Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries

Abstract For the first time, Si–Mo–O helices have been produced by the ion-assisted glancing angle electron beam co-evaporation of molybdenum oxide and silicon. Since the electron beam evaporation process forms metastable particles through the dissociation of the source material, a film that contain...
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Autor*in:	Karahan, B. Deniz [verfasserIn] Amine, K. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Oxide thin film anode Molybdenum Silicon Glancing angle deposition Structured thin films

Übergeordnetes Werk:	Enthalten in: Journal of applied electrochemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971, 49(2019), 7 vom: 28. Mai, Seite 671-680
Übergeordnetes Werk:	volume:49 ; year:2019 ; number:7 ; day:28 ; month:05 ; pages:671-680

Links:	Volltext

DOI / URN:	10.1007/s10800-019-01319-w

Katalog-ID:	SPR01331887X

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520			\|a Abstract For the first time, Si–Mo–O helices have been produced by the ion-assisted glancing angle electron beam co-evaporation of molybdenum oxide and silicon. Since the electron beam evaporation process forms metastable particles through the dissociation of the source material, a film that contains compounds of different combinations of molybdenum, silicon, and oxygen atoms is produced. This complex structure’s lithiation mechanism is different from that of the traditional electrodes in lithium-ion batteries. In the paper, the nanostructured Si–Mo–O anode was cycled in different potential windows (0.2–1.2 V, 0.2–3.0 V, 5 mV–3.0 V vs. lithium) at different rates. The anode remained cycling even at 0.7 mA $ cm^{−2} $, which makes it practical for micro- and solid-state battery applications. This research reveals that by adjusting the cutoff voltages, different particles could be activated in the anode structure to react with lithium, resulting in different performances. The electrode delivers higher capacity when cycled between 5 mV and 3.0 V windows and keeps cycling for 200 cycles under the load of 5 µA $ cm^{−2} $. This performance is believed to be related to the structural, morphological, and the compositional properties of the coating. Graphical abstract
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allfields	10.1007/s10800-019-01319-w doi (DE-627)SPR01331887X (SPR)s10800-019-01319-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl Karahan, B. Deniz verfasserin aut Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract For the first time, Si–Mo–O helices have been produced by the ion-assisted glancing angle electron beam co-evaporation of molybdenum oxide and silicon. Since the electron beam evaporation process forms metastable particles through the dissociation of the source material, a film that contains compounds of different combinations of molybdenum, silicon, and oxygen atoms is produced. This complex structure’s lithiation mechanism is different from that of the traditional electrodes in lithium-ion batteries. In the paper, the nanostructured Si–Mo–O anode was cycled in different potential windows (0.2–1.2 V, 0.2–3.0 V, 5 mV–3.0 V vs. lithium) at different rates. The anode remained cycling even at 0.7 mA $ cm^{−2} $, which makes it practical for micro- and solid-state battery applications. This research reveals that by adjusting the cutoff voltages, different particles could be activated in the anode structure to react with lithium, resulting in different performances. The electrode delivers higher capacity when cycled between 5 mV and 3.0 V windows and keeps cycling for 200 cycles under the load of 5 µA $ cm^{−2} $. This performance is believed to be related to the structural, morphological, and the compositional properties of the coating. Graphical abstract Oxide thin film anode (dpeaa)DE-He213 Molybdenum (dpeaa)DE-He213 Silicon (dpeaa)DE-He213 Glancing angle deposition (dpeaa)DE-He213 Structured thin films (dpeaa)DE-He213 Amine, K. verfasserin aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 49(2019), 7 vom: 28. Mai, Seite 671-680 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:49 year:2019 number:7 day:28 month:05 pages:671-680 https://dx.doi.org/10.1007/s10800-019-01319-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE AR 49 2019 7 28 05 671-680
