Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction
Abstract Understanding the macroscopic physical and mechanical properties of poly(p-phenylene terephthalamide) (PpTA) fibres as a function of temperature requires an understanding of how temperature influences its microscopic structure. This study investigates lattice distortions in single PpTA fibr...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Davies, R. J. [verfasserIn] Burghammer, M. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966, 44(2009), 18 vom: 25. Juli, Seite 4806-4813 |
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| Übergeordnetes Werk: |
volume:44 ; year:2009 ; number:18 ; day:25 ; month:07 ; pages:4806-4813 |
| Links: |
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| DOI / URN: |
10.1007/s10853-009-3732-0 |
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| Katalog-ID: |
SPR013845713 |
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| 245 | 1 | 0 | |a Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction |
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| 520 | |a Abstract Understanding the macroscopic physical and mechanical properties of poly(p-phenylene terephthalamide) (PpTA) fibres as a function of temperature requires an understanding of how temperature influences its microscopic structure. This study investigates lattice distortions in single PpTA fibres using the high brilliance of a synchrotron radiation microbeam. Lattice distortions are studied over a temperature range of 110–350 K and the influence of tensile deformation is also considered. The results reveal linear thermal expansion behaviour for all unit cell axes, in general agreement with literature. Expansion/contraction is greatest along the [100] direction whilst being reduced along [010] by inter-chain hydrogen bonding. During macroscopic deformation, longitudinal crystal strain dominates with respect to axial lattice distortions induced by temperature changes. There is only a small change in the [100] coefficient of thermal expansion, with the [010] and [001] directions being largely unaffected. | ||
| 650 | 4 | |a Thermal Expansion Coefficient |7 (dpeaa)DE-He213 | |
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| 650 | 4 | |a Lattice Modulus |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Crystal Strain |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Lattice Parameter Variation |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Burghammer, M. |e verfasserin |4 aut | |
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10.1007/s10853-009-3732-0 doi (DE-627)SPR013845713 (SPR)s10853-009-3732-0-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Davies, R. J. verfasserin aut Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Understanding the macroscopic physical and mechanical properties of poly(p-phenylene terephthalamide) (PpTA) fibres as a function of temperature requires an understanding of how temperature influences its microscopic structure. This study investigates lattice distortions in single PpTA fibres using the high brilliance of a synchrotron radiation microbeam. Lattice distortions are studied over a temperature range of 110–350 K and the influence of tensile deformation is also considered. The results reveal linear thermal expansion behaviour for all unit cell axes, in general agreement with literature. Expansion/contraction is greatest along the [100] direction whilst being reduced along [010] by inter-chain hydrogen bonding. During macroscopic deformation, longitudinal crystal strain dominates with respect to axial lattice distortions induced by temperature changes. There is only a small change in the [100] coefficient of thermal expansion, with the [010] and [001] directions being largely unaffected. Thermal Expansion Coefficient (dpeaa)DE-He213 Lattice Distortion (dpeaa)DE-He213 Lattice Modulus (dpeaa)DE-He213 Crystal Strain (dpeaa)DE-He213 Lattice Parameter Variation (dpeaa)DE-He213 Burghammer, M. verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 44(2009), 18 vom: 25. Juli, Seite 4806-4813 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:44 year:2009 number:18 day:25 month:07 pages:4806-4813 https://dx.doi.org/10.1007/s10853-009-3732-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 44 2009 18 25 07 4806-4813 |
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10.1007/s10853-009-3732-0 doi (DE-627)SPR013845713 (SPR)s10853-009-3732-0-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Davies, R. J. verfasserin aut Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Understanding the macroscopic physical and mechanical properties of poly(p-phenylene terephthalamide) (PpTA) fibres as a function of temperature requires an understanding of how temperature influences its microscopic structure. This study investigates lattice distortions in single PpTA fibres using the high brilliance of a synchrotron radiation microbeam. Lattice distortions are studied over a temperature range of 110–350 K and the influence of tensile deformation is also considered. The results reveal linear thermal expansion behaviour for all unit cell axes, in general agreement with literature. Expansion/contraction is greatest along the [100] direction whilst being reduced along [010] by inter-chain hydrogen bonding. During macroscopic deformation, longitudinal crystal strain dominates with respect to axial lattice distortions induced by temperature changes. There is only a small change in the [100] coefficient of thermal expansion, with the [010] and [001] directions being largely unaffected. Thermal Expansion Coefficient (dpeaa)DE-He213 Lattice Distortion (dpeaa)DE-He213 Lattice Modulus (dpeaa)DE-He213 Crystal Strain (dpeaa)DE-He213 Lattice Parameter Variation (dpeaa)DE-He213 Burghammer, M. verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 44(2009), 18 vom: 25. Juli, Seite 4806-4813 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:44 year:2009 number:18 day:25 month:07 pages:4806-4813 https://dx.doi.org/10.1007/s10853-009-3732-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 44 2009 18 25 07 4806-4813 |
