Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti

Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Cho, Eunae [verfasserIn] Choi, Jae Min [verfasserIn] Jung, Seunho [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2012

Schlagwörter:	Succinoglycan dimers Isoflavonoids Solubility enhancement Complexation

Übergeordnetes Werk:	Enthalten in: Journal of inclusion phenomena and macrocyclic chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983, 76(2012), 1-2 vom: 14. Juni, Seite 133-141
Übergeordnetes Werk:	volume:76 ; year:2012 ; number:1-2 ; day:14 ; month:06 ; pages:133-141

Links:	Volltext

DOI / URN:	10.1007/s10847-012-0182-0

Katalog-ID:	SPR013720643

Internformat


LEADER	01000caa a22002652 4500
001	SPR013720643
003	DE-627
005	20230519072244.0
007	cr uuu---uuuuu
008	201006s2012 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.1007/s10847-012-0182-0 \|2 doi
035			\|a (DE-627)SPR013720643
035			\|a (SPR)s10847-012-0182-0-e
040			\|a DE-627 \|b ger \|c DE-627 \|e rakwb
041			\|a eng
082	0	4	\|a 540 \|q ASE
084			\|a 35.80 \|2 bkl
084			\|a 35.59 \|2 bkl
100	1		\|a Cho, Eunae \|e verfasserin \|4 aut
245	1	0	\|a Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti
264		1	\|c 2012
336			\|a Text \|b txt \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids.
650		4	\|a Succinoglycan dimers \|7 (dpeaa)DE-He213
650		4	\|a Isoflavonoids \|7 (dpeaa)DE-He213
650		4	\|a Solubility enhancement \|7 (dpeaa)DE-He213
650		4	\|a Complexation \|7 (dpeaa)DE-He213
700	1		\|a Choi, Jae Min \|e verfasserin \|4 aut
700	1		\|a Jung, Seunho \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Journal of inclusion phenomena and macrocyclic chemistry \|d Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 \|g 76(2012), 1-2 vom: 14. Juni, Seite 133-141 \|w (DE-627)315293152 \|w (DE-600)2016909-7 \|x 1573-1111 \|7 nnns
773	1	8	\|g volume:76 \|g year:2012 \|g number:1-2 \|g day:14 \|g month:06 \|g pages:133-141
856	4	0	\|u https://dx.doi.org/10.1007/s10847-012-0182-0 \|z lizenzpflichtig \|3 Volltext
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_SPRINGER
912			\|a SSG-OLC-PHA
912			\|a GBV_ILN_11
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_39
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_101
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2144
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2188
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2232
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2446
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2472
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_2548
912			\|a GBV_ILN_4012
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4246
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4336
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
912			\|a GBV_ILN_4700
936	b	k	\|a 35.80 \|q ASE
936	b	k	\|a 35.59 \|q ASE
951			\|a AR
952			\|d 76 \|j 2012 \|e 1-2 \|b 14 \|c 06 \|h 133-141

