The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions
Abstract Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(ε-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In th...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Sun, Jingru [verfasserIn] He, Chaoliang [verfasserIn] Zhuang, Xiuli [verfasserIn] Jing, Xiabin [verfasserIn] Chen, Xuesi [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2011 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of polymer research - Dordrecht : Springer Science + Business Media B.V., 1994, 18(2011), 6 vom: 19. Mai, Seite 2161-2168 |
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| Übergeordnetes Werk: |
volume:18 ; year:2011 ; number:6 ; day:19 ; month:05 ; pages:2161-2168 |
| Links: |
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| DOI / URN: |
10.1007/s10965-011-9626-2 |
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| Katalog-ID: |
SPR015124347 |
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| 245 | 1 | 4 | |a The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions |
| 264 | 1 | |c 2011 | |
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| 520 | |a Abstract Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(ε-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In these copolymers, both blocks were crystallizable and biocompatible. The mutual effects between the PEG and PCL blocks were significant, leading to the obvious block composition dependence of the crystallization behavior and morphology of the PEG-b-PCL copolymers. The relative block length determined which block crystallized first. The temperature-dependent XRD measurements confirmed which block crystallized first from the copolymer during the cooling procedure. Single crystals of the PCL and PEG homopolymers and the PEG-b-PCL copolymers were obtained and observed by AFM. The block (PCL or PEG) crystallized first would determine the crystal morphology. The block crystallized later acted as a solvent, which was advantageous to forming perfect single crystals of the whole block copolymers. | ||
| 650 | 4 | |a Poly(ethylene glycol) |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Poly(ε-caprolactone) |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Block copolymer |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Crystallization |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Single crystal |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a He, Chaoliang |e verfasserin |4 aut | |
| 700 | 1 | |a Zhuang, Xiuli |e verfasserin |4 aut | |
| 700 | 1 | |a Jing, Xiabin |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Xuesi |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Journal of polymer research |d Dordrecht : Springer Science + Business Media B.V., 1994 |g 18(2011), 6 vom: 19. Mai, Seite 2161-2168 |w (DE-627)340872098 |w (DE-600)2065616-6 |x 1572-8935 |7 nnns |
| 773 | 1 | 8 | |g volume:18 |g year:2011 |g number:6 |g day:19 |g month:05 |g pages:2161-2168 |
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10.1007/s10965-011-9626-2 doi (DE-627)SPR015124347 (SPR)s10965-011-9626-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Sun, Jingru verfasserin aut The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(ε-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In these copolymers, both blocks were crystallizable and biocompatible. The mutual effects between the PEG and PCL blocks were significant, leading to the obvious block composition dependence of the crystallization behavior and morphology of the PEG-b-PCL copolymers. The relative block length determined which block crystallized first. The temperature-dependent XRD measurements confirmed which block crystallized first from the copolymer during the cooling procedure. Single crystals of the PCL and PEG homopolymers and the PEG-b-PCL copolymers were obtained and observed by AFM. The block (PCL or PEG) crystallized first would determine the crystal morphology. The block crystallized later acted as a solvent, which was advantageous to forming perfect single crystals of the whole block copolymers. Poly(ethylene glycol) (dpeaa)DE-He213 Poly(ε-caprolactone) (dpeaa)DE-He213 Block copolymer (dpeaa)DE-He213 Crystallization (dpeaa)DE-He213 Single crystal (dpeaa)DE-He213 He, Chaoliang verfasserin aut Zhuang, Xiuli verfasserin aut Jing, Xiabin verfasserin aut Chen, Xuesi verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 18(2011), 6 vom: 19. Mai, Seite 2161-2168 (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:18 year:2011 number:6 day:19 month:05 pages:2161-2168 https://dx.doi.org/10.1007/s10965-011-9626-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 18 2011 6 19 05 2161-2168 |
| spelling |
10.1007/s10965-011-9626-2 doi (DE-627)SPR015124347 (SPR)s10965-011-9626-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Sun, Jingru verfasserin aut The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(ε-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In these copolymers, both blocks were crystallizable and biocompatible. The mutual effects between the PEG and PCL blocks were significant, leading to the obvious block composition dependence of the crystallization behavior and morphology of the PEG-b-PCL copolymers. The relative block length determined which block crystallized first. The temperature-dependent XRD measurements confirmed which block crystallized first from the copolymer during the cooling procedure. Single crystals of the PCL and PEG homopolymers and the PEG-b-PCL copolymers were obtained and observed by AFM. The block (PCL or PEG) crystallized first would determine the crystal morphology. The block crystallized later acted as a solvent, which was advantageous to forming perfect single crystals of the whole block copolymers. Poly(ethylene glycol) (dpeaa)DE-He213 Poly(ε-caprolactone) (dpeaa)DE-He213 Block copolymer (dpeaa)DE-He213 Crystallization (dpeaa)DE-He213 Single crystal (dpeaa)DE-He213 He, Chaoliang verfasserin aut Zhuang, Xiuli verfasserin aut Jing, Xiabin verfasserin aut Chen, Xuesi verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 18(2011), 6 vom: 19. Mai, Seite 2161-2168 (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:18 year:2011 number:6 day:19 month:05 pages:2161-2168 https://dx.doi.org/10.1007/s10965-011-9626-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 18 2011 6 19 05 2161-2168 |
