An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $
Abstract Electrophilic aromatic nitration using $ N_{2} %$ O_{5} $ as a green nitrating agent catalyzed by $ MoO_{3} $–$ SiO_{2} $ under mild conditions has been described. A series of $ MoO_{3} $–$ SiO_{2} $ catalysts with varying $ MoO_{3} $ loadings (5–20 mol%) were prepared by sol–gel technique...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ma, Xiaoming [verfasserIn] Li, Bindong [verfasserIn] Lv, Chunxu [verfasserIn] Lu, Ming [verfasserIn] Wu, Jian [verfasserIn] Liang, Linjie [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2011 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Catalysis letters - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988, 141(2011), 12 vom: 21. Okt., Seite 1814-1820 |
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| Übergeordnetes Werk: |
volume:141 ; year:2011 ; number:12 ; day:21 ; month:10 ; pages:1814-1820 |
| Links: |
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| DOI / URN: |
10.1007/s10562-011-0721-0 |
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| Katalog-ID: |
SPR011333596 |
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| 245 | 1 | 3 | |a An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ |
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| 520 | |a Abstract Electrophilic aromatic nitration using $ N_{2} %$ O_{5} $ as a green nitrating agent catalyzed by $ MoO_{3} $–$ SiO_{2} $ under mild conditions has been described. A series of $ MoO_{3} $–$ SiO_{2} $ catalysts with varying $ MoO_{3} $ loadings (5–20 mol%) were prepared by sol–gel technique and characterized using FTIR, XRD, SEM, BET and $ NH_{3} $–TPD to study its surface properties. $ MoO_{3} $–$ SiO_{2} $ shows good catalytic activity and reusability for the nitration of alkyl and halogen aromatics giving high conversions, but less efficiency for the deactivated aromatics. Reactions conducted under non-acidic conditions using $ N_{2} %$ O_{5} $ makes the process safe and environmentally friendly. Graphical Abstract | ||
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| 650 | 4 | |a Catalysis |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Li, Bindong |e verfasserin |4 aut | |
| 700 | 1 | |a Lv, Chunxu |e verfasserin |4 aut | |
| 700 | 1 | |a Lu, Ming |e verfasserin |4 aut | |
| 700 | 1 | |a Wu, Jian |e verfasserin |4 aut | |
| 700 | 1 | |a Liang, Linjie |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Catalysis letters |d Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 |g 141(2011), 12 vom: 21. Okt., Seite 1814-1820 |w (DE-627)306717638 |w (DE-600)1501518-X |x 1572-879X |7 nnns |
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10.1007/s10562-011-0721-0 doi (DE-627)SPR011333596 (SPR)s10562-011-0721-0-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Ma, Xiaoming verfasserin aut An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Electrophilic aromatic nitration using $ N_{2} %$ O_{5} $ as a green nitrating agent catalyzed by $ MoO_{3} $–$ SiO_{2} $ under mild conditions has been described. A series of $ MoO_{3} $–$ SiO_{2} $ catalysts with varying $ MoO_{3} $ loadings (5–20 mol%) were prepared by sol–gel technique and characterized using FTIR, XRD, SEM, BET and $ NH_{3} $–TPD to study its surface properties. $ MoO_{3} $–$ SiO_{2} $ shows good catalytic activity and reusability for the nitration of alkyl and halogen aromatics giving high conversions, but less efficiency for the deactivated aromatics. Reactions conducted under non-acidic conditions using $ N_{2} %$ O_{5} $ makes the process safe and environmentally friendly. Graphical Abstract Nitration (dpeaa)DE-He213 Solid acid catalyst (dpeaa)DE-He213 N (dpeaa)DE-He213 O (dpeaa)DE-He213 Catalysis (dpeaa)DE-He213 Li, Bindong verfasserin aut Lv, Chunxu verfasserin aut Lu, Ming verfasserin aut Wu, Jian verfasserin aut Liang, Linjie verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 141(2011), 12 vom: 21. Okt., Seite 1814-1820 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:141 year:2011 number:12 day:21 month:10 pages:1814-1820 https://dx.doi.org/10.1007/s10562-011-0721-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 141 2011 12 21 10 1814-1820 |
