Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol
Abstract The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (LDH) precursor. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectro...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhang, Shaoyan [verfasserIn] Liu, Quanyao [verfasserIn] Fan, Guoli [verfasserIn] Li, Feng [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2012 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Catalysis letters - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988, 142(2012), 9 vom: 25. Juli, Seite 1121-1127 |
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| Übergeordnetes Werk: |
volume:142 ; year:2012 ; number:9 ; day:25 ; month:07 ; pages:1121-1127 |
| Links: |
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| DOI / URN: |
10.1007/s10562-012-0871-8 |
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| Katalog-ID: |
SPR011337222 |
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| 245 | 1 | 0 | |a Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol |
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| 520 | |a Abstract The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (LDH) precursor. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, $ H_{2} $ temperature programmed reduction ($ H_{2} $-TPR) and $ H_{2} $–$ N_{2} $O titration indicated that the composition, texture, and structure of resulting copper-based catalysts were profoundly affected by the calcination temperature of LDH precursor. Moreover, the as-synthesized catalyst calcined at 600 °C was found to exhibit a superior catalytic hydrogenation performance with an EG yield of 94.7 % to the other catalysts calcined at 500 and 700 °C, which should be mainly attributed to the presence of the highly-dispersed active metallic copper species over metal oxide matrix. Graphical Abstract | ||
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| 650 | 4 | |a Layered double hydroxide precursor |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a High dispersion |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Dimethyl oxalate |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Hydrogenation |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Liu, Quanyao |e verfasserin |4 aut | |
| 700 | 1 | |a Fan, Guoli |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Feng |e verfasserin |4 aut | |
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10.1007/s10562-012-0871-8 doi (DE-627)SPR011337222 (SPR)s10562-012-0871-8-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Zhang, Shaoyan verfasserin aut Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (LDH) precursor. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, $ H_{2} $ temperature programmed reduction ($ H_{2} $-TPR) and $ H_{2} $–$ N_{2} $O titration indicated that the composition, texture, and structure of resulting copper-based catalysts were profoundly affected by the calcination temperature of LDH precursor. Moreover, the as-synthesized catalyst calcined at 600 °C was found to exhibit a superior catalytic hydrogenation performance with an EG yield of 94.7 % to the other catalysts calcined at 500 and 700 °C, which should be mainly attributed to the presence of the highly-dispersed active metallic copper species over metal oxide matrix. Graphical Abstract Metallic copper (dpeaa)DE-He213 Layered double hydroxide precursor (dpeaa)DE-He213 High dispersion (dpeaa)DE-He213 Dimethyl oxalate (dpeaa)DE-He213 Hydrogenation (dpeaa)DE-He213 Liu, Quanyao verfasserin aut Fan, Guoli verfasserin aut Li, Feng verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 142(2012), 9 vom: 25. Juli, Seite 1121-1127 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:142 year:2012 number:9 day:25 month:07 pages:1121-1127 https://dx.doi.org/10.1007/s10562-012-0871-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 142 2012 9 25 07 1121-1127 |
| spelling |
10.1007/s10562-012-0871-8 doi (DE-627)SPR011337222 (SPR)s10562-012-0871-8-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Zhang, Shaoyan verfasserin aut Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (LDH) precursor. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, $ H_{2} $ temperature programmed reduction ($ H_{2} $-TPR) and $ H_{2} $–$ N_{2} $O titration indicated that the composition, texture, and structure of resulting copper-based catalysts were profoundly affected by the calcination temperature of LDH precursor. Moreover, the as-synthesized catalyst calcined at 600 °C was found to exhibit a superior catalytic hydrogenation performance with an EG yield of 94.7 % to the other catalysts calcined at 500 and 700 °C, which should be mainly attributed to the presence of the highly-dispersed active metallic copper species over metal oxide matrix. Graphical Abstract Metallic copper (dpeaa)DE-He213 Layered double hydroxide precursor (dpeaa)DE-He213 High dispersion (dpeaa)DE-He213 Dimethyl oxalate (dpeaa)DE-He213 Hydrogenation (dpeaa)DE-He213 Liu, Quanyao verfasserin aut Fan, Guoli verfasserin aut Li, Feng verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 142(2012), 9 vom: 25. Juli, Seite 1121-1127 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:142 year:2012 number:9 day:25 month:07 pages:1121-1127 https://dx.doi.org/10.1007/s10562-012-0871-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 142 2012 9 25 07 1121-1127 |
