschreibung
Autor*in: |
Rubatto, Daniela [verfasserIn] Angiboust, Samuel [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2015 |
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Übergeordnetes Werk: |
Enthalten in: Contributions to mineralogy and petrology - Berlin : Springer, 1947, 170(2015), 5-6 vom: 29. Okt. |
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Übergeordnetes Werk: |
volume:170 ; year:2015 ; number:5-6 ; day:29 ; month:10 |
Links: |
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DOI / URN: |
10.1007/s00410-015-1198-4 |
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Katalog-ID: |
SPR005256410 |
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520 | |a Abstract Fluids are considered a fundamental agent for chemical exchanges between different rock types in the subduction system. Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. The Monviso ophiolitic sequence is composed of mafic, ultramafic and minor sediments that have been subducted to ~80 km depth. In this sequence, both localized fluid flow and channelized fluids along major shear zones have been documented. We investigate the timing and source of the fluids that affected the dominant mafic rocks using microscale U–Pb dating of zircon and oxygen isotope analysis of mineral zones (garnet, zircon and antigorite) in high-pressure rocks with variable degree of metasomatic modification. In mafic eclogites, Jurassic zircon cores are the only mineralogical relicts of the protolith gabbros and retain $ δ^{18} $O values of 4.5–6 ‰, typical of mantle melts. Garnet and metamorphic zircon that grew during prograde to peak metamorphism display low $ δ^{18} $O values between 0.2 and 3.8 ‰, which are likely inherited from high-temperature alteration of the protolith on the sea floor. This is corroborated by $ δ^{18} $O values of 3.0 and 3.6 ‰ in antigorite from surrounding serpentinites. In metasomatized eclogites within the lower shear zone, garnet rim formed at the metamorphic peak shows a shift to higher $ δ^{18} $O up to 6 ‰. The age of zircons in high-pressure veins and metasomatized eclogites constrains the timing of fluid flow at high pressure at around 45–46 Ma. Although the oxygen data do not contradict previous reports of interaction with serpentinite-derived fluids, the shift to isotopically heavier oxygen compositions requires contribution from sediment-derived fluids. The scarcity of metasediments in the Monviso sequence suggests that such fluids were concentrated and fluxed along the lower shear zone in a sufficient amount to modify the oxygen composition of the eclogitic minerals. | ||
650 | 4 | |a Oxygen isotopes |7 (dpeaa)DE-He213 | |
650 | 4 | |a Subduction |7 (dpeaa)DE-He213 | |
650 | 4 | |a Garnet |7 (dpeaa)DE-He213 | |
650 | 4 | |a Zircon |7 (dpeaa)DE-He213 | |
650 | 4 | |a Shear zone |7 (dpeaa)DE-He213 | |
650 | 4 | |a Ophiolite |7 (dpeaa)DE-He213 | |
650 | 4 | |a Ion microprobe |7 (dpeaa)DE-He213 | |
700 | 1 | |a Angiboust, Samuel |e verfasserin |4 aut | |
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10.1007/s00410-015-1198-4 doi (DE-627)SPR005256410 (SPR)s00410-015-1198-4-e DE-627 ger DE-627 rakwb eng 550 ASE 38.25 bkl 38.30 bkl Rubatto, Daniela verfasserin aut Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy) 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Fluids are considered a fundamental agent for chemical exchanges between different rock types in the subduction system. Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. The Monviso ophiolitic sequence is composed of mafic, ultramafic and minor sediments that have been subducted to ~80 km depth. In this sequence, both localized fluid flow and channelized fluids along major shear zones have been documented. We investigate the timing and source of the fluids that affected the dominant mafic rocks using microscale U–Pb dating of zircon and oxygen isotope analysis of mineral zones (garnet, zircon and antigorite) in high-pressure rocks with variable degree of metasomatic modification. In mafic eclogites, Jurassic zircon cores are the only mineralogical relicts of the protolith gabbros and retain $ δ^{18} $O values of 4.5–6 ‰, typical of mantle melts. Garnet and metamorphic zircon that grew during prograde to peak metamorphism display low $ δ^{18} $O values between 0.2 and 3.8 ‰, which are likely inherited from high-temperature alteration of the protolith on the sea floor. This is corroborated by $ δ^{18} $O values of 3.0 and 3.6 ‰ in antigorite from surrounding serpentinites. In