Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes
Abstract A newly synthesized series of mono- and di-, nitro- or nitrosocalix[4]arenes has been investigated electrochemically. It was shown that besides the fundamental redox characterization, the electrochemical data contain also information about the space arrangement of the molecule as well as ab...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Liška, Alan [verfasserIn] Flídrová, Karolína [verfasserIn] Lhoták, Pavel [verfasserIn] Ludvík, Jiří [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Monatshefte für Chemie - Wien [u.a.] : Springer, 1880, 146(2015), 5 vom: 26. März, Seite 857-862 |
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| Übergeordnetes Werk: |
volume:146 ; year:2015 ; number:5 ; day:26 ; month:03 ; pages:857-862 |
| Links: |
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| DOI / URN: |
10.1007/s00706-015-1441-8 |
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| Katalog-ID: |
SPR007472498 |
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| 245 | 1 | 0 | |a Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes |
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| 520 | |a Abstract A newly synthesized series of mono- and di-, nitro- or nitrosocalix[4]arenes has been investigated electrochemically. It was shown that besides the fundamental redox characterization, the electrochemical data contain also information about the space arrangement of the molecule as well as about dynamic 3D changes. The interpretation is based on the comparison of observed electrochemical behavior of homologous couples or triads taken from the studied series of compounds. Using the nitro and nitroso group as a redox probe, it was found that unsubstituted or para-nitro-substituted cone-calixarenes are flexible, exhibiting in solution a periodic pinched cone–pinched cone interconversion, whereas the 1,3-alt conformation or any meta-substitution causes rigidity of the whole skeleton. All aromatic nitro and nitroso groups in calixarenes appeared to be reducible at the same potential showing their electronic independency on the rest of the molecule. Graphical abstract | ||
| 650 | 4 | |a Nitrocalix[4]arenes |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Nitrosocalix[4]arenes |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Electrochemical reduction |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Redox probe |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Flídrová, Karolína |e verfasserin |4 aut | |
| 700 | 1 | |a Lhoták, Pavel |e verfasserin |4 aut | |
| 700 | 1 | |a Ludvík, Jiří |e verfasserin |4 aut | |
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10.1007/s00706-015-1441-8 doi (DE-627)SPR007472498 (SPR)s00706-015-1441-8-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Liška, Alan verfasserin aut Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A newly synthesized series of mono- and di-, nitro- or nitrosocalix[4]arenes has been investigated electrochemically. It was shown that besides the fundamental redox characterization, the electrochemical data contain also information about the space arrangement of the molecule as well as about dynamic 3D changes. The interpretation is based on the comparison of observed electrochemical behavior of homologous couples or triads taken from the studied series of compounds. Using the nitro and nitroso group as a redox probe, it was found that unsubstituted or para-nitro-substituted cone-calixarenes are flexible, exhibiting in solution a periodic pinched cone–pinched cone interconversion, whereas the 1,3-alt conformation or any meta-substitution causes rigidity of the whole skeleton. All aromatic nitro and nitroso groups in calixarenes appeared to be reducible at the same potential showing their electronic independency on the rest of the molecule. Graphical abstract Nitrocalix[4]arenes (dpeaa)DE-He213 Nitrosocalix[4]arenes (dpeaa)DE-He213 Electrochemical reduction (dpeaa)DE-He213 Redox probe (dpeaa)DE-He213 Flídrová, Karolína verfasserin aut Lhoták, Pavel verfasserin aut Ludvík, Jiří verfasserin aut Enthalten in Monatshefte für Chemie Wien [u.a.] : Springer, 1880 146(2015), 5 vom: 26. März, Seite 857-862 (DE-627)25462992X (DE-600)1462037-6 1434-4475 nnns volume:146 year:2015 number:5 day:26 month:03 pages:857-862 https://dx.doi.org/10.1007/s00706-015-1441-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 146 2015 5 26 03 857-862 |
