Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode
Abstract The electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode was studied in this work. The experimental results showed that as a non-active electrode with high oxygen potential, Ti/Sb–$ SnO_{2} $ electrode had a good efficiency for degrading chitosan. The kinetic behavior o...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Gu, Zhiming [verfasserIn] Cai, Quanyuan [verfasserIn] Liu, Yan [verfasserIn] Li, Fengsheng [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2012 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of polymers and the environment - New York, NY [u.a.] : Springer Science + Business Media B.V., 1993, 21(2012), 2 vom: 15. Sept., Seite 479-486 |
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| Übergeordnetes Werk: |
volume:21 ; year:2012 ; number:2 ; day:15 ; month:09 ; pages:479-486 |
| Links: |
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| DOI / URN: |
10.1007/s10924-012-0532-4 |
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| Katalog-ID: |
SPR014671751 |
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| 245 | 1 | 0 | |a Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode |
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| 520 | |a Abstract The electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode was studied in this work. The experimental results showed that as a non-active electrode with high oxygen potential, Ti/Sb–$ SnO_{2} $ electrode had a good efficiency for degrading chitosan. The kinetic behavior of electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode and the function relationship between experimental parameters and degradation rate constant were also investigated. The kinetic analysis revealed that this electrochemical process using Ti/Sb–$ SnO_{2} $ electrode obeyed the zeroth–order reaction kinetics under the experimental conditions examined. The degradation rate constant at Ti/Sb–$ SnO_{2} $ electrode had the linear relationship with 1.13 power of current density, −1.36 power of initial concentration of chitosan and 0.19 power of concentration of acetic acid, The temperature dependences of the degradation rate constant could be expressed by the Arrhenius equation. The concentration of sodium acetate had a negligible influence on the degradation rate constant. | ||
| 650 | 4 | |a Chitosan |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Electrochemical |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Degradation |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Ti/Sb–SnO |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a electrode |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Kinetics |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Cai, Quanyuan |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Yan |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Fengsheng |e verfasserin |4 aut | |
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10.1007/s10924-012-0532-4 doi (DE-627)SPR014671751 (SPR)s10924-012-0532-4-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 58.53 bkl 58.52 bkl 43.50 bkl Gu, Zhiming verfasserin aut Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode was studied in this work. The experimental results showed that as a non-active electrode with high oxygen potential, Ti/Sb–$ SnO_{2} $ electrode had a good efficiency for degrading chitosan. The kinetic behavior of electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode and the function relationship between experimental parameters and degradation rate constant were also investigated. The kinetic analysis revealed that this electrochemical process using Ti/Sb–$ SnO_{2} $ electrode obeyed the zeroth–order reaction kinetics under the experimental conditions examined. The degradation rate constant at Ti/Sb–$ SnO_{2} $ electrode had the linear relationship with 1.13 power of current density, −1.36 power of initial concentration of chitosan and 0.19 power of concentration of acetic acid, The temperature dependences of the degradation rate constant could be expressed by the Arrhenius equation. The concentration of sodium acetate had a negligible influence on the degradation rate constant. Chitosan (dpeaa)DE-He213 Electrochemical (dpeaa)DE-He213 Degradation (dpeaa)DE-He213 Ti/Sb–SnO (dpeaa)DE-He213 electrode (dpeaa)DE-He213 Kinetics (dpeaa)DE-He213 Cai, Quanyuan verfasserin aut Liu, Yan verfasserin aut Li, Fengsheng verfasserin aut Enthalten in Journal of polymers and the environment New York, NY [u.a.] : Springer Science + Business Media B.V., 1993 21(2012), 2 vom: 15. Sept., Seite 479-486 (DE-627)320577716 (DE-600)2017207-2 1572-8900 nnns volume:21 year:2012 number:2 day:15 month:09 pages:479-486 https://dx.doi.org/10.1007/s10924-012-0532-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.53 ASE 58.52 ASE 43.50 ASE AR 21 2012 2 15 09 479-486 |
| spelling |
