New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions
Abstract The reaction of the [$ Ni_{6} $(CO)12]2− dianion with [Rh(COD)Cl]2 (COD = cyclooctadiene) in acetone affords a mixture of bimetallic Ni–Rh clusters, mainly consisting of the new [$ Ni_{7} %$ Rh_{3} $(CO)18]3− and [$ Ni_{8} $Rh(CO)18]3− trianions. A study of the reactivity of [$ Ni_{7} %$ Rh...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Collini, Davide [verfasserIn] Fedi, Serena [verfasserIn] Femoni, Cristina [verfasserIn] Kaswalder, Francesco [verfasserIn] Iapalucci, Maria Carmela [verfasserIn] Longoni, Giuliano [verfasserIn] Zanello, Piero [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2005 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of cluster science - New York, NY : Springer Science + Business Media B.V., 1990, 16(2005), 3 vom: Sept., Seite 455-476 |
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| Übergeordnetes Werk: |
volume:16 ; year:2005 ; number:3 ; month:09 ; pages:455-476 |
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| DOI / URN: |
10.1007/s10876-005-0014-0 |
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| Katalog-ID: |
SPR014250055 |
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| 100 | 1 | |a Collini, Davide |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions |
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| 520 | |a Abstract The reaction of the [$ Ni_{6} $(CO)12]2− dianion with [Rh(COD)Cl]2 (COD = cyclooctadiene) in acetone affords a mixture of bimetallic Ni–Rh clusters, mainly consisting of the new [$ Ni_{7} %$ Rh_{3} $(CO)18]3− and [$ Ni_{8} $Rh(CO)18]3− trianions. A study of the reactivity of [$ Ni_{7} %$ Rh_{3} $(CO)18]3− led to isolation of the new [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− anions. All these new bimetallic Ni–Rh carbonyl clusters have been isolated in the solid state as tetrasubstituted ammonium salts and have been characterised by elemental analysis, X-ray diffraction studies, ESI-MS and electrochemistry. The unit cell of the [$ NEt_{4} $]3[$ Ni_{7} %$ Rh_{3} $(CO)18] salt contains two orientationally-disordered $ ν_{2} $-tetrahedral [$ Ni_{7} %$ Rh_{3} $(CO)18]3− trianions with occupancy factors of 0.75 and 0.25. Besides, their inner $ Ni_{3} %$ Rh_{3} $ octahedral moieties show two cis sites purely occupied by Rh atoms, two trans sites purely occupied by Ni atoms and the remaining two cis sites are disordered Ni and Rh sites with respective occupancy fraction of 0.5. At difference from the parent [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, the octahedral [$ Ni_{3} %$ Rh_{3} $(CO)13]3− displays an ordered distribution of Ni and Rh atoms in two staggered triangles. The [$ NiRh_{8} $(CO)19]2− dianion adopts an isomeric metal frame with respect to that of the [$ PtRh_{8} $(CO)19]2− congener. As a fallout of this work, new high-yield synthesis of the known [$ Ni_{6} %$ Rh_{3} $(CO)17]3− and [$ Ni_{6} %$ Rh_{5} $(CO)21]3−, as well as other currently-investigated bimetallic Ni–Rh clusters have been obtained. | ||
| 650 | 4 | |a Carbonyl compound |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a bimetallic cluster |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a X-ray structure |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a redox behaviour |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Fedi, Serena |e verfasserin |4 aut | |
| 700 | 1 | |a Femoni, Cristina |e verfasserin |4 aut | |
| 700 | 1 | |a Kaswalder, Francesco |e verfasserin |4 aut | |
| 700 | 1 | |a Iapalucci, Maria Carmela |e verfasserin |4 aut | |
| 700 | 1 | |a Longoni, Giuliano |e verfasserin |4 aut | |
| 700 | 1 | |a Zanello, Piero |e verfasserin |4 aut | |