| spelling |
10.1007/s00706-015-1441-8 doi (DE-627)SPR007472498 (SPR)s00706-015-1441-8-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Liška, Alan verfasserin aut Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A newly synthesized series of mono- and di-, nitro- or nitrosocalix[4]arenes has been investigated electrochemically. It was shown that besides the fundamental redox characterization, the electrochemical data contain also information about the space arrangement of the molecule as well as about dynamic 3D changes. The interpretation is based on the comparison of observed electrochemical behavior of homologous couples or triads taken from the studied series of compounds. Using the nitro and nitroso group as a redox probe, it was found that unsubstituted or para-nitro-substituted cone-calixarenes are flexible, exhibiting in solution a periodic pinched cone–pinched cone interconversion, whereas the 1,3-alt conformation or any meta-substitution causes rigidity of the whole skeleton. All aromatic nitro and nitroso groups in calixarenes appeared to be reducible at the same potential showing their electronic independency on the rest of the molecule. Graphical abstract Nitrocalix[4]arenes (dpeaa)DE-He213 Nitrosocalix[4]arenes (dpeaa)DE-He213 Electrochemical reduction (dpeaa)DE-He213 Redox probe (dpeaa)DE-He213 Flídrová, Karolína verfasserin aut Lhoták, Pavel verfasserin aut Ludvík, Jiří verfasserin aut Enthalten in Monatshefte für Chemie Wien [u.a.] : Springer, 1880 146(2015), 5 vom: 26. März, Seite 857-862 (DE-627)25462992X (DE-600)1462037-6 1434-4475 nnns volume:146 year:2015 number:5 day:26 month:03 pages:857-862 https://dx.doi.org/10.1007/s00706-015-1441-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 146 2015 5 26 03 857-862 |
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10.1007/s00706-015-1441-8 doi (DE-627)SPR007472498 (SPR)s00706-015-1441-8-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Liška, Alan verfasserin aut Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A newly synthesized series of mono- and di-, nitro- or nitrosocalix[4]arenes has been investigated electrochemically. It was shown that besides the fundamental redox characterization, the electrochemical data contain also information about the space arrangement of the molecule as well as about dynamic 3D changes. The interpretation is based on the comparison of observed electrochemical behavior of homologous couples or triads taken from the studied series of compounds. Using the nitro and nitroso group as a redox probe, it was found that unsubstituted or para-nitro-substituted cone-calixarenes are flexible, exhibiting in solution a periodic pinched cone–pinched cone interconversion, whereas the 1,3-alt conformation or any meta-substitution causes rigidity of the whole skeleton. All aromatic nitro and nitroso groups in calixarenes appeared to be reducible at the same potential showing their electronic independency on the rest of the molecule. Graphical abstract Nitrocalix[4]arenes (dpeaa)DE-He213 Nitrosocalix[4]arenes (dpeaa)DE-He213 Electrochemical reduction (dpeaa)DE-He213 Redox probe (dpeaa)DE-He213 Flídrová, Karolína verfasserin aut Lhoták, Pavel verfasserin aut Ludvík, Jiří verfasserin aut Enthalten in Monatshefte für Chemie Wien [u.a.] : Springer, 1880 146(2015), 5 vom: 26. März, Seite 857-862 (DE-627)25462992X (DE-600)1462037-6 1434-4475 nnns volume:146 year:2015 number:5 day:26 month:03 pages:857-862 https://dx.doi.org/10.1007/s00706-015-1441-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 146 2015 5 26 03 857-862 |
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10.1007/s00706-015-1441-8 doi (DE-627)SPR007472498 (SPR)s00706-015-1441-8-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Liška, Alan verfasserin aut Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A newly synthesized series of mono- and di-, nitro- or nitrosocalix[4]arenes has been investigated electrochemically. It was shown that besides the fundamental redox characterization, the electrochemical data contain also information about the space arrangement of the molecule as well as about dynamic 3D changes. The interpretation is based on the comparison of observed electrochemical behavior of homologous couples or triads taken from the studied series of compounds. Using the nitro and nitroso group as a redox probe, it