Investigations on surface composition and microstructure of sintered barium titanate
Abstract The paper describes studies on surface atomic composition, microstructure and microarea elemental distribution in sintered undoped as well as donor or acceptor doped polycrystalline barium titanate ceramics. The specimens examined are derived from barium titanate powders synthesized by two...
Ausführliche Beschreibung
Autor*in: |
Kumar, Sanjiv [verfasserIn] Raju, V. S. [verfasserIn] Kutty, T. R. N. [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2007 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966, 42(2007), 11 vom: 01. Juni, Seite 3977-3984 |
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Übergeordnetes Werk: |
volume:42 ; year:2007 ; number:11 ; day:01 ; month:06 ; pages:3977-3984 |
Links: |
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DOI / URN: |
10.1007/s10853-006-1404-x |
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Katalog-ID: |
SPR013817310 |
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520 | |a Abstract The paper describes studies on surface atomic composition, microstructure and microarea elemental distribution in sintered undoped as well as donor or acceptor doped polycrystalline barium titanate ceramics. The specimens examined are derived from barium titanate powders synthesized by two different wet chemical procedures namely oxalate precursor route and gel-to-crystallite conversion. The compositional analysis is carried out by backscattering spectrometry (BS) involving 3.05 MeV 16O(α,α)16O resonant scattering while investigations on microstructure and microarea elemental distribution are performed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), respectively. The specimens prepared by either method are monophasic; however, their surface atomic composition, microstructural features as well as electrical characteristics are significantly different. The specimens obtained by oxalate precursor route generally have Ti rich surfaces and exhibit coarse to fine grained microstructure depending on the nature and extent of doping. The Mn-doped specimens exhibit appreciable O deficiency. The specimens prepared by gel to crystallite conversion, in contrast, usually have Ba enriched surfaces and exhibit fine-grained microstructure. EDS measurements show the segregation of acceptors such as Mn, Cu and Zn in the grain boundaries of oxalate precursor derived ceramics. Further, the relative atomic ratio of Ti to Ba at the sites of segregations is higher compared to other locations. | ||
650 | 4 | |a Barium Titanate |7 (dpeaa)DE-He213 | |
650 | 4 | |a Rutherford Backscattering Spectrometry |7 (dpeaa)DE-He213 | |
650 | 4 | |a Resonant Scattering |7 (dpeaa)DE-He213 | |
650 | 4 | |a Barium Titanate Ceramic |7 (dpeaa)DE-He213 | |
650 | 4 | |a Barium Titanate Powder |7 (dpeaa)DE-He213 | |
700 | 1 | |a Raju, V. S. |e verfasserin |4 aut | |
700 | 1 | |a Kutty, T. R. N. |e verfasserin |4 aut | |
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10.1007/s10853-006-1404-x doi (DE-627)SPR013817310 (SPR)s10853-006-1404-x-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Kumar, Sanjiv verfasserin aut Investigations on surface composition and microstructure of sintered barium titanate 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The paper describes studies on surface atomic composition, microstructure and microarea elemental distribution in sintered undoped as well as donor or acceptor doped polycrystalline barium titanate ceramics. The specimens examined are derived from barium titanate powders synthesized by two different wet chemical procedures namely oxalate precursor route and gel-to-crystallite conversion. The compositional analysis is carried out by backscattering spectrometry (BS) involving 3.05 MeV 16O(α,α)16O resonant scattering while investigations on microstructure and microarea elemental distribution are performed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), respectively. The specimens prepared by either method are monophasic; however, their surface atomic composition, microstructural features as well as electrical characteristics are significantly different. The specimens obtained by oxalate precursor route generally have Ti rich surfaces and exhibit coarse to fine grained microstructure depending on the nature and extent of doping. The Mn-doped specimens exhibit appreciable O deficiency. The specimens prepared by gel to crystallite conversion, in contrast, usually have Ba enriched surfaces and exhibit fine-grained microstructure. EDS measurements show the segregation of acceptors such as Mn, Cu and Zn in the grain boundaries of oxalate precursor derived ceramics. Further, the relative atomic ratio of Ti to Ba at the sites of segregations is higher compared to other locations. Barium Titanate (dpeaa)DE-He213 Rutherford Backscattering Spectrometry (dpeaa)DE-He213 Resonant Scattering (dpeaa)DE-He213 Barium Titanate Ceramic (dpeaa)DE-He213 Barium Titanate Powder (dpeaa)DE-He213 Raju, V. S. verfasserin aut Kutty, T. R. N. verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 42(2007), 11 vom: 01. Juni, Seite 3977-3984 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:42 year:2007 number:11 day:01 month:06 pages:3977-3984 https://dx.doi.org/10.1007/s10853-006-1404-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 42 2007 11 01 06 3977-3984 |
