A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone

Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} %$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% an...
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Autor*in:	Solignac, G. [verfasserIn] Magneron, I. [verfasserIn] Mellouki, A. [verfasserIn] Muñoz, A. [verfasserIn] Reviejo, M. Martin [verfasserIn] Wirtz, K. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2006

Schlagwörter:	-methyl pyrrolidinone -methyl succinimide -formyl pyrrolidinone hydroxyl radicals relative kinetic troposphere

Übergeordnetes Werk:	Enthalten in: Journal of atmospheric chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983, 54(2006), 2 vom: Juni, Seite 89-102
Übergeordnetes Werk:	volume:54 ; year:2006 ; number:2 ; month:06 ; pages:89-102

Links:	Volltext

DOI / URN:	10.1007/s10874-006-9017-y

Katalog-ID:	SPR014229595

Internformat


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100	1		\|a Solignac, G. \|e verfasserin \|4 aut
245	1	2	\|a A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone
264		1	\|c 2006
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520			\|a Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} %$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule− 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact.
650		4	\|a -methyl pyrrolidinone \|7 (dpeaa)DE-He213
650		4	\|a -methyl succinimide \|7 (dpeaa)DE-He213
650		4	\|a -formyl pyrrolidinone \|7 (dpeaa)DE-He213
650		4	\|a hydroxyl radicals \|7 (dpeaa)DE-He213
650		4	\|a relative kinetic \|7 (dpeaa)DE-He213
650		4	\|a troposphere \|7 (dpeaa)DE-He213
700	1		\|a Magneron, I. \|e verfasserin \|4 aut
700	1		\|a Mellouki, A. \|e verfasserin \|4 aut
700	1		\|a Muñoz, A. \|e verfasserin \|4 aut
700	1		\|a Reviejo, M. Martin \|e verfasserin \|4 aut
700	1		\|a Wirtz, K. \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Journal of atmospheric chemistry \|d Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 \|g 54(2006), 2 vom: Juni, Seite 89-102 \|w (DE-627)269539123 \|w (DE-600)1475524-5 \|x 1573-0662 \|7 nnns
773	1	8	\|g volume:54 \|g year:2006 \|g number:2 \|g month:06 \|g pages:89-102
856	4	0	\|u https://dx.doi.org/10.1007/s10874-006-9017-y \|z lizenzpflichtig \|3 Volltext
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912			\|a GBV_ILN_100
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912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
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912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_206
912			\|a GBV_ILN_213
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912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
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912			\|a GBV_ILN_2037
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912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
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912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
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912			\|a GBV_ILN_2113
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936	b	k	\|a 38.32 \|q ASE
936	b	k	\|a 38.81 \|q ASE
951			\|a AR
952			\|d 54 \|j 2006 \|e 2 \|c 06 \|h 89-102