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10.1007/s10853-009-3732-0 doi (DE-627)SPR013845713 (SPR)s10853-009-3732-0-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Davies, R. J. verfasserin aut Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Understanding the macroscopic physical and mechanical properties of poly(p-phenylene terephthalamide) (PpTA) fibres as a function of temperature requires an understanding of how temperature influences its microscopic structure. This study investigates lattice distortions in single PpTA fibres using the high brilliance of a synchrotron radiation microbeam. Lattice distortions are studied over a temperature range of 110–350 K and the influence of tensile deformation is also considered. The results reveal linear thermal expansion behaviour for all unit cell axes, in general agreement with literature. Expansion/contraction is greatest along the [100] direction whilst being reduced along [010] by inter-chain hydrogen bonding. During macroscopic deformation, longitudinal crystal strain dominates with respect to axial lattice distortions induced by temperature changes. There is only a small change in the [100] coefficient of thermal expansion, with the [010] and [001] directions being largely unaffected. Thermal Expansion Coefficient (dpeaa)DE-He213 Lattice Distortion (dpeaa)DE-He213 Lattice Modulus (dpeaa)DE-He213 Crystal Strain (dpeaa)DE-He213 Lattice Parameter Variation (dpeaa)DE-He213 Burghammer, M. verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 44(2009), 18 vom: 25. Juli, Seite 4806-4813 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:44 year:2009 number:18 day:25 month:07 pages:4806-4813 https://dx.doi.org/10.1007/s10853-009-3732-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 44 2009 18 25 07 4806-4813 |
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10.1007/s10853-009-3732-0 doi (DE-627)SPR013845713 (SPR)s10853-009-3732-0-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Davies, R. J. verfasserin aut Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Understanding the macroscopic physical and mechanical properties of poly(p-phenylene terephthalamide) (PpTA) fibres as a function of temperature requires an understanding of how temperature influences its microscopic structure. This study investigates lattice distortions in single PpTA fibres using the high brilliance of a synchrotron radiation microbeam. Lattice distortions are studied over a temperature range of 110–350 K and the influence of tensile deformation is also considered. The results reveal linear thermal expansion behaviour for all unit cell axes, in general agreement with literature. Expansion/contraction is greatest along the [100] direction whilst being reduced along [010] by inter-chain hydrogen bonding. During macroscopic deformation, longitudinal crystal strain dominates with respect to axial lattice distortions induced by temperature changes. There is only a small change in the [100] coefficient of thermal expansion, with the [010] and [001] directions being largely unaffected. Thermal Expansion Coefficient (dpeaa)DE-He213 Lattice Distortion (dpeaa)DE-He213 Lattice Modulus (dpeaa)DE-He213 Crystal Strain (dpeaa)DE-He213 Lattice Parameter Variation (dpeaa)DE-He213 Burghammer, M. verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 44(2009), 18 vom: 25. Juli, Seite 4806-4813 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:44 year:2009 number:18 day:25 month:07 pages:4806-4813 https://dx.doi.org/10.1007/s10853-009-3732-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 44 2009 18 25 07 4806-4813 |
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10.1007/s10853-009-3732-0 doi (DE-627)SPR013845713 (SPR)s10853-009-3732-0-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Davies, R. J. verfasserin aut Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Understanding the macroscopic physical and mechanical properties of poly(p-phenylene terephthalamide) (PpTA) fibres as a function of temperature requires an understanding of how temperature influences its microscopic structure. This study investigates lattice distortions in single PpTA fibres using the high brilliance of a synchrotron radiation microbeam. Lattice distortions are studied over a temperature range of 110–350 K and the influence of tensile deformation is also considered. The results reveal linear thermal expansion behaviour for all unit cell axes, in general agreement with literature. Expansion/contraction is greatest along the [100] direction whilst being reduced along [010] by inter-chain hydrogen bonding. During macroscopic deformation, longitudinal crystal strain dominates with respect to axial lattice distortions induced by temperature changes. There is only a small change in the [100] coefficient of thermal expansion, with the [010] and [001] directions being largely unaffected. Thermal Expansion Coefficient (dpeaa)DE-He213 Lattice Distortion (dpeaa)DE-He213 Lattice Modulus (dpeaa)DE-He213 Crystal Strain (dpeaa)DE-He213 Lattice Parameter Variation (dpeaa)DE-He213 Burghammer, M. verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 44(2009), 18 vom: 25. Juli, Seite 4806-4813 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:44 year:2009 number:18 day:25 month:07 pages:4806-4813 https://dx.doi.org/10.1007/s10853-009-3732-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 44 2009 18 25 07 4806-4813 |
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| author |
Davies, R. J. |
| spellingShingle |
