Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries

Abstract Effect of secondary particle fracture on the accumulated cycle capacity fade of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode is difficult to evaluate since performance degradation of electrode material is always caused by several factors simultaneously. Herein, $ LiNi_{0.5} %$ Co_{...
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Autor*in:	Li, Guangyin [verfasserIn] Zhang, Zhanjun [verfasserIn] Huang, Zhenlei [verfasserIn] Yang, Chengkai [verfasserIn] Zuo, Zicheng [verfasserIn] Zhou, Henghui [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2016

Schlagwörter:	Secondary particle Fracture Capacity fade Cathode

Übergeordnetes Werk:	Enthalten in: Journal of solid state electrochemistry - Berlin : Springer, 1997, 21(2016), 3 vom: 04. Okt., Seite 673-682
Übergeordnetes Werk:	volume:21 ; year:2016 ; number:3 ; day:04 ; month:10 ; pages:673-682

Links:	Volltext

DOI / URN:	10.1007/s10008-016-3399-9

Katalog-ID:	SPR007990421

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245	1	0	\|a Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries
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520			\|a Abstract Effect of secondary particle fracture on the accumulated cycle capacity fade of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode is difficult to evaluate since performance degradation of electrode material is always caused by several factors simultaneously. Herein, $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ single particles (Sin-P) are prepared and introduced as a reference to understand the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ secondary particles (Sec-P). Sec-P exhibited accumulated cycle capacity fade compared to Sin-P when cycled at high rate, high voltage, and high temperature. The accumulated cycle capacity fade was mainly caused by the secondary particle fracture of Sec-P, which was confirmed by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) analysis. Further, XPS and electrochemical impedance spectroscopy (EIS) analysis indicated that the surface property changes and resistance rise were responsible for the accumulated cycle capacity fade. The study provides a novel way to analyze the accumulated cycle capacity fade caused by the secondary particle fracture and is helpful for understanding the performance degradation mechanism of electrode material.
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700	1		\|a Zuo, Zicheng \|e verfasserin \|4 aut
700	1		\|a Zhou, Henghui \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Journal of solid state electrochemistry \|d Berlin : Springer, 1997 \|g 21(2016), 3 vom: 04. Okt., Seite 673-682 \|w (DE-627)271175400 \|w (DE-600)1478940-1 \|x 1433-0768 \|7 nnns
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author_variant	g l gl z z zz z h zh c y cy z z zz h z hz
matchkey_str	article:14330768:2016----::nesadntecuuaecceaaiyaeasdyhscnayatcercuefii1yoxn
hierarchy_sort_str	2016
bklnumber	35.14 35.90
publishDate	2016
allfields	10.1007/s10008-016-3399-9 doi (DE-627)SPR007990421 (SPR)s10008-016-3399-9-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Li, Guangyin verfasserin aut Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Effect of secondary particle fracture on the accumulated cycle capacity fade of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode is difficult to evaluate since performance degradation of electrode material is always caused by several factors simultaneously. Herein, $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ single particles (Sin-P) are prepared and introduced as a reference to understand the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ secondary particles (Sec-P). Sec-P exhibited accumulated cycle capacity fade compared to Sin-P when cycled at high rate, high voltage, and high temperature. The accumulated cycle capacity fade was mainly caused by the secondary particle fracture of Sec-P, which was confirmed by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) analysis. Further, XPS and electrochemical impedance spectroscopy (EIS) analysis indicated that the surface property changes and resistance rise were responsible for the accumulated cycle capacity fade. The study provides a novel way to analyze the accumulated cycle capacity fade caused by the secondary particle fracture and is helpful for understanding the performance degradation mechanism of electrode material. Secondary particle (dpeaa)DE-He213 Fracture (dpeaa)DE-He213 Capacity fade (dpeaa)DE-He213 Cathode (dpeaa)DE-He213 Zhang, Zhanjun verfasserin aut Huang, Zhenlei verfasserin aut Yang, Chengkai verfasserin aut Zuo, Zicheng verfasserin aut Zhou, Henghui verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 21(2016), 3 vom: 04. Okt., Seite 673-682 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:21 year:2016 number:3 day:04 month:10 pages:673-682 https://dx.doi.org/10.1007/s10008-016-3399-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 21 2016 3 04 10 673-682
