The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries
Abstract $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials were successfully prepared by sol–gel method with two different Li sources. The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yang, Tongyong [verfasserIn] Sun, Kening [verfasserIn] Lei, Zhengyu [verfasserIn] Zhang, Naiqing [verfasserIn] Lang, Ye [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2010 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of solid state electrochemistry - Berlin : Springer, 1997, 15(2010), 2 vom: 23. Mai, Seite 391-397 |
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| Übergeordnetes Werk: |
volume:15 ; year:2010 ; number:2 ; day:23 ; month:05 ; pages:391-397 |
| Links: |
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| DOI / URN: |
10.1007/s10008-010-1103-z |
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| Katalog-ID: |
SPR007966318 |
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| 100 | 1 | |a Yang, Tongyong |e verfasserin |4 aut | |
| 245 | 1 | 4 | |a The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries |
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| 520 | |a Abstract $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials were successfully prepared by sol–gel method with two different Li sources. The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by scanning electron microscopy, Fourier transform infrared, X-ray diffraction, and electrochemical method. The structure of both samples is confirmed as typical cubic spinel with Fd3m space group, whichever lithium salt is adopted. The grain size of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ powder and its electrochemical behaviors are strongly affected by Li sources. For the samples prepared with lithium acetate, more spinel nucleation should form during the precalcination process, which was stimulated by the heat released from the combustion of extra organic acetate group. Therefore, the particle size of the obtained powder presents smaller average and wider distribution, which facilitates the initial discharge capacity and deteriorates the cycling performance. More seriously, there exists cation replacement of Li sites by transition metal elements, which causes channel block for Li ion transference and deteriorates the rate capability. The compound obtained with lithium hydroxide exhibits better electrochemical responses in terms of both cycling and rate properties due to higher crystallinity, moderate particle size, narrow size distribution and lower transition cation substitute content. | ||
| 700 | 1 | |a Sun, Kening |e verfasserin |4 aut | |
| 700 | 1 | |a Lei, Zhengyu |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Naiqing |e verfasserin |4 aut | |
| 700 | 1 | |a Lang, Ye |e verfasserin |4 aut | |
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10.1007/s10008-010-1103-z doi (DE-627)SPR007966318 (SPR)s10008-010-1103-z-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Yang, Tongyong verfasserin aut The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials were successfully prepared by sol–gel method with two different Li sources. The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by scanning electron microscopy, Fourier transform infrared, X-ray diffraction, and electrochemical method. The structure of both samples is confirmed as typical cubic spinel with Fd3m space group, whichever lithium salt is adopted. The grain size of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ powder and its electrochemical behaviors are strongly affected by Li sources. For the samples prepared with lithium acetate, more spinel nucleation should form during the precalcination process, which was stimulated by the heat released from the combustion of extra organic acetate group. Therefore, the particle size of the obtained powder presents smaller average and wider distribution, which facilitates the initial discharge capacity and deteriorates the cycling performance. More seriously, there exists cation replacement of Li sites by transition metal elements, which causes channel block for Li ion transference and deteriorates the rate capability. The compound obtained with lithium hydroxide exhibits better electrochemical responses in terms of both cycling and rate properties due to higher crystallinity, moderate particle size, narrow size distribution and lower transition cation substitute content. Sun, Kening verfasserin aut Lei, Zhengyu verfasserin aut Zhang, Naiqing verfasserin aut Lang, Ye verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 15(2010), 2 vom: 23. Mai, Seite 391-397 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:15 year:2010 number:2 day:23 month:05 pages:391-397 https://dx.doi.org/10.1007/s10008-010-1103-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 15 2010 2 23 05 391-397 |
| spelling |
