Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes
Abstract In order to obtain large-scale industrial silicon/carbon composites as anode materials for lithium-ion batteries, graphite-loaded nano-silicon (GSi) composite was synthesized by a facile spray drying method, and then asphalt powders were fast fused on the surface and carbonized at 1100 °C f...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Liu, Wenping [verfasserIn] Xu, Huarui [verfasserIn] Qin, Haiqing [verfasserIn] Lv, Yanlu [verfasserIn] Zhu, Guisheng [verfasserIn] Lei, Xiaoxu [verfasserIn] Lin, Feng [verfasserIn] Zhang, Zhenjun [verfasserIn] Wang, Lihui [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966, 55(2019), 10 vom: 23. Dez., Seite 4382-4394 |
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| Übergeordnetes Werk: |
volume:55 ; year:2019 ; number:10 ; day:23 ; month:12 ; pages:4382-4394 |
| Links: |
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| DOI / URN: |
10.1007/s10853-019-04313-x |
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| Katalog-ID: |
SPR013956183 |
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| 520 | |a Abstract In order to obtain large-scale industrial silicon/carbon composites as anode materials for lithium-ion batteries, graphite-loaded nano-silicon (GSi) composite was synthesized by a facile spray drying method, and then asphalt powders were fast fused on the surface and carbonized at 1100 °C for 2 h to obtain core–shell G@Si@C composite. The nano-Si particle was pinned on the graphite surface without bareness via asphalt carbon layer. The G@Si@C composite delivers excellent electrochemical performance with an initial reversible charge capacity of 502.5 mAh $ g^{−1} $ and coulombic efficiency of 87.5%, and the capacity retention is 83.4% after 400 cycles. The superior cycle performance is attributed to the carbon layer relieving volume change, stabilizing SEI film and inhibiting particle pulverization. Moreover, the outstanding high-rate discharge properties of G@Si@C composite may be owing to the preferable electrochemistry kinetics such as fast charge transfer and lithium-ion diffusion. | ||
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| 700 | 1 | |a Qin, Haiqing |e verfasserin |4 aut | |
| 700 | 1 | |a Lv, Yanlu |e verfasserin |4 aut | |
| 700 | 1 | |a Zhu, Guisheng |e verfasserin |4 aut | |
| 700 | 1 | |a Lei, Xiaoxu |e verfasserin |4 aut | |
| 700 | 1 | |a Lin, Feng |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Zhenjun |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Lihui |e verfasserin |4 aut | |
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10.1007/s10853-019-04313-x doi (DE-627)SPR013956183 (SPR)s10853-019-04313-x-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Liu, Wenping verfasserin aut Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In order to obtain large-scale industrial silicon/carbon composites as anode materials for lithium-ion batteries, graphite-loaded nano-silicon (GSi) composite was synthesized by a facile spray drying method, and then asphalt powders were fast fused on the surface and carbonized at 1100 °C for 2 h to obtain core–shell G@Si@C composite. The nano-Si particle was pinned on the graphite surface without bareness via asphalt carbon layer. The G@Si@C composite delivers excellent electrochemical performance with an initial reversible charge capacity of 502.5 mAh $ g^{−1} $ and coulombic efficiency of 87.5%, and the capacity retention is 83.4% after 400 cycles. The superior cycle performance is attributed to the carbon layer relieving volume change, stabilizing SEI film and inhibiting particle pulverization. Moreover, the outstanding high-rate discharge properties of G@Si@C composite may be owing to the preferable electrochemistry kinetics such as fast charge transfer and lithium-ion diffusion. Xu, Huarui verfasserin aut Qin, Haiqing verfasserin aut Lv, Yanlu verfasserin aut Zhu, Guisheng verfasserin aut Lei, Xiaoxu verfasserin aut Lin, Feng verfasserin aut Zhang, Zhenjun verfasserin aut Wang, Lihui verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 55(2019), 10 vom: 23. Dez., Seite 4382-4394 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:55 year:2019 number:10 day:23 month:12 pages:4382-4394 https://dx.doi.org/10.1007/s10853-019-04313-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 55 2019 10 23 12 4382-4394 |
| spelling |