metasomatized eclogites within the lower shear zone, garnet rim formed at the metamorphic peak shows a shift to higher $ δ^{18} $O up to 6 ‰. The age of zircons in high-pressure veins and metasomatized eclogites constrains the timing of fluid flow at high pressure at around 45–46 Ma. Although the oxygen data do not contradict previous reports of interaction with serpentinite-derived fluids, the shift to isotopically heavier oxygen compositions requires contribution from sediment-derived fluids. The scarcity of metasediments in the Monviso sequence suggests that such fluids were concentrated and fluxed along the lower shear zone in a sufficient amount to modify the oxygen composition of the eclogitic minerals. Oxygen isotopes (dpeaa)DE-He213 Subduction (dpeaa)DE-He213 Garnet (dpeaa)DE-He213 Zircon (dpeaa)DE-He213 Shear zone (dpeaa)DE-He213 Ophiolite (dpeaa)DE-He213 Ion microprobe (dpeaa)DE-He213 Angiboust, Samuel verfasserin aut Enthalten in Contributions to mineralogy and petrology Berlin : Springer, 1947 170(2015), 5-6 vom: 29. Okt. (DE-627)25372208X (DE-600)1458979-5 1432-0967 nnns volume:170 year:2015 number:5-6 day:29 month:10 https://dx.doi.org/10.1007/s00410-015-1198-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.25 ASE 38.30 ASE AR 170 2015 5-6 29 10 |
spelling |
10.1007/s00410-015-1198-4 doi (DE-627)SPR005256410 (SPR)s00410-015-1198-4-e DE-627 ger DE-627 rakwb eng 550 ASE 38.25 bkl 38.30 bkl Rubatto, Daniela verfasserin aut Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy) 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Fluids are considered a fundamental agent for chemical exchanges between different rock types in the subduction system. Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. The Monviso ophiolitic sequence is composed of mafic, ultramafic and minor sediments that have been subducted to ~80 km depth. In this sequence, both localized fluid flow and channelized fluids along major shear zones have been documented. We investigate the timing and source of the fluids that affected the dominant mafic rocks using microscale U–Pb dating of zircon and oxygen isotope analysis of mineral zones (garnet, zircon and antigorite) in high-pressure rocks with variable degree of metasomatic modification. In mafic eclogites, Jurassic zircon cores are the only mineralogical relicts of the protolith gabbros and retain $ δ^{18} $O values of 4.5–6 ‰, typical of mantle melts. Garnet and metamorphic zircon that grew during prograde to peak metamorphism display low $ δ^{18} $O values between 0.2 and 3.8 ‰, which are likely inherited from high-temperature alteration of the protolith on the sea floor. This is corroborated by $ δ^{18} $O values of 3.0 and 3.6 ‰ in antigorite from surrounding serpentinites. In metasomatized eclogites within the lower shear zone, garnet rim formed at the metamorphic peak shows a shift to higher $ δ^{18} $O up to 6 ‰. The age of zircons in high-pressure veins and metasomatized eclogites constrains the timing of fluid flow at high pressure at around 45–46 Ma. Although the oxygen data do not contradict previous reports of interaction with serpentinite-derived fluids, the shift to isotopically heavier oxygen compositions requires contribution from sediment-derived fluids. The scarcity of metasediments in the Monviso sequence suggests that such fluids were concentrated and fluxed along the lower shear zone in a sufficient amount to modify the oxygen composition of the eclogitic minerals. Oxygen isotopes (dpeaa)DE-He213 Subduction (dpeaa)DE-He213 Garnet (dpeaa)DE-He213 Zircon (dpeaa)DE-He213 Shear zone (dpeaa)DE-He213 Ophiolite (dpeaa)DE-He213 Ion microprobe (dpeaa)DE-He213 Angiboust, Samuel verfasserin aut Enthalten in Contributions to mineralogy and petrology Berlin : Springer, 1947 170(2015), 5-6 vom: 29. Okt. (DE-627)25372208X (DE-600)1458979-5 1432-0967 nnns volume:170 year:2015 number:5-6 day:29 month:10 https://dx.doi.org/10.1007/s00410-015-1198-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.25 ASE 38.30 ASE AR 170 2015 5-6 29 10 |
