Complex formation of fenchone with α-cyclodextrin: NMR titrations
Abstract 13C NMR titration studies of inclusion complexes of bicyclic terpenoid, fenchone enantiomers with α-cyclodextrin revealed their 1:2 guest–host stoichiometry. Sequential binding constants were determined indicating a strong binding cooperativity of two α-cyclodextrin to fenchone. The overall...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Nowakowski, Michał [verfasserIn] Ejchart, Andrzej [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2013 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of inclusion phenomena and macrocyclic chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983, 79(2013), 3-4 vom: 10. Aug., Seite 337-342 |
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| Übergeordnetes Werk: |
volume:79 ; year:2013 ; number:3-4 ; day:10 ; month:08 ; pages:337-342 |
| Links: |
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| DOI / URN: |
10.1007/s10847-013-0356-4 |
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| Katalog-ID: |
SPR013722506 |
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| 245 | 1 | 0 | |a Complex formation of fenchone with α-cyclodextrin: NMR titrations |
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| 520 | |a Abstract 13C NMR titration studies of inclusion complexes of bicyclic terpenoid, fenchone enantiomers with α-cyclodextrin revealed their 1:2 guest–host stoichiometry. Sequential binding constants were determined indicating a strong binding cooperativity of two α-cyclodextrin to fenchone. The overall association constants were used to calculate the Gibbs free energies of diastereomeric complex formation, which might be used as a measure of chiral recognition of fenchone by α-cyclodextrin. These results were compared with corresponding data derived for camphor, which is an isomeric bicyclic terpenoid. | ||
| 650 | 4 | |a Alpha-cyclodextrin |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Fenchone |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Inclusion complexes |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a C NMR titration |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Sequential association constants |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Diastereomeric complexes |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Chiral recognition |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Ejchart, Andrzej |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Journal of inclusion phenomena and macrocyclic chemistry |d Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 |g 79(2013), 3-4 vom: 10. Aug., Seite 337-342 |w (DE-627)315293152 |w (DE-600)2016909-7 |x 1573-1111 |7 nnns |
| 773 | 1 | 8 | |g volume:79 |g year:2013 |g number:3-4 |g day:10 |g month:08 |g pages:337-342 |
| 856 | 4 | 0 | |u https://dx.doi.org/10.1007/s10847-013-0356-4 |z kostenfrei |3 Volltext |
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10.1007/s10847-013-0356-4 doi (DE-627)SPR013722506 (SPR)s10847-013-0356-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Nowakowski, Michał verfasserin aut Complex formation of fenchone with α-cyclodextrin: NMR titrations 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract 13C NMR titration studies of inclusion complexes of bicyclic terpenoid, fenchone enantiomers with α-cyclodextrin revealed their 1:2 guest–host stoichiometry. Sequential binding constants were determined indicating a strong binding cooperativity of two α-cyclodextrin to fenchone. The overall association constants were used to calculate the Gibbs free energies of diastereomeric complex formation, which might be used as a measure of chiral recognition of fenchone by α-cyclodextrin. These results were compared with corresponding data derived for camphor, which is an isomeric bicyclic terpenoid. Alpha-cyclodextrin (dpeaa)DE-He213 Fenchone (dpeaa)DE-He213 Inclusion complexes (dpeaa)DE-He213 C NMR titration (dpeaa)DE-He213 Sequential association constants (dpeaa)DE-He213 Diastereomeric complexes (dpeaa)DE-He213 Chiral recognition (dpeaa)DE-He213 Ejchart, Andrzej verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 79(2013), 3-4 vom: 10. Aug., Seite 337-342 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:79 year:2013 number:3-4 day:10 month:08 pages:337-342 https://dx.doi.org/10.1007/s10847-013-0356-4 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 79 2013 3-4 10 08 337-342 |
| spelling |
10.1007/s10847-013-0356-4 doi (DE-627)SPR013722506 (SPR)s10847-013-0356-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Nowakowski, Michał verfasserin aut Complex formation of fenchone with α-cyclodextrin: NMR titrations 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract 13C NMR titration studies of inclusion complexes of bicyclic terpenoid, fenchone enantiomers with α-cyclodextrin revealed their 1:2 guest–host stoichiometry. Sequential binding constants were determined indicating a strong binding cooperativity of two α-cyclodextrin to fenchone. The overall association constants were used to calculate the Gibbs free energies of diastereomeric complex formation, which might be used as a measure of chiral recognition of fenchone by α-cyclodextrin. These results were compared with corresponding data derived for camphor, which is an isomeric bicyclic terpenoid. Alpha-cyclodextrin (dpeaa)DE-He213 Fenchone (dpeaa)DE-He213 Inclusion complexes (dpeaa)DE-He213 C NMR titration (dpeaa)DE-He213 Sequential association constants (dpeaa)DE-He213 Diastereomeric complexes (dpeaa)DE-He213 Chiral recognition (dpeaa)DE-He213 Ejchart, Andrzej verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 79(2013), 3-4 vom: 10. Aug., Seite 337-342 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:79 year:2013 number:3-4 day:10 month:08 pages:337-342 https://dx.doi.org/10.1007/s10847-013-0356-4 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 79 2013 3-4 10 08 337-342 |