10.1007/s10924-012-0532-4 doi (DE-627)SPR014671751 (SPR)s10924-012-0532-4-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 58.53 bkl 58.52 bkl 43.50 bkl Gu, Zhiming verfasserin aut Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode was studied in this work. The experimental results showed that as a non-active electrode with high oxygen potential, Ti/Sb–$ SnO_{2} $ electrode had a good efficiency for degrading chitosan. The kinetic behavior of electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode and the function relationship between experimental parameters and degradation rate constant were also investigated. The kinetic analysis revealed that this electrochemical process using Ti/Sb–$ SnO_{2} $ electrode obeyed the zeroth–order reaction kinetics under the experimental conditions examined. The degradation rate constant at Ti/Sb–$ SnO_{2} $ electrode had the linear relationship with 1.13 power of current density, −1.36 power of initial concentration of chitosan and 0.19 power of concentration of acetic acid, The temperature dependences of the degradation rate constant could be expressed by the Arrhenius equation. The concentration of sodium acetate had a negligible influence on the degradation rate constant. Chitosan (dpeaa)DE-He213 Electrochemical (dpeaa)DE-He213 Degradation (dpeaa)DE-He213 Ti/Sb–SnO (dpeaa)DE-He213 electrode (dpeaa)DE-He213 Kinetics (dpeaa)DE-He213 Cai, Quanyuan verfasserin aut Liu, Yan verfasserin aut Li, Fengsheng verfasserin aut Enthalten in Journal of polymers and the environment New York, NY [u.a.] : Springer Science + Business Media B.V., 1993 21(2012), 2 vom: 15. Sept., Seite 479-486 (DE-627)320577716 (DE-600)2017207-2 1572-8900 nnns volume:21 year:2012 number:2 day:15 month:09 pages:479-486 https://dx.doi.org/10.1007/s10924-012-0532-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.53 ASE 58.52 ASE 43.50 ASE AR 21 2012 2 15 09 479-486 |
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10.1007/s10924-012-0532-4 doi (DE-627)SPR014671751 (SPR)s10924-012-0532-4-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 58.53 bkl 58.52 bkl 43.50 bkl Gu, Zhiming verfasserin aut Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode was studied in this work. The experimental results showed that as a non-active electrode with high oxygen potential, Ti/Sb–$ SnO_{2} $ electrode had a good efficiency for degrading chitosan. The kinetic behavior of electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode and the function relationship between experimental parameters and degradation rate constant were also investigated. The kinetic analysis revealed that this electrochemical process using Ti/Sb–$ SnO_{2} $ electrode obeyed the zeroth–order reaction kinetics under the experimental conditions examined. The degradation rate constant at Ti/Sb–$ SnO_{2} $ electrode had the linear relationship with 1.13 power of current density, −1.36 power of initial concentration of chitosan and 0.19 power of concentration of acetic acid, The temperature dependences of the degradation rate constant could be expressed by the Arrhenius equation. The concentration of sodium acetate had a negligible influence on the degradation rate constant. Chitosan (dpeaa)DE-He213 Electrochemical (dpeaa)DE-He213 Degradation (dpeaa)DE-He213 Ti/Sb–SnO (dpeaa)DE-He213 electrode (dpeaa)DE-He213 Kinetics (dpeaa)DE-He213 Cai, Quanyuan verfasserin aut Liu, Yan verfasserin aut Li, Fengsheng verfasserin aut Enthalten in Journal of polymers and the environment New York, NY [u.a.] : Springer Science + Business Media B.V., 1993 21(2012), 2 vom: 15. Sept., Seite 479-486 (DE-627)320577716 (DE-600)2017207-2 1572-8900 nnns volume:21 year:2012 number:2 day:15 month:09 pages:479-486 https://dx.doi.org/10.1007/s10924-012-0532-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.53 ASE 58.52 ASE 43.50 ASE AR 21 2012 2 15 09 479-486 |
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10.1007/s10924-012-0532-4 doi (DE-627)SPR014671751 (SPR)s10924-012-0532-4-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 58.53 bkl 58.52 bkl 43.50 bkl Gu, Zhiming verfasserin aut Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode was studied in this work. The experimental results showed that as a non-active electrode with high oxygen potential, Ti/Sb–$ SnO_{2} $ electrode had a good efficiency for degrading chitosan. The kinetic behavior of electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode and the function relationship between experimental parameters and degradation rate constant were also investigated. The kinetic analysis revealed that this electrochemical process using Ti/Sb–$ SnO_{2} $ electrode obeyed the zeroth–order reaction kinetics under the experimental conditions examined. The degradation rate constant at Ti/Sb–$ SnO_{2} $ electrode had the linear relationship with 1.13 power of current density, −1.36 power of initial concentration of chitosan and 0.19 power of concentration of acetic acid, The temperature dependences of the degradation rate constant could be expressed by the Arrhenius equation. The concentration of sodium acetate had a negligible influence on the degradation rate constant. Chitosan (dpeaa)DE-He213 Electrochemical (dpeaa)DE-He213 Degradation (dpeaa)DE-He213 Ti/Sb–SnO (dpeaa)DE-He213 electrode (dpeaa)DE-He213 Kinetics (dpeaa)DE-He213 Cai, Quanyuan verfasserin aut Liu, Yan verfasserin aut Li, Fengsheng verfasserin aut Enthalten in Journal of polymers and the environment New York, NY [u.a.] : Springer Science + Business Media B.V., 1993 21(2012), 2 vom: 15. Sept., Seite 479-486 (DE-627)320577716 (DE-600)2017207-2 1572-8900 nnns volume:21 year:2012 number:2 day:15 month:09 pages:479-486 https://dx.doi.org/10.1007/s10924-012-0532-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.53 ASE 58.52 ASE 43.50 ASE AR 21 2012 2 15 09 479-486 |