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10.1007/s00410-015-1198-4 doi (DE-627)SPR005256410 (SPR)s00410-015-1198-4-e DE-627 ger DE-627 rakwb eng 550 ASE 38.25 bkl 38.30 bkl Rubatto, Daniela verfasserin aut Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy) 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Fluids are considered a fundamental agent for chemical exchanges between different rock types in the subduction system. Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. The Monviso ophiolitic sequence is composed of mafic, ultramafic and minor sediments that have been subducted to ~80 km depth. In this sequence, both localized fluid flow and channelized fluids along major shear zones have been documented. We investigate the timing and source of the fluids that affected the dominant mafic rocks using microscale U–Pb dating of zircon and oxygen isotope analysis of mineral zones (garnet, zircon and antigorite) in high-pressure rocks with variable degree of metasomatic modification. In mafic eclogites, Jurassic zircon cores are the only mineralogical relicts of the protolith gabbros and retain $ δ^{18} $O values of 4.5–6 ‰, typical of mantle melts. Garnet and metamorphic zircon that grew during prograde to peak metamorphism display low $ δ^{18} $O values between 0.2 and 3.8 ‰, which are likely inherited from high-temperature alteration of the protolith on the sea floor. This is corroborated by $ δ^{18} $O values of 3.0 and 3.6 ‰ in antigorite from surrounding serpentinites. In metasomatized eclogites within the lower shear zone, garnet rim formed at the metamorphic peak shows a shift to higher $ δ^{18} $O up to 6 ‰. The age of zircons in high-pressure veins and metasomatized eclogites constrains the timing of fluid flow at high pressure at around 45–46 Ma. Although the oxygen data do not contradict previous reports of interaction with serpentinite-derived fluids, the shift to isotopically heavier oxygen compositions requires contribution from sediment-derived fluids. The scarcity of metasediments in the Monviso sequence suggests that such fluids were concentrated and fluxed along the lower shear zone in a sufficient amount to modify the oxygen composition of the eclogitic minerals. Oxygen isotopes (dpeaa)DE-He213 Subduction (dpeaa)DE-He213 Garnet (dpeaa)DE-He213 Zircon (dpeaa)DE-He213 Shear zone (dpeaa)DE-He213 Ophiolite (dpeaa)DE-He213 Ion microprobe (dpeaa)DE-He213 Angiboust, Samuel verfasserin aut Enthalten in Contributions to mineralogy and petrology Berlin : Springer, 1947 170(2015), 5-6 vom: 29. Okt. (DE-627)25372208X (DE-600)1458979-5 1432-0967 nnns volume:170 year:2015 number:5-6 day:29 month:10 https://dx.doi.org/10.1007/s00410-015-1198-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.25 ASE 38.30 ASE AR 170 2015 5-6 29 10 |
allfieldsGer |
10.1007/s00410-015-1198-4 doi (DE-627)SPR005256410 (SPR)s00410-015-1198-4-e DE-627 ger DE-627 rakwb eng 550 ASE 38.25 bkl 38.30 bkl Rubatto, Daniela verfasserin aut Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy) 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Fluids are considered a fundamental agent for chemical exchanges between different rock types in the subduction system. Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. The Monviso ophiolitic sequence is composed of mafic, ultramafic and minor sediments that have been subducted to ~80 km depth. In this sequence, both localized fluid flow and channelized fluids along major shear zones have been documented. We investigate the timing and source of the fluids that affected the dominant mafic rocks using microscale U–Pb dating of zircon and oxygen isotope analysis of mineral zones (garnet, zircon and antigorite) in high-pressure rocks with variable degree of metasomatic modification. In mafic eclogites, Jurassic zircon cores are the only mineralogical relicts of the protolith gabbros and retain $ δ^{18} $O values of 4.5–6 ‰, typical of mantle melts. Garnet and metamorphic zircon that grew during prograde to peak metamorphism display low $ δ^{18} $O values between 0.2 and 3.8 ‰, which are likely inherited from high-temperature alteration of the protolith on the sea floor. This is corroborated by $ δ^{18} $O values of 3.0 and 3.6 ‰ in antigorite from surrounding serpentinites. In metasomatized eclogites within the lower shear zone, garnet rim formed at the metamorphic peak shows a shift to higher $ δ^{18} $O up to 6 ‰. The age of zircons in high-pressure veins and metasomatized eclogites constrains the timing of fluid flow at high pressure at around 45–46 Ma. Although the oxygen data do not contradict previous reports of interaction with serpentinite-derived fluids, the shift to isotopically heavier oxygen compositions requires contribution from sediment-derived fluids. The scarcity of metasediments in the Monviso sequence suggests that such fluids were concentrated and fluxed along the lower shear zone in a sufficient amount to modify the oxygen composition of the eclogitic minerals. Oxygen isotopes (dpeaa)DE-He213 Subduction (dpeaa)DE-He213 Garnet (dpeaa)DE-He213 Zircon (dpeaa)DE-He213 Shear zone (dpeaa)DE-He213 Ophiolite (dpeaa)DE-He213 Ion microprobe (dpeaa)DE-He213 Angiboust, Samuel verfasserin aut Enthalten in Contributions to mineralogy and petrology Berlin : Springer, 1947 170(2015), 5-6 vom: 29. Okt. (DE-627)25372208X (DE-600)1458979-5 1432-0967 nnns volume:170 year:2015 number:5-6 day:29 month:10 https://dx.doi.org/10.1007/s00410-015-1198-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.25 ASE 38.30 ASE AR 170 2015 5-6 29 10 |