Indexfelder

author_variant	g s gs i m im a m am a m am m m r mm mmr k w kw
matchkey_str	article:15730662:2006----::suyfhratooordclwtnehlyrldnnnehlucnmd
hierarchy_sort_str	2006
bklnumber	38.32 38.81
publishDate	2006
allfields	10.1007/s10874-006-9017-y doi (DE-627)SPR014229595 (SPR)s10874-006-9017-y-e DE-627 ger DE-627 rakwb eng 540 550 ASE 38.32 bkl 38.81 bkl Solignac, G. verfasserin aut A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} %$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule− 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. -methyl pyrrolidinone (dpeaa)DE-He213 -methyl succinimide (dpeaa)DE-He213 -formyl pyrrolidinone (dpeaa)DE-He213 hydroxyl radicals (dpeaa)DE-He213 relative kinetic (dpeaa)DE-He213 troposphere (dpeaa)DE-He213 Magneron, I. verfasserin aut Mellouki, A. verfasserin aut Muñoz, A. verfasserin aut Reviejo, M. Martin verfasserin aut Wirtz, K. verfasserin aut Enthalten in Journal of atmospheric chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 54(2006), 2 vom: Juni, Seite 89-102 (DE-627)269539123 (DE-600)1475524-5 1573-0662 nnns volume:54 year:2006 number:2 month:06 pages:89-102 https://dx.doi.org/10.1007/s10874-006-9017-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2873 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.32 ASE 38.81 ASE AR 54 2006 2 06 89-102
spelling	10.1007/s10874-006-9017-y doi (DE-627)SPR014229595 (SPR)s10874-006-9017-y-e DE-627 ger DE-627 rakwb eng 540 550 ASE 38.32 bkl 38.81 bkl Solignac, G. verfasserin aut A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} %$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule− 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. -methyl pyrrolidinone (dpeaa)DE-He213 -methyl succinimide (dpeaa)DE-He213 -formyl pyrrolidinone (dpeaa)DE-He213 hydroxyl radicals (dpeaa)DE-He213 relative kinetic (dpeaa)DE-He213 troposphere (dpeaa)DE-He213 Magneron, I. verfasserin aut Mellouki, A. verfasserin aut Muñoz, A. verfasserin aut Reviejo, M. Martin verfasserin aut Wirtz, K. verfasserin aut Enthalten in Journal of atmospheric chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 54(2006), 2 vom: Juni, Seite 89-102 (DE-627)269539123 (DE-600)1475524-5 1573-0662 nnns volume:54 year:2006 number:2 month:06 pages:89-102 https://dx.doi.org/10.1007/s10874-006-9017-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2873 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.32 ASE 38.81 ASE AR 54 2006 2 06 89-102
allfields_unstemmed	10.1007/s10874-006-9017-y doi (DE-627)SPR014229595 (SPR)s10874-006-9017-y-e DE-627 ger DE-627 rakwb eng 540 550 ASE 38.32 bkl 38.81 bkl Solignac, G. verfasserin aut A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} %$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule− 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. -methyl pyrrolidinone (dpeaa)DE-He213 -methyl succinimide (dpeaa)DE-He213 -formyl pyrrolidinone (dpeaa)DE-He213 hydroxyl radicals (dpeaa)DE-He213 relative kinetic (dpeaa)DE-He213 troposphere (dpeaa)DE-He213 Magneron, I. verfasserin aut Mellouki, A. verfasserin aut Muñoz, A. verfasserin aut Reviejo, M. Martin verfasserin aut Wirtz, K. verfasserin aut Enthalten in Journal of atmospheric chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 54(2006), 2 vom: Juni, Seite 89-102 (DE-627)269539123 (DE-600)1475524-5 1573-0662 nnns volume:54 year:2006 number:2 month:06 pages:89-102 https://dx.doi.org/10.1007/s10874-006-9017-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2873 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.32 ASE 38.81 ASE AR 54 2006 2 06 89-102
allfieldsGer	10.1007/s10874-006-9017-y doi (DE-627)SPR014229595 (SPR)s10874-006-9017-y-e DE-627 ger DE-627 rakwb eng 540 550 ASE 38.32 bkl 38.81 bkl Solignac, G. verfasserin aut A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} %$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule− 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. -methyl pyrrolidinone (dpeaa)DE-He213 -methyl succinimide (dpeaa)DE-He213 -formyl pyrrolidinone (dpeaa)DE-He213 hydroxyl radicals (dpeaa)DE-He213 relative kinetic (dpeaa)DE-He213 troposphere (dpeaa)DE-He213 Magneron, I. verfasserin aut Mellouki, A. verfasserin aut Muñoz, A. verfasserin aut Reviejo, M. Martin verfasserin aut Wirtz, K. verfasserin aut Enthalten in Journal of atmospheric chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 54(2006), 2 vom: Juni, Seite 89-102 (DE-627)269539123 (DE-600)1475524-5 1573-0662 nnns volume:54 year:2006 number:2 month:06 pages:89-102 https://dx.doi.org/10.1007/s10874-006-9017-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2873 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.32 ASE 38.81 ASE AR 54 2006 2 06 89-102