was found that unsubstituted or para-nitro-substituted cone-calixarenes are flexible, exhibiting in solution a periodic pinched cone–pinched cone interconversion, whereas the 1,3-alt conformation or any meta-substitution causes rigidity of the whole skeleton. All aromatic nitro and nitroso groups in calixarenes appeared to be reducible at the same potential showing their electronic independency on the rest of the molecule. Graphical abstract Nitrocalix[4]arenes (dpeaa)DE-He213 Nitrosocalix[4]arenes (dpeaa)DE-He213 Electrochemical reduction (dpeaa)DE-He213 Redox probe (dpeaa)DE-He213 Flídrová, Karolína verfasserin aut Lhoták, Pavel verfasserin aut Ludvík, Jiří verfasserin aut Enthalten in Monatshefte für Chemie Wien [u.a.] : Springer, 1880 146(2015), 5 vom: 26. März, Seite 857-862 (DE-627)25462992X (DE-600)1462037-6 1434-4475 nnns volume:146 year:2015 number:5 day:26 month:03 pages:857-862 https://dx.doi.org/10.1007/s00706-015-1441-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 146 2015 5 26 03 857-862 |
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10.1007/s00706-015-1441-8 doi (DE-627)SPR007472498 (SPR)s00706-015-1441-8-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Liška, Alan verfasserin aut Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A newly synthesized series of mono- and di-, nitro- or nitrosocalix[4]arenes has been investigated electrochemically. It was shown that besides the fundamental redox characterization, the electrochemical data contain also information about the space arrangement of the molecule as well as about dynamic 3D changes. The interpretation is based on the comparison of observed electrochemical behavior of homologous couples or triads taken from the studied series of compounds. Using the nitro and nitroso group as a redox probe, it was found that unsubstituted or para-nitro-substituted cone-calixarenes are flexible, exhibiting in solution a periodic pinched cone–pinched cone interconversion, whereas the 1,3-alt conformation or any meta-substitution causes rigidity of the whole skeleton. All aromatic nitro and nitroso groups in calixarenes appeared to be reducible at the same potential showing their electronic independency on the rest of the molecule. Graphical abstract Nitrocalix[4]arenes (dpeaa)DE-He213 Nitrosocalix[4]arenes (dpeaa)DE-He213 Electrochemical reduction (dpeaa)DE-He213 Redox probe (dpeaa)DE-He213 Flídrová, Karolína verfasserin aut Lhoták, Pavel verfasserin aut Ludvík, Jiří verfasserin aut Enthalten in Monatshefte für Chemie Wien [u.a.] : Springer, 1880 146(2015), 5 vom: 26. März, Seite 857-862 (DE-627)25462992X (DE-600)1462037-6 1434-4475 nnns volume:146 year:2015 number:5 day:26 month:03 pages:857-862 https://dx.doi.org/10.1007/s00706-015-1441-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 146 2015 5 26 03 857-862 |
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Liška, Alan @@aut@@ Flídrová, Karolína @@aut@@ Lhoták, Pavel @@aut@@ Ludvík, Jiří @@aut@@ |
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It was shown that besides the fundamental redox characterization, the electrochemical data contain also information about the space arrangement of the molecule as well as about dynamic 3D changes. The interpretation is based on the comparison of observed electrochemical behavior of homologous couples or triads taken from the studied series of compounds. Using the nitro and nitroso group as a redox probe, it was found that unsubstituted or para-nitro-substituted cone-calixarenes are flexible, exhibiting in solution a periodic pinched cone–pinched cone interconversion, whereas the 1,3-alt conformation or any meta-substitution causes rigidity of the whole skeleton. All aromatic nitro and nitroso groups in calixarenes appeared to be reducible at the same potential showing their electronic independency on the rest of the molecule. 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Liška, Alan |
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Liška, Alan ddc 540 bkl 35.00 misc Nitrocalix[4]arenes misc Nitrosocalix[4]arenes misc Electrochemical reduction misc Redox probe Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes |
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540 ASE 35.00 bkl Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes Nitrocalix[4]arenes (dpeaa)DE-He213 Nitrosocalix[4]arenes (dpeaa)DE-He213 Electrochemical reduction (dpeaa)DE-He213 Redox probe (dpeaa)DE-He213 |
