The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis
Abstract The effects of $ H_{2} $ in the feed gasses on the Chichibabin condensation of ammonia with formaldehyde and acetaldehyde for pyridine and 3-picolines synthesis were studied in this work. It was observed that over Pt/ZSM-5 and H-ZSM-5 catalyst hydrogen can moderate the deactivation, depress...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Jin, Fang [verfasserIn] Li, Yongdan [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Catalysis letters - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988, 131(2009), 3-4 vom: 10. Apr., Seite 545-551 |
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| Übergeordnetes Werk: |
volume:131 ; year:2009 ; number:3-4 ; day:10 ; month:04 ; pages:545-551 |
| Links: |
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| DOI / URN: |
10.1007/s10562-009-9937-7 |
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| Katalog-ID: |
SPR011328673 |
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| 100 | 1 | |a Jin, Fang |e verfasserin |4 aut | |
| 245 | 1 | 4 | |a The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis |
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| 520 | |a Abstract The effects of $ H_{2} $ in the feed gasses on the Chichibabin condensation of ammonia with formaldehyde and acetaldehyde for pyridine and 3-picolines synthesis were studied in this work. It was observed that over Pt/ZSM-5 and H-ZSM-5 catalyst hydrogen can moderate the deactivation, depressed the coke formation, slightly lower the initial yield of pyridine bases and increase the selectivity of pyridine over 3-picoline. These effects cannot be simply attributed to the reactant dilution by $ H_{2} $, while are similar as those of spilt-over hydrogen on a Pt/ZSM-5 catalyst on this reaction. These phenomena are taken as the evidence to support the hypothesis that molecular $ H_{2} $ is activated by the pure zeolite during the Chichibabin condensation. | ||
| 650 | 4 | |a Chichibabin condensation |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a ZSM-5 |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Pyridine bases |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Hydrogen |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Deactivation |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Li, Yongdan |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Catalysis letters |d Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 |g 131(2009), 3-4 vom: 10. Apr., Seite 545-551 |w (DE-627)306717638 |w (DE-600)1501518-X |x 1572-879X |7 nnns |
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10.1007/s10562-009-9937-7 doi (DE-627)SPR011328673 (SPR)s10562-009-9937-7-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Jin, Fang verfasserin aut The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The effects of $ H_{2} $ in the feed gasses on the Chichibabin condensation of ammonia with formaldehyde and acetaldehyde for pyridine and 3-picolines synthesis were studied in this work. It was observed that over Pt/ZSM-5 and H-ZSM-5 catalyst hydrogen can moderate the deactivation, depressed the coke formation, slightly lower the initial yield of pyridine bases and increase the selectivity of pyridine over 3-picoline. These effects cannot be simply attributed to the reactant dilution by $ H_{2} $, while are similar as those of spilt-over hydrogen on a Pt/ZSM-5 catalyst on this reaction. These phenomena are taken as the evidence to support the hypothesis that molecular $ H_{2} $ is activated by the pure zeolite during the Chichibabin condensation. Chichibabin condensation (dpeaa)DE-He213 ZSM-5 (dpeaa)DE-He213 Pyridine bases (dpeaa)DE-He213 Hydrogen (dpeaa)DE-He213 Deactivation (dpeaa)DE-He213 Li, Yongdan verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 131(2009), 3-4 vom: 10. Apr., Seite 545-551 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:131 year:2009 number:3-4 day:10 month:04 pages:545-551 https://dx.doi.org/10.1007/s10562-009-9937-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 131 2009 3-4 10 04 545-551 |
| spelling |
10.1007/s10562-009-9937-7 doi (DE-627)SPR011328673 (SPR)s10562-009-9937-7-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Jin, Fang verfasserin aut The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The effects of $ H_{2} $ in the feed gasses on the Chichibabin condensation of ammonia with formaldehyde and acetaldehyde for pyridine and 3-picolines synthesis were studied in this work. It was observed that over Pt/ZSM-5 and H-ZSM-5 catalyst hydrogen can moderate the deactivation, depressed the coke formation, slightly lower the initial yield of pyridine bases and increase the selectivity of pyridine over 3-picoline. These effects cannot be simply attributed to the reactant dilution by $ H_{2} $, while are similar as those of spilt-over hydrogen on a Pt/ZSM-5 catalyst on this reaction. These phenomena are taken as the evidence to support the hypothesis that molecular $ H_{2} $ is activated by the pure zeolite during the Chichibabin condensation. Chichibabin condensation (dpeaa)DE-He213 ZSM-5 (dpeaa)DE-He213 Pyridine bases (dpeaa)DE-He213 Hydrogen (dpeaa)DE-He213 Deactivation (dpeaa)DE-He213 Li, Yongdan verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 131(2009), 3-4 vom: 10. Apr., Seite 545-551 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:131 year:2009 number:3-4 day:10 month:04 pages:545-551 https://dx.doi.org/10.1007/s10562-009-9937-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 131 2009 3-4 10 04 545-551 |