allfieldsSound |
10.1007/s00410-015-1198-4 doi (DE-627)SPR005256410 (SPR)s00410-015-1198-4-e DE-627 ger DE-627 rakwb eng 550 ASE 38.25 bkl 38.30 bkl Rubatto, Daniela verfasserin aut Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy) 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Fluids are considered a fundamental agent for chemical exchanges between different rock types in the subduction system. Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. The Monviso ophiolitic sequence is composed of mafic, ultramafic and minor sediments that have been subducted to ~80 km depth. In this sequence, both localized fluid flow and channelized fluids along major shear zones have been documented. We investigate the timing and source of the fluids that affected the dominant mafic rocks using microscale U–Pb dating of zircon and oxygen isotope analysis of mineral zones (garnet, zircon and antigorite) in high-pressure rocks with variable degree of metasomatic modification. In mafic eclogites, Jurassic zircon cores are the only mineralogical relicts of the protolith gabbros and retain $ δ^{18} $O values of 4.5–6 ‰, typical of mantle melts. Garnet and metamorphic zircon that grew during prograde to peak metamorphism display low $ δ^{18} $O values between 0.2 and 3.8 ‰, which are likely inherited from high-temperature alteration of the protolith on the sea floor. This is corroborated by $ δ^{18} $O values of 3.0 and 3.6 ‰ in antigorite from surrounding serpentinites. In metasomatized eclogites within the lower shear zone, garnet rim formed at the metamorphic peak shows a shift to higher $ δ^{18} $O up to 6 ‰. The age of zircons in high-pressure veins and metasomatized eclogites constrains the timing of fluid flow at high pressure at around 45–46 Ma. Although the oxygen data do not contradict previous reports of interaction with serpentinite-derived fluids, the shift to isotopically heavier oxygen compositions requires contribution from sediment-derived fluids. The scarcity of metasediments in the Monviso sequence suggests that such fluids were concentrated and fluxed along the lower shear zone in a sufficient amount to modify the oxygen composition of the eclogitic minerals. Oxygen isotopes (dpeaa)DE-He213 Subduction (dpeaa)DE-He213 Garnet (dpeaa)DE-He213 Zircon (dpeaa)DE-He213 Shear zone (dpeaa)DE-He213 Ophiolite (dpeaa)DE-He213 Ion microprobe (dpeaa)DE-He213 Angiboust, Samuel verfasserin aut Enthalten in Contributions to mineralogy and petrology Berlin : Springer, 1947 170(2015), 5-6 vom: 29. Okt. (DE-627)25372208X (DE-600)1458979-5 1432-0967 nnns volume:170 year:2015 number:5-6 day:29 month:10 https://dx.doi.org/10.1007/s00410-015-1198-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.25 ASE 38.30 ASE AR 170 2015 5-6 29 10 |
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English |
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Enthalten in Contributions to mineralogy and petrology 170(2015), 5-6 vom: 29. Okt. volume:170 year:2015 number:5-6 day:29 month:10 |
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Enthalten in Contributions to mineralogy and petrology 170(2015), 5-6 vom: 29. Okt. volume:170 year:2015 number:5-6 day:29 month:10 |
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Oxygen isotopes Subduction Garnet Zircon Shear zone Ophiolite Ion microprobe |
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Contributions to mineralogy and petrology |
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Rubatto, Daniela @@aut@@ Angiboust, Samuel @@aut@@ |
