Entropic descriptors of quantum communications in molecules

Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT addition...
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Autor*in:	Nalewajski, Roman F. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2014

Schlagwörter:	Bond multiplicity descriptors Communication systems Local communications Orbital communications Probability/current distributions Quantum information measures

Übergeordnetes Werk:	Enthalten in: Journal of mathematical chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1987, 53(2014), 1 vom: 25. Okt., Seite 1-28
Übergeordnetes Werk:	volume:53 ; year:2014 ; number:1 ; day:25 ; month:10 ; pages:1-28

Links:	Volltext

DOI / URN:	10.1007/s10910-014-0405-2

Katalog-ID:	SPR014552388

Internformat


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520			\|a Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT.
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912			\|a GBV_ILN_187
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912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
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Indexfelder

author_variant	r f n rf rfn
matchkey_str	article:15728897:2014----::nrpcecitroqatmomnct
hierarchy_sort_str	2014
bklnumber	35.05
publishDate	2014
allfields	10.1007/s10910-014-0405-2 doi (DE-627)SPR014552388 (SPR)s10910-014-0405-2-e DE-627 ger DE-627 rakwb eng 540 510 ASE 35.05 bkl Nalewajski, Roman F. verfasserin aut Entropic descriptors of quantum communications in molecules 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. Bond multiplicity descriptors (dpeaa)DE-He213 Communication systems (dpeaa)DE-He213 Local communications (dpeaa)DE-He213 Orbital communications (dpeaa)DE-He213 Probability/current distributions (dpeaa)DE-He213 Quantum information measures (dpeaa)DE-He213 Enthalten in Journal of mathematical chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1987 53(2014), 1 vom: 25. Okt., Seite 1-28 (DE-627)30246879X (DE-600)1491406-2 1572-8897 nnns volume:53 year:2014 number:1 day:25 month:10 pages:1-28 https://dx.doi.org/10.1007/s10910-014-0405-2 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-MAT SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.05 ASE AR 53 2014 1 25 10 1-28
spelling	10.1007/s10910-014-0405-2 doi (DE-627)SPR014552388 (SPR)s10910-014-0405-2-e DE-627 ger DE-627 rakwb eng 540 510 ASE 35.05 bkl Nalewajski, Roman F. verfasserin aut Entropic descriptors of quantum communications in molecules 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. Bond multiplicity descriptors (dpeaa)DE-He213 Communication systems (dpeaa)DE-He213 Local communications (dpeaa)DE-He213 Orbital communications (dpeaa)DE-He213 Probability/current distributions (dpeaa)DE-He213 Quantum information measures (dpeaa)DE-He213 Enthalten in Journal of mathematical chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1987 53(2014), 1 vom: 25. Okt., Seite 1-28 (DE-627)30246879X (DE-600)1491406-2 1572-8897 nnns volume:53 year:2014 number:1 day:25 month:10 pages:1-28 https://dx.doi.org/10.1007/s10910-014-0405-2 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-MAT SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.05 ASE AR 53 2014 1 25 10 1-28
allfields_unstemmed	10.1007/s10910-014-0405-2 doi (DE-627)SPR014552388 (SPR)s10910-014-0405-2-e DE-627 ger DE-627 rakwb eng 540 510 ASE 35.05 bkl Nalewajski, Roman F. verfasserin aut Entropic descriptors of quantum communications in molecules 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. Bond multiplicity descriptors (dpeaa)DE-He213 Communication systems (dpeaa)DE-He213 Local communications (dpeaa)DE-He213 Orbital communications (dpeaa)DE-He213 Probability/current distributions (dpeaa)DE-He213 Quantum information measures (dpeaa)DE-He213 Enthalten in Journal of mathematical chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1987 53(2014), 1 vom: 25. Okt., Seite 1-28 (DE-627)30246879X (DE-600)1491406-2 1572-8897 nnns volume:53 year:2014 number:1 day:25 month:10 pages:1-28 https://dx.doi.org/10.1007/s10910-014-0405-2 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-MAT SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.05 ASE AR 53 2014 1 25 10 1-28
allfieldsGer	10.1007/s10910-014-0405-2 doi (DE-627)SPR014552388 (SPR)s10910-014-0405-2-e DE-627 ger DE-627 rakwb eng 540 510 ASE 35.05 bkl Nalewajski, Roman F. verfasserin aut Entropic descriptors of quantum communications in molecules 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. Bond multiplicity descriptors (dpeaa)DE-He213 Communication systems (dpeaa)DE-He213 Local communications (dpeaa)DE-He213 Orbital communications (dpeaa)DE-He213 Probability/current distributions (dpeaa)DE-He213 Quantum information measures (dpeaa)DE-He213 Enthalten in Journal of mathematical chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1987 53(2014), 1 vom: 25. Okt., Seite 1-28 (DE-627)30246879X (DE-600)1491406-2 1572-8897 nnns volume:53 year:2014 number:1 day:25 month:10 pages:1-28 https://dx.doi.org/10.1007/s10910-014-0405-2 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-MAT SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.05 ASE AR 53 2014 1 25 10 1-28