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10.1007/s10876-005-0014-0 doi (DE-627)SPR014250055 (SPR)s10876-005-0014-0-e DE-627 ger DE-627 rakwb eng 500 ASE 31.00 bkl Collini, Davide verfasserin aut New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of the [$ Ni_{6} $(CO)12]2− dianion with [Rh(COD)Cl]2 (COD = cyclooctadiene) in acetone affords a mixture of bimetallic Ni–Rh clusters, mainly consisting of the new [$ Ni_{7} %$ Rh_{3} $(CO)18]3− and [$ Ni_{8} $Rh(CO)18]3− trianions. A study of the reactivity of [$ Ni_{7} %$ Rh_{3} $(CO)18]3− led to isolation of the new [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− anions. All these new bimetallic Ni–Rh carbonyl clusters have been isolated in the solid state as tetrasubstituted ammonium salts and have been characterised by elemental analysis, X-ray diffraction studies, ESI-MS and electrochemistry. The unit cell of the [$ NEt_{4} $]3[$ Ni_{7} %$ Rh_{3} $(CO)18] salt contains two orientationally-disordered $ ν_{2} $-tetrahedral [$ Ni_{7} %$ Rh_{3} $(CO)18]3− trianions with occupancy factors of 0.75 and 0.25. Besides, their inner $ Ni_{3} %$ Rh_{3} $ octahedral moieties show two cis sites purely occupied by Rh atoms, two trans sites purely occupied by Ni atoms and the remaining two cis sites are disordered Ni and Rh sites with respective occupancy fraction of 0.5. At difference from the parent [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, the octahedral [$ Ni_{3} %$ Rh_{3} $(CO)13]3− displays an ordered distribution of Ni and Rh atoms in two staggered triangles. The [$ NiRh_{8} $(CO)19]2− dianion adopts an isomeric metal frame with respect to that of the [$ PtRh_{8} $(CO)19]2− congener. As a fallout of this work, new high-yield synthesis of the known [$ Ni_{6} %$ Rh_{3} $(CO)17]3− and [$ Ni_{6} %$ Rh_{5} $(CO)21]3−, as well as other currently-investigated bimetallic Ni–Rh clusters have been obtained. Carbonyl compound (dpeaa)DE-He213 bimetallic cluster (dpeaa)DE-He213 X-ray structure (dpeaa)DE-He213 redox behaviour (dpeaa)DE-He213 Fedi, Serena verfasserin aut Femoni, Cristina verfasserin aut Kaswalder, Francesco verfasserin aut Iapalucci, Maria Carmela verfasserin aut Longoni, Giuliano verfasserin aut Zanello, Piero verfasserin aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 16(2005), 3 vom: Sept., Seite 455-476 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:16 year:2005 number:3 month:09 pages:455-476 https://dx.doi.org/10.1007/s10876-005-0014-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-MAT SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 31.00 ASE AR 16 2005 3 09 455-476 |
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10.1007/s10876-005-0014-0 doi (DE-627)SPR014250055 (SPR)s10876-005-0014-0-e DE-627 ger DE-627 rakwb eng 500 ASE 31.00 bkl Collini, Davide verfasserin aut New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of the [$ Ni_{6} $(CO)12]2− dianion with [Rh(COD)Cl]2 (COD = cyclooctadiene) in acetone affords a mixture of bimetallic Ni–Rh clusters, mainly consisting of the new [$ Ni_{7} %$ Rh_{3} $(CO)18]3− and [$ Ni_{8} $Rh(CO)18]3− trianions. A study of the reactivity of [$ Ni_{7} %$ Rh_{3} $(CO)18]3− led to isolation of the new [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− anions. All these new bimetallic Ni–Rh carbonyl clusters have been isolated in the solid state as tetrasubstituted ammonium salts and have been characterised by elemental analysis, X-ray diffraction studies, ESI-MS and electrochemistry. The unit cell of the [$ NEt_{4} $]3[$ Ni_{7} %$ Rh_{3} $(CO)18] salt contains two orientationally-disordered $ ν_{2} $-tetrahedral [$ Ni_{7} %$ Rh_{3} $(CO)18]3− trianions with occupancy factors of 0.75 and 0.25. Besides, their inner $ Ni_{3} %$ Rh_{3} $ octahedral moieties show two cis sites purely occupied by Rh atoms, two trans sites purely occupied by Ni atoms and the remaining two cis sites are disordered Ni and Rh sites with respective occupancy fraction of 0.5. At difference from the parent [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, the octahedral [$ Ni_{3} %$ Rh_{3} $(CO)13]3− displays an ordered distribution of Ni and Rh atoms in two staggered triangles. The [$ NiRh_{8} $(CO)19]2− dianion adopts an isomeric metal frame with respect to that of the [$ PtRh_{8} $(CO)19]2− congener. As a fallout of this work, new high-yield