Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems

Abstract Thermodynamic properties of solutions in binary and ternary aqueous systems which are derived from very accurate measurements of density and its changes with concentration, temperature and pressure, are examined in a detail. Precise definitions of the apparent molar volumes, the apparent mo...
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Gespeichert in:

Autor*in:	Apelblat, Alexander [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2016

Schlagwörter:	Density Aqueous binary Aqueous ternary solutions Apparent molar volumes Mean apparent molar volumes Correlation and prediction

Übergeordnetes Werk:	Enthalten in: Journal of solution chemistry - New York, NY [u.a.] : Springer Science + Business Media B.V., 1972, 45(2016), 11 vom: 29. Aug., Seite 1530-1547
Übergeordnetes Werk:	volume:45 ; year:2016 ; number:11 ; day:29 ; month:08 ; pages:1530-1547

Links:	Volltext

DOI / URN:	10.1007/s10953-016-0511-9

Katalog-ID:	SPR014991470

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520			\|a Abstract Thermodynamic properties of solutions in binary and ternary aqueous systems which are derived from very accurate measurements of density and its changes with concentration, temperature and pressure, are examined in a detail. Precise definitions of the apparent molar volumes, the apparent molar expansibilities and the apparent molar compressibilities of components in ternary solutions are discussed. The significance of errors caused when inexact formulas are used is illustrated. It is demonstrated that in ternary solutions, an experimental procedure leading to determination of the mean apparent molar volume is superior than that based on the reduction to pseudo-binary systems. The present author proposed a new two-parameter empirical equation which correlate and predict densities in binary aqueous solutions. This equation includes densities of pure water at temperature T and two adjustable parameters which are practically independent of temperature. The expected accuracy of predicted in aqueous solutions densities makes this equation most suitable for engineering calculations.
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allfields	10.1007/s10953-016-0511-9 doi (DE-627)SPR014991470 (SPR)s10953-016-0511-9-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Apelblat, Alexander verfasserin aut Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Thermodynamic properties of solutions in binary and ternary aqueous systems which are derived from very accurate measurements of density and its changes with concentration, temperature and pressure, are examined in a detail. Precise definitions of the apparent molar volumes, the apparent molar expansibilities and the apparent molar compressibilities of components in ternary solutions are discussed. The significance of errors caused when inexact formulas are used is illustrated. It is demonstrated that in ternary solutions, an experimental procedure leading to determination of the mean apparent molar volume is superior than that based on the reduction to pseudo-binary systems. The present author proposed a new two-parameter empirical equation which correlate and predict densities in binary aqueous solutions. This equation includes densities of pure water at temperature T and two adjustable parameters which are practically independent of temperature. The expected accuracy of predicted in aqueous solutions densities makes this equation most suitable for engineering calculations. Density (dpeaa)DE-He213 Aqueous binary (dpeaa)DE-He213 Aqueous ternary solutions (dpeaa)DE-He213 Apparent molar volumes (dpeaa)DE-He213 Mean apparent molar volumes (dpeaa)DE-He213 Correlation and prediction (dpeaa)DE-He213 Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 45(2016), 11 vom: 29. Aug., Seite 1530-1547 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:45 year:2016 number:11 day:29 month:08 pages:1530-1547 https://dx.doi.org/10.1007/s10953-016-0511-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 45 2016 11 29 08 1530-1547
spelling	10.1007/s10953-016-0511-9 doi (DE-627)SPR014991470 (SPR)s10953-016-0511-9-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Apelblat, Alexander verfasserin aut Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Thermodynamic properties of solutions in binary and ternary aqueous systems which are derived from very accurate measurements of density and its changes with concentration, temperature and pressure, are examined in a detail. Precise definitions of the apparent molar volumes, the apparent molar expansibilities and the apparent molar compressibilities of components in ternary solutions are discussed. The significance of errors caused when inexact formulas are used is illustrated. It is demonstrated that in ternary solutions, an experimental procedure leading to determination of the mean apparent molar volume is superior than that based on the reduction to pseudo-binary systems. The present author proposed a new two-parameter empirical equation which correlate and predict densities in binary aqueous solutions. This equation includes densities of pure water at temperature T and two adjustable parameters which are practically independent of temperature. The expected accuracy of predicted in aqueous solutions densities makes this equation most suitable for engineering calculations. Density (dpeaa)DE-He213 Aqueous binary (dpeaa)DE-He213 Aqueous ternary solutions (dpeaa)DE-He213 Apparent molar volumes (dpeaa)DE-He213 Mean apparent molar volumes (dpeaa)DE-He213 Correlation and prediction (dpeaa)DE-He213 Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 45(2016), 11 vom: 29. Aug., Seite 1530-1547 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:45 year:2016 number:11 day:29 month:08 pages:1530-1547 https://dx.doi.org/10.1007/s10953-016-0511-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 45 2016 11 29 08 1530-1547
