Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer
Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of ex...
Ausführliche Beschreibung
Autor*in: |
Yue, Ruirui [verfasserIn] Xu, Jingkun [verfasserIn] Lu, Baoyang [verfasserIn] Liu, Congcong [verfasserIn] Li, Yuzhen [verfasserIn] Zhu, Zhaojin [verfasserIn] Chen, Shuai [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2009 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966, 44(2009), 21 vom: 02. Sept., Seite 5909-5918 |
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Übergeordnetes Werk: |
volume:44 ; year:2009 ; number:21 ; day:02 ; month:09 ; pages:5909-5918 |
Links: |
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DOI / URN: |
10.1007/s10853-009-3836-6 |
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Katalog-ID: |
SPR013847503 |
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245 | 1 | 0 | |a Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
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520 | |a Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. | ||
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700 | 1 | |a Li, Yuzhen |e verfasserin |4 aut | |
700 | 1 | |a Zhu, Zhaojin |e verfasserin |4 aut | |
700 | 1 | |a Chen, Shuai |e verfasserin |4 aut | |
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10.1007/s10853-009-3836-6 doi (DE-627)SPR013847503 (SPR)s10853-009-3836-6-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Yue, Ruirui verfasserin aut Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. Feed Ratio (dpeaa)DE-He213 Common Organic Solvent (dpeaa)DE-He213 Copolymer Film (dpeaa)DE-He213 Monomer Mixture (dpeaa)DE-He213 Dope State (dpeaa)DE-He213 Xu, Jingkun verfasserin aut Lu, Baoyang verfasserin aut Liu, Congcong verfasserin aut Li, Yuzhen verfasserin aut Zhu, Zhaojin verfasserin aut Chen, Shuai verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 44(2009), 21 vom: 02. Sept., Seite 5909-5918 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 https://dx.doi.org/10.1007/s10853-009-3836-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 44 2009 21 02 09 5909-5918 |
spelling |
10.1007/s10853-009-3836-6 doi (DE-627)SPR013847503 (SPR)s10853-009-3836-6-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Yue, Ruirui verfasserin aut Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. Feed Ratio (dpeaa)DE-He213 Common Organic Solvent (dpeaa)DE-He213 Copolymer Film (dpeaa)DE-He213 Monomer Mixture (dpeaa)DE-He213 Dope State (dpeaa)DE-He213 Xu, Jingkun verfasserin aut Lu, Baoyang verfasserin aut Liu, Congcong verfasserin aut Li, Yuzhen verfasserin aut Zhu, Zhaojin verfasserin aut Chen, Shuai verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 44(2009), 21 vom: 02. Sept., Seite 5909-5918 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 https://dx.doi.org/10.1007/s10853-009-3836-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 44 2009 21 02 09 5909-5918 |
allfields_unstemmed |
10.1007/s10853-009-3836-6 doi (DE-627)SPR013847503 (SPR)s10853-009-3836-6-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Yue, Ruirui verfasserin aut Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. Feed Ratio (dpeaa)DE-He213 Common Organic Solvent (dpeaa)DE-He213 Copolymer Film (dpeaa)DE-He213 Monomer Mixture (dpeaa)DE-He213 Dope State (dpeaa)DE-He213 Xu, Jingkun verfasserin aut Lu, Baoyang verfasserin aut Liu, Congcong verfasserin aut Li, Yuzhen verfasserin aut Zhu, Zhaojin verfasserin aut Chen, Shuai verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 44(2009), 21 vom: 02. Sept., Seite 5909-5918 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 https://dx.doi.org/10.1007/s10853-009-3836-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 44 2009 21 02 09 5909-5918 |
allfieldsGer |
10.1007/s10853-009-3836-6 doi (DE-627)SPR013847503 (SPR)s10853-009-3836-6-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Yue, Ruirui verfasserin aut Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. Feed Ratio (dpeaa)DE-He213 Common Organic Solvent (dpeaa)DE-He213 Copolymer Film (dpeaa)DE-He213 Monomer Mixture (dpeaa)DE-He213 Dope State (dpeaa)DE-He213 Xu, Jingkun verfasserin aut Lu, Baoyang verfasserin aut Liu, Congcong verfasserin aut Li, Yuzhen verfasserin aut Zhu, Zhaojin verfasserin aut Chen, Shuai verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 44(2009), 21 vom: 02. Sept., Seite 5909-5918 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 https://dx.doi.org/10.1007/s10853-009-3836-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 44 2009 21 02 09 5909-5918 |
