Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene
Abstract Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yue, Ruirui [verfasserIn] Chen, Shuai [verfasserIn] Liu, Congcong [verfasserIn] Lu, Baoyang [verfasserIn] Xu, Jingkun [verfasserIn] Wang, Jianmin [verfasserIn] Liu, Guodong [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2011 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of solid state electrochemistry - Berlin : Springer, 1997, 16(2011), 1 vom: 20. Jan., Seite 117-126 |
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| Übergeordnetes Werk: |
volume:16 ; year:2011 ; number:1 ; day:20 ; month:01 ; pages:117-126 |
| Links: |
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| DOI / URN: |
10.1007/s10008-011-1292-0 |
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| Katalog-ID: |
SPR007968264 |
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| 245 | 1 | 0 | |a Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene |
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| 520 | |a Abstract Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S $ cm^{−1} $ at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S $ cm^{−1} $) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) ($ 10^{−3} $ S $ cm^{−1} $). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. As expected, the thermoelectric performance of PTT and P2Cz-D were both improved through copolymerization, which may be beneficial to the exploration and investigation of novel organic thermoelectric materials. | ||
| 650 | 4 | |a Conducting polymers |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Electrochemical copolymerization |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Thermoelectric material |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Polythiophene |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Polycarbazole |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Chen, Shuai |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Congcong |e verfasserin |4 aut | |
| 700 | 1 | |a Lu, Baoyang |e verfasserin |4 aut | |
| 700 | 1 | |a Xu, Jingkun |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Jianmin |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Guodong |e verfasserin |4 aut | |
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10.1007/s10008-011-1292-0 doi (DE-627)SPR007968264 (SPR)s10008-011-1292-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Yue, Ruirui verfasserin aut Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S $ cm^{−1} $ at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S $ cm^{−1} $) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) ($ 10^{−3} $ S $ cm^{−1} $). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. As expected, the thermoelectric performance of PTT and P2Cz-D were both improved through copolymerization, which may be beneficial to the exploration and investigation of novel organic thermoelectric materials. Conducting polymers (dpeaa)DE-He213 Electrochemical copolymerization (dpeaa)DE-He213 Thermoelectric material (dpeaa)DE-He213 Polythiophene (dpeaa)DE-He213 Polycarbazole (dpeaa)DE-He213 Chen, Shuai verfasserin aut Liu, Congcong verfasserin aut Lu, Baoyang verfasserin aut Xu, Jingkun verfasserin aut Wang, Jianmin verfasserin aut Liu, Guodong verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 16(2011), 1 vom: 20. Jan., Seite 117-126 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:16 year:2011 number:1 day:20 month:01 pages:117-126 https://dx.doi.org/10.1007/s10008-011-1292-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 16 2011 1 20 01 117-126 |
| spelling |
10.1007/s10008-011-1292-0 doi (DE-627)SPR007968264 (SPR)s10008-011-1292-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Yue, Ruirui verfasserin aut Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S $ cm^{−1} $ at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S $ cm^{−1} $) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) ($ 10^{−3} $ S $ cm^{−1} $). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. As expected, the thermoelectric performance of PTT and P2Cz-D were both improved through copolymerization, which may be beneficial to the exploration and investigation of novel organic thermoelectric materials. Conducting polymers (dpeaa)DE-He213 Electrochemical copolymerization (dpeaa)DE-He213 Thermoelectric material (dpeaa)DE-He213 Polythiophene (dpeaa)DE-He213 Polycarbazole (dpeaa)DE-He213 Chen, Shuai verfasserin aut Liu, Congcong verfasserin aut Lu, Baoyang verfasserin aut Xu, Jingkun verfasserin aut Wang, Jianmin verfasserin aut Liu, Guodong verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 16(2011), 1 vom: 20. Jan., Seite 117-126 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:16 year:2011 number:1 day:20 month:01 pages:117-126 https://dx.doi.org/10.1007/s10008-011-1292-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 16 2011 1 20 01 117-126 |
| allfields_unstemmed |