| spelling |
10.1007/s10562-011-0721-0 doi (DE-627)SPR011333596 (SPR)s10562-011-0721-0-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Ma, Xiaoming verfasserin aut An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Electrophilic aromatic nitration using $ N_{2} %$ O_{5} $ as a green nitrating agent catalyzed by $ MoO_{3} $–$ SiO_{2} $ under mild conditions has been described. A series of $ MoO_{3} $–$ SiO_{2} $ catalysts with varying $ MoO_{3} $ loadings (5–20 mol%) were prepared by sol–gel technique and characterized using FTIR, XRD, SEM, BET and $ NH_{3} $–TPD to study its surface properties. $ MoO_{3} $–$ SiO_{2} $ shows good catalytic activity and reusability for the nitration of alkyl and halogen aromatics giving high conversions, but less efficiency for the deactivated aromatics. Reactions conducted under non-acidic conditions using $ N_{2} %$ O_{5} $ makes the process safe and environmentally friendly. Graphical Abstract Nitration (dpeaa)DE-He213 Solid acid catalyst (dpeaa)DE-He213 N (dpeaa)DE-He213 O (dpeaa)DE-He213 Catalysis (dpeaa)DE-He213 Li, Bindong verfasserin aut Lv, Chunxu verfasserin aut Lu, Ming verfasserin aut Wu, Jian verfasserin aut Liang, Linjie verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 141(2011), 12 vom: 21. Okt., Seite 1814-1820 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:141 year:2011 number:12 day:21 month:10 pages:1814-1820 https://dx.doi.org/10.1007/s10562-011-0721-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 141 2011 12 21 10 1814-1820 |
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10.1007/s10562-011-0721-0 doi (DE-627)SPR011333596 (SPR)s10562-011-0721-0-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Ma, Xiaoming verfasserin aut An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Electrophilic aromatic nitration using $ N_{2} %$ O_{5} $ as a green nitrating agent catalyzed by $ MoO_{3} $–$ SiO_{2} $ under mild conditions has been described. A series of $ MoO_{3} $–$ SiO_{2} $ catalysts with varying $ MoO_{3} $ loadings (5–20 mol%) were prepared by sol–gel technique and characterized using FTIR, XRD, SEM, BET and $ NH_{3} $–TPD to study its surface properties. $ MoO_{3} $–$ SiO_{2} $ shows good catalytic activity and reusability for the nitration of alkyl and halogen aromatics giving high conversions, but less efficiency for the deactivated aromatics. Reactions conducted under non-acidic conditions using $ N_{2} %$ O_{5} $ makes the process safe and environmentally friendly. Graphical Abstract Nitration (dpeaa)DE-He213 Solid acid catalyst (dpeaa)DE-He213 N (dpeaa)DE-He213 O (dpeaa)DE-He213 Catalysis (dpeaa)DE-He213 Li, Bindong verfasserin aut Lv, Chunxu verfasserin aut Lu, Ming verfasserin aut Wu, Jian verfasserin aut Liang, Linjie verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 141(2011), 12 vom: 21. Okt., Seite 1814-1820 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:141 year:2011 number:12 day:21 month:10 pages:1814-1820 https://dx.doi.org/10.1007/s10562-011-0721-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 141 2011 12 21 10 1814-1820 |
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10.1007/s10562-011-0721-0 doi (DE-627)SPR011333596 (SPR)s10562-011-0721-0-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Ma, Xiaoming verfasserin aut An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Electrophilic aromatic nitration using $ N_{2} %$ O_{5} $ as a green nitrating agent catalyzed by $ MoO_{3} $–$ SiO_{2} $ under mild conditions has been described. A series of $ MoO_{3} $–$ SiO_{2} $ catalysts with varying $ MoO_{3} $ loadings (5–20 mol%) were prepared by sol–gel technique and characterized using FTIR, XRD, SEM, BET and $ NH_{3} $–TPD to study its surface properties. $ MoO_{3} $–$ SiO_{2} $ shows good catalytic activity and reusability for the nitration of alkyl and halogen aromatics giving high conversions, but less efficiency for the deactivated aromatics. Reactions conducted