spelling |
10.1007/s10853-006-1404-x doi (DE-627)SPR013817310 (SPR)s10853-006-1404-x-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Kumar, Sanjiv verfasserin aut Investigations on surface composition and microstructure of sintered barium titanate 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The paper describes studies on surface atomic composition, microstructure and microarea elemental distribution in sintered undoped as well as donor or acceptor doped polycrystalline barium titanate ceramics. The specimens examined are derived from barium titanate powders synthesized by two different wet chemical procedures namely oxalate precursor route and gel-to-crystallite conversion. The compositional analysis is carried out by backscattering spectrometry (BS) involving 3.05 MeV 16O(α,α)16O resonant scattering while investigations on microstructure and microarea elemental distribution are performed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), respectively. The specimens prepared by either method are monophasic; however, their surface atomic composition, microstructural features as well as electrical characteristics are significantly different. The specimens obtained by oxalate precursor route generally have Ti rich surfaces and exhibit coarse to fine grained microstructure depending on the nature and extent of doping. The Mn-doped specimens exhibit appreciable O deficiency. The specimens prepared by gel to crystallite conversion, in contrast, usually have Ba enriched surfaces and exhibit fine-grained microstructure. EDS measurements show the segregation of acceptors such as Mn, Cu and Zn in the grain boundaries of oxalate precursor derived ceramics. Further, the relative atomic ratio of Ti to Ba at the sites of segregations is higher compared to other locations. Barium Titanate (dpeaa)DE-He213 Rutherford Backscattering Spectrometry (dpeaa)DE-He213 Resonant Scattering (dpeaa)DE-He213 Barium Titanate Ceramic (dpeaa)DE-He213 Barium Titanate Powder (dpeaa)DE-He213 Raju, V. S. verfasserin aut Kutty, T. R. N. verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 42(2007), 11 vom: 01. Juni, Seite 3977-3984 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:42 year:2007 number:11 day:01 month:06 pages:3977-3984 https://dx.doi.org/10.1007/s10853-006-1404-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 42 2007 11 01 06 3977-3984 |
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10.1007/s10853-006-1404-x doi (DE-627)SPR013817310 (SPR)s10853-006-1404-x-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Kumar, Sanjiv verfasserin aut Investigations on surface composition and microstructure of sintered barium titanate 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The paper describes studies on surface atomic composition, microstructure and microarea elemental distribution in sintered undoped as well as donor or acceptor doped polycrystalline barium titanate ceramics. The specimens examined are derived from barium titanate powders synthesized by two different wet chemical procedures namely oxalate precursor route and gel-to-crystallite conversion. The compositional analysis is carried out by backscattering spectrometry (BS) involving 3.05 MeV 16O(α,α)16O resonant scattering while investigations on microstructure and microarea elemental distribution are performed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), respectively. The specimens prepared by either method are monophasic; however, their surface atomic composition, microstructural features as well as electrical characteristics are significantly different. The specimens obtained by oxalate precursor route generally have Ti rich surfaces and exhibit coarse to fine grained microstructure depending on the nature and extent of doping. The Mn-doped specimens exhibit appreciable O deficiency. The specimens prepared by gel to crystallite conversion, in contrast, usually have Ba enriched surfaces and exhibit fine-grained microstructure. EDS measurements show the segregation of acceptors such as Mn, Cu and Zn in the grain boundaries of oxalate precursor derived ceramics. Further, the relative atomic ratio of Ti to Ba at the sites of segregations is higher compared to other locations. Barium Titanate (dpeaa)DE-He213 Rutherford Backscattering Spectrometry (dpeaa)DE-He213 Resonant Scattering (dpeaa)DE-He213 Barium Titanate Ceramic (dpeaa)DE-He213 Barium Titanate Powder (dpeaa)DE-He213 Raju, V. S. verfasserin aut Kutty, T. R. N. verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 42(2007), 11 vom: 01. Juni, Seite 3977-3984 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:42 year:2007 number:11 day:01 month:06 pages:3977-3984 https://dx.doi.org/10.1007/s10853-006-1404-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 42 2007 11 01 06 3977-3984 |