10.1007/s10008-011-1292-0 doi (DE-627)SPR007968264 (SPR)s10008-011-1292-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Yue, Ruirui verfasserin aut Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S $ cm^{−1} $ at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S $ cm^{−1} $) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) ($ 10^{−3} $ S $ cm^{−1} $). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. As expected, the thermoelectric performance of PTT and P2Cz-D were both improved through copolymerization, which may be beneficial to the exploration and investigation of novel organic thermoelectric materials. Conducting polymers (dpeaa)DE-He213 Electrochemical copolymerization (dpeaa)DE-He213 Thermoelectric material (dpeaa)DE-He213 Polythiophene (dpeaa)DE-He213 Polycarbazole (dpeaa)DE-He213 Chen, Shuai verfasserin aut Liu, Congcong verfasserin aut Lu, Baoyang verfasserin aut Xu, Jingkun verfasserin aut Wang, Jianmin verfasserin aut Liu, Guodong verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 16(2011), 1 vom: 20. Jan., Seite 117-126 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:16 year:2011 number:1 day:20 month:01 pages:117-126 https://dx.doi.org/10.1007/s10008-011-1292-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 16 2011 1 20 01 117-126 |
| allfieldsGer |
10.1007/s10008-011-1292-0 doi (DE-627)SPR007968264 (SPR)s10008-011-1292-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Yue, Ruirui verfasserin aut Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S $ cm^{−1} $ at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S $ cm^{−1} $) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) ($ 10^{−3} $ S $ cm^{−1} $). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. As expected, the thermoelectric performance of PTT and P2Cz-D were both improved through copolymerization, which may be beneficial to the exploration and investigation of novel organic thermoelectric materials. Conducting polymers (dpeaa)DE-He213 Electrochemical copolymerization (dpeaa)DE-He213 Thermoelectric material (dpeaa)DE-He213 Polythiophene (dpeaa)DE-He213 Polycarbazole (dpeaa)DE-He213 Chen, Shuai verfasserin aut Liu, Congcong verfasserin aut Lu, Baoyang verfasserin aut Xu, Jingkun verfasserin aut Wang, Jianmin verfasserin aut Liu, Guodong verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 16(2011), 1 vom: 20. Jan., Seite 117-126 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:16 year:2011 number:1 day:20 month:01 pages:117-126 https://dx.doi.org/10.1007/s10008-011-1292-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 16 2011 1 20 01 117-126 |
| allfieldsSound |
10.1007/s10008-011-1292-0 doi (DE-627)SPR007968264 (SPR)s10008-011-1292-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Yue, Ruirui verfasserin aut Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S $ cm^{−1} $ at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S $ cm^{−1} $) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) ($ 10^{−3} $ S $ cm^{−1} $). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. As expected, the thermoelectric performance of PTT and P2Cz-D were both improved through copolymerization, which may be beneficial to the exploration and investigation of novel organic thermoelectric materials. Conducting polymers (dpeaa)DE-He213 Electrochemical copolymerization (dpeaa)DE-He213 Thermoelectric material (dpeaa)DE-He213 Polythiophene (dpeaa)DE-He213 Polycarbazole (dpeaa)DE-He213 Chen, Shuai verfasserin aut Liu, Congcong verfasserin aut Lu, Baoyang verfasserin aut Xu, Jingkun verfasserin aut Wang, Jianmin verfasserin aut Liu, Guodong verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 16(2011), 1 vom: 20. Jan., Seite 117-126 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:16 year:2011 number:1 day:20 month:01 pages:117-126 https://dx.doi.org/10.1007/s10008-011-1292-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 16 2011 1 20 01 117-126 |
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English |
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Enthalten in Journal of solid state electrochemistry 16(2011), 1 vom: 20. Jan., Seite 117-126 volume:16 year:2011 number:1 day:20 month:01 pages:117-126 |
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Enthalten in Journal of solid state electrochemistry 16(2011), 1 vom: 20. Jan., Seite 117-126 volume:16 year:2011 number:1 day:20 month:01 pages:117-126 |
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Article |
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findex.gbv.de |
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Conducting polymers Electrochemical copolymerization Thermoelectric material Polythiophene Polycarbazole |
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Journal of solid state electrochemistry |
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Yue, Ruirui @@aut@@ Chen, Shuai @@aut@@ Liu, Congcong @@aut@@ Lu, Baoyang @@aut@@ Xu, Jingkun @@aut@@ Wang, Jianmin @@aut@@ Liu, Guodong @@aut@@ |