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10.1007/s10965-011-9626-2 doi (DE-627)SPR015124347 (SPR)s10965-011-9626-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Sun, Jingru verfasserin aut The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(ε-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In these copolymers, both blocks were crystallizable and biocompatible. The mutual effects between the PEG and PCL blocks were significant, leading to the obvious block composition dependence of the crystallization behavior and morphology of the PEG-b-PCL copolymers. The relative block length determined which block crystallized first. The temperature-dependent XRD measurements confirmed which block crystallized first from the copolymer during the cooling procedure. Single crystals of the PCL and PEG homopolymers and the PEG-b-PCL copolymers were obtained and observed by AFM. The block (PCL or PEG) crystallized first would determine the crystal morphology. The block crystallized later acted as a solvent, which was advantageous to forming perfect single crystals of the whole block copolymers. Poly(ethylene glycol) (dpeaa)DE-He213 Poly(ε-caprolactone) (dpeaa)DE-He213 Block copolymer (dpeaa)DE-He213 Crystallization (dpeaa)DE-He213 Single crystal (dpeaa)DE-He213 He, Chaoliang verfasserin aut Zhuang, Xiuli verfasserin aut Jing, Xiabin verfasserin aut Chen, Xuesi verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 18(2011), 6 vom: 19. Mai, Seite 2161-2168 (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:18 year:2011 number:6 day:19 month:05 pages:2161-2168 https://dx.doi.org/10.1007/s10965-011-9626-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 18 2011 6 19 05 2161-2168 |
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10.1007/s10965-011-9626-2 doi (DE-627)SPR015124347 (SPR)s10965-011-9626-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Sun, Jingru verfasserin aut The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(ε-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In these copolymers, both blocks were crystallizable and biocompatible. The mutual effects between the PEG and PCL blocks were significant, leading to the obvious block composition dependence of the crystallization behavior and morphology of the PEG-b-PCL copolymers. The relative block length determined which block crystallized first. The temperature-dependent XRD measurements confirmed which block crystallized first from the copolymer during the cooling procedure. Single crystals of the PCL and PEG homopolymers and the PEG-b-PCL copolymers were obtained and observed by AFM. The block (PCL or PEG) crystallized first would determine the crystal morphology. The block crystallized later acted as a solvent, which was advantageous to forming perfect single crystals of the whole block copolymers. Poly(ethylene glycol) (dpeaa)DE-He213 Poly(ε-caprolactone) (dpeaa)DE-He213 Block copolymer (dpeaa)DE-He213 Crystallization (dpeaa)DE-He213 Single crystal (dpeaa)DE-He213 He, Chaoliang verfasserin aut Zhuang, Xiuli verfasserin aut Jing, Xiabin verfasserin aut Chen, Xuesi verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 18(2011), 6 vom: 19. Mai, Seite 2161-2168 (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:18 year:2011 number:6 day:19 month:05 pages:2161-2168 https://dx.doi.org/10.1007/s10965-011-9626-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 18 2011 6 19 05 2161-2168 |
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10.1007/s10965-011-9626-2 doi (DE-627)SPR015124347 (SPR)s10965-011-9626-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Sun, Jingru verfasserin aut The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(ε-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In these copolymers, both blocks were crystallizable and biocompatible. The mutual effects between the PEG and PCL blocks were significant, leading to the obvious block composition dependence of the crystallization behavior and morphology of the PEG-b-PCL copolymers. The relative block length determined which block crystallized first. The temperature-dependent XRD measurements confirmed which block crystallized first from the copolymer during the cooling procedure. Single crystals of the PCL and PEG homopolymers and the PEG-b-PCL copolymers were obtained and observed by AFM. The block (PCL or PEG) crystallized first would determine the crystal morphology. The block crystallized later acted as a solvent, which was advantageous to forming perfect single crystals of the whole block copolymers. Poly(ethylene glycol) (dpeaa)DE-He213 Poly(ε-caprolactone) (dpeaa)DE-He213 Block copolymer (dpeaa)DE-He213 Crystallization (dpeaa)DE-He213 Single crystal (dpeaa)DE-He213 He, Chaoliang verfasserin aut Zhuang, Xiuli verfasserin aut Jing, Xiabin verfasserin aut Chen, Xuesi verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 18(2011), 6 vom: 19. Mai, Seite 2161-2168 (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:18 year:2011 number:6 day:19 month:05 pages:2161-2168 https://dx.doi.org/10.1007/s10965-011-9626-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 18 2011 6 19 05 2161-2168 |
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Enthalten in Journal of polymer research 18(2011), 6 vom: 19. Mai, Seite 2161-2168 volume:18 year:2011 number:6 day:19 month:05 pages:2161-2168 |
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Enthalten in Journal of polymer research 18(2011), 6 vom: 19. Mai, Seite 2161-2168 volume:18 year:2011 number:6 day:19 month:05 pages:2161-2168 |
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Poly(ethylene glycol) Poly(ε-caprolactone) Block copolymer Crystallization Single crystal |
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Sun, Jingru @@aut@@ He, Chaoliang @@aut@@ Zhuang, Xiuli @@aut@@ Jing, Xiabin @@aut@@ Chen, Xuesi @@aut@@ |