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10.1007/s10562-012-0871-8 doi (DE-627)SPR011337222 (SPR)s10562-012-0871-8-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Zhang, Shaoyan verfasserin aut Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (LDH) precursor. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, $ H_{2} $ temperature programmed reduction ($ H_{2} $-TPR) and $ H_{2} $–$ N_{2} $O titration indicated that the composition, texture, and structure of resulting copper-based catalysts were profoundly affected by the calcination temperature of LDH precursor. Moreover, the as-synthesized catalyst calcined at 600 °C was found to exhibit a superior catalytic hydrogenation performance with an EG yield of 94.7 % to the other catalysts calcined at 500 and 700 °C, which should be mainly attributed to the presence of the highly-dispersed active metallic copper species over metal oxide matrix. Graphical Abstract Metallic copper (dpeaa)DE-He213 Layered double hydroxide precursor (dpeaa)DE-He213 High dispersion (dpeaa)DE-He213 Dimethyl oxalate (dpeaa)DE-He213 Hydrogenation (dpeaa)DE-He213 Liu, Quanyao verfasserin aut Fan, Guoli verfasserin aut Li, Feng verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 142(2012), 9 vom: 25. Juli, Seite 1121-1127 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:142 year:2012 number:9 day:25 month:07 pages:1121-1127 https://dx.doi.org/10.1007/s10562-012-0871-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 142 2012 9 25 07 1121-1127 |
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10.1007/s10562-012-0871-8 doi (DE-627)SPR011337222 (SPR)s10562-012-0871-8-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Zhang, Shaoyan verfasserin aut Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (LDH) precursor. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, $ H_{2} $ temperature programmed reduction ($ H_{2} $-TPR) and $ H_{2} $–$ N_{2} $O titration indicated that the composition, texture, and structure of resulting copper-based catalysts were profoundly affected by the calcination temperature of LDH precursor. Moreover, the as-synthesized catalyst calcined at 600 °C was found to exhibit a superior catalytic hydrogenation performance with an EG yield of 94.7 % to the other catalysts calcined at 500 and 700 °C, which should be mainly attributed to the presence of the highly-dispersed active metallic copper species over metal oxide matrix. Graphical Abstract Metallic copper (dpeaa)DE-He213 Layered double hydroxide precursor (dpeaa)DE-He213 High dispersion (dpeaa)DE-He213 Dimethyl oxalate (dpeaa)DE-He213 Hydrogenation (dpeaa)DE-He213 Liu, Quanyao verfasserin aut Fan, Guoli verfasserin aut Li, Feng verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 142(2012), 9 vom: 25. Juli, Seite 1121-1127 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:142 year:2012 number:9 day:25 month:07 pages:1121-1127 https://dx.doi.org/10.1007/s10562-012-0871-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 142 2012 9 25 07 1121-1127 |
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10.1007/s10562-012-0871-8 doi (DE-627)SPR011337222 (SPR)s10562-012-0871-8-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Zhang, Shaoyan verfasserin aut Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (LDH) precursor. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, $ H_{2} $ temperature programmed reduction ($ H_{2} $-TPR) and $ H_{2} $–$ N_{2} $O titration indicated that the composition, texture, and structure of resulting copper-based catalysts were profoundly affected by the calcination temperature of LDH precursor. Moreover, the as-synthesized catalyst calcined at 600 °C was found to exhibit a superior catalytic hydrogenation performance with an EG yield of 94.7 % to the other catalysts calcined at 500 and 700 °C, which should be mainly attributed to the presence of the highly-dispersed active metallic copper species over metal oxide matrix. Graphical Abstract Metallic copper (dpeaa)DE-He213 Layered double hydroxide precursor (dpeaa)DE-He213 High dispersion (dpeaa)DE-He213 Dimethyl oxalate (dpeaa)DE-He213 Hydrogenation (dpeaa)DE-He213 Liu, Quanyao verfasserin aut Fan, Guoli verfasserin aut Li, Feng verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 142(2012), 9 vom: 25. Juli, Seite 1121-1127 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:142 year:2012 number:9 day:25 month:07 pages:1121-1127 https://dx.doi.org/10.1007/s10562-012-0871-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 142 2012 9 25 07 1121-1127 |
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Metallic copper Layered double hydroxide precursor High dispersion Dimethyl oxalate Hydrogenation |
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Zhang, Shaoyan @@aut@@ Liu, Quanyao @@aut@@ Fan, Guoli @@aut@@ Li, Feng @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR011337222</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519165340.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201005s2012 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10562-012-0871-8</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR011337222</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10562-012-0871-8-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="a">660</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.17</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zhang, Shaoyan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2012</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (LDH) precursor. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, $ H_{2} $ temperature programmed reduction ($ H_{2} $-TPR) and $ H_{2} $–$ N_{2} $O titration indicated that the composition, texture, and structure of resulting copper-based catalysts were profoundly affected by the calcination temperature of LDH precursor. Moreover, the as-synthesized catalyst calcined at 600 °C was found to exhibit a superior catalytic hydrogenation performance with an EG yield of 94.7 % to the other catalysts calcined at 500 and 700 °C, which should be mainly attributed to the presence of the highly-dispersed active metallic copper species over metal oxide matrix. 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Zhang, Shaoyan |
