Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids
Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and %${{\rm BrO}_3^-}%$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} %$ SO_{4} $–%${{\rm BrO}_3^{-}}%$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Pu, X. H. [verfasserIn] Li, Z. X. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2012 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: International journal of thermophysics - New York, NY : Springer Science + Business Media B.V., 1980, 33(2012), 3 vom: 12. Feb., Seite 505-512 |
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| Übergeordnetes Werk: |
volume:33 ; year:2012 ; number:3 ; day:12 ; month:02 ; pages:505-512 |
| Links: |
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| DOI / URN: |
10.1007/s10765-012-1155-7 |
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| Katalog-ID: |
SPR013106538 |
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| 520 | |a Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and %${{\rm BrO}_3^-}%$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} %$ SO_{4} $–%${{\rm BrO}_3^{-}}%$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. | ||
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10.1007/s10765-012-1155-7 doi (DE-627)SPR013106538 (SPR)s10765-012-1155-7-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Pu, X. H. verfasserin aut Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and %${{\rm BrO}_3^-}%$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} %$ SO_{4} $–%${{\rm BrO}_3^{-}}%$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. Activation (dpeaa)DE-He213 Chemical oscillation (dpeaa)DE-He213 Entropy flow (dpeaa)DE-He213 Open system (dpeaa)DE-He213 Thermodynamic function (dpeaa)DE-He213 Li, Z. X. verfasserin aut Enthalten in International journal of thermophysics New York, NY : Springer Science + Business Media B.V., 1980 33(2012), 3 vom: 12. Feb., Seite 505-512 (DE-627)319584321 (DE-600)2016169-4 1572-9567 nnns volume:33 year:2012 number:3 day:12 month:02 pages:505-512 https://dx.doi.org/10.1007/s10765-012-1155-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 33 2012 3 12 02 505-512 |
| spelling |
10.1007/s10765-012-1155-7 doi (DE-627)SPR013106538 (SPR)s10765-012-1155-7-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Pu, X. H. verfasserin aut Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and %${{\rm BrO}_3^-}%$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} %$ SO_{4} $–%${{\rm BrO}_3^{-}}%$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. Activation (dpeaa)DE-He213 Chemical oscillation (dpeaa)DE-He213 Entropy flow (dpeaa)DE-He213 Open system (dpeaa)DE-He213 Thermodynamic function (dpeaa)DE-He213 Li, Z. X. verfasserin aut Enthalten in International journal of thermophysics New York, NY : Springer Science + Business Media B.V., 1980 33(2012), 3 vom: 12. Feb., Seite 505-512 (DE-627)319584321 (DE-600)2016169-4 1572-9567 nnns volume:33 year:2012 number:3 day:12 month:02 pages:505-512 https://dx.doi.org/10.1007/s10765-012-1155-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 33 2012 3 12 02 505-512 |
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10.1007/s10765-012-1155-7 doi (DE-627)SPR013106538 (SPR)s10765-012-1155-7-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Pu, X. H. verfasserin aut Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and %${{\rm BrO}_3^-}%$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} %$ SO_{4} $–%${{\rm BrO}_3^{-}}%$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. Activation (dpeaa)DE-He213 Chemical oscillation (dpeaa)DE-He213 Entropy flow (dpeaa)DE-He213 Open system (dpeaa)DE-He213 Thermodynamic function (dpeaa)DE-He213 Li, Z. X. verfasserin aut Enthalten in International journal of thermophysics New York, NY : Springer Science + Business Media B.V., 1980 33(2012), 3 vom: 12. Feb., Seite 505-512 (DE-627)319584321 (DE-600)2016169-4 1572-9567 nnns volume:33 year:2012 number:3 day:12 month:02 pages:505-512 https://dx.doi.org/10.1007/s10765-012-1155-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 33 2012 3 12 02 505-512 |
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10.1007/s10765-012-1155-7 doi (DE-627)SPR013106538 (SPR)s10765-012-1155-7-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Pu, X. H. verfasserin aut Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and %${{\rm BrO}_3^-}%$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} %$ SO_{4} $–%${{\rm BrO}_3^{-}}%$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. Activation (dpeaa)DE-He213 Chemical oscillation (dpeaa)DE-He213 Entropy flow (dpeaa)DE-He213 Open system (dpeaa)DE-He213 Thermodynamic function (dpeaa)DE-He213 Li, Z. X. verfasserin aut Enthalten in International journal of thermophysics New York, NY : Springer Science + Business Media B.V., 1980 33(2012), 3 vom: 12. Feb., Seite 505-512 (DE-627)319584321 (DE-600)2016169-4 1572-9567 nnns volume:33 year:2012 number:3 day:12 month:02 pages:505-512 https://dx.doi.org/10.1007/s10765-012-1155-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 33 2012 3 12 02 505-512 |
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10.1007/s10765-012-1155-7 doi (DE-627)SPR013106538 (SPR)s10765-012-1155-7-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Pu, X. H. verfasserin aut Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and %${{\rm BrO}_3^-}%$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} %$ SO_{4} $–%${{\rm BrO}_3^{-}}%$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. Activation (dpeaa)DE-He213 Chemical oscillation (dpeaa)DE-He213 Entropy flow (dpeaa)DE-He213 Open system (dpeaa)DE-He213 Thermodynamic function (dpeaa)DE-He213 Li, Z. X. verfasserin aut Enthalten in International journal of thermophysics New York, NY : Springer Science + Business Media B.V., 1980 33(2012), 3 vom: 12. Feb., Seite 505-512 (DE-627)319584321 (DE-600)2016169-4 1572-9567 nnns volume:33 year:2012 number:3 day:12 month:02 pages:505-512 https://dx.doi.org/10.1007/s10765-012-1155-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 33 2012 3 12 02 505-512 |
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Pu, X. H. |
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Pu, X. H. ddc 530 bkl 33.00 misc Activation misc Chemical oscillation misc Entropy flow misc Open system misc Thermodynamic function Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids |
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530 ASE 33.00 bkl Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids Activation (dpeaa)DE-He213 Chemical oscillation (dpeaa)DE-He213 Entropy flow (dpeaa)DE-He213 Open system (dpeaa)DE-He213 Thermodynamic function (dpeaa)DE-He213 |
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ddc 530 bkl 33.00 misc Activation misc Chemical oscillation misc Entropy flow misc Open system misc Thermodynamic function |
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ddc 530 bkl 33.00 misc Activation misc Chemical oscillation misc Entropy flow misc Open system misc Thermodynamic function |
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entropy flow of chemical oscillating reactions involving amino acids |
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Entropy Flow of Chemical Oscillating Reactions Involving Amino Acids |
| abstract |
Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and %${{\rm BrO}_3^-}%$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} %$ SO_{4} $–%${{\rm BrO}_3^{-}}%$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. |
| abstractGer |
Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and %${{\rm BrO}_3^-}%$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} %$ SO_{4} $–%${{\rm BrO}_3^{-}}%$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. |
| abstract_unstemmed |
Abstract Variations of $ H^{+} $, $ Mn^{2+} $, and %${{\rm BrO}_3^-}%$ during chemical oscillating reactions involving amino acids were investigated using $ H_{2} %$ SO_{4} $–%${{\rm BrO}_3^{-}}%$ –$ Mn^{2+} $–acetone as an oscillator, and the thermodynamic functions (ΔS, ΔH, and ΔG) were calculated. The results indicated that the oscillating reaction is a process from disorder to order. In the oscillating system, the heat provided by the environment is used to increase the internal energy and entropy. When external positive entropy flow could make the system reach negative entropy flow, the system starts to oscillate and to maintain oscillations by a stable entropy. |
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