Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound
Abstract In the present study, $ NaYP_{2} %$ O_{7} $ compound was prepared by solid-state method and was characterized by powder X-ray diffraction and Raman spectroscopy. The X-ray diffraction of the sample at room temperature showed a monoclinic phase. Electrical conductivity and modulus studies ov...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Oueslati, A. [verfasserIn] Gargouri, M. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2018 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of electroceramics - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1997, 42(2018), 3-4 vom: 28. Sept., Seite 129-135 |
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| Übergeordnetes Werk: |
volume:42 ; year:2018 ; number:3-4 ; day:28 ; month:09 ; pages:129-135 |
| Links: |
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| DOI / URN: |
10.1007/s10832-018-0162-x |
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| Katalog-ID: |
SPR013757938 |
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| 245 | 1 | 0 | |a Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound |
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| 520 | |a Abstract In the present study, $ NaYP_{2} %$ O_{7} $ compound was prepared by solid-state method and was characterized by powder X-ray diffraction and Raman spectroscopy. The X-ray diffraction of the sample at room temperature showed a monoclinic phase. Electrical conductivity and modulus studies over a wide range of frequencies (40 Hz to 7 MHz) and temperature (400–560 K) were studied using impedance spectroscopic technique. The impedance plane plot shows semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to explain the impedance results. The ac conductivity of the investigated compound obeys the power law: $ σ_{ac} $(ω) = $ σ_{dc} $ + $ Aω^{n} $ where n < 1. The frequency-dependent maxima of the imaginary part of modulus are found to obey Arrhenius law with activation energy 0.64 eV. The activation energy responsible for dielectric relaxation extracted from the modulus spectra is found to be almost the same as the value obtained from the equivalent circuit. These results indicate that the transport is through ion hopping mechanism dominated by the motion of the $ Na^{+} $ ion in the structure of the investigated material. | ||
| 650 | 4 | |a Sodium pyrophosphate |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Impedance |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Ionic conductivity |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a CBH model |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Modulus |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Gargouri, M. |e verfasserin |4 aut | |
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| 856 | 4 | 0 | |u https://dx.doi.org/10.1007/s10832-018-0162-x |z lizenzpflichtig |3 Volltext |
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10.1007/s10832-018-0162-x doi (DE-627)SPR013757938 (SPR)s10832-018-0162-x-e DE-627 ger DE-627 rakwb eng 620 ASE 53.09 bkl Oueslati, A. verfasserin aut Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In the present study, $ NaYP_{2} %$ O_{7} $ compound was prepared by solid-state method and was characterized by powder X-ray diffraction and Raman spectroscopy. The X-ray diffraction of the sample at room temperature showed a monoclinic phase. Electrical conductivity and modulus studies over a wide range of frequencies (40 Hz to 7 MHz) and temperature (400–560 K) were studied using impedance spectroscopic technique. The impedance plane plot shows semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to explain the impedance results. The ac conductivity of the investigated compound obeys the power law: $ σ_{ac} $(ω) = $ σ_{dc} $ + $ Aω^{n} $ where n < 1. The frequency-dependent maxima of the imaginary part of modulus are found to obey Arrhenius law with activation energy 0.64 eV. The activation energy responsible for dielectric relaxation extracted from the modulus spectra is found to be almost the same as the value obtained from the equivalent circuit. These results indicate that the transport is through ion hopping mechanism dominated by the motion of the $ Na^{+} $ ion in the structure of the investigated material. Sodium pyrophosphate (dpeaa)DE-He213 Impedance (dpeaa)DE-He213 Ionic conductivity (dpeaa)DE-He213 CBH model (dpeaa)DE-He213 Modulus (dpeaa)DE-He213 Gargouri, M. verfasserin aut Enthalten in Journal of electroceramics Dordrecht [u.a.] : Springer Science + Business Media B.V, 1997 42(2018), 3-4 vom: 28. Sept., Seite 129-135 (DE-627)268754381 (DE-600)1472395-5 1573-8663 nnns volume:42 year:2018 number:3-4 day:28 month:09 pages:129-135 https://dx.doi.org/10.1007/s10832-018-0162-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 53.09 ASE AR 42 2018 3-4 28 09 129-135 |
| spelling |
10.1007/s10832-018-0162-x doi (DE-627)SPR013757938 (SPR)s10832-018-0162-x-e DE-627 ger DE-627 rakwb eng 620 ASE 53.09 bkl Oueslati, A. verfasserin aut Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In the present study, $ NaYP_{2} %$ O_{7} $ compound was prepared by solid-state method and was characterized by powder X-ray diffraction and Raman spectroscopy. The X-ray diffraction of the sample at room temperature showed a monoclinic phase. Electrical conductivity and modulus studies over a wide range of frequencies (40 Hz to 7 MHz) and temperature (400–560 K) were studied using impedance spectroscopic technique. The impedance plane plot shows semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to explain the impedance results. The ac conductivity of the investigated compound obeys the power law: $ σ_{ac} $(ω) = $ σ_{dc} $ + $ Aω^{n} $ where n < 1. The frequency-dependent maxima of the imaginary part of modulus are found to obey Arrhenius law with activation energy 0.64 eV. The activation energy responsible for dielectric relaxation extracted from the modulus spectra is found to be almost the same as the value obtained from the equivalent circuit. These results indicate that the transport is through ion hopping mechanism dominated by the motion of the $ Na^{+} $ ion in the structure of the investigated material. Sodium pyrophosphate (dpeaa)DE-He213 Impedance (dpeaa)DE-He213 Ionic conductivity (dpeaa)DE-He213 CBH model (dpeaa)DE-He213 Modulus (dpeaa)DE-He213 Gargouri, M. verfasserin aut Enthalten in Journal of electroceramics Dordrecht [u.a.] : Springer Science + Business Media B.V, 1997 42(2018), 3-4 vom: 28. Sept., Seite 129-135 (DE-627)268754381 (DE-600)1472395-5 1573-8663 nnns volume:42 year:2018 number:3-4 day:28 month:09 pages:129-135 https://dx.doi.org/10.1007/s10832-018-0162-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 53.09 ASE AR 42 2018 3-4 28 09 129-135 |
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10.1007/s10832-018-0162-x doi (DE-627)SPR013757938 (SPR)s10832-018-0162-x-e DE-627 ger DE-627 rakwb eng 620 ASE 53.09 bkl Oueslati, A. verfasserin aut Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In the present study, $ NaYP_{2} %$ O_{7} $ compound was prepared by solid-state method and was characterized by powder X-ray diffraction and Raman spectroscopy. The X-ray diffraction of the sample at room temperature showed a monoclinic phase. Electrical conductivity and modulus studies over a wide range of frequencies (40 Hz to 7 MHz) and temperature (400–560 K) were studied using impedance spectroscopic technique. The impedance plane plot shows semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to explain the impedance results. The ac conductivity of the investigated compound obeys the power law: $ σ_{ac} $(ω) = $ σ_{dc} $ + $ Aω^{n} $ where n < 1. The frequency-dependent maxima of the imaginary part of modulus are found to obey Arrhenius law with activation energy 0.64 eV. The activation energy responsible for dielectric relaxation extracted from the modulus spectra is found to be almost the same as the value obtained from the equivalent circuit. These results indicate that the transport is through ion hopping mechanism dominated by the motion of the $ Na^{+} $ ion in the structure of the investigated material. Sodium pyrophosphate (dpeaa)DE-He213 Impedance (dpeaa)DE-He213 Ionic conductivity (dpeaa)DE-He213 CBH model (dpeaa)DE-He213 Modulus (dpeaa)DE-He213 Gargouri, M. verfasserin aut Enthalten in Journal of electroceramics Dordrecht [u.a.] : Springer Science + Business Media B.V, 1997 42(2018), 3-4 vom: 28. Sept., Seite 129-135 (DE-627)268754381 (DE-600)1472395-5 1573-8663 nnns volume:42 year:2018 number:3-4 day:28 month:09 pages:129-135 https://dx.doi.org/10.1007/s10832-018-0162-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 53.09 ASE AR 42 2018 3-4 28 09 129-135 |
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10.1007/s10832-018-0162-x doi (DE-627)SPR013757938 (SPR)s10832-018-0162-x-e DE-627 ger DE-627 rakwb eng 620 ASE 53.09 bkl Oueslati, A. verfasserin aut Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In the present study, $ NaYP_{2} %$ O_{7} $ compound was prepared by solid-state method and was characterized by powder X-ray diffraction and Raman spectroscopy. The X-ray diffraction of the sample at room temperature showed a monoclinic phase. Electrical conductivity and modulus studies over a wide range of frequencies (40 Hz to 7 MHz) and temperature (400–560 K) were studied using impedance spectroscopic technique. The impedance plane plot shows semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to explain the impedance results. The ac conductivity of the investigated compound obeys the power law: $ σ_{ac} $(ω) = $ σ_{dc} $ + $ Aω^{n} $ where n < 1. The frequency-dependent maxima of the imaginary part of modulus are found to obey Arrhenius law with activation energy 0.64 eV. The activation energy responsible for dielectric relaxation extracted from the modulus spectra is found to be almost the same as the value obtained from the equivalent circuit. These results indicate that the transport is through ion hopping mechanism dominated by the motion of the $ Na^{+} $ ion in the structure of the investigated material. Sodium pyrophosphate (dpeaa)DE-He213 Impedance (dpeaa)DE-He213 Ionic conductivity (dpeaa)DE-He213 CBH model (dpeaa)DE-He213 Modulus (dpeaa)DE-He213 Gargouri, M. verfasserin aut Enthalten in Journal of electroceramics Dordrecht [u.a.] : Springer Science + Business Media B.V, 1997 42(2018), 3-4 vom: 28. Sept., Seite 129-135 (DE-627)268754381 (DE-600)1472395-5 1573-8663 nnns volume:42 year:2018 number:3-4 day:28 month:09 pages:129-135 https://dx.doi.org/10.1007/s10832-018-0162-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 53.09 ASE AR 42 2018 3-4 28 09 129-135 |