allfieldsSound	10.1007/s10910-014-0405-2 doi (DE-627)SPR014552388 (SPR)s10910-014-0405-2-e DE-627 ger DE-627 rakwb eng 540 510 ASE 35.05 bkl Nalewajski, Roman F. verfasserin aut Entropic descriptors of quantum communications in molecules 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT. Bond multiplicity descriptors (dpeaa)DE-He213 Communication systems (dpeaa)DE-He213 Local communications (dpeaa)DE-He213 Orbital communications (dpeaa)DE-He213 Probability/current distributions (dpeaa)DE-He213 Quantum information measures (dpeaa)DE-He213 Enthalten in Journal of mathematical chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1987 53(2014), 1 vom: 25. Okt., Seite 1-28 (DE-627)30246879X (DE-600)1491406-2 1572-8897 nnns volume:53 year:2014 number:1 day:25 month:10 pages:1-28 https://dx.doi.org/10.1007/s10910-014-0405-2 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-MAT SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.05 ASE AR 53 2014 1 25 10 1-28
language	English
source	Enthalten in Journal of mathematical chemistry 53(2014), 1 vom: 25. Okt., Seite 1-28 volume:53 year:2014 number:1 day:25 month:10 pages:1-28
sourceStr	Enthalten in Journal of mathematical chemistry 53(2014), 1 vom: 25. Okt., Seite 1-28 volume:53 year:2014 number:1 day:25 month:10 pages:1-28
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Bond multiplicity descriptors Communication systems Local communications Orbital communications Probability/current distributions Quantum information measures
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container_title	Journal of mathematical chemistry
authorswithroles_txt_mv	Nalewajski, Roman F. @@aut@@
publishDateDaySort_date	2014-10-25T00:00:00Z
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author	Nalewajski, Roman F.
spellingShingle	Nalewajski, Roman F. ddc 540 bkl 35.05 misc Bond multiplicity descriptors misc Communication systems misc Local communications misc Orbital communications misc Probability/current distributions misc Quantum information measures Entropic descriptors of quantum communications in molecules
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topic_title	540 510 ASE 35.05 bkl Entropic descriptors of quantum communications in molecules Bond multiplicity descriptors (dpeaa)DE-He213 Communication systems (dpeaa)DE-He213 Local communications (dpeaa)DE-He213 Orbital communications (dpeaa)DE-He213 Probability/current distributions (dpeaa)DE-He213 Quantum information measures (dpeaa)DE-He213
topic	ddc 540 bkl 35.05 misc Bond multiplicity descriptors misc Communication systems misc Local communications misc Orbital communications misc Probability/current distributions misc Quantum information measures
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title_full	Entropic descriptors of quantum communications in molecules
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title_sort	entropic descriptors of quantum communications in molecules
title_auth	Entropic descriptors of quantum communications in molecules
abstract	Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT.
abstractGer	Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT.
abstract_unstemmed	Abstract The classical Information Theory (IT) deals with entropic descriptors of the probability distributions and probability-propagation (communication) systems, e.g., the electronic channels in molecules reflecting the information scattering via the system chemical bonds. The quantum IT additionally accounts for the non-classical (current/phase)-related contributions in the resultant information content of electronic states. The classical and non-classical terms in the quantum Shannon entropy and Fisher information are reexamined. The associated probability-propagation and current-scattering networks are introduced and their Fisher- and Shannon-type descriptors are identified. The non-additive and additive information descriptors of the probability channels in both the Atomic Orbital and local resolution levels are related to the network conditional-entropy and mutual-information, which represent the IT covalency and ionicity components in the classical communication theory of the chemical bond. A similar partition identifies the associated bond indices in the molecular current/phase channels. The resultant bond descriptors combining the classical and non-classical terms, due to the probability and current distributions, respectively, are proposed as generalized communication-noise (covalency) and information-flow (iconicity) concepts in the quantum IT.
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title_short	Entropic descriptors of quantum communications in molecules
url	https://dx.doi.org/10.1007/s10910-014-0405-2
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doi_str	10.1007/s10910-014-0405-2
up_date	2024-07-04T02:13:42.759Z
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