under non-acidic conditions using $ N_{2} %$ O_{5} $ makes the process safe and environmentally friendly. Graphical Abstract Nitration (dpeaa)DE-He213 Solid acid catalyst (dpeaa)DE-He213 N (dpeaa)DE-He213 O (dpeaa)DE-He213 Catalysis (dpeaa)DE-He213 Li, Bindong verfasserin aut Lv, Chunxu verfasserin aut Lu, Ming verfasserin aut Wu, Jian verfasserin aut Liang, Linjie verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 141(2011), 12 vom: 21. Okt., Seite 1814-1820 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:141 year:2011 number:12 day:21 month:10 pages:1814-1820 https://dx.doi.org/10.1007/s10562-011-0721-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 141 2011 12 21 10 1814-1820 |
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10.1007/s10562-011-0721-0 doi (DE-627)SPR011333596 (SPR)s10562-011-0721-0-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Ma, Xiaoming verfasserin aut An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Electrophilic aromatic nitration using $ N_{2} %$ O_{5} $ as a green nitrating agent catalyzed by $ MoO_{3} $–$ SiO_{2} $ under mild conditions has been described. A series of $ MoO_{3} $–$ SiO_{2} $ catalysts with varying $ MoO_{3} $ loadings (5–20 mol%) were prepared by sol–gel technique and characterized using FTIR, XRD, SEM, BET and $ NH_{3} $–TPD to study its surface properties. $ MoO_{3} $–$ SiO_{2} $ shows good catalytic activity and reusability for the nitration of alkyl and halogen aromatics giving high conversions, but less efficiency for the deactivated aromatics. Reactions conducted under non-acidic conditions using $ N_{2} %$ O_{5} $ makes the process safe and environmentally friendly. Graphical Abstract Nitration (dpeaa)DE-He213 Solid acid catalyst (dpeaa)DE-He213 N (dpeaa)DE-He213 O (dpeaa)DE-He213 Catalysis (dpeaa)DE-He213 Li, Bindong verfasserin aut Lv, Chunxu verfasserin aut Lu, Ming verfasserin aut Wu, Jian verfasserin aut Liang, Linjie verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 141(2011), 12 vom: 21. Okt., Seite 1814-1820 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:141 year:2011 number:12 day:21 month:10 pages:1814-1820 https://dx.doi.org/10.1007/s10562-011-0721-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 141 2011 12 21 10 1814-1820 |
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Enthalten in Catalysis letters 141(2011), 12 vom: 21. Okt., Seite 1814-1820 volume:141 year:2011 number:12 day:21 month:10 pages:1814-1820 |
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Nitration Solid acid catalyst N O Catalysis |
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Ma, Xiaoming @@aut@@ Li, Bindong @@aut@@ Lv, Chunxu @@aut@@ Lu, Ming @@aut@@ Wu, Jian @@aut@@ Liang, Linjie @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR011333596</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519165335.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201005s2011 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10562-011-0721-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR011333596</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10562-011-0721-0-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="a">660</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.17</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Ma, Xiaoming</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="3"><subfield code="a">An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2011</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Electrophilic aromatic nitration using $ N_{2} %$ O_{5} $ as a green nitrating agent catalyzed by $ MoO_{3} $–$ SiO_{2} $ under mild conditions has been described. A series of $ MoO_{3} $–$ SiO_{2} $ catalysts with varying $ MoO_{3} $ loadings (5–20 mol%) were prepared by sol–gel technique and characterized using FTIR, XRD, SEM, BET and $ NH_{3} $–TPD to study its surface properties. $ MoO_{3} $–$ SiO_{2} $ shows good catalytic activity and reusability for the nitration of alkyl and halogen aromatics giving high conversions, but less efficiency for the deactivated aromatics. Reactions conducted under non-acidic conditions using $ N_{2} %$ O_{5} $ makes the process safe and environmentally friendly. 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Ma, Xiaoming |