| allfieldsSound |
10.1007/s10924-012-0532-4 doi (DE-627)SPR014671751 (SPR)s10924-012-0532-4-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 58.53 bkl 58.52 bkl 43.50 bkl Gu, Zhiming verfasserin aut Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode was studied in this work. The experimental results showed that as a non-active electrode with high oxygen potential, Ti/Sb–$ SnO_{2} $ electrode had a good efficiency for degrading chitosan. The kinetic behavior of electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode and the function relationship between experimental parameters and degradation rate constant were also investigated. The kinetic analysis revealed that this electrochemical process using Ti/Sb–$ SnO_{2} $ electrode obeyed the zeroth–order reaction kinetics under the experimental conditions examined. The degradation rate constant at Ti/Sb–$ SnO_{2} $ electrode had the linear relationship with 1.13 power of current density, −1.36 power of initial concentration of chitosan and 0.19 power of concentration of acetic acid, The temperature dependences of the degradation rate constant could be expressed by the Arrhenius equation. The concentration of sodium acetate had a negligible influence on the degradation rate constant. Chitosan (dpeaa)DE-He213 Electrochemical (dpeaa)DE-He213 Degradation (dpeaa)DE-He213 Ti/Sb–SnO (dpeaa)DE-He213 electrode (dpeaa)DE-He213 Kinetics (dpeaa)DE-He213 Cai, Quanyuan verfasserin aut Liu, Yan verfasserin aut Li, Fengsheng verfasserin aut Enthalten in Journal of polymers and the environment New York, NY [u.a.] : Springer Science + Business Media B.V., 1993 21(2012), 2 vom: 15. Sept., Seite 479-486 (DE-627)320577716 (DE-600)2017207-2 1572-8900 nnns volume:21 year:2012 number:2 day:15 month:09 pages:479-486 https://dx.doi.org/10.1007/s10924-012-0532-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.53 ASE 58.52 ASE 43.50 ASE AR 21 2012 2 15 09 479-486 |
| language |
English |
| source |
Enthalten in Journal of polymers and the environment 21(2012), 2 vom: 15. Sept., Seite 479-486 volume:21 year:2012 number:2 day:15 month:09 pages:479-486 |
| sourceStr |
Enthalten in Journal of polymers and the environment 21(2012), 2 vom: 15. Sept., Seite 479-486 volume:21 year:2012 number:2 day:15 month:09 pages:479-486 |
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findex.gbv.de |
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Chitosan Electrochemical Degradation Ti/Sb–SnO electrode Kinetics |
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false |
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Journal of polymers and the environment |
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Gu, Zhiming @@aut@@ Cai, Quanyuan @@aut@@ Liu, Yan @@aut@@ Li, Fengsheng @@aut@@ |
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2012-09-15T00:00:00Z |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR014671751</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519192951.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2012 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10924-012-0532-4</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR014671751</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10924-012-0532-4-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.53</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.52</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">43.50</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Gu, Zhiming</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2012</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode was studied in this work. The experimental results showed that as a non-active electrode with high oxygen potential, Ti/Sb–$ SnO_{2} $ electrode had a good efficiency for degrading chitosan. The kinetic behavior of electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode and the function relationship between experimental parameters and degradation rate constant were also investigated. The kinetic analysis revealed that this electrochemical process using Ti/Sb–$ SnO_{2} $ electrode obeyed the zeroth–order reaction kinetics under the experimental conditions examined. The degradation rate constant at Ti/Sb–$ SnO_{2} $ electrode had the linear relationship with 1.13 power of current density, −1.36 power of initial concentration of chitosan and 0.19 power of concentration of acetic acid, The temperature dependences of the degradation rate constant could be expressed by the Arrhenius equation. 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|