spelling	10.1007/s10800-019-01319-w doi (DE-627)SPR01331887X (SPR)s10800-019-01319-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl Karahan, B. Deniz verfasserin aut Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract For the first time, Si–Mo–O helices have been produced by the ion-assisted glancing angle electron beam co-evaporation of molybdenum oxide and silicon. Since the electron beam evaporation process forms metastable particles through the dissociation of the source material, a film that contains compounds of different combinations of molybdenum, silicon, and oxygen atoms is produced. This complex structure’s lithiation mechanism is different from that of the traditional electrodes in lithium-ion batteries. In the paper, the nanostructured Si–Mo–O anode was cycled in different potential windows (0.2–1.2 V, 0.2–3.0 V, 5 mV–3.0 V vs. lithium) at different rates. The anode remained cycling even at 0.7 mA $ cm^{−2} $, which makes it practical for micro- and solid-state battery applications. This research reveals that by adjusting the cutoff voltages, different particles could be activated in the anode structure to react with lithium, resulting in different performances. The electrode delivers higher capacity when cycled between 5 mV and 3.0 V windows and keeps cycling for 200 cycles under the load of 5 µA $ cm^{−2} $. This performance is believed to be related to the structural, morphological, and the compositional properties of the coating. Graphical abstract Oxide thin film anode (dpeaa)DE-He213 Molybdenum (dpeaa)DE-He213 Silicon (dpeaa)DE-He213 Glancing angle deposition (dpeaa)DE-He213 Structured thin films (dpeaa)DE-He213 Amine, K. verfasserin aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 49(2019), 7 vom: 28. Mai, Seite 671-680 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:49 year:2019 number:7 day:28 month:05 pages:671-680 https://dx.doi.org/10.1007/s10800-019-01319-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE AR 49 2019 7 28 05 671-680
allfields_unstemmed	10.1007/s10800-019-01319-w doi (DE-627)SPR01331887X (SPR)s10800-019-01319-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl Karahan, B. Deniz verfasserin aut Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract For the first time, Si–Mo–O helices have been produced by the ion-assisted glancing angle electron beam co-evaporation of molybdenum oxide and silicon. Since the electron beam evaporation process forms metastable particles through the dissociation of the source material, a film that contains compounds of different combinations of molybdenum, silicon, and oxygen atoms is produced. This complex structure’s lithiation mechanism is different from that of the traditional electrodes in lithium-ion batteries. In the paper, the nanostructured Si–Mo–O anode was cycled in different potential windows (0.2–1.2 V, 0.2–3.0 V, 5 mV–3.0 V vs. lithium) at different rates. The anode remained cycling even at 0.7 mA $ cm^{−2} $, which makes it practical for micro- and solid-state battery applications. This research reveals that by adjusting the cutoff voltages, different particles could be activated in the anode structure to react with lithium, resulting in different performances. The electrode delivers higher capacity when cycled between 5 mV and 3.0 V windows and keeps cycling for 200 cycles under the load of 5 µA $ cm^{−2} $. This performance is believed to be related to the structural, morphological, and the compositional properties of the coating. Graphical abstract Oxide thin film anode (dpeaa)DE-He213 Molybdenum (dpeaa)DE-He213 Silicon (dpeaa)DE-He213 Glancing angle deposition (dpeaa)DE-He213 Structured thin films (dpeaa)DE-He213 Amine, K. verfasserin aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 49(2019), 7 vom: 28. Mai, Seite 671-680 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:49 year:2019 number:7 day:28 month:05 pages:671-680 https://dx.doi.org/10.1007/s10800-019-01319-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE AR 49 2019 7 28 05 671-680
allfieldsGer	10.1007/s10800-019-01319-w doi (DE-627)SPR01331887X (SPR)s10800-019-01319-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl Karahan, B. Deniz verfasserin aut Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract For the first time, Si–Mo–O helices have been produced by the ion-assisted glancing angle electron beam co-evaporation of molybdenum oxide and silicon. Since the electron beam evaporation process forms metastable particles through the dissociation of the source material, a film that contains compounds of different combinations of molybdenum, silicon, and oxygen atoms is produced. This complex structure’s lithiation mechanism is different from that of the traditional electrodes in lithium-ion batteries. In the paper, the nanostructured Si–Mo–O anode was cycled in different potential windows (0.2–1.2 V, 0.2–3.0 V, 5 mV–3.0 V vs. lithium) at different rates. The anode remained cycling even at 0.7 mA $ cm^{−2} $, which makes it practical for micro- and solid-state battery applications. This research reveals that by adjusting the cutoff voltages, different particles could be activated in the anode structure to react with lithium, resulting in different performances. The electrode delivers higher capacity when cycled between 5 mV and 3.0 V windows and keeps cycling for 200 cycles under the load of 5 µA $ cm^{−2} $. This performance is believed to be related to the structural, morphological, and the compositional properties of the coating. Graphical abstract Oxide thin film anode (dpeaa)DE-He213 Molybdenum (dpeaa)DE-He213 Silicon (dpeaa)DE-He213 Glancing angle deposition (dpeaa)DE-He213 Structured thin films (dpeaa)DE-He213 Amine, K. verfasserin aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 49(2019), 7 vom: 28. Mai, Seite 671-680 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:49 year:2019 number:7 day:28 month:05 pages:671-680 https://dx.doi.org/10.1007/s10800-019-01319-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE AR 49 2019 7 28 05 671-680