10.1007/s10008-010-1103-z doi (DE-627)SPR007966318 (SPR)s10008-010-1103-z-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Yang, Tongyong verfasserin aut The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials were successfully prepared by sol–gel method with two different Li sources. The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by scanning electron microscopy, Fourier transform infrared, X-ray diffraction, and electrochemical method. The structure of both samples is confirmed as typical cubic spinel with Fd3m space group, whichever lithium salt is adopted. The grain size of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ powder and its electrochemical behaviors are strongly affected by Li sources. For the samples prepared with lithium acetate, more spinel nucleation should form during the precalcination process, which was stimulated by the heat released from the combustion of extra organic acetate group. Therefore, the particle size of the obtained powder presents smaller average and wider distribution, which facilitates the initial discharge capacity and deteriorates the cycling performance. More seriously, there exists cation replacement of Li sites by transition metal elements, which causes channel block for Li ion transference and deteriorates the rate capability. The compound obtained with lithium hydroxide exhibits better electrochemical responses in terms of both cycling and rate properties due to higher crystallinity, moderate particle size, narrow size distribution and lower transition cation substitute content. Sun, Kening verfasserin aut Lei, Zhengyu verfasserin aut Zhang, Naiqing verfasserin aut Lang, Ye verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 15(2010), 2 vom: 23. Mai, Seite 391-397 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:15 year:2010 number:2 day:23 month:05 pages:391-397 https://dx.doi.org/10.1007/s10008-010-1103-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 15 2010 2 23 05 391-397 |
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10.1007/s10008-010-1103-z doi (DE-627)SPR007966318 (SPR)s10008-010-1103-z-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Yang, Tongyong verfasserin aut The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials were successfully prepared by sol–gel method with two different Li sources. The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by scanning electron microscopy, Fourier transform infrared, X-ray diffraction, and electrochemical method. The structure of both samples is confirmed as typical cubic spinel with Fd3m space group, whichever lithium salt is adopted. The grain size of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ powder and its electrochemical behaviors are strongly affected by Li sources. For the samples prepared with lithium acetate, more spinel nucleation should form during the precalcination process, which was stimulated by the heat released from the combustion of extra organic acetate group. Therefore, the particle size of the obtained powder presents smaller average and wider distribution, which facilitates the initial discharge capacity and deteriorates the cycling performance. More seriously, there exists cation replacement of Li sites by transition metal elements, which causes channel block for Li ion transference and deteriorates the rate capability. The compound obtained with lithium hydroxide exhibits better electrochemical responses in terms of both cycling and rate properties due to higher crystallinity, moderate particle size, narrow size distribution and lower transition cation substitute content. Sun, Kening verfasserin aut Lei, Zhengyu verfasserin aut Zhang, Naiqing verfasserin aut Lang, Ye verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 15(2010), 2 vom: 23. Mai, Seite 391-397 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:15 year:2010 number:2 day:23 month:05 pages:391-397 https://dx.doi.org/10.1007/s10008-010-1103-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 15 2010 2 23 05 391-397 |
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10.1007/s10008-010-1103-z doi (DE-627)SPR007966318 (SPR)s10008-010-1103-z-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Yang, Tongyong verfasserin aut The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials were successfully prepared by sol–gel method with two different Li sources. The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by scanning electron microscopy, Fourier transform infrared, X-ray diffraction, and electrochemical method. The structure of both samples is confirmed as typical cubic spinel with Fd3m space group, whichever lithium salt is adopted. The grain size of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ powder and its electrochemical behaviors are strongly affected by Li sources. For the samples prepared with lithium acetate, more spinel nucleation should form during the precalcination process, which was stimulated by the heat released from the combustion of extra organic acetate group. Therefore, the particle size of the obtained powder presents smaller average and wider distribution, which facilitates the initial discharge capacity and deteriorates the cycling performance. More seriously, there exists cation replacement of Li sites by transition metal elements, which causes channel block for Li ion transference and deteriorates the rate capability. The compound obtained with lithium hydroxide exhibits better electrochemical responses in terms of both cycling and rate properties due to higher crystallinity, moderate particle size, narrow size distribution and lower transition cation substitute content. Sun, Kening verfasserin aut Lei, Zhengyu verfasserin aut Zhang, Naiqing verfasserin aut Lang, Ye verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 15(2010), 2 vom: 23. Mai, Seite 391-397 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:15 year:2010 number:2 day:23 month:05 pages:391-397 https://dx.doi.org/10.1007/s10008-010-1103-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 15 2010 2 23 05 391-397 |
