Voltammetric investigation of polyelectrolyte-Cu(II) complexes
Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepare...
Ausführliche Beschreibung
Autor*in: |
Gökçeören, A. [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2007 |
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Schlagwörter: |
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Anmerkung: |
© Springer Science+Business Media B.V. 2007 |
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Übergeordnetes Werk: |
Enthalten in: Journal of applied electrochemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971, 37(2007), 8 vom: 15. Mai, Seite 941-948 |
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Übergeordnetes Werk: |
volume:37 ; year:2007 ; number:8 ; day:15 ; month:05 ; pages:941-948 |
Links: |
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DOI / URN: |
10.1007/s10800-007-9334-0 |
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Katalog-ID: |
SPR013299328 |
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520 | |a Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. | ||
650 | 4 | |a Poly |7 (dpeaa)DE-He213 | |
650 | 4 | |a N-vinylcarbazole) |7 (dpeaa)DE-He213 | |
650 | 4 | |a Poly(acrylic acid) |7 (dpeaa)DE-He213 | |
650 | 4 | |a Poly(itaconic acid) |7 (dpeaa)DE-He213 | |
650 | 4 | |a Poly(N-vinylcarbazole-co-itaconic acid) |7 (dpeaa)DE-He213 | |
650 | 4 | |a Cu(II)-polymer complexes |7 (dpeaa)DE-He213 | |
650 | 4 | |a Voltammetric investigations |7 (dpeaa)DE-He213 | |
700 | 1 | |a Erbil, C. |4 aut | |
700 | 1 | |a Sezer, E. |4 aut | |
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10.1007/s10800-007-9334-0 doi (DE-627)SPR013299328 (SPR)s10800-007-9334-0-e DE-627 ger DE-627 rakwb eng Gökçeören, A. verfasserin aut Voltammetric investigation of polyelectrolyte-Cu(II) complexes 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media B.V. 2007 Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213 Erbil, C. aut Sezer, E. aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 37(2007), 8 vom: 15. Mai, Seite 941-948 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:37 year:2007 number:8 day:15 month:05 pages:941-948 https://dx.doi.org/10.1007/s10800-007-9334-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 37 2007 8 15 05 941-948 |
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10.1007/s10800-007-9334-0 doi (DE-627)SPR013299328 (SPR)s10800-007-9334-0-e DE-627 ger DE-627 rakwb eng Gökçeören, A. verfasserin aut Voltammetric investigation of polyelectrolyte-Cu(II) complexes 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media B.V. 2007 Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213 Erbil, C. aut Sezer, E. aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 37(2007), 8 vom: 15. Mai, Seite 941-948 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:37 year:2007 number:8 day:15 month:05 pages:941-948 https://dx.doi.org/10.1007/s10800-007-9334-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 37 2007 8 15 05 941-948 |
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10.1007/s10800-007-9334-0 doi (DE-627)SPR013299328 (SPR)s10800-007-9334-0-e DE-627 ger DE-627 rakwb eng Gökçeören, A. verfasserin aut Voltammetric investigation of polyelectrolyte-Cu(II) complexes 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media B.V. 2007 Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213 Erbil, C. aut Sezer, E. aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 37(2007), 8 vom: 15. Mai, Seite 941-948 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:37 year:2007 number:8 day:15 month:05 pages:941-948 https://dx.doi.org/10.1007/s10800-007-9334-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 37 2007 8 15 05 941-948 |
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10.1007/s10800-007-9334-0 doi (DE-627)SPR013299328 (SPR)s10800-007-9334-0-e DE-627 ger DE-627 rakwb eng Gökçeören, A. verfasserin aut Voltammetric investigation of polyelectrolyte-Cu(II) complexes 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media B.V. 2007 Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213 Erbil, C. aut Sezer, E. aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 37(2007), 8 vom: 15. Mai, Seite 941-948 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:37 year:2007 number:8 day:15 month:05 pages:941-948 https://dx.doi.org/10.1007/s10800-007-9334-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 37 2007 8 15 05 941-948 |