Davies, R. J. ddc 670 bkl 51.00 misc Thermal Expansion Coefficient misc Lattice Distortion misc Lattice Modulus misc Crystal Strain misc Lattice Parameter Variation Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction |
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670 ASE 51.00 bkl Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction Thermal Expansion Coefficient (dpeaa)DE-He213 Lattice Distortion (dpeaa)DE-He213 Lattice Modulus (dpeaa)DE-He213 Crystal Strain (dpeaa)DE-He213 Lattice Parameter Variation (dpeaa)DE-He213 |
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ddc 670 bkl 51.00 misc Thermal Expansion Coefficient misc Lattice Distortion misc Lattice Modulus misc Crystal Strain misc Lattice Parameter Variation |
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ddc 670 bkl 51.00 misc Thermal Expansion Coefficient misc Lattice Distortion misc Lattice Modulus misc Crystal Strain misc Lattice Parameter Variation |
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ddc 670 bkl 51.00 misc Thermal Expansion Coefficient misc Lattice Distortion misc Lattice Modulus misc Crystal Strain misc Lattice Parameter Variation |
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Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction |
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| title_full |
Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction |
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Davies, R. J. |
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Journal of materials science |
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Davies, R. J. Burghammer, M. |
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670 ASE 51.00 bkl |
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Elektronische Aufsätze |
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Davies, R. J. |
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10.1007/s10853-009-3732-0 |
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verfasserin |
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thermal- and stress-induced lattice distortions in a single kevlar49 fibre studied by microfocus x-ray diffraction |
| title_auth |
Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction |
| abstract |
Abstract Understanding the macroscopic physical and mechanical properties of poly(p-phenylene terephthalamide) (PpTA) fibres as a function of temperature requires an understanding of how temperature influences its microscopic structure. This study investigates lattice distortions in single PpTA fibres using the high brilliance of a synchrotron radiation microbeam. Lattice distortions are studied over a temperature range of 110–350 K and the influence of tensile deformation is also considered. The results reveal linear thermal expansion behaviour for all unit cell axes, in general agreement with literature. Expansion/contraction is greatest along the [100] direction whilst being reduced along [010] by inter-chain hydrogen bonding. During macroscopic deformation, longitudinal crystal strain dominates with respect to axial lattice distortions induced by temperature changes. There is only a small change in the [100] coefficient of thermal expansion, with the [010] and [001] directions being largely unaffected. |
| abstractGer |
Abstract Understanding the macroscopic physical and mechanical properties of poly(p-phenylene terephthalamide) (PpTA) fibres as a function of temperature requires an understanding of how temperature influences its microscopic structure. This study investigates lattice distortions in single PpTA fibres using the high brilliance of a synchrotron radiation microbeam. Lattice distortions are studied over a temperature range of 110–350 K and the influence of tensile deformation is also considered. The results reveal linear thermal expansion behaviour for all unit cell axes, in general agreement with literature. Expansion/contraction is greatest along the [100] direction whilst being reduced along [010] by inter-chain hydrogen bonding. During macroscopic deformation, longitudinal crystal strain dominates with respect to axial lattice distortions induced by temperature changes. There is only a small change in the [100] coefficient of thermal expansion, with the [010] and [001] directions being largely unaffected. |
| abstract_unstemmed |
Abstract Understanding the macroscopic physical and mechanical properties of poly(p-phenylene terephthalamide) (PpTA) fibres as a function of temperature requires an understanding of how temperature influences its microscopic structure. This study investigates lattice distortions in single PpTA fibres using the high brilliance of a synchrotron radiation microbeam. Lattice distortions are studied over a temperature range of 110–350 K and the influence of tensile deformation is also considered. The results reveal linear thermal expansion behaviour for all unit cell axes, in general agreement with literature. Expansion/contraction is greatest along the [100] direction whilst being reduced along [010] by inter-chain hydrogen bonding. During macroscopic deformation, longitudinal crystal strain dominates with respect to axial lattice distortions induced by temperature changes. There is only a small change in the [100] coefficient of thermal expansion, with the [010] and [001] directions being largely unaffected. |
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Thermal- and stress-induced lattice distortions in a single Kevlar49 fibre studied by microfocus X-ray diffraction |
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https://dx.doi.org/10.1007/s10853-009-3732-0 |
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Burghammer, M. |
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10.1007/s10853-009-3732-0 |
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2024-07-03T22:31:37.033Z |
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| score |
7.4032135 |