allfieldsSound |
10.1007/s10853-009-3836-6 doi (DE-627)SPR013847503 (SPR)s10853-009-3836-6-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Yue, Ruirui verfasserin aut Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. Feed Ratio (dpeaa)DE-He213 Common Organic Solvent (dpeaa)DE-He213 Copolymer Film (dpeaa)DE-He213 Monomer Mixture (dpeaa)DE-He213 Dope State (dpeaa)DE-He213 Xu, Jingkun verfasserin aut Lu, Baoyang verfasserin aut Liu, Congcong verfasserin aut Li, Yuzhen verfasserin aut Zhu, Zhaojin verfasserin aut Chen, Shuai verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 44(2009), 21 vom: 02. Sept., Seite 5909-5918 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 https://dx.doi.org/10.1007/s10853-009-3836-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 44 2009 21 02 09 5909-5918 |
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Enthalten in Journal of materials science 44(2009), 21 vom: 02. Sept., Seite 5909-5918 volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 |
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Enthalten in Journal of materials science 44(2009), 21 vom: 02. Sept., Seite 5909-5918 volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 |
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Yue, Ruirui @@aut@@ Xu, Jingkun @@aut@@ Lu, Baoyang @@aut@@ Liu, Congcong @@aut@@ Li, Yuzhen @@aut@@ Zhu, Zhaojin @@aut@@ Chen, Shuai @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR013847503</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20220111003921.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2009 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10853-009-3836-6</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR013847503</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10853-009-3836-6-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Yue, Ruirui</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2009</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. 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|
author |
Yue, Ruirui |
spellingShingle |
Yue, Ruirui ddc 670 bkl 51.00 misc Feed Ratio misc Common Organic Solvent misc Copolymer Film misc Monomer Mixture misc Dope State Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
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670 ASE 51.00 bkl Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer Feed Ratio (dpeaa)DE-He213 Common Organic Solvent (dpeaa)DE-He213 Copolymer Film (dpeaa)DE-He213 Monomer Mixture (dpeaa)DE-He213 Dope State (dpeaa)DE-He213 |
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ddc 670 bkl 51.00 misc Feed Ratio misc Common Organic Solvent misc Copolymer Film misc Monomer Mixture misc Dope State |
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Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
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Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
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Yue, Ruirui |
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Journal of materials science |
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Yue, Ruirui Xu, Jingkun Lu, Baoyang Liu, Congcong Li, Yuzhen Zhu, Zhaojin Chen, Shuai |
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670 ASE 51.00 bkl |
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Yue, Ruirui |
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verfasserin |
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electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
title_auth |
Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
abstract |
Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. |
abstractGer |
Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. |
abstract_unstemmed |
Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. |
collection_details |
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container_issue |
21 |
title_short |
Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
url |
https://dx.doi.org/10.1007/s10853-009-3836-6 |
remote_bool |
true |
author2 |
Xu, Jingkun Lu, Baoyang Liu, Congcong Li, Yuzhen Zhu, Zhaojin Chen, Shuai |
author2Str |
Xu, Jingkun Lu, Baoyang Liu, Congcong Li, Yuzhen Zhu, Zhaojin Chen, Shuai |
ppnlink |
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isOA_txt |
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hochschulschrift_bool |
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doi_str |
10.1007/s10853-009-3836-6 |
up_date |
2024-07-03T22:32:18.436Z |
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|
score |
7.399932 |