Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments
Abstract The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and inc...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Biemond, G. J. E. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2010 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s) 2009 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966, 45(2010), 1 vom: 01. Jan., Seite 158-167 |
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| Übergeordnetes Werk: |
volume:45 ; year:2010 ; number:1 ; day:01 ; month:01 ; pages:158-167 |
| Links: |
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| DOI / URN: |
10.1007/s10853-009-3911-z |
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SPR013850997 |
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| 100 | 1 | |a Biemond, G. J. E. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments |
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| 520 | |a Abstract The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values. | ||
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| 700 | 1 | |a Gaymans, Reinoud J. |4 aut | |
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10.1007/s10853-009-3911-z doi (DE-627)SPR013850997 (SPR)s10853-009-3911-z-e DE-627 ger DE-627 rakwb eng Biemond, G. J. E. verfasserin aut Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2009 Abstract The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values. Stress Relaxation (dpeaa)DE-He213 Applied Strain (dpeaa)DE-He213 Hard Segment (dpeaa)DE-He213 Yield Strain (dpeaa)DE-He213 Thermoplastic Elastomer (dpeaa)DE-He213 Gaymans, Reinoud J. aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 45(2010), 1 vom: 01. Jan., Seite 158-167 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:45 year:2010 number:1 day:01 month:01 pages:158-167 https://dx.doi.org/10.1007/s10853-009-3911-z kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 45 2010 1 01 01 158-167 |
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10.1007/s10853-009-3911-z doi (DE-627)SPR013850997 (SPR)s10853-009-3911-z-e DE-627 ger DE-627 rakwb eng Biemond, G. J. E. verfasserin aut Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2009 Abstract The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values. Stress Relaxation (dpeaa)DE-He213 Applied Strain (dpeaa)DE-He213 Hard Segment (dpeaa)DE-He213 Yield Strain (dpeaa)DE-He213 Thermoplastic Elastomer (dpeaa)DE-He213 Gaymans, Reinoud J. aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 45(2010), 1 vom: 01. Jan., Seite 158-167 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:45 year:2010 number:1 day:01 month:01 pages:158-167 https://dx.doi.org/10.1007/s10853-009-3911-z kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 45 2010 1 01 01 158-167 |
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10.1007/s10853-009-3911-z doi (DE-627)SPR013850997 (SPR)s10853-009-3911-z-e DE-627 ger DE-627 rakwb eng Biemond, G. J. E. verfasserin aut Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2009 Abstract The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values. Stress Relaxation (dpeaa)DE-He213 Applied Strain (dpeaa)DE-He213 Hard Segment (dpeaa)DE-He213 Yield Strain (dpeaa)DE-He213 Thermoplastic Elastomer (dpeaa)DE-He213 Gaymans, Reinoud J. aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 45(2010), 1 vom: 01. Jan., Seite 158-167 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:45 year:2010 number:1 day:01 month:01 pages:158-167 https://dx.doi.org/10.1007/s10853-009-3911-z kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 45 2010 1 01 01 158-167 |
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10.1007/s10853-009-3911-z doi (DE-627)SPR013850997 (SPR)s10853-009-3911-z-e DE-627 ger DE-627 rakwb eng Biemond, G. J. E. verfasserin aut Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2009 Abstract The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values. Stress Relaxation (dpeaa)DE-He213 Applied Strain (dpeaa)DE-He213 Hard Segment (dpeaa)DE-He213 Yield Strain (dpeaa)DE-He213 Thermoplastic Elastomer (dpeaa)DE-He213 Gaymans, Reinoud J. aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 45(2010), 1 vom: 01. Jan., Seite 158-167 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:45 year:2010 number:1 day:01 month:01 pages:158-167 https://dx.doi.org/10.1007/s10853-009-3911-z kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 45 2010 1 01 01 158-167 |
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10.1007/s10853-009-3911-z doi (DE-627)SPR013850997 (SPR)s10853-009-3911-z-e DE-627 ger DE-627 rakwb eng Biemond, G. J. E. verfasserin aut Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2009 Abstract The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values. Stress Relaxation (dpeaa)DE-He213 Applied Strain (dpeaa)DE-He213 Hard Segment (dpeaa)DE-He213 Yield Strain (dpeaa)DE-He213 Thermoplastic Elastomer (dpeaa)DE-He213 Gaymans, Reinoud J. aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 45(2010), 1 vom: 01. Jan., Seite 158-167 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:45 year:2010 number:1 day:01 month:01 pages:158-167 https://dx.doi.org/10.1007/s10853-009-3911-z kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 45 2010 1 01 01 158-167 |
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Biemond, G. J. E. |
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Biemond, G. J. E. misc Stress Relaxation misc Applied Strain misc Hard Segment misc Yield Strain misc Thermoplastic Elastomer Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments |
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Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments Stress Relaxation (dpeaa)DE-He213 Applied Strain (dpeaa)DE-He213 Hard Segment (dpeaa)DE-He213 Yield Strain (dpeaa)DE-He213 Thermoplastic Elastomer (dpeaa)DE-He213 |
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Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments |
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Biemond, G. J. E. |
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Biemond, G. J. E. Gaymans, Reinoud J. |
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Biemond, G. J. E. |
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elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments |
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Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments |
| abstract |
Abstract The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values. © The Author(s) 2009 |
| abstractGer |
Abstract The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values. © The Author(s) 2009 |
| abstract_unstemmed |
Abstract The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values. © The Author(s) 2009 |
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Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments |
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https://dx.doi.org/10.1007/s10853-009-3911-z |
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Gaymans, Reinoud J. |
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10.1007/s10853-009-3911-z |
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| score |
7.398197 |