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10.1007/s10832-018-0162-x doi (DE-627)SPR013757938 (SPR)s10832-018-0162-x-e DE-627 ger DE-627 rakwb eng 620 ASE 53.09 bkl Oueslati, A. verfasserin aut Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In the present study, $ NaYP_{2} %$ O_{7} $ compound was prepared by solid-state method and was characterized by powder X-ray diffraction and Raman spectroscopy. The X-ray diffraction of the sample at room temperature showed a monoclinic phase. Electrical conductivity and modulus studies over a wide range of frequencies (40 Hz to 7 MHz) and temperature (400–560 K) were studied using impedance spectroscopic technique. The impedance plane plot shows semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to explain the impedance results. The ac conductivity of the investigated compound obeys the power law: $ σ_{ac} $(ω) = $ σ_{dc} $ + $ Aω^{n} $ where n < 1. The frequency-dependent maxima of the imaginary part of modulus are found to obey Arrhenius law with activation energy 0.64 eV. The activation energy responsible for dielectric relaxation extracted from the modulus spectra is found to be almost the same as the value obtained from the equivalent circuit. These results indicate that the transport is through ion hopping mechanism dominated by the motion of the $ Na^{+} $ ion in the structure of the investigated material. Sodium pyrophosphate (dpeaa)DE-He213 Impedance (dpeaa)DE-He213 Ionic conductivity (dpeaa)DE-He213 CBH model (dpeaa)DE-He213 Modulus (dpeaa)DE-He213 Gargouri, M. verfasserin aut Enthalten in Journal of electroceramics Dordrecht [u.a.] : Springer Science + Business Media B.V, 1997 42(2018), 3-4 vom: 28. Sept., Seite 129-135 (DE-627)268754381 (DE-600)1472395-5 1573-8663 nnns volume:42 year:2018 number:3-4 day:28 month:09 pages:129-135 https://dx.doi.org/10.1007/s10832-018-0162-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 53.09 ASE AR 42 2018 3-4 28 09 129-135 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR013757938</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20220111003622.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2018 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10832-018-0162-x</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR013757938</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10832-018-0162-x-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">620</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">53.09</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Oueslati, A.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2018</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract In the present study, $ NaYP_{2} %$ O_{7} $ compound was prepared by solid-state method and was characterized by powder X-ray diffraction and Raman spectroscopy. The X-ray diffraction of the sample at room temperature showed a monoclinic phase. Electrical conductivity and modulus studies over a wide range of frequencies (40 Hz to 7 MHz) and temperature (400–560 K) were studied using impedance spectroscopic technique. The impedance plane plot shows semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to explain the impedance results. The ac conductivity of the investigated compound obeys the power law: $ σ_{ac} $(ω) = $ σ_{dc} $ + $ Aω^{n} $ where n < 1. The frequency-dependent maxima of the imaginary part of modulus are found to obey Arrhenius law with activation energy 0.64 eV. The activation energy responsible for dielectric relaxation extracted from the modulus spectra is found to be almost the same as the value obtained from the equivalent circuit. These results indicate that the transport is through ion hopping mechanism dominated by the motion of the $ Na^{+} $ ion in the structure of the investigated material.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sodium pyrophosphate</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Impedance</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ionic conductivity</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">CBH model</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Modulus</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gargouri, M.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of electroceramics</subfield><subfield code="d">Dordrecht [u.a.] : Springer Science + Business Media B.V, 1997</subfield><subfield code="g">42(2018), 3-4 vom: 28. 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Oueslati, A. |
