The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy

Abstract The SiKβ fluorescence X-ray and infra-red absorption spectra of $ Na_{2} $O-$ TiO_{2} $-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses have been measured in order to study the Si-O bonding as a function of the composition of glass. The chemical shifts of the SiKβ peak relative t...
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Gespeichert in:

Autor*in:	Sakka, Sumio [verfasserIn] Hotta, Hitoshi [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	1979

Schlagwörter:	TiO2 Chemical Shift Total Content Silica Glass GeO2

Übergeordnetes Werk:	Enthalten in: Journal of materials science - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966, 14(1979), 10 vom: 01. Okt., Seite 2335-2342
Übergeordnetes Werk:	volume:14 ; year:1979 ; number:10 ; day:01 ; month:10 ; pages:2335-2342

Links:	Volltext

DOI / URN:	10.1007/BF00737022

Katalog-ID:	SPR013752375

Internformat


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245	1	4	\|a The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy
264		1	\|c 1979
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520			\|a Abstract The SiKβ fluorescence X-ray and infra-red absorption spectra of $ Na_{2} $O-$ TiO_{2} $-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses have been measured in order to study the Si-O bonding as a function of the composition of glass. The chemical shifts of the SiKβ peak relative to that of silica glass [Δλ=λ($ SiO_{2} $)-λ(specimen)>0] and the wavenumbers of the infra-red absorption peaks around $ 950cm^{−1} $ and 1100 $ cm^{−1} $ have been determined from the spectra. The SiKβ chemical shift in both series of glasses increased with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ K_{2} $O+$ TiO_{2} $), where $ R_{2} $O represents $ Na_{2} $O or $ K_{2} $O. The infra-red peaks around 950 $ cm^{−1} $ and 1100 $ cm^{−1} $ shifted towards lower wavenumbers with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ R_{2} $O+$ TiO_{2} $). These experimental facts were interpreted as showing that the Si-O bond in glass was weakened as the total content of $ R_{2} $O and $ TiO_{2} $ increased and that the Si-O bond was weakened by $ R_{2} $O more than by $ TiO_{2} $.
650		4	\|a TiO2 \|7 (dpeaa)DE-He213
650		4	\|a Chemical Shift \|7 (dpeaa)DE-He213
650		4	\|a Total Content \|7 (dpeaa)DE-He213
650		4	\|a Silica Glass \|7 (dpeaa)DE-He213
650		4	\|a GeO2 \|7 (dpeaa)DE-He213
700	1		\|a Hotta, Hitoshi \|e verfasserin \|4 aut
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856	4	0	\|u https://dx.doi.org/10.1007/BF00737022 \|z lizenzpflichtig \|3 Volltext
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912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_121
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_206
912			\|a GBV_ILN_224
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_374
912			\|a GBV_ILN_602
912			\|a GBV_ILN_647
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2018
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
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912			\|a GBV_ILN_2039
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912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
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912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4328
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4336
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4346
912			\|a GBV_ILN_4367
912			\|a GBV_ILN_4393
912			\|a GBV_ILN_4700
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936	b	k	\|a 51.00 \|q ASE
951			\|a AR
952			\|d 14 \|j 1979 \|e 10 \|b 01 \|c 10 \|h 2335-2342