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10.1007/s10008-010-1103-z doi (DE-627)SPR007966318 (SPR)s10008-010-1103-z-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Yang, Tongyong verfasserin aut The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials were successfully prepared by sol–gel method with two different Li sources. The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by scanning electron microscopy, Fourier transform infrared, X-ray diffraction, and electrochemical method. The structure of both samples is confirmed as typical cubic spinel with Fd3m space group, whichever lithium salt is adopted. The grain size of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ powder and its electrochemical behaviors are strongly affected by Li sources. For the samples prepared with lithium acetate, more spinel nucleation should form during the precalcination process, which was stimulated by the heat released from the combustion of extra organic acetate group. Therefore, the particle size of the obtained powder presents smaller average and wider distribution, which facilitates the initial discharge capacity and deteriorates the cycling performance. More seriously, there exists cation replacement of Li sites by transition metal elements, which causes channel block for Li ion transference and deteriorates the rate capability. The compound obtained with lithium hydroxide exhibits better electrochemical responses in terms of both cycling and rate properties due to higher crystallinity, moderate particle size, narrow size distribution and lower transition cation substitute content. Sun, Kening verfasserin aut Lei, Zhengyu verfasserin aut Zhang, Naiqing verfasserin aut Lang, Ye verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 15(2010), 2 vom: 23. Mai, Seite 391-397 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:15 year:2010 number:2 day:23 month:05 pages:391-397 https://dx.doi.org/10.1007/s10008-010-1103-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 15 2010 2 23 05 391-397 |
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Yang, Tongyong @@aut@@ Sun, Kening @@aut@@ Lei, Zhengyu @@aut@@ Zhang, Naiqing @@aut@@ Lang, Ye @@aut@@ |
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The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by scanning electron microscopy, Fourier transform infrared, X-ray diffraction, and electrochemical method. The structure of both samples is confirmed as typical cubic spinel with Fd3m space group, whichever lithium salt is adopted. The grain size of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ powder and its electrochemical behaviors are strongly affected by Li sources. For the samples prepared with lithium acetate, more spinel nucleation should form during the precalcination process, which was stimulated by the heat released from the combustion of extra organic acetate group. Therefore, the particle size of the obtained powder presents smaller average and wider distribution, which facilitates the initial discharge capacity and deteriorates the cycling performance. More seriously, there exists cation replacement of Li sites by transition metal elements, which causes channel block for Li ion transference and deteriorates the rate capability. The compound obtained with lithium hydroxide exhibits better electrochemical responses in terms of both cycling and rate properties due to higher crystallinity, moderate particle size, narrow size distribution and lower transition cation substitute content.</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sun, Kening</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lei, Zhengyu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Naiqing</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lang, Ye</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of solid state electrochemistry</subfield><subfield code="d">Berlin : Springer, 1997</subfield><subfield code="g">15(2010), 2 vom: 23. 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Yang, Tongyong |
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Yang, Tongyong ddc 540 bkl 35.14 bkl 35.90 The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries |
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540 ASE 35.14 bkl 35.90 bkl The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries |
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ddc 540 bkl 35.14 bkl 35.90 |
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The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries |
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(DE-627)SPR007966318 (SPR)s10008-010-1103-z-e |
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The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries |
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Yang, Tongyong |
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Journal of solid state electrochemistry |
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Yang, Tongyong Sun, Kening Lei, Zhengyu Zhang, Naiqing Lang, Ye |
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Yang, Tongyong |
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10.1007/s10008-010-1103-z |
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verfasserin |
| title_sort |
influence of li sources on physical and electrochemical properties of $ lini_{0.5} %$ mn_{1.5} %$ o_{4} $ cathode materials for lithium-ion batteries |
| title_auth |
The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries |
| abstract |