synthesis of the known [$ Ni_{6} %$ Rh_{3} $(CO)17]3− and [$ Ni_{6} %$ Rh_{5} $(CO)21]3−, as well as other currently-investigated bimetallic Ni–Rh clusters have been obtained. Carbonyl compound (dpeaa)DE-He213 bimetallic cluster (dpeaa)DE-He213 X-ray structure (dpeaa)DE-He213 redox behaviour (dpeaa)DE-He213 Fedi, Serena verfasserin aut Femoni, Cristina verfasserin aut Kaswalder, Francesco verfasserin aut Iapalucci, Maria Carmela verfasserin aut Longoni, Giuliano verfasserin aut Zanello, Piero verfasserin aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 16(2005), 3 vom: Sept., Seite 455-476 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:16 year:2005 number:3 month:09 pages:455-476 https://dx.doi.org/10.1007/s10876-005-0014-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-MAT SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 31.00 ASE AR 16 2005 3 09 455-476 |
| allfields_unstemmed |
10.1007/s10876-005-0014-0 doi (DE-627)SPR014250055 (SPR)s10876-005-0014-0-e DE-627 ger DE-627 rakwb eng 500 ASE 31.00 bkl Collini, Davide verfasserin aut New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of the [$ Ni_{6} $(CO)12]2− dianion with [Rh(COD)Cl]2 (COD = cyclooctadiene) in acetone affords a mixture of bimetallic Ni–Rh clusters, mainly consisting of the new [$ Ni_{7} %$ Rh_{3} $(CO)18]3− and [$ Ni_{8} $Rh(CO)18]3− trianions. A study of the reactivity of [$ Ni_{7} %$ Rh_{3} $(CO)18]3− led to isolation of the new [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− anions. All these new bimetallic Ni–Rh carbonyl clusters have been isolated in the solid state as tetrasubstituted ammonium salts and have been characterised by elemental analysis, X-ray diffraction studies, ESI-MS and electrochemistry. The unit cell of the [$ NEt_{4} $]3[$ Ni_{7} %$ Rh_{3} $(CO)18] salt contains two orientationally-disordered $ ν_{2} $-tetrahedral [$ Ni_{7} %$ Rh_{3} $(CO)18]3− trianions with occupancy factors of 0.75 and 0.25. Besides, their inner $ Ni_{3} %$ Rh_{3} $ octahedral moieties show two cis sites purely occupied by Rh atoms, two trans sites purely occupied by Ni atoms and the remaining two cis sites are disordered Ni and Rh sites with respective occupancy fraction of 0.5. At difference from the parent [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, the octahedral [$ Ni_{3} %$ Rh_{3} $(CO)13]3− displays an ordered distribution of Ni and Rh atoms in two staggered triangles. The [$ NiRh_{8} $(CO)19]2− dianion adopts an isomeric metal frame with respect to that of the [$ PtRh_{8} $(CO)19]2− congener. As a fallout of this work, new high-yield synthesis of the known [$ Ni_{6} %$ Rh_{3} $(CO)17]3− and [$ Ni_{6} %$ Rh_{5} $(CO)21]3−, as well as other currently-investigated bimetallic Ni–Rh clusters have been obtained. Carbonyl compound (dpeaa)DE-He213 bimetallic cluster (dpeaa)DE-He213 X-ray structure (dpeaa)DE-He213 redox behaviour (dpeaa)DE-He213 Fedi, Serena verfasserin aut Femoni, Cristina verfasserin aut Kaswalder, Francesco verfasserin aut Iapalucci, Maria Carmela verfasserin aut Longoni, Giuliano verfasserin aut Zanello, Piero verfasserin aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 16(2005), 3 vom: Sept., Seite 455-476 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:16 year:2005 number:3 month:09 pages:455-476 https://dx.doi.org/10.1007/s10876-005-0014-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-MAT SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 31.00 ASE AR 16 2005 3 09 455-476 |
| allfieldsGer |
