Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics
Abstract There have been increasing needs for high-thermal stability and high-electrical conductivity materials. In this study, we in situ synthesized silicon oxycarbide (SiOC)–$ TiC_{x} %$ O_{y} $ composites based on the pyrolysis of polysiloxane and carbothermal reaction between $ TiO_{2} $ nanopa...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Lu, Kathy [verfasserIn] Erb, Donald [verfasserIn] Liu, Mengying [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966, 51(2016), 22 vom: 27. Juli, Seite 10166-10177 |
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| Übergeordnetes Werk: |
volume:51 ; year:2016 ; number:22 ; day:27 ; month:07 ; pages:10166-10177 |
| Links: |
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| DOI / URN: |
10.1007/s10853-016-0244-6 |
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| Katalog-ID: |
SPR013914723 |
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| 520 | |a Abstract There have been increasing needs for high-thermal stability and high-electrical conductivity materials. In this study, we in situ synthesized silicon oxycarbide (SiOC)–$ TiC_{x} %$ O_{y} $ composites based on the pyrolysis of polysiloxane and carbothermal reaction between $ TiO_{2} $ nanoparticles and free carbon in SiOC. The $ TiO_{2} $ to $ TiC_{x} %$ O_{y} $ conversion is dependent on the pyrolysis temperature. Higher pyrolysis temperature leads to more TiC formation but lower thermal stability. With more homogeneous distribution of $ TiO_{2} $, the thermal stability of the SiOC–$ TiC_{x} %$ O_{y} $ composite increases. This family of SiOC composite also demonstrates high electrical conductivity. The highest electrical conductivity is 5.03 S $ cm^{−1} $ at 400 °C measurement temperature, the highest for air atmosphere condition. The key issue for tuning the SiOC–$ TiC_{x} %$ O_{y} $ system for both thermal stability and electrical conductivity is to avoid the destabilization of the SiOC system. | ||
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| 650 | 4 | |a Pyrolysis Temperature |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Free Carbon |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a TiO2 Content |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Erb, Donald |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Mengying |e verfasserin |4 aut | |
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10.1007/s10853-016-0244-6 doi (DE-627)SPR013914723 (SPR)s10853-016-0244-6-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Lu, Kathy verfasserin aut Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract There have been increasing needs for high-thermal stability and high-electrical conductivity materials. In this study, we in situ synthesized silicon oxycarbide (SiOC)–$ TiC_{x} %$ O_{y} $ composites based on the pyrolysis of polysiloxane and carbothermal reaction between $ TiO_{2} $ nanoparticles and free carbon in SiOC. The $ TiO_{2} $ to $ TiC_{x} %$ O_{y} $ conversion is dependent on the pyrolysis temperature. Higher pyrolysis temperature leads to more TiC formation but lower thermal stability. With more homogeneous distribution of $ TiO_{2} $, the thermal stability of the SiOC–$ TiC_{x} %$ O_{y} $ composite increases. This family of SiOC composite also demonstrates high electrical conductivity. The highest electrical conductivity is 5.03 S $ cm^{−1} $ at 400 °C measurement temperature, the highest for air atmosphere condition. The key issue for tuning the SiOC–$ TiC_{x} %$ O_{y} $ system for both thermal stability and electrical conductivity is to avoid the destabilization of the SiOC system. TiO2 (dpeaa)DE-He213 TiO2 Nanoparticles (dpeaa)DE-He213 Pyrolysis Temperature (dpeaa)DE-He213 Free Carbon (dpeaa)DE-He213 TiO2 Content (dpeaa)DE-He213 Erb, Donald verfasserin aut Liu, Mengying verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 51(2016), 22 vom: 27. Juli, Seite 10166-10177 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:51 year:2016 number:22 day:27 month:07 pages:10166-10177 https://dx.doi.org/10.1007/s10853-016-0244-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 51 2016 22 27 07 10166-10177 |
| spelling |