allfieldsSound	10.1007/s10800-019-01319-w doi (DE-627)SPR01331887X (SPR)s10800-019-01319-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl Karahan, B. Deniz verfasserin aut Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract For the first time, Si–Mo–O helices have been produced by the ion-assisted glancing angle electron beam co-evaporation of molybdenum oxide and silicon. Since the electron beam evaporation process forms metastable particles through the dissociation of the source material, a film that contains compounds of different combinations of molybdenum, silicon, and oxygen atoms is produced. This complex structure’s lithiation mechanism is different from that of the traditional electrodes in lithium-ion batteries. In the paper, the nanostructured Si–Mo–O anode was cycled in different potential windows (0.2–1.2 V, 0.2–3.0 V, 5 mV–3.0 V vs. lithium) at different rates. The anode remained cycling even at 0.7 mA $ cm^{−2} $, which makes it practical for micro- and solid-state battery applications. This research reveals that by adjusting the cutoff voltages, different particles could be activated in the anode structure to react with lithium, resulting in different performances. The electrode delivers higher capacity when cycled between 5 mV and 3.0 V windows and keeps cycling for 200 cycles under the load of 5 µA $ cm^{−2} $. This performance is believed to be related to the structural, morphological, and the compositional properties of the coating. Graphical abstract Oxide thin film anode (dpeaa)DE-He213 Molybdenum (dpeaa)DE-He213 Silicon (dpeaa)DE-He213 Glancing angle deposition (dpeaa)DE-He213 Structured thin films (dpeaa)DE-He213 Amine, K. verfasserin aut Enthalten in Journal of applied electrochemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1971 49(2019), 7 vom: 28. Mai, Seite 671-680 (DE-627)302466037 (DE-600)1491094-9 1572-8838 nnns volume:49 year:2019 number:7 day:28 month:05 pages:671-680 https://dx.doi.org/10.1007/s10800-019-01319-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE AR 49 2019 7 28 05 671-680
language	English
source	Enthalten in Journal of applied electrochemistry 49(2019), 7 vom: 28. Mai, Seite 671-680 volume:49 year:2019 number:7 day:28 month:05 pages:671-680
sourceStr	Enthalten in Journal of applied electrochemistry 49(2019), 7 vom: 28. Mai, Seite 671-680 volume:49 year:2019 number:7 day:28 month:05 pages:671-680
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Oxide thin film anode Molybdenum Silicon Glancing angle deposition Structured thin films
dewey-raw	540
isfreeaccess_bool	false
container_title	Journal of applied electrochemistry
authorswithroles_txt_mv	Karahan, B. Deniz @@aut@@ Amine, K. @@aut@@
publishDateDaySort_date	2019-05-28T00:00:00Z
hierarchy_top_id	302466037
dewey-sort	3540
id	SPR01331887X
language_de	englisch
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author	Karahan, B. Deniz
spellingShingle	Karahan, B. Deniz ddc 540 bkl 35.14 misc Oxide thin film anode misc Molybdenum misc Silicon misc Glancing angle deposition misc Structured thin films Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries
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topic_title	540 ASE 35.14 bkl Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries Oxide thin film anode (dpeaa)DE-He213 Molybdenum (dpeaa)DE-He213 Silicon (dpeaa)DE-He213 Glancing angle deposition (dpeaa)DE-He213 Structured thin films (dpeaa)DE-He213
topic	ddc 540 bkl 35.14 misc Oxide thin film anode misc Molybdenum misc Silicon misc Glancing angle deposition misc Structured thin films
topic_unstemmed	ddc 540 bkl 35.14 misc Oxide thin film anode misc Molybdenum misc Silicon misc Glancing angle deposition misc Structured thin films
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title	Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries
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title_full	Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries
author_sort	Karahan, B. Deniz
journal	Journal of applied electrochemistry
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author_browse	Karahan, B. Deniz Amine, K.