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ddc 540 bkl 35.00 misc Nitrocalix[4]arenes misc Nitrosocalix[4]arenes misc Electrochemical reduction misc Redox probe |
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Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes |
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Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes |
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Liška, Alan |
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influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes |
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Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes |
| abstract |
Abstract A newly synthesized series of mono- and di-, nitro- or nitrosocalix[4]arenes has been investigated electrochemically. It was shown that besides the fundamental redox characterization, the electrochemical data contain also information about the space arrangement of the molecule as well as about dynamic 3D changes. The interpretation is based on the comparison of observed electrochemical behavior of homologous couples or triads taken from the studied series of compounds. Using the nitro and nitroso group as a redox probe, it was found that unsubstituted or para-nitro-substituted cone-calixarenes are flexible, exhibiting in solution a periodic pinched cone–pinched cone interconversion, whereas the 1,3-alt conformation or any meta-substitution causes rigidity of the whole skeleton. All aromatic nitro and nitroso groups in calixarenes appeared to be reducible at the same potential showing their electronic independency on the rest of the molecule. Graphical abstract |
| abstractGer |
Abstract A newly synthesized series of mono- and di-, nitro- or nitrosocalix[4]arenes has been investigated electrochemically. It was shown that besides the fundamental redox characterization, the electrochemical data contain also information about the space arrangement of the molecule as well as about dynamic 3D changes. The interpretation is based on the comparison of observed electrochemical behavior of homologous couples or triads taken from the studied series of compounds. Using the nitro and nitroso group as a redox probe, it was found that unsubstituted or para-nitro-substituted cone-calixarenes are flexible, exhibiting in solution a periodic pinched cone–pinched cone interconversion, whereas the 1,3-alt conformation or any meta-substitution causes rigidity of the whole skeleton. All aromatic nitro and nitroso groups in calixarenes appeared to be reducible at the same potential showing their electronic independency on the rest of the molecule. Graphical abstract |
| abstract_unstemmed |
Abstract A newly synthesized series of mono- and di-, nitro- or nitrosocalix[4]arenes has been investigated electrochemically. It was shown that besides the fundamental redox characterization, the electrochemical data contain also information about the space arrangement of the molecule as well as about dynamic 3D changes. The interpretation is based on the comparison of observed electrochemical behavior of homologous couples or triads taken from the studied series of compounds. Using the nitro and nitroso group as a redox probe, it was found that unsubstituted or para-nitro-substituted cone-calixarenes are flexible, exhibiting in solution a periodic pinched cone–pinched cone interconversion, whereas the 1,3-alt conformation or any meta-substitution causes rigidity of the whole skeleton. All aromatic nitro and nitroso groups in calixarenes appeared to be reducible at the same potential showing their electronic independency on the rest of the molecule. Graphical abstract |
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5 |
| title_short |
Influence of structure on electrochemical reduction of isomeric mono- and di-, nitro- or nitrosocalix[4]arenes |
| url |
https://dx.doi.org/10.1007/s00706-015-1441-8 |
| remote_bool |
true |
| author2 |
Flídrová, Karolína Lhoták, Pavel Ludvík, Jiří |
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Flídrová, Karolína Lhoták, Pavel Ludvík, Jiří |
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c |
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| doi_str |
10.1007/s00706-015-1441-8 |
| up_date |
2024-07-04T03:22:34.401Z |
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| score |
7.4013395 |