allfieldsGer |
10.1007/s10853-006-1404-x doi (DE-627)SPR013817310 (SPR)s10853-006-1404-x-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Kumar, Sanjiv verfasserin aut Investigations on surface composition and microstructure of sintered barium titanate 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The paper describes studies on surface atomic composition, microstructure and microarea elemental distribution in sintered undoped as well as donor or acceptor doped polycrystalline barium titanate ceramics. The specimens examined are derived from barium titanate powders synthesized by two different wet chemical procedures namely oxalate precursor route and gel-to-crystallite conversion. The compositional analysis is carried out by backscattering spectrometry (BS) involving 3.05 MeV 16O(α,α)16O resonant scattering while investigations on microstructure and microarea elemental distribution are performed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), respectively. The specimens prepared by either method are monophasic; however, their surface atomic composition, microstructural features as well as electrical characteristics are significantly different. The specimens obtained by oxalate precursor route generally have Ti rich surfaces and exhibit coarse to fine grained microstructure depending on the nature and extent of doping. The Mn-doped specimens exhibit appreciable O deficiency. The specimens prepared by gel to crystallite conversion, in contrast, usually have Ba enriched surfaces and exhibit fine-grained microstructure. EDS measurements show the segregation of acceptors such as Mn, Cu and Zn in the grain boundaries of oxalate precursor derived ceramics. Further, the relative atomic ratio of Ti to Ba at the sites of segregations is higher compared to other locations. Barium Titanate (dpeaa)DE-He213 Rutherford Backscattering Spectrometry (dpeaa)DE-He213 Resonant Scattering (dpeaa)DE-He213 Barium Titanate Ceramic (dpeaa)DE-He213 Barium Titanate Powder (dpeaa)DE-He213 Raju, V. S. verfasserin aut Kutty, T. R. N. verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 42(2007), 11 vom: 01. Juni, Seite 3977-3984 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:42 year:2007 number:11 day:01 month:06 pages:3977-3984 https://dx.doi.org/10.1007/s10853-006-1404-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 42 2007 11 01 06 3977-3984 |
allfieldsSound |
10.1007/s10853-006-1404-x doi (DE-627)SPR013817310 (SPR)s10853-006-1404-x-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Kumar, Sanjiv verfasserin aut Investigations on surface composition and microstructure of sintered barium titanate 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The paper describes studies on surface atomic composition, microstructure and microarea elemental distribution in sintered undoped as well as donor or acceptor doped polycrystalline barium titanate ceramics. The specimens examined are derived from barium titanate powders synthesized by two different wet chemical procedures namely oxalate precursor route and gel-to-crystallite conversion. The compositional analysis is carried out by backscattering spectrometry (BS) involving 3.05 MeV 16O(α,α)16O resonant scattering while investigations on microstructure and microarea elemental distribution are performed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), respectively. The specimens prepared by either method are monophasic; however, their surface atomic composition, microstructural features as well as electrical characteristics are significantly different. The specimens obtained by oxalate precursor route generally have Ti rich surfaces and exhibit coarse to fine grained microstructure depending on the nature and extent of doping. The Mn-doped specimens exhibit appreciable O deficiency. The specimens prepared by gel to crystallite conversion, in contrast, usually have Ba enriched surfaces and exhibit fine-grained microstructure. EDS measurements show the segregation of acceptors such as Mn, Cu and Zn in the grain boundaries of oxalate precursor derived ceramics. Further, the relative atomic ratio of Ti to Ba at the sites of segregations is higher compared to other locations. Barium Titanate (dpeaa)DE-He213 Rutherford Backscattering Spectrometry (dpeaa)DE-He213 Resonant Scattering (dpeaa)DE-He213 Barium Titanate Ceramic (dpeaa)DE-He213 Barium Titanate Powder (dpeaa)DE-He213 Raju, V. S. verfasserin aut Kutty, T. R. N. verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 42(2007), 11 vom: 01. Juni, Seite 3977-3984 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:42 year:2007 number:11 day:01 month:06 pages:3977-3984 https://dx.doi.org/10.1007/s10853-006-1404-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 42 2007 11 01 06 3977-3984 |