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Oueslati, A. ddc 620 bkl 53.09 misc Sodium pyrophosphate misc Impedance misc Ionic conductivity misc CBH model misc Modulus Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound |
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620 ASE 53.09 bkl Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound Sodium pyrophosphate (dpeaa)DE-He213 Impedance (dpeaa)DE-He213 Ionic conductivity (dpeaa)DE-He213 CBH model (dpeaa)DE-He213 Modulus (dpeaa)DE-He213 |
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ddc 620 bkl 53.09 misc Sodium pyrophosphate misc Impedance misc Ionic conductivity misc CBH model misc Modulus |
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Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound |
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Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound |
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impedance spectroscopy and conduction mechanism of $ nayp_{2} %$ o_{7} $ ceramic compound |
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Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound |
| abstract |
Abstract In the present study, $ NaYP_{2} %$ O_{7} $ compound was prepared by solid-state method and was characterized by powder X-ray diffraction and Raman spectroscopy. The X-ray diffraction of the sample at room temperature showed a monoclinic phase. Electrical conductivity and modulus studies over a wide range of frequencies (40 Hz to 7 MHz) and temperature (400–560 K) were studied using impedance spectroscopic technique. The impedance plane plot shows semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to explain the impedance results. The ac conductivity of the investigated compound obeys the power law: $ σ_{ac} $(ω) = $ σ_{dc} $ + $ Aω^{n} $ where n < 1. The frequency-dependent maxima of the imaginary part of modulus are found to obey Arrhenius law with activation energy 0.64 eV. The activation energy responsible for dielectric relaxation extracted from the modulus spectra is found to be almost the same as the value obtained from the equivalent circuit. These results indicate that the transport is through ion hopping mechanism dominated by the motion of the $ Na^{+} $ ion in the structure of the investigated material. |
| abstractGer |
Abstract In the present study, $ NaYP_{2} %$ O_{7} $ compound was prepared by solid-state method and was characterized by powder X-ray diffraction and Raman spectroscopy. The X-ray diffraction of the sample at room temperature showed a monoclinic phase. Electrical conductivity and modulus studies over a wide range of frequencies (40 Hz to 7 MHz) and temperature (400–560 K) were studied using impedance spectroscopic technique. The impedance plane plot shows semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to explain the impedance results. The ac conductivity of the investigated compound obeys the power law: $ σ_{ac} $(ω) = $ σ_{dc} $ + $ Aω^{n} $ where n < 1. The frequency-dependent maxima of the imaginary part of modulus are found to obey Arrhenius law with activation energy 0.64 eV. The activation energy responsible for dielectric relaxation extracted from the modulus spectra is found to be almost the same as the value obtained from the equivalent circuit. These results indicate that the transport is through ion hopping mechanism dominated by the motion of the $ Na^{+} $ ion in the structure of the investigated material. |
| abstract_unstemmed |
Abstract In the present study, $ NaYP_{2} %$ O_{7} $ compound was prepared by solid-state method and was characterized by powder X-ray diffraction and Raman spectroscopy. The X-ray diffraction of the sample at room temperature showed a monoclinic phase. Electrical conductivity and modulus studies over a wide range of frequencies (40 Hz to 7 MHz) and temperature (400–560 K) were studied using impedance spectroscopic technique. The impedance plane plot shows semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to explain the impedance results. The ac conductivity of the investigated compound obeys the power law: $ σ_{ac} $(ω) = $ σ_{dc} $ + $ Aω^{n} $ where n < 1. The frequency-dependent maxima of the imaginary part of modulus are found to obey Arrhenius law with activation energy 0.64 eV. The activation energy responsible for dielectric relaxation extracted from the modulus spectra is found to be almost the same as the value obtained from the equivalent circuit. These results indicate that the transport is through ion hopping mechanism dominated by the motion of the $ Na^{+} $ ion in the structure of the investigated material. |
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3-4 |
| title_short |
Impedance spectroscopy and conduction mechanism of $ NaYP_{2} %$ O_{7} $ ceramic compound |
| url |
https://dx.doi.org/10.1007/s10832-018-0162-x |
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true |
| author2 |
Gargouri, M. |
| author2Str |
Gargouri, M. |
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| doi_str |
10.1007/s10832-018-0162-x |
| up_date |
2024-07-03T21:58:13.664Z |
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| score |
7.4001455 |