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Ma, Xiaoming ddc 540 bkl 35.17 misc Nitration misc Solid acid catalyst misc N misc O misc Catalysis An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ |
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540 660 ASE 35.17 bkl An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ Nitration (dpeaa)DE-He213 Solid acid catalyst (dpeaa)DE-He213 N (dpeaa)DE-He213 O (dpeaa)DE-He213 Catalysis (dpeaa)DE-He213 |
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An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ |
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An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ |
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efficient and eco-friendly $ moo_{3} $–$ sio_{2} $ solid acid catalyst for electrophilic aromatic nitration with $ n_{2} %$ o_{5} $ |
| title_auth |
An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ |
| abstract |
Abstract Electrophilic aromatic nitration using $ N_{2} %$ O_{5} $ as a green nitrating agent catalyzed by $ MoO_{3} $–$ SiO_{2} $ under mild conditions has been described. A series of $ MoO_{3} $–$ SiO_{2} $ catalysts with varying $ MoO_{3} $ loadings (5–20 mol%) were prepared by sol–gel technique and characterized using FTIR, XRD, SEM, BET and $ NH_{3} $–TPD to study its surface properties. $ MoO_{3} $–$ SiO_{2} $ shows good catalytic activity and reusability for the nitration of alkyl and halogen aromatics giving high conversions, but less efficiency for the deactivated aromatics. Reactions conducted under non-acidic conditions using $ N_{2} %$ O_{5} $ makes the process safe and environmentally friendly. Graphical Abstract |
| abstractGer |
Abstract Electrophilic aromatic nitration using $ N_{2} %$ O_{5} $ as a green nitrating agent catalyzed by $ MoO_{3} $–$ SiO_{2} $ under mild conditions has been described. A series of $ MoO_{3} $–$ SiO_{2} $ catalysts with varying $ MoO_{3} $ loadings (5–20 mol%) were prepared by sol–gel technique and characterized using FTIR, XRD, SEM, BET and $ NH_{3} $–TPD to study its surface properties. $ MoO_{3} $–$ SiO_{2} $ shows good catalytic activity and reusability for the nitration of alkyl and halogen aromatics giving high conversions, but less efficiency for the deactivated aromatics. Reactions conducted under non-acidic conditions using $ N_{2} %$ O_{5} $ makes the process safe and environmentally friendly. Graphical Abstract |
| abstract_unstemmed |
Abstract Electrophilic aromatic nitration using $ N_{2} %$ O_{5} $ as a green nitrating agent catalyzed by $ MoO_{3} $–$ SiO_{2} $ under mild conditions has been described. A series of $ MoO_{3} $–$ SiO_{2} $ catalysts with varying $ MoO_{3} $ loadings (5–20 mol%) were prepared by sol–gel technique and characterized using FTIR, XRD, SEM, BET and $ NH_{3} $–TPD to study its surface properties. $ MoO_{3} $–$ SiO_{2} $ shows good catalytic activity and reusability for the nitration of alkyl and halogen aromatics giving high conversions, but less efficiency for the deactivated aromatics. Reactions conducted under non-acidic conditions using $ N_{2} %$ O_{5} $ makes the process safe and environmentally friendly. Graphical Abstract |
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| container_issue |
12 |
| title_short |
An Efficient and Eco-friendly $ MoO_{3} $–$ SiO_{2} $ Solid Acid Catalyst for Electrophilic Aromatic Nitration with $ N_{2} %$ O_{5} $ |
| url |
https://dx.doi.org/10.1007/s10562-011-0721-0 |
| remote_bool |
true |
| author2 |
Li, Bindong Lv, Chunxu Lu, Ming Wu, Jian Liang, Linjie |
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Li, Bindong Lv, Chunxu Lu, Ming Wu, Jian Liang, Linjie |
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| doi_str |
10.1007/s10562-011-0721-0 |
| up_date |
2024-07-03T22:00:02.847Z |
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| score |
7.402135 |