Indexfelder

author_variant	e c ec j m c jm jmc s j sj
matchkey_str	article:15731111:2012----::ouiiynacmnoiolvnisyopeainihccihxdcschrdsucngyadmr
hierarchy_sort_str	2012
bklnumber	35.80 35.59
publishDate	2012
allfields	10.1007/s10847-012-0182-0 doi (DE-627)SPR013720643 (SPR)s10847-012-0182-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Cho, Eunae verfasserin aut Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213 Choi, Jae Min verfasserin aut Jung, Seunho verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 76(2012), 1-2 vom: 14. Juni, Seite 133-141 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 https://dx.doi.org/10.1007/s10847-012-0182-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 76 2012 1-2 14 06 133-141
spelling	10.1007/s10847-012-0182-0 doi (DE-627)SPR013720643 (SPR)s10847-012-0182-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Cho, Eunae verfasserin aut Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213 Choi, Jae Min verfasserin aut Jung, Seunho verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 76(2012), 1-2 vom: 14. Juni, Seite 133-141 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 https://dx.doi.org/10.1007/s10847-012-0182-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 76 2012 1-2 14 06 133-141
allfields_unstemmed	10.1007/s10847-012-0182-0 doi (DE-627)SPR013720643 (SPR)s10847-012-0182-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Cho, Eunae verfasserin aut Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213 Choi, Jae Min verfasserin aut Jung, Seunho verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 76(2012), 1-2 vom: 14. Juni, Seite 133-141 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 https://dx.doi.org/10.1007/s10847-012-0182-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 76 2012 1-2 14 06 133-141
allfieldsGer	10.1007/s10847-012-0182-0 doi (DE-627)SPR013720643 (SPR)s10847-012-0182-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Cho, Eunae verfasserin aut Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213 Choi, Jae Min verfasserin aut Jung, Seunho verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 76(2012), 1-2 vom: 14. Juni, Seite 133-141 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 https://dx.doi.org/10.1007/s10847-012-0182-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 76 2012 1-2 14 06 133-141
allfieldsSound	10.1007/s10847-012-0182-0 doi (DE-627)SPR013720643 (SPR)s10847-012-0182-0-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Cho, Eunae verfasserin aut Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids. Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213 Choi, Jae Min verfasserin aut Jung, Seunho verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 76(2012), 1-2 vom: 14. Juni, Seite 133-141 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141 https://dx.doi.org/10.1007/s10847-012-0182-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 76 2012 1-2 14 06 133-141
language	English
source	Enthalten in Journal of inclusion phenomena and macrocyclic chemistry 76(2012), 1-2 vom: 14. Juni, Seite 133-141 volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141
sourceStr	Enthalten in Journal of inclusion phenomena and macrocyclic chemistry 76(2012), 1-2 vom: 14. Juni, Seite 133-141 volume:76 year:2012 number:1-2 day:14 month:06 pages:133-141
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Succinoglycan dimers Isoflavonoids Solubility enhancement Complexation
dewey-raw	540
isfreeaccess_bool	false
container_title	Journal of inclusion phenomena and macrocyclic chemistry
authorswithroles_txt_mv	Cho, Eunae @@aut@@ Choi, Jae Min @@aut@@ Jung, Seunho @@aut@@
publishDateDaySort_date	2012-06-14T00:00:00Z
hierarchy_top_id	315293152
dewey-sort	3540
id	SPR013720643
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR013720643</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519072244.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2012 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10847-012-0182-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR013720643</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10847-012-0182-0-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.80</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.59</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Cho, Eunae</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2012</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Succinoglycan dimers</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Isoflavonoids</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Solubility enhancement</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Complexation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Choi, Jae Min</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Jung, Seunho</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of inclusion phenomena and macrocyclic chemistry</subfield><subfield code="d">Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983</subfield><subfield code="g">76(2012), 1-2 vom: 14. Juni, Seite 133-141</subfield><subfield code="w">(DE-627)315293152</subfield><subfield code="w">(DE-600)2016909-7</subfield><subfield code="x">1573-1111</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:76</subfield><subfield code="g">year:2012</subfield><subfield code="g">number:1-2</subfield><subfield code="g">day:14</subfield><subfield code="g">month:06</subfield><subfield code="g">pages:133-141</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s10847-012-0182-0</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_101</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2070</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2086</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2116</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2119</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.80</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.59</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">76</subfield><subfield code="j">2012</subfield><subfield code="e">1-2</subfield><subfield code="b">14</subfield><subfield code="c">06</subfield><subfield code="h">133-141</subfield></datafield></record></collection>
author	Cho, Eunae
spellingShingle	Cho, Eunae ddc 540 bkl 35.80 bkl 35.59 misc Succinoglycan dimers misc Isoflavonoids misc Solubility enhancement misc Complexation Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti
authorStr	Cho, Eunae
ppnlink_with_tag_str_mv	@@773@@(DE-627)315293152
format	electronic Article
dewey-ones	540 - Chemistry & allied sciences
delete_txt_mv	keep
author_role	aut aut aut
collection	springer
remote_str	true
