Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K
Abstract The densities of l-alanine and l-serine in aqueous solutions of N,N-dimethylformamide (DMF) have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes %$ (V_{\phi } ) %$, standard partial molar volumes %$ (V_{\phi }^{0} ) %$, standard partial molar volumes...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Liu, Chunli [verfasserIn] Zhou, Li [verfasserIn] Ma, Lin [verfasserIn] Lin, Ruisen [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2013 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of solution chemistry - New York, NY [u.a.] : Springer Science + Business Media B.V., 1972, 42(2013), 8 vom: 14. Aug., Seite 1572-1579 |
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| Übergeordnetes Werk: |
volume:42 ; year:2013 ; number:8 ; day:14 ; month:08 ; pages:1572-1579 |
| Links: |
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| DOI / URN: |
10.1007/s10953-013-0060-4 |
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| Katalog-ID: |
SPR014988011 |
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| 245 | 1 | 0 | |a Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K |
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| 520 | |a Abstract The densities of l-alanine and l-serine in aqueous solutions of N,N-dimethylformamide (DMF) have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes %$ (V_{\phi } ) %$, standard partial molar volumes %$ (V_{\phi }^{0} ) %$, standard partial molar volumes of transfer %$ (\Updelta_{\text{tr}} V_{\phi }^{0} ) %$ and hydration numbers have been determined for the amino acids. The %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ values of l-serine are positive which suggest that hydrophilic–hydrophilic interactions between l-serine and DMF are predominant. The –$ CH_{3} $ group of l-alanine has much more influence on the volumetric properties and the %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ have smaller negative values. The results have been interpreted in terms of the cosphere overlap model. | ||
| 650 | 4 | |a -Alanine |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a -Serine |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a DMF |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Standard partial molar volumes of transfer |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Hydration number |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Zhou, Li |e verfasserin |4 aut | |
| 700 | 1 | |a Ma, Lin |e verfasserin |4 aut | |
| 700 | 1 | |a Lin, Ruisen |e verfasserin |4 aut | |
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10.1007/s10953-013-0060-4 doi (DE-627)SPR014988011 (SPR)s10953-013-0060-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Liu, Chunli verfasserin aut Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The densities of l-alanine and l-serine in aqueous solutions of N,N-dimethylformamide (DMF) have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes %$ (V_{\phi } ) %$, standard partial molar volumes %$ (V_{\phi }^{0} ) %$, standard partial molar volumes of transfer %$ (\Updelta_{\text{tr}} V_{\phi }^{0} ) %$ and hydration numbers have been determined for the amino acids. The %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ values of l-serine are positive which suggest that hydrophilic–hydrophilic interactions between l-serine and DMF are predominant. The –$ CH_{3} $ group of l-alanine has much more influence on the volumetric properties and the %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ have smaller negative values. The results have been interpreted in terms of the cosphere overlap model. -Alanine (dpeaa)DE-He213 -Serine (dpeaa)DE-He213 DMF (dpeaa)DE-He213 Standard partial molar volumes of transfer (dpeaa)DE-He213 Hydration number (dpeaa)DE-He213 Zhou, Li verfasserin aut Ma, Lin verfasserin aut Lin, Ruisen verfasserin aut Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 42(2013), 8 vom: 14. Aug., Seite 1572-1579 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:42 year:2013 number:8 day:14 month:08 pages:1572-1579 https://dx.doi.org/10.1007/s10953-013-0060-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 42 2013 8 14 08 1572-1579 |
| spelling |
10.1007/s10953-013-0060-4 doi (DE-627)SPR014988011 (SPR)s10953-013-0060-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Liu, Chunli verfasserin aut Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The densities of l-alanine and l-serine in aqueous solutions of N,N-dimethylformamide (DMF) have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes %$ (V_{\phi } ) %$, standard partial molar volumes %$ (V_{\phi }^{0} ) %$, standard partial molar volumes of transfer %$ (\Updelta_{\text{tr}} V_{\phi }^{0} ) %$ and hydration numbers have been determined for the amino acids. The %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ values of l-serine are positive which suggest that hydrophilic–hydrophilic interactions between l-serine and DMF are predominant. The –$ CH_{3} $ group of l-alanine has much more influence on the volumetric properties and the %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ have smaller negative values. The results have been interpreted in terms of the cosphere overlap model. -Alanine (dpeaa)DE-He213 -Serine (dpeaa)DE-He213 DMF (dpeaa)DE-He213 Standard partial molar volumes of transfer (dpeaa)DE-He213 Hydration number (dpeaa)DE-He213 Zhou, Li verfasserin aut Ma, Lin verfasserin aut Lin, Ruisen verfasserin aut Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 42(2013), 8 vom: 14. Aug., Seite 1572-1579 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:42 year:2013 number:8 day:14 month:08 pages:1572-1579 https://dx.doi.org/10.1007/s10953-013-0060-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 42 2013 8 14 08 1572-1579 |