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10.1007/s10800-007-9334-0 doi (DE-627)SPR013299328 (SPR)s10800-007-9334-0-e DE-627 ger DE-627 rakwb eng Gökçeören, A. verfasserin aut Voltammetric investigation of polyelectrolyte-Cu(II) complexes 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media B.V. 2007 Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213 Erbil, C. aut Sezer, E. aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 37(2007), 8 vom: 15. Mai, Seite 941-948 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:37 year:2007 number:8 day:15 month:05 pages:941-948 https://dx.doi.org/10.1007/s10800-007-9334-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 37 2007 8 15 05 941-948 |
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Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. 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author |
Gökçeören, A. |
spellingShingle |
Gökçeören, A. misc Poly misc N-vinylcarbazole) misc Poly(acrylic acid) misc Poly(itaconic acid) misc Poly(N-vinylcarbazole-co-itaconic acid) misc Cu(II)-polymer complexes misc Voltammetric investigations Voltammetric investigation of polyelectrolyte-Cu(II) complexes |
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Voltammetric investigation of polyelectrolyte-Cu(II) complexes Poly (dpeaa)DE-He213 N-vinylcarbazole) (dpeaa)DE-He213 Poly(acrylic acid) (dpeaa)DE-He213 Poly(itaconic acid) (dpeaa)DE-He213 Poly(N-vinylcarbazole-co-itaconic acid) (dpeaa)DE-He213 Cu(II)-polymer complexes (dpeaa)DE-He213 Voltammetric investigations (dpeaa)DE-He213 |
topic |
misc Poly misc N-vinylcarbazole) misc Poly(acrylic acid) misc Poly(itaconic acid) misc Poly(N-vinylcarbazole-co-itaconic acid) misc Cu(II)-polymer complexes misc Voltammetric investigations |
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misc Poly misc N-vinylcarbazole) misc Poly(acrylic acid) misc Poly(itaconic acid) misc Poly(N-vinylcarbazole-co-itaconic acid) misc Cu(II)-polymer complexes misc Voltammetric investigations |
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misc Poly misc N-vinylcarbazole) misc Poly(acrylic acid) misc Poly(itaconic acid) misc Poly(N-vinylcarbazole-co-itaconic acid) misc Cu(II)-polymer complexes misc Voltammetric investigations |
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Voltammetric investigation of polyelectrolyte-Cu(II) complexes |
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Journal of applied electrochemistry |
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Gökçeören, A. |
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10.1007/s10800-007-9334-0 |
title_sort |
voltammetric investigation of polyelectrolyte-cu(ii) complexes |
title_auth |
Voltammetric investigation of polyelectrolyte-Cu(II) complexes |
abstract |
Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. © Springer Science+Business Media B.V. 2007 |
abstractGer |
Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. © Springer Science+Business Media B.V. 2007 |
abstract_unstemmed |
Abstract The complexation behaviours of poly(N-vinylcarbazole) (PNVCz), poly(acrylic acid) (PAA) poly(itaconic acid) (PIA) and their copolymers, synthesized by using different initial monomer compositions, with Cu(II) ions were investigated by the voltammetric technique. Their solutions were prepared in THF-water mixture according to the water-insoluble nature of PNVCz and its copolymers. The polymeric ligand-Cu(II) interactions, i.e. complex formations were studied as a function of copper ion concentration and copolymer composition. It was observed that although the cyclic voltammogram (CV) of Cu(II) alone in THF-water mixture was characterized by one redox wave, which has an irreversible nature, it became more reversible in the presence of polymer. Further, the CV results indicated the presence of two different electron transfer mechanisms, depending on the nCOOH/nCu(II) ratio and the carboxyl content of the copolymers. © Springer Science+Business Media B.V. 2007 |
collection_details |
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container_issue |
8 |
title_short |
Voltammetric investigation of polyelectrolyte-Cu(II) complexes |
url |
https://dx.doi.org/10.1007/s10800-007-9334-0 |
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author2 |
Erbil, C. Sezer, E. |
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10.1007/s10800-007-9334-0 |
up_date |
2024-07-03T18:45:05.237Z |
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|
score |
7.39931 |