10.1007/s10876-005-0014-0 doi (DE-627)SPR014250055 (SPR)s10876-005-0014-0-e DE-627 ger DE-627 rakwb eng 500 ASE 31.00 bkl Collini, Davide verfasserin aut New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of the [$ Ni_{6} $(CO)12]2− dianion with [Rh(COD)Cl]2 (COD = cyclooctadiene) in acetone affords a mixture of bimetallic Ni–Rh clusters, mainly consisting of the new [$ Ni_{7} %$ Rh_{3} $(CO)18]3− and [$ Ni_{8} $Rh(CO)18]3− trianions. A study of the reactivity of [$ Ni_{7} %$ Rh_{3} $(CO)18]3− led to isolation of the new [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− anions. All these new bimetallic Ni–Rh carbonyl clusters have been isolated in the solid state as tetrasubstituted ammonium salts and have been characterised by elemental analysis, X-ray diffraction studies, ESI-MS and electrochemistry. The unit cell of the [$ NEt_{4} $]3[$ Ni_{7} %$ Rh_{3} $(CO)18] salt contains two orientationally-disordered $ ν_{2} $-tetrahedral [$ Ni_{7} %$ Rh_{3} $(CO)18]3− trianions with occupancy factors of 0.75 and 0.25. Besides, their inner $ Ni_{3} %$ Rh_{3} $ octahedral moieties show two cis sites purely occupied by Rh atoms, two trans sites purely occupied by Ni atoms and the remaining two cis sites are disordered Ni and Rh sites with respective occupancy fraction of 0.5. At difference from the parent [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, the octahedral [$ Ni_{3} %$ Rh_{3} $(CO)13]3− displays an ordered distribution of Ni and Rh atoms in two staggered triangles. The [$ NiRh_{8} $(CO)19]2− dianion adopts an isomeric metal frame with respect to that of the [$ PtRh_{8} $(CO)19]2− congener. As a fallout of this work, new high-yield synthesis of the known [$ Ni_{6} %$ Rh_{3} $(CO)17]3− and [$ Ni_{6} %$ Rh_{5} $(CO)21]3−, as well as other currently-investigated bimetallic Ni–Rh clusters have been obtained. Carbonyl compound (dpeaa)DE-He213 bimetallic cluster (dpeaa)DE-He213 X-ray structure (dpeaa)DE-He213 redox behaviour (dpeaa)DE-He213 Fedi, Serena verfasserin aut Femoni, Cristina verfasserin aut Kaswalder, Francesco verfasserin aut Iapalucci, Maria Carmela verfasserin aut Longoni, Giuliano verfasserin aut Zanello, Piero verfasserin aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 16(2005), 3 vom: Sept., Seite 455-476 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:16 year:2005 number:3 month:09 pages:455-476 https://dx.doi.org/10.1007/s10876-005-0014-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-MAT SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 31.00 ASE AR 16 2005 3 09 455-476 |
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10.1007/s10876-005-0014-0 doi (DE-627)SPR014250055 (SPR)s10876-005-0014-0-e DE-627 ger DE-627 rakwb eng 500 ASE 31.00 bkl Collini, Davide verfasserin aut New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of the [$ Ni_{6} $(CO)12]2− dianion with [Rh(COD)Cl]2 (COD = cyclooctadiene) in acetone affords a mixture of bimetallic Ni–Rh clusters, mainly consisting of the new [$ Ni_{7} %$ Rh_{3} $(CO)18]3− and [$ Ni_{8} $Rh(CO)18]3− trianions. A study of the reactivity of [$ Ni_{7} %$ Rh_{3} $(CO)18]3− led to isolation of the new [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− anions. All these new bimetallic Ni–Rh carbonyl clusters have been isolated in the solid state as tetrasubstituted ammonium salts and have been characterised by elemental analysis, X-ray diffraction studies, ESI-MS and electrochemistry. The unit cell of the [$ NEt_{4} $]3[$ Ni_{7} %$ Rh_{3} $(CO)18] salt contains two orientationally-disordered $ ν_{2} $-tetrahedral [$ Ni_{7} %$ Rh_{3} $(CO)18]3− trianions with occupancy factors of 0.75 and 0.25. Besides, their inner $ Ni_{3} %$ Rh_{3} $ octahedral moieties show two cis sites purely occupied by Rh atoms, two trans sites purely occupied by Ni atoms and the remaining two cis sites are disordered Ni and Rh sites with respective occupancy fraction of 0.5. At difference from the parent [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, the octahedral [$ Ni_{3} %$ Rh_{3} $(CO)13]3− displays an ordered distribution of Ni and Rh atoms in two staggered triangles. The [$ NiRh_{8} $(CO)19]2− dianion adopts an isomeric metal frame with respect to that of the [$ PtRh_{8} $(CO)19]2− congener. As a fallout of this work, new high-yield synthesis of the known [$ Ni_{6} %$ Rh_{3} $(CO)17]3− and [$ Ni_{6} %$ Rh_{5} $(CO)21]3−, as well as other currently-investigated bimetallic Ni–Rh clusters have been obtained. Carbonyl compound (dpeaa)DE-He213 bimetallic cluster (dpeaa)DE-He213 