spelling	10.1007/s10008-016-3399-9 doi (DE-627)SPR007990421 (SPR)s10008-016-3399-9-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Li, Guangyin verfasserin aut Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Effect of secondary particle fracture on the accumulated cycle capacity fade of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode is difficult to evaluate since performance degradation of electrode material is always caused by several factors simultaneously. Herein, $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ single particles (Sin-P) are prepared and introduced as a reference to understand the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ secondary particles (Sec-P). Sec-P exhibited accumulated cycle capacity fade compared to Sin-P when cycled at high rate, high voltage, and high temperature. The accumulated cycle capacity fade was mainly caused by the secondary particle fracture of Sec-P, which was confirmed by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) analysis. Further, XPS and electrochemical impedance spectroscopy (EIS) analysis indicated that the surface property changes and resistance rise were responsible for the accumulated cycle capacity fade. The study provides a novel way to analyze the accumulated cycle capacity fade caused by the secondary particle fracture and is helpful for understanding the performance degradation mechanism of electrode material. Secondary particle (dpeaa)DE-He213 Fracture (dpeaa)DE-He213 Capacity fade (dpeaa)DE-He213 Cathode (dpeaa)DE-He213 Zhang, Zhanjun verfasserin aut Huang, Zhenlei verfasserin aut Yang, Chengkai verfasserin aut Zuo, Zicheng verfasserin aut Zhou, Henghui verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 21(2016), 3 vom: 04. Okt., Seite 673-682 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:21 year:2016 number:3 day:04 month:10 pages:673-682 https://dx.doi.org/10.1007/s10008-016-3399-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 21 2016 3 04 10 673-682
allfields_unstemmed	10.1007/s10008-016-3399-9 doi (DE-627)SPR007990421 (SPR)s10008-016-3399-9-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Li, Guangyin verfasserin aut Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Effect of secondary particle fracture on the accumulated cycle capacity fade of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode is difficult to evaluate since performance degradation of electrode material is always caused by several factors simultaneously. Herein, $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ single particles (Sin-P) are prepared and introduced as a reference to understand the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ secondary particles (Sec-P). Sec-P exhibited accumulated cycle capacity fade compared to Sin-P when cycled at high rate, high voltage, and high temperature. The accumulated cycle capacity fade was mainly caused by the secondary particle fracture of Sec-P, which was confirmed by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) analysis. Further, XPS and electrochemical impedance spectroscopy (EIS) analysis indicated that the surface property changes and resistance rise were responsible for the accumulated cycle capacity fade. The study provides a novel way to analyze the accumulated cycle capacity fade caused by the secondary particle fracture and is helpful for understanding the performance degradation mechanism of electrode material. Secondary particle (dpeaa)DE-He213 Fracture (dpeaa)DE-He213 Capacity fade (dpeaa)DE-He213 Cathode (dpeaa)DE-He213 Zhang, Zhanjun verfasserin aut Huang, Zhenlei verfasserin aut Yang, Chengkai verfasserin aut Zuo, Zicheng verfasserin aut Zhou, Henghui verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 21(2016), 3 vom: 04. Okt., Seite 673-682 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:21 year:2016 number:3 day:04 month:10 pages:673-682 https://dx.doi.org/10.1007/s10008-016-3399-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 21 2016 3 04 10 673-682
allfieldsGer	10.1007/s10008-016-3399-9 doi (DE-627)SPR007990421 (SPR)s10008-016-3399-9-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Li, Guangyin verfasserin aut Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Effect of secondary particle fracture on the accumulated cycle capacity fade of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode is difficult to evaluate since performance degradation of electrode material is always caused by several factors simultaneously. Herein, $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ single particles (Sin-P) are prepared and introduced as a reference to understand the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ secondary particles (Sec-P). Sec-P exhibited accumulated cycle capacity fade compared to Sin-P when cycled at high rate, high voltage, and high temperature. The accumulated cycle capacity fade was mainly caused by the secondary particle fracture of Sec-P, which was confirmed by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) analysis. Further, XPS and electrochemical impedance spectroscopy (EIS) analysis indicated that the surface property changes and resistance rise were responsible for the accumulated cycle capacity fade. The study provides a novel way to analyze the accumulated cycle capacity fade caused by the secondary particle fracture and is helpful for understanding the performance degradation mechanism of electrode material. Secondary particle (dpeaa)DE-He213 Fracture (dpeaa)DE-He213 Capacity fade (dpeaa)DE-He213 Cathode (dpeaa)DE-He213 Zhang, Zhanjun verfasserin aut Huang, Zhenlei verfasserin aut Yang, Chengkai verfasserin aut Zuo, Zicheng verfasserin aut Zhou, Henghui verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 21(2016), 3 vom: 04. Okt., Seite 673-682 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:21 year:2016 number:3 day:04 month:10 pages:673-682 https://dx.doi.org/10.1007/s10008-016-3399-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 21 2016 3 04 10 673-682
allfieldsSound	10.1007/s10008-016-3399-9 doi (DE-627)SPR007990421 (SPR)s10008-016-3399-9-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Li, Guangyin verfasserin aut Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Effect of secondary particle fracture on the accumulated cycle capacity fade of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode is difficult to evaluate since performance degradation of electrode material is always caused by several factors simultaneously. Herein, $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ single particles (Sin-P) are prepared and introduced as a reference to understand the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ secondary particles (Sec-P). Sec-P exhibited accumulated cycle capacity fade compared to Sin-P when cycled at high rate, high voltage, and high temperature. The accumulated cycle capacity fade was mainly caused by the secondary particle fracture of Sec-P, which was confirmed by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) analysis. Further, XPS and electrochemical impedance spectroscopy (EIS) analysis indicated that the surface property changes and resistance rise were responsible for the accumulated cycle capacity fade. The study provides a novel way to analyze the accumulated cycle capacity fade caused by the secondary particle fracture and is helpful for understanding the performance degradation mechanism of electrode material. Secondary particle (dpeaa)DE-He213 Fracture (dpeaa)DE-He213 Capacity fade (dpeaa)DE-He213 Cathode (dpeaa)DE-He213 Zhang, Zhanjun verfasserin aut Huang, Zhenlei verfasserin aut Yang, Chengkai verfasserin aut Zuo, Zicheng verfasserin aut Zhou, Henghui verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 21(2016), 3 vom: 04. Okt., Seite 673-682 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:21 year:2016 number:3 day:04 month:10 pages:673-682 https://dx.doi.org/10.1007/s10008-016-3399-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 21 2016 3 04 10 673-682
language	English
source	Enthalten in Journal of solid state electrochemistry 21(2016), 3 vom: 04. Okt., Seite 673-682 volume:21 year:2016 number:3 day:04 month:10 pages:673-682
sourceStr	Enthalten in Journal of solid state electrochemistry 21(2016), 3 vom: 04. Okt., Seite 673-682 volume:21 year:2016 number:3 day:04 month:10 pages:673-682
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Secondary particle Fracture Capacity fade Cathode
dewey-raw	540
isfreeaccess_bool	false
container_title	Journal of solid state electrochemistry
authorswithroles_txt_mv	Li, Guangyin @@aut@@ Zhang, Zhanjun @@aut@@ Huang, Zhenlei @@aut@@ Yang, Chengkai @@aut@@ Zuo, Zicheng @@aut@@ Zhou, Henghui @@aut@@
publishDateDaySort_date	2016-10-04T00:00:00Z
hierarchy_top_id	271175400
dewey-sort	3540
id	SPR007990421
language_de	englisch
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author	Li, Guangyin
spellingShingle	Li, Guangyin ddc 540 bkl 35.14 bkl 35.90 misc Secondary particle misc Fracture misc Capacity fade misc Cathode Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries
authorStr	Li, Guangyin
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topic_title	540 ASE 35.14 bkl 35.90 bkl Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries Secondary particle (dpeaa)DE-He213 Fracture (dpeaa)DE-He213 Capacity fade (dpeaa)DE-He213 Cathode (dpeaa)DE-He213
topic	ddc 540 bkl 35.14 bkl 35.90 misc Secondary particle misc Fracture misc Capacity fade misc Cathode
topic_unstemmed	ddc 540 bkl 35.14 bkl 35.90 misc Secondary particle misc Fracture misc Capacity fade misc Cathode
topic_browse	ddc 540 bkl 35.14 bkl 35.90 misc Secondary particle misc Fracture misc Capacity fade misc Cathode
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
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title	Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries
ctrlnum	(DE-627)SPR007990421 (SPR)s10008-016-3399-9-e
title_full	Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries
author_sort	Li, Guangyin
journal	Journal of solid state electrochemistry
journalStr	Journal of solid state electrochemistry