Indexfelder

author_variant	s s ss h h hh
matchkey_str	article:15734803:1979----::hsoodnin_oiso2nk2to2i_gassstdebskryloecnen
hierarchy_sort_str	1979
bklnumber	51.00
publishDate	1979
allfields	10.1007/BF00737022 doi (DE-627)SPR013752375 (SPR)BF00737022-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Sakka, Sumio verfasserin aut The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy 1979 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The SiKβ fluorescence X-ray and infra-red absorption spectra of $ Na_{2} $O-$ TiO_{2} $-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses have been measured in order to study the Si-O bonding as a function of the composition of glass. The chemical shifts of the SiKβ peak relative to that of silica glass [Δλ=λ($ SiO_{2} $)-λ(specimen)>0] and the wavenumbers of the infra-red absorption peaks around $ 950cm^{−1} $ and 1100 $ cm^{−1} $ have been determined from the spectra. The SiKβ chemical shift in both series of glasses increased with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ K_{2} $O+$ TiO_{2} $), where $ R_{2} $O represents $ Na_{2} $O or $ K_{2} $O. The infra-red peaks around 950 $ cm^{−1} $ and 1100 $ cm^{−1} $ shifted towards lower wavenumbers with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ R_{2} $O+$ TiO_{2} $). These experimental facts were interpreted as showing that the Si-O bond in glass was weakened as the total content of $ R_{2} $O and $ TiO_{2} $ increased and that the Si-O bond was weakened by $ R_{2} $O more than by $ TiO_{2} $. TiO2 (dpeaa)DE-He213 Chemical Shift (dpeaa)DE-He213 Total Content (dpeaa)DE-He213 Silica Glass (dpeaa)DE-He213 GeO2 (dpeaa)DE-He213 Hotta, Hitoshi verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 14(1979), 10 vom: 01. Okt., Seite 2335-2342 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:14 year:1979 number:10 day:01 month:10 pages:2335-2342 https://dx.doi.org/10.1007/BF00737022 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_224 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2043 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2158 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2193 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2808 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 51.00 ASE AR 14 1979 10 01 10 2335-2342
spelling	10.1007/BF00737022 doi (DE-627)SPR013752375 (SPR)BF00737022-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Sakka, Sumio verfasserin aut The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy 1979 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The SiKβ fluorescence X-ray and infra-red absorption spectra of $ Na_{2} $O-$ TiO_{2} $-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses have been measured in order to study the Si-O bonding as a function of the composition of glass. The chemical shifts of the SiKβ peak relative to that of silica glass [Δλ=λ($ SiO_{2} $)-λ(specimen)>0] and the wavenumbers of the infra-red absorption peaks around $ 950cm^{−1} $ and 1100 $ cm^{−1} $ have been determined from the spectra. The SiKβ chemical shift in both series of glasses increased with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ K_{2} $O+$ TiO_{2} $), where $ R_{2} $O represents $ Na_{2} $O or $ K_{2} $O. The infra-red peaks around 950 $ cm^{−1} $ and 1100 $ cm^{−1} $ shifted towards lower wavenumbers with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ R_{2} $O+$ TiO_{2} $). These experimental facts were interpreted as showing that the Si-O bond in glass was weakened as the total content of $ R_{2} $O and $ TiO_{2} $ increased and that the Si-O bond was weakened by $ R_{2} $O more than by $ TiO_{2} $. TiO2 (dpeaa)DE-He213 Chemical Shift (dpeaa)DE-He213 Total Content (dpeaa)DE-He213 Silica Glass (dpeaa)DE-He213 GeO2 (dpeaa)DE-He213 Hotta, Hitoshi verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 14(1979), 10 vom: 01. Okt., Seite 2335-2342 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:14 year:1979 number:10 day:01 month:10 pages:2335-2342 https://dx.doi.org/10.1007/BF00737022 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_224 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2043 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2158 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2193 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2808 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 51.00 ASE AR 14 1979 10 01 10 2335-2342