X-ray structure (dpeaa)DE-He213 redox behaviour (dpeaa)DE-He213 Fedi, Serena verfasserin aut Femoni, Cristina verfasserin aut Kaswalder, Francesco verfasserin aut Iapalucci, Maria Carmela verfasserin aut Longoni, Giuliano verfasserin aut Zanello, Piero verfasserin aut Enthalten in Journal of cluster science New York, NY : Springer Science + Business Media B.V., 1990 16(2005), 3 vom: Sept., Seite 455-476 (DE-627)320573427 (DE-600)2016762-3 1572-8862 nnns volume:16 year:2005 number:3 month:09 pages:455-476 https://dx.doi.org/10.1007/s10876-005-0014-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-MAT SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 31.00 ASE AR 16 2005 3 09 455-476 |
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Enthalten in Journal of cluster science 16(2005), 3 vom: Sept., Seite 455-476 volume:16 year:2005 number:3 month:09 pages:455-476 |
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Carbonyl compound bimetallic cluster X-ray structure redox behaviour |
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Journal of cluster science |
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Collini, Davide @@aut@@ Fedi, Serena @@aut@@ Femoni, Cristina @@aut@@ Kaswalder, Francesco @@aut@@ Iapalucci, Maria Carmela @@aut@@ Longoni, Giuliano @@aut@@ Zanello, Piero @@aut@@ |
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| author |
Collini, Davide |
| spellingShingle |
Collini, Davide ddc 500 bkl 31.00 misc Carbonyl compound misc bimetallic cluster misc X-ray structure misc redox behaviour New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions |
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Collini, Davide |
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500 - Natural sciences & mathematics |
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1572-8862 |
| topic_title |
500 ASE 31.00 bkl New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions Carbonyl compound (dpeaa)DE-He213 bimetallic cluster (dpeaa)DE-He213 X-ray structure (dpeaa)DE-He213 redox behaviour (dpeaa)DE-He213 |
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ddc 500 bkl 31.00 misc Carbonyl compound misc bimetallic cluster misc X-ray structure misc redox behaviour |
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ddc 500 bkl 31.00 misc Carbonyl compound misc bimetallic cluster misc X-ray structure misc redox behaviour |
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ddc 500 bkl 31.00 misc Carbonyl compound misc bimetallic cluster misc X-ray structure misc redox behaviour |
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Elektronische Aufsätze Aufsätze Elektronische Ressource |
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Journal of cluster science |
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Journal of cluster science |
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| title |
New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions |
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(DE-627)SPR014250055 (SPR)s10876-005-0014-0-e |
| title_full |
New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions |
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Collini, Davide |
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Journal of cluster science |
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2005 |
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Collini, Davide Fedi, Serena Femoni, Cristina Kaswalder, Francesco Iapalucci, Maria Carmela Longoni, Giuliano Zanello, Piero |
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16 |
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Elektronische Aufsätze |
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Collini, Davide |
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10.1007/s10876-005-0014-0 |
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500 |
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verfasserin |
| title_sort |