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10.1007/s10562-009-9937-7 doi (DE-627)SPR011328673 (SPR)s10562-009-9937-7-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Jin, Fang verfasserin aut The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The effects of $ H_{2} $ in the feed gasses on the Chichibabin condensation of ammonia with formaldehyde and acetaldehyde for pyridine and 3-picolines synthesis were studied in this work. It was observed that over Pt/ZSM-5 and H-ZSM-5 catalyst hydrogen can moderate the deactivation, depressed the coke formation, slightly lower the initial yield of pyridine bases and increase the selectivity of pyridine over 3-picoline. These effects cannot be simply attributed to the reactant dilution by $ H_{2} $, while are similar as those of spilt-over hydrogen on a Pt/ZSM-5 catalyst on this reaction. These phenomena are taken as the evidence to support the hypothesis that molecular $ H_{2} $ is activated by the pure zeolite during the Chichibabin condensation. Chichibabin condensation (dpeaa)DE-He213 ZSM-5 (dpeaa)DE-He213 Pyridine bases (dpeaa)DE-He213 Hydrogen (dpeaa)DE-He213 Deactivation (dpeaa)DE-He213 Li, Yongdan verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 131(2009), 3-4 vom: 10. Apr., Seite 545-551 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:131 year:2009 number:3-4 day:10 month:04 pages:545-551 https://dx.doi.org/10.1007/s10562-009-9937-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 131 2009 3-4 10 04 545-551 |
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10.1007/s10562-009-9937-7 doi (DE-627)SPR011328673 (SPR)s10562-009-9937-7-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Jin, Fang verfasserin aut The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The effects of $ H_{2} $ in the feed gasses on the Chichibabin condensation of ammonia with formaldehyde and acetaldehyde for pyridine and 3-picolines synthesis were studied in this work. It was observed that over Pt/ZSM-5 and H-ZSM-5 catalyst hydrogen can moderate the deactivation, depressed the coke formation, slightly lower the initial yield of pyridine bases and increase the selectivity of pyridine over 3-picoline. These effects cannot be simply attributed to the reactant dilution by $ H_{2} $, while are similar as those of spilt-over hydrogen on a Pt/ZSM-5 catalyst on this reaction. These phenomena are taken as the evidence to support the hypothesis that molecular $ H_{2} $ is activated by the pure zeolite during the Chichibabin condensation. Chichibabin condensation (dpeaa)DE-He213 ZSM-5 (dpeaa)DE-He213 Pyridine bases (dpeaa)DE-He213 Hydrogen (dpeaa)DE-He213 Deactivation (dpeaa)DE-He213 Li, Yongdan verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 131(2009), 3-4 vom: 10. Apr., Seite 545-551 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:131 year:2009 number:3-4 day:10 month:04 pages:545-551 https://dx.doi.org/10.1007/s10562-009-9937-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 131 2009 3-4 10 04 545-551 |
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10.1007/s10562-009-9937-7 doi (DE-627)SPR011328673 (SPR)s10562-009-9937-7-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Jin, Fang verfasserin aut The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The effects of $ H_{2} $ in the feed gasses on the Chichibabin condensation of ammonia with formaldehyde and acetaldehyde for pyridine and 3-picolines synthesis were studied in this work. It was observed that over Pt/ZSM-5 and H-ZSM-5 catalyst hydrogen can moderate the deactivation, depressed the coke formation, slightly lower the initial yield of pyridine bases and increase the selectivity of pyridine over 3-picoline. These effects cannot be simply attributed to the reactant dilution by $ H_{2} $, while are similar as those of spilt-over hydrogen on a Pt/ZSM-5 catalyst on this reaction. These phenomena are taken as the evidence to support the hypothesis that molecular $ H_{2} $ is activated by the pure zeolite during the Chichibabin condensation. Chichibabin condensation (dpeaa)DE-He213 ZSM-5 (dpeaa)DE-He213 Pyridine bases (dpeaa)DE-He213 Hydrogen (dpeaa)DE-He213 Deactivation (dpeaa)DE-He213 Li, Yongdan verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 131(2009), 3-4 vom: 10. Apr., Seite 545-551 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:131 year:2009 number:3-4 day:10 month:04 pages:545-551 https://dx.doi.org/10.1007/s10562-009-9937-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 131 2009 3-4 10 04 545-551 |