10.1007/s10853-019-04313-x doi (DE-627)SPR013956183 (SPR)s10853-019-04313-x-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Liu, Wenping verfasserin aut Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In order to obtain large-scale industrial silicon/carbon composites as anode materials for lithium-ion batteries, graphite-loaded nano-silicon (GSi) composite was synthesized by a facile spray drying method, and then asphalt powders were fast fused on the surface and carbonized at 1100 °C for 2 h to obtain core–shell G@Si@C composite. The nano-Si particle was pinned on the graphite surface without bareness via asphalt carbon layer. The G@Si@C composite delivers excellent electrochemical performance with an initial reversible charge capacity of 502.5 mAh $ g^{−1} $ and coulombic efficiency of 87.5%, and the capacity retention is 83.4% after 400 cycles. The superior cycle performance is attributed to the carbon layer relieving volume change, stabilizing SEI film and inhibiting particle pulverization. Moreover, the outstanding high-rate discharge properties of G@Si@C composite may be owing to the preferable electrochemistry kinetics such as fast charge transfer and lithium-ion diffusion. Xu, Huarui verfasserin aut Qin, Haiqing verfasserin aut Lv, Yanlu verfasserin aut Zhu, Guisheng verfasserin aut Lei, Xiaoxu verfasserin aut Lin, Feng verfasserin aut Zhang, Zhenjun verfasserin aut Wang, Lihui verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 55(2019), 10 vom: 23. Dez., Seite 4382-4394 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:55 year:2019 number:10 day:23 month:12 pages:4382-4394 https://dx.doi.org/10.1007/s10853-019-04313-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 55 2019 10 23 12 4382-4394 |
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10.1007/s10853-019-04313-x doi (DE-627)SPR013956183 (SPR)s10853-019-04313-x-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Liu, Wenping verfasserin aut Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In order to obtain large-scale industrial silicon/carbon composites as anode materials for lithium-ion batteries, graphite-loaded nano-silicon (GSi) composite was synthesized by a facile spray drying method, and then asphalt powders were fast fused on the surface and carbonized at 1100 °C for 2 h to obtain core–shell G@Si@C composite. The nano-Si particle was pinned on the graphite surface without bareness via asphalt carbon layer. The G@Si@C composite delivers excellent electrochemical performance with an initial reversible charge capacity of 502.5 mAh $ g^{−1} $ and coulombic efficiency of 87.5%, and the capacity retention is 83.4% after 400 cycles. The superior cycle performance is attributed to the carbon layer relieving volume change, stabilizing SEI film and inhibiting particle pulverization. Moreover, the outstanding high-rate discharge properties of G@Si@C composite may be owing to the preferable electrochemistry kinetics such as fast charge transfer and lithium-ion diffusion. Xu, Huarui verfasserin aut Qin, Haiqing verfasserin aut Lv, Yanlu verfasserin aut Zhu, Guisheng verfasserin aut Lei, Xiaoxu verfasserin aut Lin, Feng verfasserin aut Zhang, Zhenjun verfasserin aut Wang, Lihui verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 55(2019), 10 vom: 23. Dez., Seite 4382-4394 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:55 year:2019 number:10 day:23 month:12 pages:4382-4394 https://dx.doi.org/10.1007/s10853-019-04313-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 55 2019 10 23 12 4382-4394 |
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10.1007/s10853-019-04313-x doi (DE-627)SPR013956183 (SPR)s10853-019-04313-x-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Liu, Wenping verfasserin aut Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In order to obtain large-scale industrial silicon/carbon composites as anode materials for lithium-ion batteries, graphite-loaded nano-silicon (GSi) composite was synthesized by a facile spray drying method, and then asphalt powders were fast fused on the surface and carbonized at 1100 °C for 2 h to obtain core–shell G@Si@C composite. The nano-Si particle was pinned on the graphite surface without bareness via asphalt carbon layer. The G@Si@C composite delivers excellent electrochemical performance with an initial reversible charge capacity of 502.5 mAh $ g^{−1} $ and coulombic efficiency of 87.5%, and the capacity retention is 83.4% after 400 cycles. The superior cycle performance is attributed to the carbon layer relieving volume change, stabilizing SEI film and inhibiting particle pulverization. Moreover, the