10.1007/s10853-016-0244-6 doi (DE-627)SPR013914723 (SPR)s10853-016-0244-6-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Lu, Kathy verfasserin aut Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract There have been increasing needs for high-thermal stability and high-electrical conductivity materials. In this study, we in situ synthesized silicon oxycarbide (SiOC)–$ TiC_{x} %$ O_{y} $ composites based on the pyrolysis of polysiloxane and carbothermal reaction between $ TiO_{2} $ nanoparticles and free carbon in SiOC. The $ TiO_{2} $ to $ TiC_{x} %$ O_{y} $ conversion is dependent on the pyrolysis temperature. Higher pyrolysis temperature leads to more TiC formation but lower thermal stability. With more homogeneous distribution of $ TiO_{2} $, the thermal stability of the SiOC–$ TiC_{x} %$ O_{y} $ composite increases. This family of SiOC composite also demonstrates high electrical conductivity. The highest electrical conductivity is 5.03 S $ cm^{−1} $ at 400 °C measurement temperature, the highest for air atmosphere condition. The key issue for tuning the SiOC–$ TiC_{x} %$ O_{y} $ system for both thermal stability and electrical conductivity is to avoid the destabilization of the SiOC system. TiO2 (dpeaa)DE-He213 TiO2 Nanoparticles (dpeaa)DE-He213 Pyrolysis Temperature (dpeaa)DE-He213 Free Carbon (dpeaa)DE-He213 TiO2 Content (dpeaa)DE-He213 Erb, Donald verfasserin aut Liu, Mengying verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 51(2016), 22 vom: 27. Juli, Seite 10166-10177 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:51 year:2016 number:22 day:27 month:07 pages:10166-10177 https://dx.doi.org/10.1007/s10853-016-0244-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 51 2016 22 27 07 10166-10177 |
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10.1007/s10853-016-0244-6 doi (DE-627)SPR013914723 (SPR)s10853-016-0244-6-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Lu, Kathy verfasserin aut Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract There have been increasing needs for high-thermal stability and high-electrical conductivity materials. In this study, we in situ synthesized silicon oxycarbide (SiOC)–$ TiC_{x} %$ O_{y} $ composites based on the pyrolysis of polysiloxane and carbothermal reaction between $ TiO_{2} $ nanoparticles and free carbon in SiOC. The $ TiO_{2} $ to $ TiC_{x} %$ O_{y} $ conversion is dependent on the pyrolysis temperature. Higher pyrolysis temperature leads to more TiC formation but lower thermal stability. With more homogeneous distribution of $ TiO_{2} $, the thermal stability of the SiOC–$ TiC_{x} %$ O_{y} $ composite increases. This family of SiOC composite also demonstrates high electrical conductivity. The highest electrical conductivity is 5.03 S $ cm^{−1} $ at 400 °C measurement temperature, the highest for air atmosphere condition. The key issue for tuning the SiOC–$ TiC_{x} %$ O_{y} $ system for both thermal stability and electrical conductivity is to avoid the destabilization of the SiOC system. TiO2 (dpeaa)DE-He213 TiO2 Nanoparticles (dpeaa)DE-He213 Pyrolysis Temperature (dpeaa)DE-He213 Free Carbon (dpeaa)DE-He213 TiO2 Content (dpeaa)DE-He213 Erb, Donald verfasserin aut Liu, Mengying verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 51(2016), 22 vom: 27. Juli, Seite 10166-10177 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:51 year:2016 number:22 day:27 month:07 pages:10166-10177 https://dx.doi.org/10.1007/s10853-016-0244-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 51 2016 22 27 07 10166-10177 |
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10.1007/s10853-016-0244-6 doi (DE-627)SPR013914723 (SPR)s10853-016-0244-6-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Lu, Kathy verfasserin aut Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract There have been increasing needs for high-thermal stability and high-electrical conductivity materials. In this study, we in situ synthesized silicon oxycarbide (SiOC)–$ TiC_{x} %$ O_{y} $ composites based on the pyrolysis of polysiloxane and carbothermal reaction between $ TiO_{2} $ nanoparticles and free carbon in SiOC. The $ TiO_{2} $ to $ TiC_{x} %$ O_{y} $ conversion is dependent on the pyrolysis temperature. Higher pyrolysis temperature leads to more TiC formation but lower thermal stability. With more homogeneous distribution of $ TiO_{2} $, the thermal stability of the SiOC–$ TiC_{x} %$ O_{y} $ composite increases. This family of SiOC composite also demonstrates high electrical conductivity. The highest electrical conductivity is 5.03 S $ cm^{−1} $ at 400 °C measurement temperature, the highest for air atmosphere condition. The key issue for tuning the SiOC–$ TiC_{x} %$ O_{y} $ system for both thermal stability and electrical conductivity is to avoid the destabilization of the SiOC system. TiO2 (dpeaa)DE-He213 TiO2 Nanoparticles (dpeaa)DE-He213 Pyrolysis Temperature (dpeaa)DE-He213 Free Carbon (dpeaa)DE-He213 TiO2 Content (dpeaa)DE-He213 Erb, Donald verfasserin aut Liu, Mengying verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 51(2016), 22 vom: 27. Juli, Seite 10166-10177 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:51 year:2016 number:22 day:27 month:07 pages:10166-10177 https://dx.doi.org/10.1007/s10853-016-0244-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 51 2016 22 27 07 10166-10177 |