new bimetallic ni–rh carbonyl clusters: synthesis and x-ray structure of the [$ ni_{7} %$ rh_{3} $(co)18]3−, [$ ni_{3} %$ rh_{3} $(co)13]3− and [$ nirh_{8} $(co)19]2− cluster anions |
| title_auth |
New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions |
| abstract |
Abstract The reaction of the [$ Ni_{6} $(CO)12]2− dianion with [Rh(COD)Cl]2 (COD = cyclooctadiene) in acetone affords a mixture of bimetallic Ni–Rh clusters, mainly consisting of the new [$ Ni_{7} %$ Rh_{3} $(CO)18]3− and [$ Ni_{8} $Rh(CO)18]3− trianions. A study of the reactivity of [$ Ni_{7} %$ Rh_{3} $(CO)18]3− led to isolation of the new [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− anions. All these new bimetallic Ni–Rh carbonyl clusters have been isolated in the solid state as tetrasubstituted ammonium salts and have been characterised by elemental analysis, X-ray diffraction studies, ESI-MS and electrochemistry. The unit cell of the [$ NEt_{4} $]3[$ Ni_{7} %$ Rh_{3} $(CO)18] salt contains two orientationally-disordered $ ν_{2} $-tetrahedral [$ Ni_{7} %$ Rh_{3} $(CO)18]3− trianions with occupancy factors of 0.75 and 0.25. Besides, their inner $ Ni_{3} %$ Rh_{3} $ octahedral moieties show two cis sites purely occupied by Rh atoms, two trans sites purely occupied by Ni atoms and the remaining two cis sites are disordered Ni and Rh sites with respective occupancy fraction of 0.5. At difference from the parent [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, the octahedral [$ Ni_{3} %$ Rh_{3} $(CO)13]3− displays an ordered distribution of Ni and Rh atoms in two staggered triangles. The [$ NiRh_{8} $(CO)19]2− dianion adopts an isomeric metal frame with respect to that of the [$ PtRh_{8} $(CO)19]2− congener. As a fallout of this work, new high-yield synthesis of the known [$ Ni_{6} %$ Rh_{3} $(CO)17]3− and [$ Ni_{6} %$ Rh_{5} $(CO)21]3−, as well as other currently-investigated bimetallic Ni–Rh clusters have been obtained. |
| abstractGer |
Abstract The reaction of the [$ Ni_{6} $(CO)12]2− dianion with [Rh(COD)Cl]2 (COD = cyclooctadiene) in acetone affords a mixture of bimetallic Ni–Rh clusters, mainly consisting of the new [$ Ni_{7} %$ Rh_{3} $(CO)18]3− and [$ Ni_{8} $Rh(CO)18]3− trianions. A study of the reactivity of [$ Ni_{7} %$ Rh_{3} $(CO)18]3− led to isolation of the new [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− anions. All these new bimetallic Ni–Rh carbonyl clusters have been isolated in the solid state as tetrasubstituted ammonium salts and have been characterised by elemental analysis, X-ray diffraction studies, ESI-MS and electrochemistry. The unit cell of the [$ NEt_{4} $]3[$ Ni_{7} %$ Rh_{3} $(CO)18] salt contains two orientationally-disordered $ ν_{2} $-tetrahedral [$ Ni_{7} %$ Rh_{3} $(CO)18]3− trianions with occupancy factors of 0.75 and 0.25. Besides, their inner $ Ni_{3} %$ Rh_{3} $ octahedral moieties show two cis sites purely occupied by Rh atoms, two trans sites purely occupied by Ni atoms and the remaining two cis sites are disordered Ni and Rh sites with respective occupancy fraction of 0.5. At difference from the parent [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, the octahedral [$ Ni_{3} %$ Rh_{3} $(CO)13]3− displays an ordered distribution of Ni and Rh atoms in two staggered triangles. The [$ NiRh_{8} $(CO)19]2− dianion adopts an isomeric metal frame with respect to that of the [$ PtRh_{8} $(CO)19]2− congener. As a fallout of this work, new high-yield synthesis of the known [$ Ni_{6} %$ Rh_{3} $(CO)17]3− and [$ Ni_{6} %$ Rh_{5} $(CO)21]3−, as well as other currently-investigated bimetallic Ni–Rh clusters have been obtained. |
| abstract_unstemmed |