illustrated	Not Illustrated
issn	1573-1111
topic_title	540 ASE 35.80 bkl 35.59 bkl Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti Succinoglycan dimers (dpeaa)DE-He213 Isoflavonoids (dpeaa)DE-He213 Solubility enhancement (dpeaa)DE-He213 Complexation (dpeaa)DE-He213
topic	ddc 540 bkl 35.80 bkl 35.59 misc Succinoglycan dimers misc Isoflavonoids misc Solubility enhancement misc Complexation
topic_unstemmed	ddc 540 bkl 35.80 bkl 35.59 misc Succinoglycan dimers misc Isoflavonoids misc Solubility enhancement misc Complexation
topic_browse	ddc 540 bkl 35.80 bkl 35.59 misc Succinoglycan dimers misc Isoflavonoids misc Solubility enhancement misc Complexation
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	Journal of inclusion phenomena and macrocyclic chemistry
hierarchy_parent_id	315293152
dewey-tens	540 - Chemistry
hierarchy_top_title	Journal of inclusion phenomena and macrocyclic chemistry
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)315293152 (DE-600)2016909-7
title	Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti
ctrlnum	(DE-627)SPR013720643 (SPR)s10847-012-0182-0-e
title_full	Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti
author_sort	Cho, Eunae
journal	Journal of inclusion phenomena and macrocyclic chemistry
journalStr	Journal of inclusion phenomena and macrocyclic chemistry
lang_code	eng
isOA_bool	false
dewey-hundreds	500 - Science
recordtype	marc
publishDateSort	2012
contenttype_str_mv	txt
container_start_page	133
author_browse	Cho, Eunae Choi, Jae Min Jung, Seunho
container_volume	76
class	540 ASE 35.80 bkl 35.59 bkl
format_se	Elektronische Aufsätze
author-letter	Cho, Eunae
doi_str_mv	10.1007/s10847-012-0182-0
dewey-full	540
author2-role	verfasserin
title_sort	solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from sinorhizobium meliloti
title_auth	Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti
abstract	Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids.
abstractGer	Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids.
abstract_unstemmed	Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700
container_issue	1-2
title_short	Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti
url	https://dx.doi.org/10.1007/s10847-012-0182-0
remote_bool	true
author2	Choi, Jae Min Jung, Seunho
author2Str	Choi, Jae Min Jung, Seunho
ppnlink	315293152
mediatype_str_mv	c
isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1007/s10847-012-0182-0
up_date	2024-07-03T21:42:41.476Z
_version_	1803595768382095360
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR013720643</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519072244.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2012 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10847-012-0182-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR013720643</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10847-012-0182-0-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.80</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.59</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Cho, Eunae</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2012</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Sinorhizobium meliloti produces succinoglycan, an acidic exopolysaccharide composed of a monomeric octasaccharide repeating unit with acetyl, succinyl, and pyruvyl groups, in both low- and high-molecular-weight forms. Among the low-molecular-weight succinoglycans, dimers were isolated from S. meliloti and purified using various chromatographic techniques. The dimers were classified as four types (D1, D2, D3, and D4) based on the number of succinyl moieties in their structure. The effect of succinoglycan dimers on the aqueous solubility of isoflavonoids, daidzein and genistein was investigated. The solubility of isoflavonoids increased in the presence of succinoglycan dimers, and the complexation between isoflavonoids and succinoglycan dimers was analyzed by UV–Vis (ultraviolet–visible) and NMR (nuclear magnetic resonance) spectroscopy. In the phase solubility study, succinoglycan dimer D3 was shown to have the highest stability constants (4951 $ M^{−1} $ for daidzein, and 4452 $ M^{−1} $ for genistein) among the four succinoglycan dimers. The morphological structures of daidzein and genistein with D3 were studied using scanning electron microscopy, and X-ray powder diffractometry. The results showed the natures of the complexes significantly different from the free isoflavonoids. Herein, we suggest that the succinoglycan dimers are able to act as effective complexing agents for the isoflavonoids.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Succinoglycan dimers</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Isoflavonoids</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Solubility enhancement</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Complexation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Choi, Jae Min</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Jung, Seunho</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of inclusion phenomena and macrocyclic chemistry</subfield><subfield code="d">Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983</subfield><subfield code="g">76(2012), 1-2 vom: 14. Juni, Seite 133-141</subfield><subfield code="w">(DE-627)315293152</subfield><subfield code="w">(DE-600)2016909-7</subfield><subfield code="x">1573-1111</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:76</subfield><subfield code="g">year:2012</subfield><subfield code="g">number:1-2</subfield><subfield code="g">day:14</subfield><subfield code="g">month:06</subfield><subfield code="g">pages:133-141</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s10847-012-0182-0</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_101</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2070</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2086</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2116</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2119</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.80</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.59</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">76</subfield><subfield code="j">2012</subfield><subfield code="e">1-2</subfield><subfield code="b">14</subfield><subfield code="c">06</subfield><subfield code="h">133-141</subfield></datafield></record></collection>
score	7.4005327

Nicht das Richtige dabei?

Schreiben Sie uns!

Solubility enhancement of isoflavonoids by complexation with acyclic hexadecasaccharides, succinoglycan dimers isolated from Sinorhizobium meliloti

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?