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10.1007/s10853-016-0244-6 doi (DE-627)SPR013914723 (SPR)s10853-016-0244-6-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Lu, Kathy verfasserin aut Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract There have been increasing needs for high-thermal stability and high-electrical conductivity materials. In this study, we in situ synthesized silicon oxycarbide (SiOC)–$ TiC_{x} %$ O_{y} $ composites based on the pyrolysis of polysiloxane and carbothermal reaction between $ TiO_{2} $ nanoparticles and free carbon in SiOC. The $ TiO_{2} $ to $ TiC_{x} %$ O_{y} $ conversion is dependent on the pyrolysis temperature. Higher pyrolysis temperature leads to more TiC formation but lower thermal stability. With more homogeneous distribution of $ TiO_{2} $, the thermal stability of the SiOC–$ TiC_{x} %$ O_{y} $ composite increases. This family of SiOC composite also demonstrates high electrical conductivity. The highest electrical conductivity is 5.03 S $ cm^{−1} $ at 400 °C measurement temperature, the highest for air atmosphere condition. The key issue for tuning the SiOC–$ TiC_{x} %$ O_{y} $ system for both thermal stability and electrical conductivity is to avoid the destabilization of the SiOC system. TiO2 (dpeaa)DE-He213 TiO2 Nanoparticles (dpeaa)DE-He213 Pyrolysis Temperature (dpeaa)DE-He213 Free Carbon (dpeaa)DE-He213 TiO2 Content (dpeaa)DE-He213 Erb, Donald verfasserin aut Liu, Mengying verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 51(2016), 22 vom: 27. Juli, Seite 10166-10177 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:51 year:2016 number:22 day:27 month:07 pages:10166-10177 https://dx.doi.org/10.1007/s10853-016-0244-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 51 2016 22 27 07 10166-10177 |
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TiO2 TiO2 Nanoparticles Pyrolysis Temperature Free Carbon TiO2 Content |
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Lu, Kathy @@aut@@ Erb, Donald @@aut@@ Liu, Mengying @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR013914723</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20220111004139.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2016 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10853-016-0244-6</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR013914723</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10853-016-0244-6-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Lu, Kathy</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2016</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract There have been increasing needs for high-thermal stability and high-electrical conductivity materials. In this study, we in situ synthesized silicon oxycarbide (SiOC)–$ TiC_{x} %$ O_{y} $ composites based on the pyrolysis of polysiloxane and carbothermal reaction between $ TiO_{2} $ nanoparticles and free carbon in SiOC. The $ TiO_{2} $ to $ TiC_{x} %$ O_{y} $ conversion is dependent on the pyrolysis temperature. Higher pyrolysis temperature leads to more TiC formation but lower thermal stability. With more homogeneous distribution of $ TiO_{2} $, the thermal stability of the SiOC–$ TiC_{x} %$ O_{y} $ composite increases. This family of SiOC composite also demonstrates high electrical conductivity. The highest electrical conductivity is 5.03 S $ cm^{−1} $ at 400 °C measurement temperature, the highest for air atmosphere condition. The key issue for tuning the SiOC–$ TiC_{x} %$ O_{y} $ system for both thermal stability and electrical conductivity is to avoid the destabilization of the SiOC system.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">TiO2</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">TiO2 Nanoparticles</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Pyrolysis Temperature</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Free Carbon</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">TiO2 Content</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Erb, Donald</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Liu, Mengying</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of materials science</subfield><subfield code="d">Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966</subfield><subfield code="g">51(2016), 22 vom: 27. Juli, Seite 10166-10177</subfield><subfield code="w">(DE-627)315293969</subfield><subfield code="w">(DE-600)2015305-3</subfield><subfield code="x">1573-4803</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:51</subfield><subfield code="g">year:2016</subfield><subfield code="g">number:22</subfield><subfield code="g">day:27</subfield><subfield code="g">month:07</subfield><subfield code="g">pages:10166-10177</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s10853-016-0244-6</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield 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Lu, Kathy |