Abstract The reaction of the [$ Ni_{6} $(CO)12]2− dianion with [Rh(COD)Cl]2 (COD = cyclooctadiene) in acetone affords a mixture of bimetallic Ni–Rh clusters, mainly consisting of the new [$ Ni_{7} %$ Rh_{3} $(CO)18]3− and [$ Ni_{8} $Rh(CO)18]3− trianions. A study of the reactivity of [$ Ni_{7} %$ Rh_{3} $(CO)18]3− led to isolation of the new [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− anions. All these new bimetallic Ni–Rh carbonyl clusters have been isolated in the solid state as tetrasubstituted ammonium salts and have been characterised by elemental analysis, X-ray diffraction studies, ESI-MS and electrochemistry. The unit cell of the [$ NEt_{4} $]3[$ Ni_{7} %$ Rh_{3} $(CO)18] salt contains two orientationally-disordered $ ν_{2} $-tetrahedral [$ Ni_{7} %$ Rh_{3} $(CO)18]3− trianions with occupancy factors of 0.75 and 0.25. Besides, their inner $ Ni_{3} %$ Rh_{3} $ octahedral moieties show two cis sites purely occupied by Rh atoms, two trans sites purely occupied by Ni atoms and the remaining two cis sites are disordered Ni and Rh sites with respective occupancy fraction of 0.5. At difference from the parent [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, the octahedral [$ Ni_{3} %$ Rh_{3} $(CO)13]3− displays an ordered distribution of Ni and Rh atoms in two staggered triangles. The [$ NiRh_{8} $(CO)19]2− dianion adopts an isomeric metal frame with respect to that of the [$ PtRh_{8} $(CO)19]2− congener. As a fallout of this work, new high-yield synthesis of the known [$ Ni_{6} %$ Rh_{3} $(CO)17]3− and [$ Ni_{6} %$ Rh_{5} $(CO)21]3−, as well as other currently-investigated bimetallic Ni–Rh clusters have been obtained. |
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New Bimetallic Ni–Rh Carbonyl Clusters: Synthesis and X-ray Structure of the [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− Cluster Anions |
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https://dx.doi.org/10.1007/s10876-005-0014-0 |
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Fedi, Serena Femoni, Cristina Kaswalder, Francesco Iapalucci, Maria Carmela Longoni, Giuliano Zanello, Piero |
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Fedi, Serena Femoni, Cristina Kaswalder, Francesco Iapalucci, Maria Carmela Longoni, Giuliano Zanello, Piero |
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320573427 |
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| doi_str |
10.1007/s10876-005-0014-0 |
| up_date |
2024-07-04T00:51:34.422Z |
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1803607651829940225 |
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A study of the reactivity of [$ Ni_{7} %$ Rh_{3} $(CO)18]3− led to isolation of the new [$ Ni_{3} %$ Rh_{3} $(CO)13]3− and [$ NiRh_{8} $(CO)19]2− anions. All these new bimetallic Ni–Rh carbonyl clusters have been isolated in the solid state as tetrasubstituted ammonium salts and have been characterised by elemental analysis, X-ray diffraction studies, ESI-MS and electrochemistry. The unit cell of the [$ NEt_{4} $]3[$ Ni_{7} %$ Rh_{3} $(CO)18] salt contains two orientationally-disordered $ ν_{2} $-tetrahedral [$ Ni_{7} %$ Rh_{3} $(CO)18]3− trianions with occupancy factors of 0.75 and 0.25. Besides, their inner $ Ni_{3} %$ Rh_{3} $ octahedral moieties show two cis sites purely occupied by Rh atoms, two trans sites purely occupied by Ni atoms and the remaining two cis sites are disordered Ni and Rh sites with respective occupancy fraction of 0.5. At difference from the parent [$ Ni_{7} %$ Rh_{3} $(CO)18]3−, the octahedral [$ Ni_{3} %$ Rh_{3} $(CO)13]3− displays an ordered distribution of Ni and Rh atoms in two staggered triangles. The [$ NiRh_{8} $(CO)19]2− dianion adopts an isomeric metal frame with respect to that of the [$ PtRh_{8} $(CO)19]2− congener. As a fallout of this work, new high-yield synthesis of the known [$ Ni_{6} %$ Rh_{3} $(CO)17]3− and [$ Ni_{6} %$ Rh_{5} $(CO)21]3−, as well as other currently-investigated bimetallic Ni–Rh clusters have been obtained.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Carbonyl compound</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">bimetallic cluster</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">X-ray structure</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">redox behaviour</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Fedi, Serena</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" 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