allfields_unstemmed	10.1007/s10953-016-0511-9 doi (DE-627)SPR014991470 (SPR)s10953-016-0511-9-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Apelblat, Alexander verfasserin aut Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Thermodynamic properties of solutions in binary and ternary aqueous systems which are derived from very accurate measurements of density and its changes with concentration, temperature and pressure, are examined in a detail. Precise definitions of the apparent molar volumes, the apparent molar expansibilities and the apparent molar compressibilities of components in ternary solutions are discussed. The significance of errors caused when inexact formulas are used is illustrated. It is demonstrated that in ternary solutions, an experimental procedure leading to determination of the mean apparent molar volume is superior than that based on the reduction to pseudo-binary systems. The present author proposed a new two-parameter empirical equation which correlate and predict densities in binary aqueous solutions. This equation includes densities of pure water at temperature T and two adjustable parameters which are practically independent of temperature. The expected accuracy of predicted in aqueous solutions densities makes this equation most suitable for engineering calculations. Density (dpeaa)DE-He213 Aqueous binary (dpeaa)DE-He213 Aqueous ternary solutions (dpeaa)DE-He213 Apparent molar volumes (dpeaa)DE-He213 Mean apparent molar volumes (dpeaa)DE-He213 Correlation and prediction (dpeaa)DE-He213 Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 45(2016), 11 vom: 29. Aug., Seite 1530-1547 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:45 year:2016 number:11 day:29 month:08 pages:1530-1547 https://dx.doi.org/10.1007/s10953-016-0511-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 45 2016 11 29 08 1530-1547
allfieldsGer	10.1007/s10953-016-0511-9 doi (DE-627)SPR014991470 (SPR)s10953-016-0511-9-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Apelblat, Alexander verfasserin aut Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Thermodynamic properties of solutions in binary and ternary aqueous systems which are derived from very accurate measurements of density and its changes with concentration, temperature and pressure, are examined in a detail. Precise definitions of the apparent molar volumes, the apparent molar expansibilities and the apparent molar compressibilities of components in ternary solutions are discussed. The significance of errors caused when inexact formulas are used is illustrated. It is demonstrated that in ternary solutions, an experimental procedure leading to determination of the mean apparent molar volume is superior than that based on the reduction to pseudo-binary systems. The present author proposed a new two-parameter empirical equation which correlate and predict densities in binary aqueous solutions. This equation includes densities of pure water at temperature T and two adjustable parameters which are practically independent of temperature. The expected accuracy of predicted in aqueous solutions densities makes this equation most suitable for engineering calculations. Density (dpeaa)DE-He213 Aqueous binary (dpeaa)DE-He213 Aqueous ternary solutions (dpeaa)DE-He213 Apparent molar volumes (dpeaa)DE-He213 Mean apparent molar volumes (dpeaa)DE-He213 Correlation and prediction (dpeaa)DE-He213 Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 45(2016), 11 vom: 29. Aug., Seite 1530-1547 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:45 year:2016 number:11 day:29 month:08 pages:1530-1547 https://dx.doi.org/10.1007/s10953-016-0511-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 45 2016 11 29 08 1530-1547
allfieldsSound	10.1007/s10953-016-0511-9 doi (DE-627)SPR014991470 (SPR)s10953-016-0511-9-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Apelblat, Alexander verfasserin aut Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Thermodynamic properties of solutions in binary and ternary aqueous systems which are derived from very accurate measurements of density and its changes with concentration, temperature and pressure, are examined in a detail. Precise definitions of the apparent molar volumes, the apparent molar expansibilities and the apparent molar compressibilities of components in ternary solutions are discussed. The significance of errors caused when inexact formulas are used is illustrated. It is demonstrated that in ternary solutions, an experimental procedure leading to determination of the mean apparent molar volume is superior than that based on the reduction to pseudo-binary systems. The present author proposed a new two-parameter empirical equation which correlate and predict densities in binary aqueous solutions. This equation includes densities of pure water at temperature T and two adjustable parameters which are practically independent of temperature. The expected accuracy of predicted in aqueous solutions densities makes this equation most suitable for engineering calculations. Density (dpeaa)DE-He213 Aqueous binary (dpeaa)DE-He213 Aqueous ternary solutions (dpeaa)DE-He213 Apparent molar volumes (dpeaa)DE-He213 Mean apparent molar volumes (dpeaa)DE-He213 Correlation and prediction (dpeaa)DE-He213 Enthalten in Journal of solution chemistry New York, NY [u.a.] : Springer Science + Business Media B.V., 1972 45(2016), 11 vom: 29. Aug., Seite 1530-1547 (DE-627)317881876 (DE-600)2017287-4 1572-8927 nnns volume:45 year:2016 number:11 day:29 month:08 pages:1530-1547 https://dx.doi.org/10.1007/s10953-016-0511-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 45 2016 11 29 08 1530-1547
language	English
source	Enthalten in Journal of solution chemistry 45(2016), 11 vom: 29. Aug., Seite 1530-1547 volume:45 year:2016 number:11 day:29 month:08 pages:1530-1547
sourceStr	Enthalten in Journal of solution chemistry 45(2016), 11 vom: 29. Aug., Seite 1530-1547 volume:45 year:2016 number:11 day:29 month:08 pages:1530-1547