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Kumar, Sanjiv @@aut@@ Raju, V. S. @@aut@@ Kutty, T. R. N. @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR013817310</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20220111003824.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2007 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10853-006-1404-x</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR013817310</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10853-006-1404-x-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Kumar, Sanjiv</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Investigations on surface composition and microstructure of sintered barium titanate</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2007</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The paper describes studies on surface atomic composition, microstructure and microarea elemental distribution in sintered undoped as well as donor or acceptor doped polycrystalline barium titanate ceramics. The specimens examined are derived from barium titanate powders synthesized by two different wet chemical procedures namely oxalate precursor route and gel-to-crystallite conversion. The compositional analysis is carried out by backscattering spectrometry (BS) involving 3.05 MeV 16O(α,α)16O resonant scattering while investigations on microstructure and microarea elemental distribution are performed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), respectively. The specimens prepared by either method are monophasic; however, their surface atomic composition, microstructural features as well as electrical characteristics are significantly different. The specimens obtained by oxalate precursor route generally have Ti rich surfaces and exhibit coarse to fine grained microstructure depending on the nature and extent of doping. The Mn-doped specimens exhibit appreciable O deficiency. The specimens prepared by gel to crystallite conversion, in contrast, usually have Ba enriched surfaces and exhibit fine-grained microstructure. EDS measurements show the segregation of acceptors such as Mn, Cu and Zn in the grain boundaries of oxalate precursor derived ceramics. Further, the relative atomic ratio of Ti to Ba at the sites of segregations is higher compared to other locations.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Barium Titanate</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Rutherford Backscattering Spectrometry</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Resonant Scattering</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Barium Titanate Ceramic</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Barium Titanate Powder</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Raju, V. 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Kumar, Sanjiv |
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Kumar, Sanjiv ddc 670 bkl 51.00 misc Barium Titanate misc Rutherford Backscattering Spectrometry misc Resonant Scattering misc Barium Titanate Ceramic misc Barium Titanate Powder Investigations on surface composition and microstructure of sintered barium titanate |
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670 ASE 51.00 bkl Investigations on surface composition and microstructure of sintered barium titanate Barium Titanate (dpeaa)DE-He213 Rutherford Backscattering Spectrometry (dpeaa)DE-He213 Resonant Scattering (dpeaa)DE-He213 Barium Titanate Ceramic (dpeaa)DE-He213 Barium Titanate Powder (dpeaa)DE-He213 |
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ddc 670 bkl 51.00 misc Barium Titanate misc Rutherford Backscattering Spectrometry misc Resonant Scattering misc Barium Titanate Ceramic misc Barium Titanate Powder |
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ddc 670 bkl 51.00 misc Barium Titanate misc Rutherford Backscattering Spectrometry misc Resonant Scattering misc Barium Titanate Ceramic misc Barium Titanate Powder |
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Investigations on surface composition and microstructure of sintered barium titanate |
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Kumar, Sanjiv Raju, V. S. Kutty, T. R. N. |
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investigations on surface composition and microstructure of sintered barium titanate |
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Investigations on surface composition and microstructure of sintered barium titanate |
abstract |