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Gu, Zhiming |
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Gu, Zhiming ddc 540 bkl 58.53 bkl 58.52 bkl 43.50 misc Chitosan misc Electrochemical misc Degradation misc Ti/Sb–SnO misc electrode misc Kinetics Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode |
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540 ASE 58.53 bkl 58.52 bkl 43.50 bkl Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode Chitosan (dpeaa)DE-He213 Electrochemical (dpeaa)DE-He213 Degradation (dpeaa)DE-He213 Ti/Sb–SnO (dpeaa)DE-He213 electrode (dpeaa)DE-He213 Kinetics (dpeaa)DE-He213 |
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ddc 540 bkl 58.53 bkl 58.52 bkl 43.50 misc Chitosan misc Electrochemical misc Degradation misc Ti/Sb–SnO misc electrode misc Kinetics |
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ddc 540 bkl 58.53 bkl 58.52 bkl 43.50 misc Chitosan misc Electrochemical misc Degradation misc Ti/Sb–SnO misc electrode misc Kinetics |
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Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode |
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Gu, Zhiming Cai, Quanyuan Liu, Yan Li, Fengsheng |
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electrochemical degradation of chitosan using ti/sb–$ sno_{2} $ electrode |
| title_auth |
Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode |
| abstract |
Abstract The electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode was studied in this work. The experimental results showed that as a non-active electrode with high oxygen potential, Ti/Sb–$ SnO_{2} $ electrode had a good efficiency for degrading chitosan. The kinetic behavior of electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode and the function relationship between experimental parameters and degradation rate constant were also investigated. The kinetic analysis revealed that this electrochemical process using Ti/Sb–$ SnO_{2} $ electrode obeyed the zeroth–order reaction kinetics under the experimental conditions examined. The degradation rate constant at Ti/Sb–$ SnO_{2} $ electrode had the linear relationship with 1.13 power of current density, −1.36 power of initial concentration of chitosan and 0.19 power of concentration of acetic acid, The temperature dependences of the degradation rate constant could be expressed by the Arrhenius equation. The concentration of sodium acetate had a negligible influence on the degradation rate constant. |
| abstractGer |
Abstract The electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode was studied in this work. The experimental results showed that as a non-active electrode with high oxygen potential, Ti/Sb–$ SnO_{2} $ electrode had a good efficiency for degrading chitosan. The kinetic behavior of electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode and the function relationship between experimental parameters and degradation rate constant were also investigated. The kinetic analysis revealed that this electrochemical process using Ti/Sb–$ SnO_{2} $ electrode obeyed the zeroth–order reaction kinetics under the experimental conditions examined. The degradation rate constant at Ti/Sb–$ SnO_{2} $ electrode had the linear relationship with 1.13 power of current density, −1.36 power of initial concentration of chitosan and 0.19 power of concentration of acetic acid, The temperature dependences of the degradation rate constant could be expressed by the Arrhenius equation. The concentration of sodium acetate had a negligible influence on the degradation rate constant. |
| abstract_unstemmed |
Abstract The electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode was studied in this work. The experimental results showed that as a non-active electrode with high oxygen potential, Ti/Sb–$ SnO_{2} $ electrode had a good efficiency for degrading chitosan. The kinetic behavior of electrochemical degradation of chitosan using Ti/Sb–$ SnO_{2} $ electrode and the function relationship between experimental parameters and degradation rate constant were also investigated. The kinetic analysis revealed that this electrochemical process using Ti/Sb–$ SnO_{2} $ electrode obeyed the zeroth–order reaction kinetics under the experimental conditions examined. The degradation rate constant at Ti/Sb–$ SnO_{2} $ electrode had the linear relationship with 1.13 power of current density, −1.36 power of initial concentration of chitosan and 0.19 power of concentration of acetic acid, The temperature dependences of the degradation rate constant could be expressed by the Arrhenius equation. The concentration of sodium acetate had a negligible influence on the degradation rate constant. |
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Electrochemical Degradation of Chitosan Using Ti/Sb–$ SnO_{2} $ Electrode |
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| score |
7.4004383 |