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Lu, Kathy ddc 670 bkl 51.00 misc TiO2 misc TiO2 Nanoparticles misc Pyrolysis Temperature misc Free Carbon misc TiO2 Content Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics |
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670 ASE 51.00 bkl Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics TiO2 (dpeaa)DE-He213 TiO2 Nanoparticles (dpeaa)DE-He213 Pyrolysis Temperature (dpeaa)DE-He213 Free Carbon (dpeaa)DE-He213 TiO2 Content (dpeaa)DE-He213 |
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ddc 670 bkl 51.00 misc TiO2 misc TiO2 Nanoparticles misc Pyrolysis Temperature misc Free Carbon misc TiO2 Content |
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Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics |
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phase transformation, oxidation stability, and electrical conductivity of $ tio_{2} $-polysiloxane derived ceramics |
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Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics |
| abstract |
Abstract There have been increasing needs for high-thermal stability and high-electrical conductivity materials. In this study, we in situ synthesized silicon oxycarbide (SiOC)–$ TiC_{x} %$ O_{y} $ composites based on the pyrolysis of polysiloxane and carbothermal reaction between $ TiO_{2} $ nanoparticles and free carbon in SiOC. The $ TiO_{2} $ to $ TiC_{x} %$ O_{y} $ conversion is dependent on the pyrolysis temperature. Higher pyrolysis temperature leads to more TiC formation but lower thermal stability. With more homogeneous distribution of $ TiO_{2} $, the thermal stability of the SiOC–$ TiC_{x} %$ O_{y} $ composite increases. This family of SiOC composite also demonstrates high electrical conductivity. The highest electrical conductivity is 5.03 S $ cm^{−1} $ at 400 °C measurement temperature, the highest for air atmosphere condition. The key issue for tuning the SiOC–$ TiC_{x} %$ O_{y} $ system for both thermal stability and electrical conductivity is to avoid the destabilization of the SiOC system. |
| abstractGer |
Abstract There have been increasing needs for high-thermal stability and high-electrical conductivity materials. In this study, we in situ synthesized silicon oxycarbide (SiOC)–$ TiC_{x} %$ O_{y} $ composites based on the pyrolysis of polysiloxane and carbothermal reaction between $ TiO_{2} $ nanoparticles and free carbon in SiOC. The $ TiO_{2} $ to $ TiC_{x} %$ O_{y} $ conversion is dependent on the pyrolysis temperature. Higher pyrolysis temperature leads to more TiC formation but lower thermal stability. With more homogeneous distribution of $ TiO_{2} $, the thermal stability of the SiOC–$ TiC_{x} %$ O_{y} $ composite increases. This family of SiOC composite also demonstrates high electrical conductivity. The highest electrical conductivity is 5.03 S $ cm^{−1} $ at 400 °C measurement temperature, the highest for air atmosphere condition. The key issue for tuning the SiOC–$ TiC_{x} %$ O_{y} $ system for both thermal stability and electrical conductivity is to avoid the destabilization of the SiOC system. |
| abstract_unstemmed |
Abstract There have been increasing needs for high-thermal stability and high-electrical conductivity materials. In this study, we in situ synthesized silicon oxycarbide (SiOC)–$ TiC_{x} %$ O_{y} $ composites based on the pyrolysis of polysiloxane and carbothermal reaction between $ TiO_{2} $ nanoparticles and free carbon in SiOC. The $ TiO_{2} $ to $ TiC_{x} %$ O_{y} $ conversion is dependent on the pyrolysis temperature. Higher pyrolysis temperature leads to more TiC formation but lower thermal stability. With more homogeneous distribution of $ TiO_{2} $, the thermal stability of the SiOC–$ TiC_{x} %$ O_{y} $ composite increases. This family of SiOC composite also demonstrates high electrical conductivity. The highest electrical conductivity is 5.03 S $ cm^{−1} $ at 400 °C measurement temperature, the highest for air atmosphere condition. The key issue for tuning the SiOC–$ TiC_{x} %$ O_{y} $ system for both thermal stability and electrical conductivity is to avoid the destabilization of the SiOC system. |
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| container_issue |
22 |
| title_short |
Phase transformation, oxidation stability, and electrical conductivity of $ TiO_{2} $-polysiloxane derived ceramics |
| url |
https://dx.doi.org/10.1007/s10853-016-0244-6 |
| remote_bool |
true |
| author2 |
Erb, Donald Liu, Mengying |
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Erb, Donald Liu, Mengying |
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| doi_str |
10.1007/s10853-016-0244-6 |
| up_date |
2024-07-03T22:59:10.668Z |
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1803600580495540224 |
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| score |
7.401865 |