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10.1007/s10847-013-0356-4 doi (DE-627)SPR013722506 (SPR)s10847-013-0356-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Nowakowski, Michał verfasserin aut Complex formation of fenchone with α-cyclodextrin: NMR titrations 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract 13C NMR titration studies of inclusion complexes of bicyclic terpenoid, fenchone enantiomers with α-cyclodextrin revealed their 1:2 guest–host stoichiometry. Sequential binding constants were determined indicating a strong binding cooperativity of two α-cyclodextrin to fenchone. The overall association constants were used to calculate the Gibbs free energies of diastereomeric complex formation, which might be used as a measure of chiral recognition of fenchone by α-cyclodextrin. These results were compared with corresponding data derived for camphor, which is an isomeric bicyclic terpenoid. Alpha-cyclodextrin (dpeaa)DE-He213 Fenchone (dpeaa)DE-He213 Inclusion complexes (dpeaa)DE-He213 C NMR titration (dpeaa)DE-He213 Sequential association constants (dpeaa)DE-He213 Diastereomeric complexes (dpeaa)DE-He213 Chiral recognition (dpeaa)DE-He213 Ejchart, Andrzej verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 79(2013), 3-4 vom: 10. Aug., Seite 337-342 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:79 year:2013 number:3-4 day:10 month:08 pages:337-342 https://dx.doi.org/10.1007/s10847-013-0356-4 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 79 2013 3-4 10 08 337-342 |
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10.1007/s10847-013-0356-4 doi (DE-627)SPR013722506 (SPR)s10847-013-0356-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Nowakowski, Michał verfasserin aut Complex formation of fenchone with α-cyclodextrin: NMR titrations 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract 13C NMR titration studies of inclusion complexes of bicyclic terpenoid, fenchone enantiomers with α-cyclodextrin revealed their 1:2 guest–host stoichiometry. Sequential binding constants were determined indicating a strong binding cooperativity of two α-cyclodextrin to fenchone. The overall association constants were used to calculate the Gibbs free energies of diastereomeric complex formation, which might be used as a measure of chiral recognition of fenchone by α-cyclodextrin. These results were compared with corresponding data derived for camphor, which is an isomeric bicyclic terpenoid. Alpha-cyclodextrin (dpeaa)DE-He213 Fenchone (dpeaa)DE-He213 Inclusion complexes (dpeaa)DE-He213 C NMR titration (dpeaa)DE-He213 Sequential association constants (dpeaa)DE-He213 Diastereomeric complexes (dpeaa)DE-He213 Chiral recognition (dpeaa)DE-He213 Ejchart, Andrzej verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 79(2013), 3-4 vom: 10. Aug., Seite 337-342 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:79 year:2013 number:3-4 day:10 month:08 pages:337-342 https://dx.doi.org/10.1007/s10847-013-0356-4 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 79 2013 3-4 10 08 337-342 |
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10.1007/s10847-013-0356-4 doi (DE-627)SPR013722506 (SPR)s10847-013-0356-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.80 bkl 35.59 bkl Nowakowski, Michał verfasserin aut Complex formation of fenchone with α-cyclodextrin: NMR titrations 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract 13C NMR titration studies of inclusion complexes of bicyclic terpenoid, fenchone enantiomers with α-cyclodextrin revealed their 1:2 guest–host stoichiometry. Sequential binding constants were determined indicating a strong binding cooperativity of two α-cyclodextrin to fenchone. The overall association constants were used to calculate the Gibbs free energies of diastereomeric complex formation, which might be used as a measure of chiral recognition of fenchone by α-cyclodextrin. These results were compared with corresponding data derived for camphor, which is an isomeric bicyclic terpenoid. Alpha-cyclodextrin (dpeaa)DE-He213 Fenchone (dpeaa)DE-He213 Inclusion complexes (dpeaa)DE-He213 C NMR titration (dpeaa)DE-He213 Sequential association constants (dpeaa)DE-He213 Diastereomeric complexes (dpeaa)DE-He213 Chiral recognition (dpeaa)DE-He213 Ejchart, Andrzej verfasserin aut Enthalten in Journal of inclusion phenomena and macrocyclic chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 79(2013), 3-4 vom: 10. Aug., Seite 337-342 (DE-627)315293152 (DE-600)2016909-7 1573-1111 nnns volume:79 year:2013 number:3-4 day:10 month:08 pages:337-342 https://dx.doi.org/10.1007/s10847-013-0356-4 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.80 ASE 35.59 ASE AR 79 2013 3-4 10 08 337-342 |
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English |