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2011-05-19T00:00:00Z |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR015124347</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519170734.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2011 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10965-011-9626-2</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR015124347</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10965-011-9626-2-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Sun, Jingru</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="4"><subfield code="a">The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2011</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(ε-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In these copolymers, both blocks were crystallizable and biocompatible. The mutual effects between the PEG and PCL blocks were significant, leading to the obvious block composition dependence of the crystallization behavior and morphology of the PEG-b-PCL copolymers. The relative block length determined which block crystallized first. The temperature-dependent XRD measurements confirmed which block crystallized first from the copolymer during the cooling procedure. Single crystals of the PCL and PEG homopolymers and the PEG-b-PCL copolymers were obtained and observed by AFM. The block (PCL or PEG) crystallized first would determine the crystal morphology. 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Sun, Jingru |
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Sun, Jingru ddc 540 bkl 35.00 misc Poly(ethylene glycol) misc Poly(ε-caprolactone) misc Block copolymer misc Crystallization misc Single crystal The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions |
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540 ASE 35.00 bkl The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions Poly(ethylene glycol) (dpeaa)DE-He213 Poly(ε-caprolactone) (dpeaa)DE-He213 Block copolymer (dpeaa)DE-He213 Crystallization (dpeaa)DE-He213 Single crystal (dpeaa)DE-He213 |
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ddc 540 bkl 35.00 misc Poly(ethylene glycol) misc Poly(ε-caprolactone) misc Block copolymer misc Crystallization misc Single crystal |
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ddc 540 bkl 35.00 misc Poly(ethylene glycol) misc Poly(ε-caprolactone) misc Block copolymer misc Crystallization misc Single crystal |
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The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions |
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The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions |
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Sun, Jingru He, Chaoliang Zhuang, Xiuli Jing, Xiabin Chen, Xuesi |
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crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions |
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The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions |
| abstract |
Abstract Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(ε-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In these copolymers, both blocks were crystallizable and biocompatible. The mutual effects between the PEG and PCL blocks were significant, leading to the obvious block composition dependence of the crystallization behavior and morphology of the PEG-b-PCL copolymers. The relative block length determined which block crystallized first. The temperature-dependent XRD measurements confirmed which block crystallized first from the copolymer during the cooling procedure. Single crystals of the PCL and PEG homopolymers and the PEG-b-PCL copolymers were obtained and observed by AFM. The block (PCL or PEG) crystallized first would determine the crystal morphology. The block crystallized later acted as a solvent, which was advantageous to forming perfect single crystals of the whole block copolymers. |
| abstractGer |
Abstract Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(ε-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In these copolymers, both blocks were crystallizable and biocompatible. The mutual effects between the PEG and PCL blocks were significant, leading to the obvious block composition dependence of the crystallization behavior and morphology of the PEG-b-PCL copolymers. The relative block length determined which block crystallized first. The temperature-dependent XRD measurements confirmed which block crystallized first from the copolymer during the cooling procedure. Single crystals of the PCL and PEG homopolymers and the PEG-b-PCL copolymers were obtained and observed by AFM. The block (PCL or PEG) crystallized first would determine the crystal morphology. The block crystallized later acted as a solvent, which was advantageous to forming perfect single crystals of the whole block copolymers. |
| abstract_unstemmed |
Abstract Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(ε-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In these copolymers, both blocks were crystallizable and biocompatible. The mutual effects between the PEG and PCL blocks were significant, leading to the obvious block composition dependence of the crystallization behavior and morphology of the PEG-b-PCL copolymers. The relative block length determined which block crystallized first. The temperature-dependent XRD measurements confirmed which block crystallized first from the copolymer during the cooling procedure. Single crystals of the PCL and PEG homopolymers and the PEG-b-PCL copolymers were obtained and observed by AFM. The block (PCL or PEG) crystallized first would determine the crystal morphology. The block crystallized later acted as a solvent, which was advantageous to forming perfect single crystals of the whole block copolymers. |
| collection_details |
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6 |
| title_short |
The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions |
| url |
https://dx.doi.org/10.1007/s10965-011-9626-2 |
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| author2 |
He, Chaoliang Zhuang, Xiuli Jing, Xiabin Chen, Xuesi |
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He, Chaoliang Zhuang, Xiuli Jing, Xiabin Chen, Xuesi |
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| doi_str |
10.1007/s10965-011-9626-2 |
| up_date |
2024-07-03T14:04:06.866Z |
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| score |
7.400646 |