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10.1007/s10953-013-0060-4 doi (DE-627)SPR014988011 (SPR)s10953-013-0060-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Liu, Chunli verfasserin aut Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The densities of l-alanine and l-serine in aqueous solutions of N,N-dimethylformamide (DMF) have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes %$ (V_{\phi } ) %$, standard partial molar volumes %$ (V_{\phi }^{0} ) %$, standard partial molar volumes of transfer %$ (\Updelta_{\text{tr}} V_{\phi }^{0} ) %$ and hydration numbers have been determined for the amino acids. The %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ values of l-serine are positive which suggest that hydrophilic–hydrophilic interactions between l-serine and DMF are predominant. The –$ CH_{3} $ group of l-alanine has much more influence on the volumetric properties and the %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ have smaller negative values. The results have been interpreted in terms of the cosphere overlap model. -Alanine (dpeaa)DE-He213 -Serine (dpeaa)DE-He213 DMF (dpeaa)DE-He213 Standard partial molar volumes of transfer (dpeaa)DE-He213 Hydration number (dpeaa)DE-He213 Zhou, Li verfasserin aut Ma, Lin verfasserin aut Lin, Ruisen verfasserin aut Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 42(2013), 8 vom: 14. Aug., Seite 1572-1579 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:42 year:2013 number:8 day:14 month:08 pages:1572-1579 https://dx.doi.org/10.1007/s10953-013-0060-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 42 2013 8 14 08 1572-1579 |
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10.1007/s10953-013-0060-4 doi (DE-627)SPR014988011 (SPR)s10953-013-0060-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Liu, Chunli verfasserin aut Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The densities of l-alanine and l-serine in aqueous solutions of N,N-dimethylformamide (DMF) have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes %$ (V_{\phi } ) %$, standard partial molar volumes %$ (V_{\phi }^{0} ) %$, standard partial molar volumes of transfer %$ (\Updelta_{\text{tr}} V_{\phi }^{0} ) %$ and hydration numbers have been determined for the amino acids. The %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ values of l-serine are positive which suggest that hydrophilic–hydrophilic interactions between l-serine and DMF are predominant. The –$ CH_{3} $ group of l-alanine has much more influence on the volumetric properties and the %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ have smaller negative values. The results have been interpreted in terms of the cosphere overlap model. -Alanine (dpeaa)DE-He213 -Serine (dpeaa)DE-He213 DMF (dpeaa)DE-He213 Standard partial molar volumes of transfer (dpeaa)DE-He213 Hydration number (dpeaa)DE-He213 Zhou, Li verfasserin aut Ma, Lin verfasserin aut Lin, Ruisen verfasserin aut Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 42(2013), 8 vom: 14. Aug., Seite 1572-1579 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:42 year:2013 number:8 day:14 month:08 pages:1572-1579 https://dx.doi.org/10.1007/s10953-013-0060-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 42 2013 8 14 08 1572-1579 |
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10.1007/s10953-013-0060-4 doi (DE-627)SPR014988011 (SPR)s10953-013-0060-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Liu, Chunli verfasserin aut Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The densities of l-alanine and l-serine in aqueous solutions of N,N-dimethylformamide (DMF) have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes %$ (V_{\phi } ) %$, standard partial molar volumes %$ (V_{\phi }^{0} ) %$, standard partial molar volumes of transfer %$ (\Updelta_{\text{tr}} V_{\phi }^{0} ) %$ and hydration numbers have been determined for the amino acids. The %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ values of l-serine are positive which suggest that hydrophilic–hydrophilic interactions between l-serine and DMF are predominant. The –$ CH_{3} $ group of l-alanine has much more influence on the volumetric properties and the %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ have smaller negative values. The results have been interpreted in terms of the cosphere overlap model. -Alanine (dpeaa)DE-He213 -Serine (dpeaa)DE-He213 DMF (dpeaa)DE-He213 Standard partial molar volumes of transfer (dpeaa)DE-He213 Hydration number (dpeaa)DE-He213 Zhou, Li verfasserin aut Ma, Lin verfasserin aut Lin, Ruisen verfasserin aut Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 42(2013), 8 vom: 14. Aug., Seite 1572-1579 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:42 year:2013 number:8 day:14 month:08 pages:1572-1579 https://dx.doi.org/10.1007/s10953-013-0060-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 42 2013 8 14 08 1572-1579 |
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-Alanine -Serine DMF Standard partial molar volumes of transfer Hydration number |