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Enthalten in Journal of inclusion phenomena and macrocyclic chemistry 79(2013), 3-4 vom: 10. Aug., Seite 337-342 volume:79 year:2013 number:3-4 day:10 month:08 pages:337-342 |
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Enthalten in Journal of inclusion phenomena and macrocyclic chemistry 79(2013), 3-4 vom: 10. Aug., Seite 337-342 volume:79 year:2013 number:3-4 day:10 month:08 pages:337-342 |
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findex.gbv.de |
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Alpha-cyclodextrin Fenchone Inclusion complexes C NMR titration Sequential association constants Diastereomeric complexes Chiral recognition |
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540 |
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Journal of inclusion phenomena and macrocyclic chemistry |
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Nowakowski, Michał @@aut@@ Ejchart, Andrzej @@aut@@ |
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2013-08-10T00:00:00Z |
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3540 |
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| author |
Nowakowski, Michał |
| spellingShingle |
Nowakowski, Michał ddc 540 bkl 35.80 bkl 35.59 misc Alpha-cyclodextrin misc Fenchone misc Inclusion complexes misc C NMR titration misc Sequential association constants misc Diastereomeric complexes misc Chiral recognition Complex formation of fenchone with α-cyclodextrin: NMR titrations |
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540 ASE 35.80 bkl 35.59 bkl Complex formation of fenchone with α-cyclodextrin: NMR titrations Alpha-cyclodextrin (dpeaa)DE-He213 Fenchone (dpeaa)DE-He213 Inclusion complexes (dpeaa)DE-He213 C NMR titration (dpeaa)DE-He213 Sequential association constants (dpeaa)DE-He213 Diastereomeric complexes (dpeaa)DE-He213 Chiral recognition (dpeaa)DE-He213 |
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ddc 540 bkl 35.80 bkl 35.59 misc Alpha-cyclodextrin misc Fenchone misc Inclusion complexes misc C NMR titration misc Sequential association constants misc Diastereomeric complexes misc Chiral recognition |
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ddc 540 bkl 35.80 bkl 35.59 misc Alpha-cyclodextrin misc Fenchone misc Inclusion complexes misc C NMR titration misc Sequential association constants misc Diastereomeric complexes misc Chiral recognition |
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Complex formation of fenchone with α-cyclodextrin: NMR titrations |
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Complex formation of fenchone with α-cyclodextrin: NMR titrations |
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Nowakowski, Michał |
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Journal of inclusion phenomena and macrocyclic chemistry |
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Nowakowski, Michał Ejchart, Andrzej |
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complex formation of fenchone with α-cyclodextrin: nmr titrations |
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Complex formation of fenchone with α-cyclodextrin: NMR titrations |
| abstract |
Abstract 13C NMR titration studies of inclusion complexes of bicyclic terpenoid, fenchone enantiomers with α-cyclodextrin revealed their 1:2 guest–host stoichiometry. Sequential binding constants were determined indicating a strong binding cooperativity of two α-cyclodextrin to fenchone. The overall association constants were used to calculate the Gibbs free energies of diastereomeric complex formation, which might be used as a measure of chiral recognition of fenchone by α-cyclodextrin. These results were compared with corresponding data derived for camphor, which is an isomeric bicyclic terpenoid. |
| abstractGer |
Abstract 13C NMR titration studies of inclusion complexes of bicyclic terpenoid, fenchone enantiomers with α-cyclodextrin revealed their 1:2 guest–host stoichiometry. Sequential binding constants were determined indicating a strong binding cooperativity of two α-cyclodextrin to fenchone. The overall association constants were used to calculate the Gibbs free energies of diastereomeric complex formation, which might be used as a measure of chiral recognition of fenchone by α-cyclodextrin. These results were compared with corresponding data derived for camphor, which is an isomeric bicyclic terpenoid. |
| abstract_unstemmed |
Abstract 13C NMR titration studies of inclusion complexes of bicyclic terpenoid, fenchone enantiomers with α-cyclodextrin revealed their 1:2 guest–host stoichiometry. Sequential binding constants were determined indicating a strong binding cooperativity of two α-cyclodextrin to fenchone. The overall association constants were used to calculate the Gibbs free energies of diastereomeric complex formation, which might be used as a measure of chiral recognition of fenchone by α-cyclodextrin. These results were compared with corresponding data derived for camphor, which is an isomeric bicyclic terpenoid. |
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Complex formation of fenchone with α-cyclodextrin: NMR titrations |
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https://dx.doi.org/10.1007/s10847-013-0356-4 |
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10.1007/s10847-013-0356-4 |
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| score |
7.401416 |