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author_browse	Li, Guangyin Zhang, Zhanjun Huang, Zhenlei Yang, Chengkai Zuo, Zicheng Zhou, Henghui
container_volume	21
class	540 ASE 35.14 bkl 35.90 bkl
format_se	Elektronische Aufsätze
author-letter	Li, Guangyin
doi_str_mv	10.1007/s10008-016-3399-9
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author2-role	verfasserin
title_sort	understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ lini_{1-x-y} %$ co_{x} %$ mn_{y} %$ o_{2} $ cathode for lithium ion batteries
title_auth	Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries
abstract	Abstract Effect of secondary particle fracture on the accumulated cycle capacity fade of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode is difficult to evaluate since performance degradation of electrode material is always caused by several factors simultaneously. Herein, $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ single particles (Sin-P) are prepared and introduced as a reference to understand the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ secondary particles (Sec-P). Sec-P exhibited accumulated cycle capacity fade compared to Sin-P when cycled at high rate, high voltage, and high temperature. The accumulated cycle capacity fade was mainly caused by the secondary particle fracture of Sec-P, which was confirmed by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) analysis. Further, XPS and electrochemical impedance spectroscopy (EIS) analysis indicated that the surface property changes and resistance rise were responsible for the accumulated cycle capacity fade. The study provides a novel way to analyze the accumulated cycle capacity fade caused by the secondary particle fracture and is helpful for understanding the performance degradation mechanism of electrode material.
abstractGer	Abstract Effect of secondary particle fracture on the accumulated cycle capacity fade of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode is difficult to evaluate since performance degradation of electrode material is always caused by several factors simultaneously. Herein, $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ single particles (Sin-P) are prepared and introduced as a reference to understand the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ secondary particles (Sec-P). Sec-P exhibited accumulated cycle capacity fade compared to Sin-P when cycled at high rate, high voltage, and high temperature. The accumulated cycle capacity fade was mainly caused by the secondary particle fracture of Sec-P, which was confirmed by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) analysis. Further, XPS and electrochemical impedance spectroscopy (EIS) analysis indicated that the surface property changes and resistance rise were responsible for the accumulated cycle capacity fade. The study provides a novel way to analyze the accumulated cycle capacity fade caused by the secondary particle fracture and is helpful for understanding the performance degradation mechanism of electrode material.
abstract_unstemmed	Abstract Effect of secondary particle fracture on the accumulated cycle capacity fade of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode is difficult to evaluate since performance degradation of electrode material is always caused by several factors simultaneously. Herein, $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ single particles (Sin-P) are prepared and introduced as a reference to understand the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $ secondary particles (Sec-P). Sec-P exhibited accumulated cycle capacity fade compared to Sin-P when cycled at high rate, high voltage, and high temperature. The accumulated cycle capacity fade was mainly caused by the secondary particle fracture of Sec-P, which was confirmed by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) analysis. Further, XPS and electrochemical impedance spectroscopy (EIS) analysis indicated that the surface property changes and resistance rise were responsible for the accumulated cycle capacity fade. The study provides a novel way to analyze the accumulated cycle capacity fade caused by the secondary particle fracture and is helpful for understanding the performance degradation mechanism of electrode material.
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container_issue	3
title_short	Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries
url	https://dx.doi.org/10.1007/s10008-016-3399-9
remote_bool	true
author2	Zhang, Zhanjun Huang, Zhenlei Yang, Chengkai Zuo, Zicheng Zhou, Henghui
author2Str	Zhang, Zhanjun Huang, Zhenlei Yang, Chengkai Zuo, Zicheng Zhou, Henghui
ppnlink	271175400
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hochschulschrift_bool	false
doi_str	10.1007/s10008-016-3399-9
up_date	2024-07-03T16:37:09.783Z
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Understanding the accumulated cycle capacity fade caused by the secondary particle fracture of $ LiNi_{1-x-y} %$ Co_{x} %$ Mn_{y} %$ O_{2} $ cathode for lithium ion batteries

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