Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti
Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from...
Ausführliche Beschreibung
Autor*in: |
Cho, Eunae [verfasserIn] Choi, Jae Min [verfasserIn] Jung, Seunho [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2012 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Journal of inclusion phenomena and macrocyclic chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983, 76(2012), 1-2 vom: 14. Juni, Seite 133-141 |
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Übergeordnetes Werk: |
volume:76 ; year:2012 ; number:1-2 ; day:14 ; month:06 ; pages:133-141 |
Links: |
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DOI / URN: |
10.1007/s10847-012-0182-0 |
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Katalog-ID: |
SPR013720643 |
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245 | 1 | 0 | |a Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti |
264 | 1 | |c 2012 | |
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520 | |a Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. | ||
650 | 4 | |a Succinoglycan dimers |7 (dpeaa)DE-He213 | |
650 | 4 | |a Isoflavonoids |7 (dpeaa)DE-He213 | |
650 | 4 | |a Solubility enhancement |7 (dpeaa)DE-He213 | |
650 | 4 | |a Complexation |7 (dpeaa)DE-He213 | |
700 | 1 | |a Choi, Jae Min |e verfasserin |4 aut | |
700 | 1 | |a Jung, Seunho |e verfasserin |4 aut | |
773 | 0 | 8 | |i Enthalten in |t Journal of inclusion phenomena and macrocyclic chemistry |d Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 |g 76(2012), 1-2 vom: 14. Juni, Seite 133-141 |w (DE-627)315293152 |w (DE-600)2016909-7 |x 1573-1111 |7 nnns |
773 | 1 | 8 | |g volume:76 |g year:2012 |g number:1-2 |g day:14 |g month:06 |g pages:133-141 |
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2012 |
bklnumber |
35.80 35.59 |
publishDate |
2012 |
allfields |
10.1007/s10847-012-0182-0 doi (DE-627)SPR013720643 (SPR)s10847-012-0182-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Cho, Eunae verfasserin aut Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213 Choi, Jae Min verfasserin aut Jung, Seunho verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 76(2012), 1-2 vom: 14. Juni, Seite 133-141 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 https://dx.doi.org/10.1007/s10847-012-0182-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 76 2012 1-2 14 06 133-141 |
spelling |
10.1007/s10847-012-0182-0 doi (DE-627)SPR013720643 (SPR)s10847-012-0182-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Cho, Eunae verfasserin aut Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213 Choi, Jae Min verfasserin aut Jung, Seunho verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 76(2012), 1-2 vom: 14. Juni, Seite 133-141 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 https://dx.doi.org/10.1007/s10847-012-0182-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 76 2012 1-2 14 06 133-141 |
allfields_unstemmed |
10.1007/s10847-012-0182-0 doi (DE-627)SPR013720643 (SPR)s10847-012-0182-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Cho, Eunae verfasserin aut Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213 Choi, Jae Min verfasserin aut Jung, Seunho verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 76(2012), 1-2 vom: 14. Juni, Seite 133-141 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 https://dx.doi.org/10.1007/s10847-012-0182-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 76 2012 1-2 14 06 133-141 |
allfieldsGer |
10.1007/s10847-012-0182-0 doi (DE-627)SPR013720643 (SPR)s10847-012-0182-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Cho, Eunae verfasserin aut Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213 Choi, Jae Min verfasserin aut Jung, Seunho verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 76(2012), 1-2 vom: 14. Juni, Seite 133-141 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 https://dx.doi.org/10.1007/s10847-012-0182-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 76 2012 1-2 14 06 133-141 |
allfieldsSound |
10.1007/s10847-012-0182-0 doi (DE-627)SPR013720643 (SPR)s10847-012-0182-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Cho, Eunae verfasserin aut Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213 Choi, Jae Min verfasserin aut Jung, Seunho verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 76(2012), 1-2 vom: 14. Juni, Seite 133-141 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 https://dx.doi.org/10.1007/s10847-012-0182-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 76 2012 1-2 14 06 133-141 |
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English |
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Enthalten in Journal of inclusion phenomena and macrocyclic chemistry 76(2012), 1-2 vom: 14. Juni, Seite 133-141 volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 |
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Enthalten in Journal of inclusion phenomena and macrocyclic chemistry 76(2012), 1-2 vom: 14. Juni, Seite 133-141 volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 |
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Succinoglycan dimers Isoflavonoids Solubility enhancement Complexation |
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Journal of inclusion phenomena and macrocyclic chemistry |
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Cho, Eunae @@aut@@ Choi, Jae Min @@aut@@ Jung, Seunho @@aut@@ |
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2012-06-14T00:00:00Z |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR013720643</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519072244.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2012 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10847-012-0182-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR013720643</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10847-012-0182-0-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.80</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.59</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Cho, Eunae</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2012</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Succinoglycan dimers</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Isoflavonoids</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Solubility enhancement</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Complexation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Choi, Jae Min</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Jung, Seunho</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of inclusion phenomena and macrocyclic chemistry</subfield><subfield code="d">Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983</subfield><subfield code="g">76(2012), 1-2 vom: 14. 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|
author |
Cho, Eunae |
spellingShingle |
Cho, Eunae ddc 540 bkl 35.80 bkl 35.59 misc Succinoglycan dimers misc Isoflavonoids misc Solubility enhancement misc Complexation Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti |
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540 ASE 35.80 bkl 35.59 bkl Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213 |
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ddc 540 bkl 35.80 bkl 35.59 misc Succinoglycan dimers misc Isoflavonoids misc Solubility enhancement misc Complexation |
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ddc 540 bkl 35.80 bkl 35.59 misc Succinoglycan dimers misc Isoflavonoids misc Solubility enhancement misc Complexation |
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ddc 540 bkl 35.80 bkl 35.59 misc Succinoglycan dimers misc Isoflavonoids misc Solubility enhancement misc Complexation |
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Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti |
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Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti |
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Cho, Eunae |
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Journal of inclusion phenomena and macrocyclic chemistry |
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Cho, Eunae Choi, Jae Min Jung, Seunho |
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540 ASE 35.80 bkl 35.59 bkl |
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solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from sinorhizobium meliloti |
title_auth |
Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti |
abstract |
Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. |
abstractGer |
Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. |
abstract_unstemmed |
Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. |
collection_details |
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container_issue |
1-2 |
title_short |
Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti |
url |
https://dx.doi.org/10.1007/s10847-012-0182-0 |
remote_bool |
true |
author2 |
Choi, Jae Min Jung, Seunho |
author2Str |
Choi, Jae Min Jung, Seunho |
ppnlink |
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isOA_txt |
false |
hochschulschrift_bool |
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doi_str |
10.1007/s10847-012-0182-0 |
up_date |
2024-07-03T21:42:41.476Z |
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score |
7.4005327 |