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Liu, Chunli @@aut@@ Zhou, Li @@aut@@ Ma, Lin @@aut@@ Lin, Ruisen @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR014988011</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519082551.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2013 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10953-013-0060-4</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR014988011</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10953-013-0060-4-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Liu, Chunli</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2013</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The densities of l-alanine and l-serine in aqueous solutions of N,N-dimethylformamide (DMF) have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes %$ (V_{\phi } ) %$, standard partial molar volumes %$ (V_{\phi }^{0} ) %$, standard partial molar volumes of transfer %$ (\Updelta_{\text{tr}} V_{\phi }^{0} ) %$ and hydration numbers have been determined for the amino acids. The %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ values of l-serine are positive which suggest that hydrophilic–hydrophilic interactions between l-serine and DMF are predominant. The –$ CH_{3} $ group of l-alanine has much more influence on the volumetric properties and the %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ have smaller negative values. 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Liu, Chunli |
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Liu, Chunli ddc 540 bkl 35.00 misc -Alanine misc -Serine misc DMF misc Standard partial molar volumes of transfer misc Hydration number Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K |
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540 ASE 35.00 bkl Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K -Alanine (dpeaa)DE-He213 -Serine (dpeaa)DE-He213 DMF (dpeaa)DE-He213 Standard partial molar volumes of transfer (dpeaa)DE-He213 Hydration number (dpeaa)DE-He213 |
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Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K |
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Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K |
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volumetric properties of l-alanine and l-serine in aqueous n,n-dimethylformamide solutions at 298.15 k |
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Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K |
| abstract |
Abstract The densities of l-alanine and l-serine in aqueous solutions of N,N-dimethylformamide (DMF) have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes %$ (V_{\phi } ) %$, standard partial molar volumes %$ (V_{\phi }^{0} ) %$, standard partial molar volumes of transfer %$ (\Updelta_{\text{tr}} V_{\phi }^{0} ) %$ and hydration numbers have been determined for the amino acids. The %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ values of l-serine are positive which suggest that hydrophilic–hydrophilic interactions between l-serine and DMF are predominant. The –$ CH_{3} $ group of l-alanine has much more influence on the volumetric properties and the %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ have smaller negative values. The results have been interpreted in terms of the cosphere overlap model. |
| abstractGer |
Abstract The densities of l-alanine and l-serine in aqueous solutions of N,N-dimethylformamide (DMF) have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes %$ (V_{\phi } ) %$, standard partial molar volumes %$ (V_{\phi }^{0} ) %$, standard partial molar volumes of transfer %$ (\Updelta_{\text{tr}} V_{\phi }^{0} ) %$ and hydration numbers have been determined for the amino acids. The %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ values of l-serine are positive which suggest that hydrophilic–hydrophilic interactions between l-serine and DMF are predominant. The –$ CH_{3} $ group of l-alanine has much more influence on the volumetric properties and the %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ have smaller negative values. The results have been interpreted in terms of the cosphere overlap model. |
| abstract_unstemmed |
Abstract The densities of l-alanine and l-serine in aqueous solutions of N,N-dimethylformamide (DMF) have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes %$ (V_{\phi } ) %$, standard partial molar volumes %$ (V_{\phi }^{0} ) %$, standard partial molar volumes of transfer %$ (\Updelta_{\text{tr}} V_{\phi }^{0} ) %$ and hydration numbers have been determined for the amino acids. The %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ values of l-serine are positive which suggest that hydrophilic–hydrophilic interactions between l-serine and DMF are predominant. The –$ CH_{3} $ group of l-alanine has much more influence on the volumetric properties and the %$ \Updelta_{\text{tr}} V_{\phi }^{0} %$ have smaller negative values. The results have been interpreted in terms of the cosphere overlap model. |
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| container_issue |
8 |
| title_short |
Volumetric Properties of l-Alanine and l-Serine in Aqueous N,N-Dimethylformamide Solutions at 298.15 K |
| url |
https://dx.doi.org/10.1007/s10953-013-0060-4 |
| remote_bool |
true |
| author2 |
Zhou, Li Ma, Lin Lin, Ruisen |
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Zhou, Li Ma, Lin Lin, Ruisen |
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c |
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false |
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| doi_str |
10.1007/s10953-013-0060-4 |
| up_date |
2024-07-04T03:42:22.019Z |
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1803618397216309248 |
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| score |
7.400505 |