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Zhang, Shaoyan ddc 540 bkl 35.17 misc Metallic copper misc Layered double hydroxide precursor misc High dispersion misc Dimethyl oxalate misc Hydrogenation Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol |
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540 660 ASE 35.17 bkl Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol Metallic copper (dpeaa)DE-He213 Layered double hydroxide precursor (dpeaa)DE-He213 High dispersion (dpeaa)DE-He213 Dimethyl oxalate (dpeaa)DE-He213 Hydrogenation (dpeaa)DE-He213 |
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ddc 540 bkl 35.17 misc Metallic copper misc Layered double hydroxide precursor misc High dispersion misc Dimethyl oxalate misc Hydrogenation |
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ddc 540 bkl 35.17 misc Metallic copper misc Layered double hydroxide precursor misc High dispersion misc Dimethyl oxalate misc Hydrogenation |
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ddc 540 bkl 35.17 misc Metallic copper misc Layered double hydroxide precursor misc High dispersion misc Dimethyl oxalate misc Hydrogenation |
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Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol |
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Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol |
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Zhang, Shaoyan Liu, Quanyao Fan, Guoli Li, Feng |
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10.1007/s10562-012-0871-8 |
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highly-dispersed copper-based catalysts from cu–zn–al layered double hydroxide precursor for gas-phase hydrogenation of dimethyl oxalate to ethylene glycol |
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Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol |
| abstract |
Abstract The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (LDH) precursor. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, $ H_{2} $ temperature programmed reduction ($ H_{2} $-TPR) and $ H_{2} $–$ N_{2} $O titration indicated that the composition, texture, and structure of resulting copper-based catalysts were profoundly affected by the calcination temperature of LDH precursor. Moreover, the as-synthesized catalyst calcined at 600 °C was found to exhibit a superior catalytic hydrogenation performance with an EG yield of 94.7 % to the other catalysts calcined at 500 and 700 °C, which should be mainly attributed to the presence of the highly-dispersed active metallic copper species over metal oxide matrix. Graphical Abstract |
| abstractGer |
Abstract The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (LDH) precursor. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, $ H_{2} $ temperature programmed reduction ($ H_{2} $-TPR) and $ H_{2} $–$ N_{2} $O titration indicated that the composition, texture, and structure of resulting copper-based catalysts were profoundly affected by the calcination temperature of LDH precursor. Moreover, the as-synthesized catalyst calcined at 600 °C was found to exhibit a superior catalytic hydrogenation performance with an EG yield of 94.7 % to the other catalysts calcined at 500 and 700 °C, which should be mainly attributed to the presence of the highly-dispersed active metallic copper species over metal oxide matrix. Graphical Abstract |
| abstract_unstemmed |
Abstract The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (LDH) precursor. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, $ H_{2} $ temperature programmed reduction ($ H_{2} $-TPR) and $ H_{2} $–$ N_{2} $O titration indicated that the composition, texture, and structure of resulting copper-based catalysts were profoundly affected by the calcination temperature of LDH precursor. Moreover, the as-synthesized catalyst calcined at 600 °C was found to exhibit a superior catalytic hydrogenation performance with an EG yield of 94.7 % to the other catalysts calcined at 500 and 700 °C, which should be mainly attributed to the presence of the highly-dispersed active metallic copper species over metal oxide matrix. Graphical Abstract |
| collection_details |
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9 |
| title_short |
Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol |
| url |
https://dx.doi.org/10.1007/s10562-012-0871-8 |
| remote_bool |
true |
| author2 |
Liu, Quanyao Fan, Guoli Li, Feng |
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Liu, Quanyao Fan, Guoli Li, Feng |
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306717638 |
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c |
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| doi_str |
10.1007/s10562-012-0871-8 |
| up_date |
2024-07-03T22:01:25.817Z |
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| score |
7.4014235 |