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author-letter	Karahan, B. Deniz
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title_sort	engineering self-standing si–mo–o based nanostructure arrays as anodes for new era lithium-ion batteries
title_auth	Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries
abstract	Abstract For the first time, Si–Mo–O helices have been produced by the ion-assisted glancing angle electron beam co-evaporation of molybdenum oxide and silicon. Since the electron beam evaporation process forms metastable particles through the dissociation of the source material, a film that contains compounds of different combinations of molybdenum, silicon, and oxygen atoms is produced. This complex structure’s lithiation mechanism is different from that of the traditional electrodes in lithium-ion batteries. In the paper, the nanostructured Si–Mo–O anode was cycled in different potential windows (0.2–1.2 V, 0.2–3.0 V, 5 mV–3.0 V vs. lithium) at different rates. The anode remained cycling even at 0.7 mA $ cm^{−2} $, which makes it practical for micro- and solid-state battery applications. This research reveals that by adjusting the cutoff voltages, different particles could be activated in the anode structure to react with lithium, resulting in different performances. The electrode delivers higher capacity when cycled between 5 mV and 3.0 V windows and keeps cycling for 200 cycles under the load of 5 µA $ cm^{−2} $. This performance is believed to be related to the structural, morphological, and the compositional properties of the coating. Graphical abstract
abstractGer	Abstract For the first time, Si–Mo–O helices have been produced by the ion-assisted glancing angle electron beam co-evaporation of molybdenum oxide and silicon. Since the electron beam evaporation process forms metastable particles through the dissociation of the source material, a film that contains compounds of different combinations of molybdenum, silicon, and oxygen atoms is produced. This complex structure’s lithiation mechanism is different from that of the traditional electrodes in lithium-ion batteries. In the paper, the nanostructured Si–Mo–O anode was cycled in different potential windows (0.2–1.2 V, 0.2–3.0 V, 5 mV–3.0 V vs. lithium) at different rates. The anode remained cycling even at 0.7 mA $ cm^{−2} $, which makes it practical for micro- and solid-state battery applications. This research reveals that by adjusting the cutoff voltages, different particles could be activated in the anode structure to react with lithium, resulting in different performances. The electrode delivers higher capacity when cycled between 5 mV and 3.0 V windows and keeps cycling for 200 cycles under the load of 5 µA $ cm^{−2} $. This performance is believed to be related to the structural, morphological, and the compositional properties of the coating. Graphical abstract
abstract_unstemmed	Abstract For the first time, Si–Mo–O helices have been produced by the ion-assisted glancing angle electron beam co-evaporation of molybdenum oxide and silicon. Since the electron beam evaporation process forms metastable particles through the dissociation of the source material, a film that contains compounds of different combinations of molybdenum, silicon, and oxygen atoms is produced. This complex structure’s lithiation mechanism is different from that of the traditional electrodes in lithium-ion batteries. In the paper, the nanostructured Si–Mo–O anode was cycled in different potential windows (0.2–1.2 V, 0.2–3.0 V, 5 mV–3.0 V vs. lithium) at different rates. The anode remained cycling even at 0.7 mA $ cm^{−2} $, which makes it practical for micro- and solid-state battery applications. This research reveals that by adjusting the cutoff voltages, different particles could be activated in the anode structure to react with lithium, resulting in different performances. The electrode delivers higher capacity when cycled between 5 mV and 3.0 V windows and keeps cycling for 200 cycles under the load of 5 µA $ cm^{−2} $. This performance is believed to be related to the structural, morphological, and the compositional properties of the coating. Graphical abstract
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container_issue	7
title_short	Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries
url	https://dx.doi.org/10.1007/s10800-019-01319-w
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author2	Amine, K.
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doi_str	10.1007/s10800-019-01319-w
up_date	2024-07-03T18:53:43.577Z
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Deniz</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Engineering self-standing Si–Mo–O based nanostructure arrays as anodes for new era lithium-ion batteries</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract For the first time, Si–Mo–O helices have been produced by the ion-assisted glancing angle electron beam co-evaporation of molybdenum oxide and silicon. Since the electron beam evaporation process forms metastable particles through the dissociation of the source material, a film that contains compounds of different combinations of molybdenum, silicon, and oxygen atoms is produced. This complex structure’s lithiation mechanism is different from that of the traditional electrodes in lithium-ion batteries. In the paper, the nanostructured Si–Mo–O anode was cycled in different potential windows (0.2–1.2 V, 0.2–3.0 V, 5 mV–3.0 V vs. lithium) at different rates. The anode remained cycling even at 0.7 mA $ cm^{−2} $, which makes it practical for micro- and solid-state battery applications. This research reveals that by adjusting the cutoff voltages, different particles could be activated in the anode structure to react with lithium, resulting in different performances. The electrode delivers higher capacity when cycled between 5 mV and 3.0 V windows and keeps cycling for 200 cycles under the load of 5 µA $ cm^{−2} $. This performance is believed to be related to the structural, morphological, and the compositional properties of the coating. 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