allfields_unstemmed	10.1007/BF00737022 doi (DE-627)SPR013752375 (SPR)BF00737022-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Sakka, Sumio verfasserin aut The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy 1979 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The SiKβ fluorescence X-ray and infra-red absorption spectra of $ Na_{2} $O-$ TiO_{2} $-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses have been measured in order to study the Si-O bonding as a function of the composition of glass. The chemical shifts of the SiKβ peak relative to that of silica glass [Δλ=λ($ SiO_{2} $)-λ(specimen)>0] and the wavenumbers of the infra-red absorption peaks around $ 950cm^{−1} $ and 1100 $ cm^{−1} $ have been determined from the spectra. The SiKβ chemical shift in both series of glasses increased with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ K_{2} $O+$ TiO_{2} $), where $ R_{2} $O represents $ Na_{2} $O or $ K_{2} $O. The infra-red peaks around 950 $ cm^{−1} $ and 1100 $ cm^{−1} $ shifted towards lower wavenumbers with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ R_{2} $O+$ TiO_{2} $). These experimental facts were interpreted as showing that the Si-O bond in glass was weakened as the total content of $ R_{2} $O and $ TiO_{2} $ increased and that the Si-O bond was weakened by $ R_{2} $O more than by $ TiO_{2} $. TiO2 (dpeaa)DE-He213 Chemical Shift (dpeaa)DE-He213 Total Content (dpeaa)DE-He213 Silica Glass (dpeaa)DE-He213 GeO2 (dpeaa)DE-He213 Hotta, Hitoshi verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 14(1979), 10 vom: 01. Okt., Seite 2335-2342 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:14 year:1979 number:10 day:01 month:10 pages:2335-2342 https://dx.doi.org/10.1007/BF00737022 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_224 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2043 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2158 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2193 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2808 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 51.00 ASE AR 14 1979 10 01 10 2335-2342
allfieldsGer	10.1007/BF00737022 doi (DE-627)SPR013752375 (SPR)BF00737022-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Sakka, Sumio verfasserin aut The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy 1979 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The SiKβ fluorescence X-ray and infra-red absorption spectra of $ Na_{2} $O-$ TiO_{2} $-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses have been measured in order to study the Si-O bonding as a function of the composition of glass. The chemical shifts of the SiKβ peak relative to that of silica glass [Δλ=λ($ SiO_{2} $)-λ(specimen)>0] and the wavenumbers of the infra-red absorption peaks around $ 950cm^{−1} $ and 1100 $ cm^{−1} $ have been determined from the spectra. The SiKβ chemical shift in both series of glasses increased with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ K_{2} $O+$ TiO_{2} $), where $ R_{2} $O represents $ Na_{2} $O or $ K_{2} $O. The infra-red peaks around 950 $ cm^{−1} $ and 1100 $ cm^{−1} $ shifted towards lower wavenumbers with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ R_{2} $O+$ TiO_{2} $). These experimental facts were interpreted as showing that the Si-O bond in glass was weakened as the total content of $ R_{2} $O and $ TiO_{2} $ increased and that the Si-O bond was weakened by $ R_{2} $O more than by $ TiO_{2} $. TiO2 (dpeaa)DE-He213 Chemical Shift (dpeaa)DE-He213 Total Content (dpeaa)DE-He213 Silica Glass (dpeaa)DE-He213 GeO2 (dpeaa)DE-He213 Hotta, Hitoshi verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 14(1979), 10 vom: 01. Okt., Seite 2335-2342 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:14 year:1979 number:10 day:01 month:10 pages:2335-2342 https://dx.doi.org/10.1007/BF00737022 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_224 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2043 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2158 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2193 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2808 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 51.00 ASE AR 14 1979 10 01 10 2335-2342
allfieldsSound	10.1007/BF00737022 doi (DE-627)SPR013752375 (SPR)BF00737022-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Sakka, Sumio verfasserin aut The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy 1979 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The SiKβ fluorescence X-ray and infra-red absorption spectra of $ Na_{2} $O-$ TiO_{2} $-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses have been measured in order to study the Si-O bonding as a function of the composition of glass. The chemical shifts of the SiKβ peak relative to that of silica glass [Δλ=λ($ SiO_{2} $)-λ(specimen)>0] and the wavenumbers of the infra-red absorption peaks around $ 950cm^{−1} $ and 1100 $ cm^{−1} $ have been determined from the spectra. The SiKβ chemical shift in both series of glasses increased with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ K_{2} $O+$ TiO_{2} $), where $ R_{2} $O represents $ Na_{2} $O or $ K_{2} $O. The infra-red peaks around 950 $ cm^{−1} $ and 1100 $ cm^{−1} $ shifted towards lower wavenumbers with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ R_{2} $O+$ TiO_{2} $). These experimental facts were interpreted as showing that the Si-O bond in glass was weakened as the total content of $ R_{2} $O and $ TiO_{2} $ increased and that the Si-O bond was weakened by $ R_{2} $O more than by $ TiO_{2} $. TiO2 (dpeaa)DE-He213 Chemical Shift (dpeaa)DE-He213 Total Content (dpeaa)DE-He213 Silica Glass (dpeaa)DE-He213 GeO2 (dpeaa)DE-He213 Hotta, Hitoshi verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 14(1979), 10 vom: 01. Okt., Seite 2335-2342 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:14 year:1979 number:10 day:01 month:10 pages:2335-2342 https://dx.doi.org/10.1007/BF00737022 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_224 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2043 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2158 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2193 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2808 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 51.00 ASE AR 14 1979 10 01 10 2335-2342
language	English
source	Enthalten in Journal of materials science 14(1979), 10 vom: 01. Okt., Seite 2335-2342 volume:14 year:1979 number:10 day:01 month:10 pages:2335-2342
sourceStr	Enthalten in Journal of materials science 14(1979), 10 vom: 01. Okt., Seite 2335-2342 volume:14 year:1979 number:10 day:01 month:10 pages:2335-2342
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	TiO2 Chemical Shift Total Content Silica Glass GeO2
dewey-raw	670
isfreeaccess_bool	false
container_title	Journal of materials science
authorswithroles_txt_mv	Sakka, Sumio @@aut@@ Hotta, Hitoshi @@aut@@
publishDateDaySort_date	1979-10-01T00:00:00Z
hierarchy_top_id	315293969
dewey-sort	3670
id	SPR013752375
language_de	englisch
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The chemical shifts of the SiKβ peak relative to that of silica glass [Δλ=λ($ SiO_{2} $)-λ(specimen)>0] and the wavenumbers of the infra-red absorption peaks around $ 950cm^{−1} $ and 1100 $ cm^{−1} $ have been determined from the spectra. The SiKβ chemical shift in both series of glasses increased with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ K_{2} $O+$ TiO_{2} $), where $ R_{2} $O represents $ Na_{2} $O or $ K_{2} $O. The infra-red peaks around 950 $ cm^{−1} $ and 1100 $ cm^{−1} $ shifted towards lower wavenumbers with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ R_{2} $O+$ TiO_{2} $). These experimental facts were interpreted as showing that the Si-O bond in glass was weakened as the total content of $ R_{2} $O and $ TiO_{2} $ increased and that the Si-O bond was weakened by $ R_{2} $O more than by $ TiO_{2} $.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">TiO2</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chemical Shift</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Total Content</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Silica Glass</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">GeO2</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Hotta, Hitoshi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of materials science</subfield><subfield code="d">Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966</subfield><subfield code="g">14(1979), 10 vom: 01. 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author	Sakka, Sumio
spellingShingle	Sakka, Sumio ddc 670 bkl 51.00 misc TiO2 misc Chemical Shift misc Total Content misc Silica Glass misc GeO2 The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy
authorStr	Sakka, Sumio
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issn	1573-4803
topic_title	670 ASE 51.00 bkl The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy TiO2 (dpeaa)DE-He213 Chemical Shift (dpeaa)DE-He213 Total Content (dpeaa)DE-He213 Silica Glass (dpeaa)DE-He213 GeO2 (dpeaa)DE-He213
topic	ddc 670 bkl 51.00 misc TiO2 misc Chemical Shift misc Total Content misc Silica Glass misc GeO2
topic_unstemmed	ddc 670 bkl 51.00 misc TiO2 misc Chemical Shift misc Total Content misc Silica Glass misc GeO2
topic_browse	ddc 670 bkl 51.00 misc TiO2 misc Chemical Shift misc Total Content misc Silica Glass misc GeO2
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
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dewey-tens	670 - Manufacturing
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title	The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy
ctrlnum	(DE-627)SPR013752375 (SPR)BF00737022-e
title_full	The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy
author_sort	Sakka, Sumio
journal	Journal of materials science
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author_browse	Sakka, Sumio Hotta, Hitoshi
container_volume	14
class	670 ASE 51.00 bkl
format_se	Elektronische Aufsätze
author-letter	Sakka, Sumio
doi_str_mv	10.1007/BF00737022
dewey-full	670
author2-role	verfasserin
title_sort	si-o bonding in $ na_{2} $o-tio-$ sio_{2} $ and $ k_{2} $o-$ tio_{2} $-$ sio_{2} $ glasses as studied by sikβ x-ray fluorescence and infra-red absorption spectroscopy
title_auth	The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy
abstract	Abstract The SiKβ fluorescence X-ray and infra-red absorption spectra of $ Na_{2} $O-$ TiO_{2} $-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses have been measured in order to study the Si-O bonding as a function of the composition of glass. The chemical shifts of the SiKβ peak relative to that of silica glass [Δλ=λ($ SiO_{2} $)-λ(specimen)>0] and the wavenumbers of the infra-red absorption peaks around $ 950cm^{−1} $ and 1100 $ cm^{−1} $ have been determined from the spectra. The SiKβ chemical shift in both series of glasses increased with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ K_{2} $O+$ TiO_{2} $), where $ R_{2} $O represents $ Na_{2} $O or $ K_{2} $O. The infra-red peaks around 950 $ cm^{−1} $ and 1100 $ cm^{−1} $ shifted towards lower wavenumbers with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ R_{2} $O+$ TiO_{2} $). These experimental facts were interpreted as showing that the Si-O bond in glass was weakened as the total content of $ R_{2} $O and $ TiO_{2} $ increased and that the Si-O bond was weakened by $ R_{2} $O more than by $ TiO_{2} $.
abstractGer	Abstract The SiKβ fluorescence X-ray and infra-red absorption spectra of $ Na_{2} $O-$ TiO_{2} $-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses have been measured in order to study the Si-O bonding as a function of the composition of glass. The chemical shifts of the SiKβ peak relative to that of silica glass [Δλ=λ($ SiO_{2} $)-λ(specimen)>0] and the wavenumbers of the infra-red absorption peaks around $ 950cm^{−1} $ and 1100 $ cm^{−1} $ have been determined from the spectra. The SiKβ chemical shift in both series of glasses increased with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ K_{2} $O+$ TiO_{2} $), where $ R_{2} $O represents $ Na_{2} $O or $ K_{2} $O. The infra-red peaks around 950 $ cm^{−1} $ and 1100 $ cm^{−1} $ shifted towards lower wavenumbers with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ R_{2} $O+$ TiO_{2} $). These experimental facts were interpreted as showing that the Si-O bond in glass was weakened as the total content of $ R_{2} $O and $ TiO_{2} $ increased and that the Si-O bond was weakened by $ R_{2} $O more than by $ TiO_{2} $.
abstract_unstemmed	Abstract The SiKβ fluorescence X-ray and infra-red absorption spectra of $ Na_{2} $O-$ TiO_{2} $-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses have been measured in order to study the Si-O bonding as a function of the composition of glass. The chemical shifts of the SiKβ peak relative to that of silica glass [Δλ=λ($ SiO_{2} $)-λ(specimen)>0] and the wavenumbers of the infra-red absorption peaks around $ 950cm^{−1} $ and 1100 $ cm^{−1} $ have been determined from the spectra. The SiKβ chemical shift in both series of glasses increased with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ K_{2} $O+$ TiO_{2} $), where $ R_{2} $O represents $ Na_{2} $O or $ K_{2} $O. The infra-red peaks around 950 $ cm^{−1} $ and 1100 $ cm^{−1} $ shifted towards lower wavenumbers with increasing total content of $ R_{2} $O and $ TiO_{2} $ and with decreasing ratio of $ TiO_{2} $/($ R_{2} $O+$ TiO_{2} $). These experimental facts were interpreted as showing that the Si-O bond in glass was weakened as the total content of $ R_{2} $O and $ TiO_{2} $ increased and that the Si-O bond was weakened by $ R_{2} $O more than by $ TiO_{2} $.
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container_issue	10
title_short	The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy
url	https://dx.doi.org/10.1007/BF00737022
remote_bool	true
author2	Hotta, Hitoshi
author2Str	Hotta, Hitoshi
ppnlink	315293969
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isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1007/BF00737022
up_date	2024-07-03T21:55:53.012Z
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The Si-O bonding in $ Na_{2} $O-TiO-$ SiO_{2} $ and $ K_{2} $O-$ TiO_{2} $-$ SiO_{2} $ glasses as studied by SiKβ X-ray fluorescence and infra-red absorption spectroscopy

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