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2011-01-20T00:00:00Z |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR007968264</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230520004720.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201005s2011 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10008-011-1292-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR007968264</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10008-011-1292-0-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.14</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.90</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Yue, Ruirui</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2011</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S $ cm^{−1} $ at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S $ cm^{−1} $) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) ($ 10^{−3} $ S $ cm^{−1} $). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. 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Yue, Ruirui |
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Yue, Ruirui ddc 540 bkl 35.14 bkl 35.90 misc Conducting polymers misc Electrochemical copolymerization misc Thermoelectric material misc Polythiophene misc Polycarbazole Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene |
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540 ASE 35.14 bkl 35.90 bkl Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene Conducting polymers (dpeaa)DE-He213 Electrochemical copolymerization (dpeaa)DE-He213 Thermoelectric material (dpeaa)DE-He213 Polythiophene (dpeaa)DE-He213 Polycarbazole (dpeaa)DE-He213 |
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ddc 540 bkl 35.14 bkl 35.90 misc Conducting polymers misc Electrochemical copolymerization misc Thermoelectric material misc Polythiophene misc Polycarbazole |
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ddc 540 bkl 35.14 bkl 35.90 misc Conducting polymers misc Electrochemical copolymerization misc Thermoelectric material misc Polythiophene misc Polycarbazole |
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ddc 540 bkl 35.14 bkl 35.90 misc Conducting polymers misc Electrochemical copolymerization misc Thermoelectric material misc Polythiophene misc Polycarbazole |
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Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene |
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(DE-627)SPR007968264 (SPR)s10008-011-1292-0-e |
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Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene |
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Journal of solid state electrochemistry |
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Yue, Ruirui Chen, Shuai Liu, Congcong Lu, Baoyang Xu, Jingkun Wang, Jianmin Liu, Guodong |
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Elektronische Aufsätze |
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Yue, Ruirui |
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10.1007/s10008-011-1292-0 |
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540 |
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synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene |
| title_auth |
Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene |
| abstract |
Abstract Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S $ cm^{−1} $ at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S $ cm^{−1} $) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) ($ 10^{−3} $ S $ cm^{−1} $). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. As expected, the thermoelectric performance of PTT and P2Cz-D were both improved through copolymerization, which may be beneficial to the exploration and investigation of novel organic thermoelectric materials. |
| abstractGer |
Abstract Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S $ cm^{−1} $ at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S $ cm^{−1} $) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) ($ 10^{−3} $ S $ cm^{−1} $). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. As expected, the thermoelectric performance of PTT and P2Cz-D were both improved through copolymerization, which may be beneficial to the exploration and investigation of novel organic thermoelectric materials. |
| abstract_unstemmed |
Abstract Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S $ cm^{−1} $ at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S $ cm^{−1} $) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) ($ 10^{−3} $ S $ cm^{−1} $). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. As expected, the thermoelectric performance of PTT and P2Cz-D were both improved through copolymerization, which may be beneficial to the exploration and investigation of novel organic thermoelectric materials. |
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Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene |
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https://dx.doi.org/10.1007/s10008-011-1292-0 |
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Chen, Shuai Liu, Congcong Lu, Baoyang Xu, Jingkun Wang, Jianmin Liu, Guodong |
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Chen, Shuai Liu, Congcong Lu, Baoyang Xu, Jingkun Wang, Jianmin Liu, Guodong |
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| score |
7.3996267 |