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Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. The Monviso ophiolitic sequence is composed of mafic, ultramafic and minor sediments that have been subducted to ~80 km depth. In this sequence, both localized fluid flow and channelized fluids along major shear zones have been documented. We investigate the timing and source of the fluids that affected the dominant mafic rocks using microscale U–Pb dating of zircon and oxygen isotope analysis of mineral zones (garnet, zircon and antigorite) in high-pressure rocks with variable degree of metasomatic modification. In mafic eclogites, Jurassic zircon cores are the only mineralogical relicts of the protolith gabbros and retain $ δ^{18} $O values of 4.5–6 ‰, typical of mantle melts. Garnet and metamorphic zircon that grew during prograde to peak metamorphism display low $ δ^{18} $O values between 0.2 and 3.8 ‰, which are likely inherited from high-temperature alteration of the protolith on the sea floor. This is corroborated by $ δ^{18} $O values of 3.0 and 3.6 ‰ in antigorite from surrounding serpentinites. In metasomatized eclogites within the lower shear zone, garnet rim formed at the metamorphic peak shows a shift to higher $ δ^{18} $O up to 6 ‰. The age of zircons in high-pressure veins and metasomatized eclogites constrains the timing of fluid flow at high pressure at around 45–46 Ma. Although the oxygen data do not contradict previous reports of interaction with serpentinite-derived fluids, the shift to isotopically heavier oxygen compositions requires contribution from sediment-derived fluids. 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|
author |
Rubatto, Daniela |
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Rubatto, Daniela ddc 550 bkl 38.25 bkl 38.30 misc Oxygen isotopes misc Subduction misc Garnet misc Zircon misc Shear zone misc Ophiolite misc Ion microprobe Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy) |
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550 ASE 38.25 bkl 38.30 bkl Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy) Oxygen isotopes (dpeaa)DE-He213 Subduction (dpeaa)DE-He213 Garnet (dpeaa)DE-He213 Zircon (dpeaa)DE-He213 Shear zone (dpeaa)DE-He213 Ophiolite (dpeaa)DE-He213 Ion microprobe (dpeaa)DE-He213 |
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ddc 550 bkl 38.25 bkl 38.30 misc Oxygen isotopes misc Subduction misc Garnet misc Zircon misc Shear zone misc Ophiolite misc Ion microprobe |
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ddc 550 bkl 38.25 bkl 38.30 misc Oxygen isotopes misc Subduction misc Garnet misc Zircon misc Shear zone misc Ophiolite misc Ion microprobe |
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Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy) |
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Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy) |
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Rubatto, Daniela |
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Rubatto, Daniela Angiboust, Samuel |
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Rubatto, Daniela |
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oxygen isotope record of oceanic and high-pressure metasomatism: a p–t–time–fluid path for the monviso eclogites (italy) |
title_auth |
Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy) |
abstract |
Abstract Fluids are considered a fundamental agent for chemical exchanges between different rock types in the subduction system. Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. The Monviso ophiolitic sequence is composed of mafic, ultramafic and minor sediments that have been subducted to ~80 km depth. In this sequence, both localized fluid flow and channelized fluids along major shear zones have been documented. We investigate the timing and source of the fluids that affected the dominant mafic rocks using microscale U–Pb dating of zircon and oxygen isotope analysis of mineral zones (garnet, zircon and antigorite) in high-pressure rocks with variable degree of metasomatic modification. In mafic eclogites, Jurassic zircon cores are the only mineralogical relicts of the protolith gabbros and retain $ δ^{18} $O values of 4.5–6 ‰, typical of mantle melts. Garnet and metamorphic zircon that grew during prograde to peak metamorphism display low $ δ^{18} $O values between 0.2 and 3.8 ‰, which are likely inherited from high-temperature alteration of the protolith on the sea floor. This is corroborated by $ δ^{18} $O values of 3.0 and 3.6 ‰ in antigorite from surrounding serpentinites. In metasomatized eclogites within the lower shear zone, garnet rim formed at the metamorphic peak shows a shift to higher $ δ^{18} $O up to 6 ‰. The age of zircons in high-pressure veins and metasomatized eclogites constrains the timing of fluid flow at high pressure at around 45–46 Ma. Although the oxygen data do not contradict previous reports of interaction with serpentinite-derived fluids, the shift to isotopically heavier oxygen compositions requires contribution from sediment-derived fluids. The scarcity of metasediments in the Monviso sequence suggests that such fluids were concentrated and fluxed along the lower shear zone in a sufficient amount to modify the oxygen composition of the eclogitic minerals. |
