Voltammetric investigation of polyelectrolyte-Cu(II) complexes

Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepare...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Gökçeören, A. [verfasserIn] Erbil, C. Sezer, E.

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2007

Schlagwörter:	Poly N-vinylcarbazole) Poly(acrylic acid) Poly(itaconic acid) Poly(N-vinylcarbazole-co-itaconic acid) Cu(II)-polymer complexes Voltammetric investigations

Anmerkung:	© Springer Science+Business Media B.V. 2007

Übergeordnetes Werk:	Enthalten in: Journal of applied electrochemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971, 37(2007), 8 vom: 15. Mai, Seite 941-948
Übergeordnetes Werk:	volume:37 ; year:2007 ; number:8 ; day:15 ; month:05 ; pages:941-948

Links:	Volltext

DOI / URN:	10.1007/s10800-007-9334-0

Katalog-ID:	SPR013299328

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520			\|a Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers.
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912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_206
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2144
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
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publishDate	2007
allfields	10.1007/s10800-007-9334-0 doi (DE-627)SPR013299328 (SPR)s10800-007-9334-0-e DE-627 ger DE-627 rakwb eng Gökçeören, A. verfasserin aut Voltammetric investigation of polyelectrolyte-Cu(II) complexes 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media B.V. 2007 Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213 Erbil, C. aut Sezer, E. aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 37(2007), 8 vom: 15. Mai, Seite 941-948 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:37 year:2007 number:8 day:15 month:05 pages:941-948 https://dx.doi.org/10.1007/s10800-007-9334-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 37 2007 8 15 05 941-948
spelling	10.1007/s10800-007-9334-0 doi (DE-627)SPR013299328 (SPR)s10800-007-9334-0-e DE-627 ger DE-627 rakwb eng Gökçeören, A. verfasserin aut Voltammetric investigation of polyelectrolyte-Cu(II) complexes 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media B.V. 2007 Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213 Erbil, C. aut Sezer, E. aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 37(2007), 8 vom: 15. Mai, Seite 941-948 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:37 year:2007 number:8 day:15 month:05 pages:941-948 https://dx.doi.org/10.1007/s10800-007-9334-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 37 2007 8 15 05 941-948
allfields_unstemmed	10.1007/s10800-007-9334-0 doi (DE-627)SPR013299328 (SPR)s10800-007-9334-0-e DE-627 ger DE-627 rakwb eng Gökçeören, A. verfasserin aut Voltammetric investigation of polyelectrolyte-Cu(II) complexes 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media B.V. 2007 Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213 Erbil, C. aut Sezer, E. aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 37(2007), 8 vom: 15. Mai, Seite 941-948 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:37 year:2007 number:8 day:15 month:05 pages:941-948 https://dx.doi.org/10.1007/s10800-007-9334-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 37 2007 8 15 05 941-948
allfieldsGer	10.1007/s10800-007-9334-0 doi (DE-627)SPR013299328 (SPR)s10800-007-9334-0-e DE-627 ger DE-627 rakwb eng Gökçeören, A. verfasserin aut Voltammetric investigation of polyelectrolyte-Cu(II) complexes 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media B.V. 2007 Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213 Erbil, C. aut Sezer, E. aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 37(2007), 8 vom: 15. Mai, Seite 941-948 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:37 year:2007 number:8 day:15 month:05 pages:941-948 https://dx.doi.org/10.1007/s10800-007-9334-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 37 2007 8 15 05 941-948
allfieldsSound	10.1007/s10800-007-9334-0 doi (DE-627)SPR013299328 (SPR)s10800-007-9334-0-e DE-627 ger DE-627 rakwb eng Gökçeören, A. verfasserin aut Voltammetric investigation of polyelectrolyte-Cu(II) complexes 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media B.V. 2007 Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213 Erbil, C. aut Sezer, E. aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 37(2007), 8 vom: 15. Mai, Seite 941-948 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:37 year:2007 number:8 day:15 month:05 pages:941-948 https://dx.doi.org/10.1007/s10800-007-9334-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 37 2007 8 15 05 941-948