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Jin, Fang @@aut@@ Li, Yongdan @@aut@@ |
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Jin, Fang |
| spellingShingle |
Jin, Fang ddc 540 bkl 35.17 misc Chichibabin condensation misc ZSM-5 misc Pyridine bases misc Hydrogen misc Deactivation The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis |
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540 660 ASE 35.17 bkl The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis Chichibabin condensation (dpeaa)DE-He213 ZSM-5 (dpeaa)DE-He213 Pyridine bases (dpeaa)DE-He213 Hydrogen (dpeaa)DE-He213 Deactivation (dpeaa)DE-He213 |
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ddc 540 bkl 35.17 misc Chichibabin condensation misc ZSM-5 misc Pyridine bases misc Hydrogen misc Deactivation |
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ddc 540 bkl 35.17 misc Chichibabin condensation misc ZSM-5 misc Pyridine bases misc Hydrogen misc Deactivation |
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The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis |
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(DE-627)SPR011328673 (SPR)s10562-009-9937-7-e |
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The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis |
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Jin, Fang Li, Yongdan |
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verfasserin |
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effect of $ h_{2} $ on chichibabin condensation catalyzed by pure zsm-5 and pt/zsm-5 for pyridine and 3-picoline synthesis |
| title_auth |
The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis |
| abstract |
Abstract The effects of $ H_{2} $ in the feed gasses on the Chichibabin condensation of ammonia with formaldehyde and acetaldehyde for pyridine and 3-picolines synthesis were studied in this work. It was observed that over Pt/ZSM-5 and H-ZSM-5 catalyst hydrogen can moderate the deactivation, depressed the coke formation, slightly lower the initial yield of pyridine bases and increase the selectivity of pyridine over 3-picoline. These effects cannot be simply attributed to the reactant dilution by $ H_{2} $, while are similar as those of spilt-over hydrogen on a Pt/ZSM-5 catalyst on this reaction. These phenomena are taken as the evidence to support the hypothesis that molecular $ H_{2} $ is activated by the pure zeolite during the Chichibabin condensation. |
| abstractGer |
Abstract The effects of $ H_{2} $ in the feed gasses on the Chichibabin condensation of ammonia with formaldehyde and acetaldehyde for pyridine and 3-picolines synthesis were studied in this work. It was observed that over Pt/ZSM-5 and H-ZSM-5 catalyst hydrogen can moderate the deactivation, depressed the coke formation, slightly lower the initial yield of pyridine bases and increase the selectivity of pyridine over 3-picoline. These effects cannot be simply attributed to the reactant dilution by $ H_{2} $, while are similar as those of spilt-over hydrogen on a Pt/ZSM-5 catalyst on this reaction. These phenomena are taken as the evidence to support the hypothesis that molecular $ H_{2} $ is activated by the pure zeolite during the Chichibabin condensation. |
| abstract_unstemmed |
Abstract The effects of $ H_{2} $ in the feed gasses on the Chichibabin condensation of ammonia with formaldehyde and acetaldehyde for pyridine and 3-picolines synthesis were studied in this work. It was observed that over Pt/ZSM-5 and H-ZSM-5 catalyst hydrogen can moderate the deactivation, depressed the coke formation, slightly lower the initial yield of pyridine bases and increase the selectivity of pyridine over 3-picoline. These effects cannot be simply attributed to the reactant dilution by $ H_{2} $, while are similar as those of spilt-over hydrogen on a Pt/ZSM-5 catalyst on this reaction. These phenomena are taken as the evidence to support the hypothesis that molecular $ H_{2} $ is activated by the pure zeolite during the Chichibabin condensation. |
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3-4 |
| title_short |
The Effect of $ H_{2} $ on Chichibabin Condensation Catalyzed by Pure ZSM-5 and Pt/ZSM-5 for Pyridine and 3-Picoline Synthesis |
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https://dx.doi.org/10.1007/s10562-009-9937-7 |
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Li, Yongdan |
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| doi_str |
10.1007/s10562-009-9937-7 |
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2024-07-03T21:58:12.134Z |
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| score |
7.400728 |