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Density Aqueous binary Aqueous ternary solutions Apparent molar volumes Mean apparent molar volumes Correlation and prediction
dewey-raw	540
isfreeaccess_bool	false
container_title	Journal of solution chemistry
authorswithroles_txt_mv	Apelblat, Alexander @@aut@@
publishDateDaySort_date	2016-08-29T00:00:00Z
hierarchy_top_id	317881876
dewey-sort	3540
id	SPR014991470
language_de	englisch
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author	Apelblat, Alexander
spellingShingle	Apelblat, Alexander ddc 540 bkl 35.00 misc Density misc Aqueous binary misc Aqueous ternary solutions misc Apparent molar volumes misc Mean apparent molar volumes misc Correlation and prediction Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems
authorStr	Apelblat, Alexander
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topic_title	540 ASE 35.00 bkl Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems Density (dpeaa)DE-He213 Aqueous binary (dpeaa)DE-He213 Aqueous ternary solutions (dpeaa)DE-He213 Apparent molar volumes (dpeaa)DE-He213 Mean apparent molar volumes (dpeaa)DE-He213 Correlation and prediction (dpeaa)DE-He213
topic	ddc 540 bkl 35.00 misc Density misc Aqueous binary misc Aqueous ternary solutions misc Apparent molar volumes misc Mean apparent molar volumes misc Correlation and prediction
topic_unstemmed	ddc 540 bkl 35.00 misc Density misc Aqueous binary misc Aqueous ternary solutions misc Apparent molar volumes misc Mean apparent molar volumes misc Correlation and prediction
topic_browse	ddc 540 bkl 35.00 misc Density misc Aqueous binary misc Aqueous ternary solutions misc Apparent molar volumes misc Mean apparent molar volumes misc Correlation and prediction
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title	Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems
ctrlnum	(DE-627)SPR014991470 (SPR)s10953-016-0511-9-e
title_full	Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems
author_sort	Apelblat, Alexander
journal	Journal of solution chemistry
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title_sort	representation of volumetric and compressibility properties in binary and ternary systems
title_auth	Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems
abstract	Abstract Thermodynamic properties of solutions in binary and ternary aqueous systems which are derived from very accurate measurements of density and its changes with concentration, temperature and pressure, are examined in a detail. Precise definitions of the apparent molar volumes, the apparent molar expansibilities and the apparent molar compressibilities of components in ternary solutions are discussed. The significance of errors caused when inexact formulas are used is illustrated. It is demonstrated that in ternary solutions, an experimental procedure leading to determination of the mean apparent molar volume is superior than that based on the reduction to pseudo-binary systems. The present author proposed a new two-parameter empirical equation which correlate and predict densities in binary aqueous solutions. This equation includes densities of pure water at temperature T and two adjustable parameters which are practically independent of temperature. The expected accuracy of predicted in aqueous solutions densities makes this equation most suitable for engineering calculations.
abstractGer	Abstract Thermodynamic properties of solutions in binary and ternary aqueous systems which are derived from very accurate measurements of density and its changes with concentration, temperature and pressure, are examined in a detail. Precise definitions of the apparent molar volumes, the apparent molar expansibilities and the apparent molar compressibilities of components in ternary solutions are discussed. The significance of errors caused when inexact formulas are used is illustrated. It is demonstrated that in ternary solutions, an experimental procedure leading to determination of the mean apparent molar volume is superior than that based on the reduction to pseudo-binary systems. The present author proposed a new two-parameter empirical equation which correlate and predict densities in binary aqueous solutions. This equation includes densities of pure water at temperature T and two adjustable parameters which are practically independent of temperature. The expected accuracy of predicted in aqueous solutions densities makes this equation most suitable for engineering calculations.
abstract_unstemmed	Abstract Thermodynamic properties of solutions in binary and ternary aqueous systems which are derived from very accurate measurements of density and its changes with concentration, temperature and pressure, are examined in a detail. Precise definitions of the apparent molar volumes, the apparent molar expansibilities and the apparent molar compressibilities of components in ternary solutions are discussed. The significance of errors caused when inexact formulas are used is illustrated. It is demonstrated that in ternary solutions, an experimental procedure leading to determination of the mean apparent molar volume is superior than that based on the reduction to pseudo-binary systems. The present author proposed a new two-parameter empirical equation which correlate and predict densities in binary aqueous solutions. This equation includes densities of pure water at temperature T and two adjustable parameters which are practically independent of temperature. The expected accuracy of predicted in aqueous solutions densities makes this equation most suitable for engineering calculations.
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container_issue	11
title_short	Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems
url	https://dx.doi.org/10.1007/s10953-016-0511-9
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doi_str	10.1007/s10953-016-0511-9
up_date	2024-07-04T03:43:07.428Z
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Representation of Volumetric and Compressibility Properties in Binary and Ternary Systems

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