Abstract The paper describes studies on surface atomic composition, microstructure and microarea elemental distribution in sintered undoped as well as donor or acceptor doped polycrystalline barium titanate ceramics. The specimens examined are derived from barium titanate powders synthesized by two different wet chemical procedures namely oxalate precursor route and gel-to-crystallite conversion. The compositional analysis is carried out by backscattering spectrometry (BS) involving 3.05 MeV 16O(α,α)16O resonant scattering while investigations on microstructure and microarea elemental distribution are performed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), respectively. The specimens prepared by either method are monophasic; however, their surface atomic composition, microstructural features as well as electrical characteristics are significantly different. The specimens obtained by oxalate precursor route generally have Ti rich surfaces and exhibit coarse to fine grained microstructure depending on the nature and extent of doping. The Mn-doped specimens exhibit appreciable O deficiency. The specimens prepared by gel to crystallite conversion, in contrast, usually have Ba enriched surfaces and exhibit fine-grained microstructure. EDS measurements show the segregation of acceptors such as Mn, Cu and Zn in the grain boundaries of oxalate precursor derived ceramics. Further, the relative atomic ratio of Ti to Ba at the sites of segregations is higher compared to other locations. |
abstractGer |
Abstract The paper describes studies on surface atomic composition, microstructure and microarea elemental distribution in sintered undoped as well as donor or acceptor doped polycrystalline barium titanate ceramics. The specimens examined are derived from barium titanate powders synthesized by two different wet chemical procedures namely oxalate precursor route and gel-to-crystallite conversion. The compositional analysis is carried out by backscattering spectrometry (BS) involving 3.05 MeV 16O(α,α)16O resonant scattering while investigations on microstructure and microarea elemental distribution are performed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), respectively. The specimens prepared by either method are monophasic; however, their surface atomic composition, microstructural features as well as electrical characteristics are significantly different. The specimens obtained by oxalate precursor route generally have Ti rich surfaces and exhibit coarse to fine grained microstructure depending on the nature and extent of doping. The Mn-doped specimens exhibit appreciable O deficiency. The specimens prepared by gel to crystallite conversion, in contrast, usually have Ba enriched surfaces and exhibit fine-grained microstructure. EDS measurements show the segregation of acceptors such as Mn, Cu and Zn in the grain boundaries of oxalate precursor derived ceramics. Further, the relative atomic ratio of Ti to Ba at the sites of segregations is higher compared to other locations. |
abstract_unstemmed |
Abstract The paper describes studies on surface atomic composition, microstructure and microarea elemental distribution in sintered undoped as well as donor or acceptor doped polycrystalline barium titanate ceramics. The specimens examined are derived from barium titanate powders synthesized by two different wet chemical procedures namely oxalate precursor route and gel-to-crystallite conversion. The compositional analysis is carried out by backscattering spectrometry (BS) involving 3.05 MeV 16O(α,α)16O resonant scattering while investigations on microstructure and microarea elemental distribution are performed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), respectively. The specimens prepared by either method are monophasic; however, their surface atomic composition, microstructural features as well as electrical characteristics are significantly different. The specimens obtained by oxalate precursor route generally have Ti rich surfaces and exhibit coarse to fine grained microstructure depending on the nature and extent of doping. The Mn-doped specimens exhibit appreciable O deficiency. The specimens prepared by gel to crystallite conversion, in contrast, usually have Ba enriched surfaces and exhibit fine-grained microstructure. EDS measurements show the segregation of acceptors such as Mn, Cu and Zn in the grain boundaries of oxalate precursor derived ceramics. Further, the relative atomic ratio of Ti to Ba at the sites of segregations is higher compared to other locations. |
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container_issue |
11 |
title_short |
Investigations on surface composition and microstructure of sintered barium titanate |
url |
https://dx.doi.org/10.1007/s10853-006-1404-x |
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author2 |
Raju, V. S. Kutty, T. R. N. |
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Raju, V. S. Kutty, T. R. N. |
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doi_str |
10.1007/s10853-006-1404-x |
up_date |
2024-07-03T22:20:34.646Z |
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score |
7.3998976 |