outstanding high-rate discharge properties of G@Si@C composite may be owing to the preferable electrochemistry kinetics such as fast charge transfer and lithium-ion diffusion. Xu, Huarui verfasserin aut Qin, Haiqing verfasserin aut Lv, Yanlu verfasserin aut Zhu, Guisheng verfasserin aut Lei, Xiaoxu verfasserin aut Lin, Feng verfasserin aut Zhang, Zhenjun verfasserin aut Wang, Lihui verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 55(2019), 10 vom: 23. Dez., Seite 4382-4394 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:55 year:2019 number:10 day:23 month:12 pages:4382-4394 https://dx.doi.org/10.1007/s10853-019-04313-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 55 2019 10 23 12 4382-4394 |
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10.1007/s10853-019-04313-x doi (DE-627)SPR013956183 (SPR)s10853-019-04313-x-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Liu, Wenping verfasserin aut Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In order to obtain large-scale industrial silicon/carbon composites as anode materials for lithium-ion batteries, graphite-loaded nano-silicon (GSi) composite was synthesized by a facile spray drying method, and then asphalt powders were fast fused on the surface and carbonized at 1100 °C for 2 h to obtain core–shell G@Si@C composite. The nano-Si particle was pinned on the graphite surface without bareness via asphalt carbon layer. The G@Si@C composite delivers excellent electrochemical performance with an initial reversible charge capacity of 502.5 mAh $ g^{−1} $ and coulombic efficiency of 87.5%, and the capacity retention is 83.4% after 400 cycles. The superior cycle performance is attributed to the carbon layer relieving volume change, stabilizing SEI film and inhibiting particle pulverization. Moreover, the outstanding high-rate discharge properties of G@Si@C composite may be owing to the preferable electrochemistry kinetics such as fast charge transfer and lithium-ion diffusion. Xu, Huarui verfasserin aut Qin, Haiqing verfasserin aut Lv, Yanlu verfasserin aut Zhu, Guisheng verfasserin aut Lei, Xiaoxu verfasserin aut Lin, Feng verfasserin aut Zhang, Zhenjun verfasserin aut Wang, Lihui verfasserin aut Enthalten in Journal of materials science Dordrecht [u.a.] : Springer Science + Business Media B.V, 1966 55(2019), 10 vom: 23. Dez., Seite 4382-4394 (DE-627)315293969 (DE-600)2015305-3 1573-4803 nnns volume:55 year:2019 number:10 day:23 month:12 pages:4382-4394 https://dx.doi.org/10.1007/s10853-019-04313-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 55 2019 10 23 12 4382-4394 |
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Liu, Wenping @@aut@@ Xu, Huarui @@aut@@ Qin, Haiqing @@aut@@ Lv, Yanlu @@aut@@ Zhu, Guisheng @@aut@@ Lei, Xiaoxu @@aut@@ Lin, Feng @@aut@@ Zhang, Zhenjun @@aut@@ Wang, Lihui @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR013956183</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20220111004305.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2019 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10853-019-04313-x</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR013956183</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10853-019-04313-x-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Liu, Wenping</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract In order to obtain large-scale industrial silicon/carbon composites as anode materials for lithium-ion batteries, graphite-loaded nano-silicon (GSi) composite was synthesized by a facile spray drying method, and then asphalt powders were fast fused on the surface and carbonized at 1100 °C for 2 h to obtain core–shell G@Si@C composite. The nano-Si particle was pinned on the graphite surface without bareness via asphalt carbon layer. The G@Si@C composite delivers excellent electrochemical performance with an initial reversible charge capacity of 502.5 mAh $ g^{−1} $ and coulombic efficiency of 87.5%, and the capacity retention is 83.4% after 400 cycles. The superior cycle performance is attributed to the carbon layer relieving volume change, stabilizing SEI film and inhibiting particle pulverization. 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Liu, Wenping |
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Liu, Wenping ddc 670 bkl 51.00 Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes |
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670 ASE 51.00 bkl Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes |
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Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes |
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Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes |
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Liu, Wenping |
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Liu, Wenping Xu, Huarui Qin, Haiqing Lv, Yanlu Zhu, Guisheng Lei, Xiaoxu Lin, Feng Zhang, Zhenjun Wang, Lihui |
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rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes |
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Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes |
| abstract |
Abstract In order to obtain large-scale industrial silicon/carbon composites as anode materials for lithium-ion batteries, graphite-loaded nano-silicon (GSi) composite was synthesized by a facile spray drying method, and then asphalt powders were fast fused on the surface and carbonized at 1100 °C for 2 h to obtain core–shell G@Si@C composite. The nano-Si particle was pinned on the graphite surface without bareness via asphalt carbon layer. The G@Si@C composite delivers excellent electrochemical performance with an initial reversible charge capacity of 502.5 mAh $ g^{−1} $ and coulombic efficiency of 87.5%, and the capacity retention is 83.4% after 400 cycles. The superior cycle performance is attributed to the carbon layer relieving volume change, stabilizing SEI film and inhibiting particle pulverization. Moreover, the outstanding high-rate discharge properties of G@Si@C composite may be owing to the preferable electrochemistry kinetics such as fast charge transfer and lithium-ion diffusion. |
| abstractGer |
Abstract In order to obtain large-scale industrial silicon/carbon composites as anode materials for lithium-ion batteries, graphite-loaded nano-silicon (GSi) composite was synthesized by a facile spray drying method, and then asphalt powders were fast fused on the surface and carbonized at 1100 °C for 2 h to obtain core–shell G@Si@C composite. The nano-Si particle was pinned on the graphite surface without bareness via asphalt carbon layer. The G@Si@C composite delivers excellent electrochemical performance with an initial reversible charge capacity of 502.5 mAh $ g^{−1} $ and coulombic efficiency of 87.5%, and the capacity retention is 83.4% after 400 cycles. The superior cycle performance is attributed to the carbon layer relieving volume change, stabilizing SEI film and inhibiting particle pulverization. Moreover, the outstanding high-rate discharge properties of G@Si@C composite may be owing to the preferable electrochemistry kinetics such as fast charge transfer and lithium-ion diffusion. |
| abstract_unstemmed |
Abstract In order to obtain large-scale industrial silicon/carbon composites as anode materials for lithium-ion batteries, graphite-loaded nano-silicon (GSi) composite was synthesized by a facile spray drying method, and then asphalt powders were fast fused on the surface and carbonized at 1100 °C for 2 h to obtain core–shell G@Si@C composite. The nano-Si particle was pinned on the graphite surface without bareness via asphalt carbon layer. The G@Si@C composite delivers excellent electrochemical performance with an initial reversible charge capacity of 502.5 mAh $ g^{−1} $ and coulombic efficiency of 87.5%, and the capacity retention is 83.4% after 400 cycles. The superior cycle performance is attributed to the carbon layer relieving volume change, stabilizing SEI film and inhibiting particle pulverization. Moreover, the outstanding high-rate discharge properties of G@Si@C composite may be owing to the preferable electrochemistry kinetics such as fast charge transfer and lithium-ion diffusion. |
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10 |
| title_short |
Rapid coating of asphalt to prepare carbon-encapsulated composites of nano-silicon and graphite for lithium battery anodes |
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https://dx.doi.org/10.1007/s10853-019-04313-x |
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Xu, Huarui Qin, Haiqing Lv, Yanlu Zhu, Guisheng Lei, Xiaoxu Lin, Feng Zhang, Zhenjun Wang, Lihui |
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Xu, Huarui Qin, Haiqing Lv, Yanlu Zhu, Guisheng Lei, Xiaoxu Lin, Feng Zhang, Zhenjun Wang, Lihui |
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| doi_str |
10.1007/s10853-019-04313-x |
| up_date |
2024-07-03T23:15:29.270Z |
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| score |
7.398844 |