abstractGer |
Abstract Fluids are considered a fundamental agent for chemical exchanges between different rock types in the subduction system. Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. The Monviso ophiolitic sequence is composed of mafic, ultramafic and minor sediments that have been subducted to ~80 km depth. In this sequence, both localized fluid flow and channelized fluids along major shear zones have been documented. We investigate the timing and source of the fluids that affected the dominant mafic rocks using microscale U–Pb dating of zircon and oxygen isotope analysis of mineral zones (garnet, zircon and antigorite) in high-pressure rocks with variable degree of metasomatic modification. In mafic eclogites, Jurassic zircon cores are the only mineralogical relicts of the protolith gabbros and retain $ δ^{18} $O values of 4.5–6 ‰, typical of mantle melts. Garnet and metamorphic zircon that grew during prograde to peak metamorphism display low $ δ^{18} $O values between 0.2 and 3.8 ‰, which are likely inherited from high-temperature alteration of the protolith on the sea floor. This is corroborated by $ δ^{18} $O values of 3.0 and 3.6 ‰ in antigorite from surrounding serpentinites. In metasomatized eclogites within the lower shear zone, garnet rim formed at the metamorphic peak shows a shift to higher $ δ^{18} $O up to 6 ‰. The age of zircons in high-pressure veins and metasomatized eclogites constrains the timing of fluid flow at high pressure at around 45–46 Ma. Although the oxygen data do not contradict previous reports of interaction with serpentinite-derived fluids, the shift to isotopically heavier oxygen compositions requires contribution from sediment-derived fluids. The scarcity of metasediments in the Monviso sequence suggests that such fluids were concentrated and fluxed along the lower shear zone in a sufficient amount to modify the oxygen composition of the eclogitic minerals. |
abstract_unstemmed |
Abstract Fluids are considered a fundamental agent for chemical exchanges between different rock types in the subduction system. Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. The Monviso ophiolitic sequence is composed of mafic, ultramafic and minor sediments that have been subducted to ~80 km depth. In this sequence, both localized fluid flow and channelized fluids along major shear zones have been documented. We investigate the timing and source of the fluids that affected the dominant mafic rocks using microscale U–Pb dating of zircon and oxygen isotope analysis of mineral zones (garnet, zircon and antigorite) in high-pressure rocks with variable degree of metasomatic modification. In mafic eclogites, Jurassic zircon cores are the only mineralogical relicts of the protolith gabbros and retain $ δ^{18} $O values of 4.5–6 ‰, typical of mantle melts. Garnet and metamorphic zircon that grew during prograde to peak metamorphism display low $ δ^{18} $O values between 0.2 and 3.8 ‰, which are likely inherited from high-temperature alteration of the protolith on the sea floor. This is corroborated by $ δ^{18} $O values of 3.0 and 3.6 ‰ in antigorite from surrounding serpentinites. In metasomatized eclogites within the lower shear zone, garnet rim formed at the metamorphic peak shows a shift to higher $ δ^{18} $O up to 6 ‰. The age of zircons in high-pressure veins and metasomatized eclogites constrains the timing of fluid flow at high pressure at around 45–46 Ma. Although the oxygen data do not contradict previous reports of interaction with serpentinite-derived fluids, the shift to isotopically heavier oxygen compositions requires contribution from sediment-derived fluids. The scarcity of metasediments in the Monviso sequence suggests that such fluids were concentrated and fluxed along the lower shear zone in a sufficient amount to modify the oxygen composition of the eclogitic minerals. |
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container_issue |
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title_short |
Oxygen isotope record of oceanic and high-pressure metasomatism: a P–T–time–fluid path for the Monviso eclogites (Italy) |
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score |
7.4013567 |