language	English
source	Enthalten in Journal of applied electrochemistry 37(2007), 8 vom: 15. Mai, Seite 941-948 volume:37 year:2007 number:8 day:15 month:05 pages:941-948
sourceStr	Enthalten in Journal of applied electrochemistry 37(2007), 8 vom: 15. Mai, Seite 941-948 volume:37 year:2007 number:8 day:15 month:05 pages:941-948
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Poly N-vinylcarbazole) Poly(acrylic acid) Poly(itaconic acid) Poly(N-vinylcarbazole-co-itaconic acid) Cu(II)-polymer complexes Voltammetric investigations
isfreeaccess_bool	false
container_title	Journal of applied electrochemistry
authorswithroles_txt_mv	Gökçeören, A. @@aut@@ Erbil, C. @@aut@@ Sezer, E. @@aut@@
publishDateDaySort_date	2007-05-15T00:00:00Z
hierarchy_top_id	302466037
id	SPR013299328
language_de	englisch
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author	Gökçeören, A.
spellingShingle	Gökçeören, A. misc Poly misc N-vinylcarbazole) misc Poly(acrylic acid) misc Poly(itaconic acid) misc Poly(N-vinylcarbazole-co-itaconic acid) misc Cu(II)-polymer complexes misc Voltammetric investigations Voltammetric investigation of polyelectrolyte-Cu(II) complexes
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topic_title	Voltammetric investigation of polyelectrolyte-Cu(II) complexes Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213
topic	misc Poly misc N-vinylcarbazole) misc Poly(acrylic acid) misc Poly(itaconic acid) misc Poly(N-vinylcarbazole-co-itaconic acid) misc Cu(II)-polymer complexes misc Voltammetric investigations
topic_unstemmed	misc Poly misc N-vinylcarbazole) misc Poly(acrylic acid) misc Poly(itaconic acid) misc Poly(N-vinylcarbazole-co-itaconic acid) misc Cu(II)-polymer complexes misc Voltammetric investigations
topic_browse	misc Poly misc N-vinylcarbazole) misc Poly(acrylic acid) misc Poly(itaconic acid) misc Poly(N-vinylcarbazole-co-itaconic acid) misc Cu(II)-polymer complexes misc Voltammetric investigations
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title	Voltammetric investigation of polyelectrolyte-Cu(II) complexes
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title_full	Voltammetric investigation of polyelectrolyte-Cu(II) complexes
author_sort	Gökçeören, A.
journal	Journal of applied electrochemistry
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author_browse	Gökçeören, A. Erbil, C. Sezer, E.
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author-letter	Gökçeören, A.
doi_str_mv	10.1007/s10800-007-9334-0
title_sort	voltammetric investigation of polyelectrolyte-cu(ii) complexes
title_auth	Voltammetric investigation of polyelectrolyte-Cu(II) complexes
abstract	Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. © Springer Science+Business Media B.V. 2007
abstractGer	Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. © Springer Science+Business Media B.V. 2007
abstract_unstemmed	Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. © Springer Science+Business Media B.V. 2007
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title_short	Voltammetric investigation of polyelectrolyte-Cu(II) complexes
url	https://dx.doi.org/10.1007/s10800-007-9334-0
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author2	Erbil, C. Sezer, E.
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doi_str	10.1007/s10800-007-9334-0
up_date	2024-07-03T18:45:05.237Z
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fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR013299328</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519185814.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2007 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10800-007-9334-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR013299328</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10800-007-9334-0-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Gökçeören, A.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Voltammetric investigation of polyelectrolyte-Cu(II) complexes</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2007</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media B.V. 2007</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. 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Voltammetric investigation of polyelectrolyte-Cu(II) complexes

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