allfieldsSound	10.1007/s10874-006-9017-y doi (DE-627)SPR014229595 (SPR)s10874-006-9017-y-e DE-627 ger DE-627 rakwb eng 540 550 ASE 38.32 bkl 38.81 bkl Solignac, G. verfasserin aut A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} %$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule− 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact. -methyl pyrrolidinone (dpeaa)DE-He213 -methyl succinimide (dpeaa)DE-He213 -formyl pyrrolidinone (dpeaa)DE-He213 hydroxyl radicals (dpeaa)DE-He213 relative kinetic (dpeaa)DE-He213 troposphere (dpeaa)DE-He213 Magneron, I. verfasserin aut Mellouki, A. verfasserin aut Muñoz, A. verfasserin aut Reviejo, M. Martin verfasserin aut Wirtz, K. verfasserin aut Enthalten in Journal of atmospheric chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1983 54(2006), 2 vom: Juni, Seite 89-102 (DE-627)269539123 (DE-600)1475524-5 1573-0662 nnns volume:54 year:2006 number:2 month:06 pages:89-102 https://dx.doi.org/10.1007/s10874-006-9017-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2873 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.32 ASE 38.81 ASE AR 54 2006 2 06 89-102
language	English
source	Enthalten in Journal of atmospheric chemistry 54(2006), 2 vom: Juni, Seite 89-102 volume:54 year:2006 number:2 month:06 pages:89-102
sourceStr	Enthalten in Journal of atmospheric chemistry 54(2006), 2 vom: Juni, Seite 89-102 volume:54 year:2006 number:2 month:06 pages:89-102
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	-methyl pyrrolidinone -methyl succinimide -formyl pyrrolidinone hydroxyl radicals relative kinetic troposphere
dewey-raw	540
isfreeaccess_bool	false
container_title	Journal of atmospheric chemistry
authorswithroles_txt_mv	Solignac, G. @@aut@@ Magneron, I. @@aut@@ Mellouki, A. @@aut@@ Muñoz, A. @@aut@@ Reviejo, M. Martin @@aut@@ Wirtz, K. @@aut@@
publishDateDaySort_date	2006-06-01T00:00:00Z
hierarchy_top_id	269539123
dewey-sort	3540
id	SPR014229595
language_de	englisch
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author	Solignac, G.
spellingShingle	Solignac, G. ddc 540 bkl 38.32 bkl 38.81 misc -methyl pyrrolidinone misc -methyl succinimide misc -formyl pyrrolidinone misc hydroxyl radicals misc relative kinetic misc troposphere A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone
authorStr	Solignac, G.
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topic_title	540 550 ASE 38.32 bkl 38.81 bkl A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone -methyl pyrrolidinone (dpeaa)DE-He213 -methyl succinimide (dpeaa)DE-He213 -formyl pyrrolidinone (dpeaa)DE-He213 hydroxyl radicals (dpeaa)DE-He213 relative kinetic (dpeaa)DE-He213 troposphere (dpeaa)DE-He213
topic	ddc 540 bkl 38.32 bkl 38.81 misc -methyl pyrrolidinone misc -methyl succinimide misc -formyl pyrrolidinone misc hydroxyl radicals misc relative kinetic misc troposphere
topic_unstemmed	ddc 540 bkl 38.32 bkl 38.81 misc -methyl pyrrolidinone misc -methyl succinimide misc -formyl pyrrolidinone misc hydroxyl radicals misc relative kinetic misc troposphere
topic_browse	ddc 540 bkl 38.32 bkl 38.81 misc -methyl pyrrolidinone misc -methyl succinimide misc -formyl pyrrolidinone misc hydroxyl radicals misc relative kinetic misc troposphere
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title	A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone
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title_full	A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone
author_sort	Solignac, G.
journal	Journal of atmospheric chemistry
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author_browse	Solignac, G. Magneron, I. Mellouki, A. Muñoz, A. Reviejo, M. Martin Wirtz, K.
container_volume	54
class	540 550 ASE 38.32 bkl 38.81 bkl
format_se	Elektronische Aufsätze
author-letter	Solignac, G.
doi_str_mv	10.1007/s10874-006-9017-y
dewey-full	540 550
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title_sort	study of the reaction of oh radicals with n-methyl pyrrolidinone,n-methyl succinimide and n-formyl pyrrolidinone
title_auth	A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone
abstract	Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} %$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule− 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact.
abstractGer	Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} %$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule− 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact.
abstract_unstemmed	Abstract A study of the oxidation mechanism of N-methyl pyrrolidinone ($ C_{5} %$ H_{9} $NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of $ cm^{3} $ molecule− 1 $ s^{− 1} $): $ k_{NMP} $ = (2.2 ± 0.4) × $ 10^{− 11} $, $ k_{NMS} $ = (1.4 ± 0.3) × $ 10^{− 12} $ and $ k_{FP} $ = (6 ± 1) × $ 10^{− 12} $. The results are presented and discussed in terms of the atmospheric impact.
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container_issue	2
title_short	A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone
url	https://dx.doi.org/10.1007/s10874-006-9017-y
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author2	Magneron, I. Mellouki, A. Muñoz, A. Reviejo, M. Martin Wirtz, K.
author2Str	Magneron, I. Mellouki, A. Muñoz, A. Reviejo, M. Martin Wirtz, K.
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doi_str	10.1007/s10874-006-9017-y
up_date	2024-07-04T00:44:40.528Z
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A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone

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