Abstract $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials were successfully prepared by sol–gel method with two different Li sources. The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by scanning electron microscopy, Fourier transform infrared, X-ray diffraction, and electrochemical method. The structure of both samples is confirmed as typical cubic spinel with Fd3m space group, whichever lithium salt is adopted. The grain size of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ powder and its electrochemical behaviors are strongly affected by Li sources. For the samples prepared with lithium acetate, more spinel nucleation should form during the precalcination process, which was stimulated by the heat released from the combustion of extra organic acetate group. Therefore, the particle size of the obtained powder presents smaller average and wider distribution, which facilitates the initial discharge capacity and deteriorates the cycling performance. More seriously, there exists cation replacement of Li sites by transition metal elements, which causes channel block for Li ion transference and deteriorates the rate capability. The compound obtained with lithium hydroxide exhibits better electrochemical responses in terms of both cycling and rate properties due to higher crystallinity, moderate particle size, narrow size distribution and lower transition cation substitute content. |
| abstractGer |
Abstract $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials were successfully prepared by sol–gel method with two different Li sources. The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by scanning electron microscopy, Fourier transform infrared, X-ray diffraction, and electrochemical method. The structure of both samples is confirmed as typical cubic spinel with Fd3m space group, whichever lithium salt is adopted. The grain size of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ powder and its electrochemical behaviors are strongly affected by Li sources. For the samples prepared with lithium acetate, more spinel nucleation should form during the precalcination process, which was stimulated by the heat released from the combustion of extra organic acetate group. Therefore, the particle size of the obtained powder presents smaller average and wider distribution, which facilitates the initial discharge capacity and deteriorates the cycling performance. More seriously, there exists cation replacement of Li sites by transition metal elements, which causes channel block for Li ion transference and deteriorates the rate capability. The compound obtained with lithium hydroxide exhibits better electrochemical responses in terms of both cycling and rate properties due to higher crystallinity, moderate particle size, narrow size distribution and lower transition cation substitute content. |
| abstract_unstemmed |
Abstract $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials were successfully prepared by sol–gel method with two different Li sources. The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by scanning electron microscopy, Fourier transform infrared, X-ray diffraction, and electrochemical method. The structure of both samples is confirmed as typical cubic spinel with Fd3m space group, whichever lithium salt is adopted. The grain size of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ powder and its electrochemical behaviors are strongly affected by Li sources. For the samples prepared with lithium acetate, more spinel nucleation should form during the precalcination process, which was stimulated by the heat released from the combustion of extra organic acetate group. Therefore, the particle size of the obtained powder presents smaller average and wider distribution, which facilitates the initial discharge capacity and deteriorates the cycling performance. More seriously, there exists cation replacement of Li sites by transition metal elements, which causes channel block for Li ion transference and deteriorates the rate capability. The compound obtained with lithium hydroxide exhibits better electrochemical responses in terms of both cycling and rate properties due to higher crystallinity, moderate particle size, narrow size distribution and lower transition cation substitute content. |
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2 |
| title_short |
The influence of Li sources on physical and electrochemical properties of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ cathode materials for lithium-ion batteries |
| url |
https://dx.doi.org/10.1007/s10008-010-1103-z |
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true |
| author2 |
Sun, Kening Lei, Zhengyu Zhang, Naiqing Lang, Ye |
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Sun, Kening Lei, Zhengyu Zhang, Naiqing Lang, Ye |
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271175400 |
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c |
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| doi_str |
10.1007/s10008-010-1103-z |
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2024-07-03T16:26:03.062Z |
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The effect of both lithium acetate and lithium hydroxide on physical and electrochemical performances of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ was investigated by scanning electron microscopy, Fourier transform infrared, X-ray diffraction, and electrochemical method. The structure of both samples is confirmed as typical cubic spinel with Fd3m space group, whichever lithium salt is adopted. The grain size of $ LiNi_{0.5} %$ Mn_{1.5} %$ O_{4} $ powder and its electrochemical behaviors are strongly affected by Li sources. For the samples prepared with lithium acetate, more spinel nucleation should form during the precalcination process, which was stimulated by the heat released from the combustion of extra organic acetate group. Therefore, the particle size of the obtained powder presents smaller average and wider distribution, which facilitates the initial discharge capacity and deteriorates the cycling performance. 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| score |
7.4011555 |