Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples
Abstract We compare the analytical performance of a modern quadrupole-based ICP-MS (“X-Series”, Thermo-Electron, Winsford, UK) with a single-collector double-focusing sector-field ICP-MS (“Axiom”, VG Elemental, Winsford, UK) for uranium isotopic measurements in environmental samples. We focus on the...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Pointurier, F. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2008 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC. 2007 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of radioanalytical and nuclear chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968, 276(2008), 2 vom: Mai, Seite 505-511 |
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| Übergeordnetes Werk: |
volume:276 ; year:2008 ; number:2 ; month:05 ; pages:505-511 |
| Links: |
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| DOI / URN: |
10.1007/s10967-008-0534-9 |
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| Katalog-ID: |
SPR01515713X |
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| 245 | 1 | 0 | |a Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples |
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| 520 | |a Abstract We compare the analytical performance of a modern quadrupole-based ICP-MS (“X-Series”, Thermo-Electron, Winsford, UK) with a single-collector double-focusing sector-field ICP-MS (“Axiom”, VG Elemental, Winsford, UK) for uranium isotopic measurements in environmental samples. We focus on the precision and accuracy obtained with both instruments for the 235U/238U isotopic ratios and on the abundance sensitivity that is a key parameter for low 236U/238U isotopic ratios measurements. We observe that isotopic measurements are more precise accurate with the “X-Series” than with the “Axiom”. Besides, we demonstrate that the “Axiom’s” higher abundance sensitivity limits its capability to measure 236U/238U ratio below a few ppm. | ||
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| 700 | 1 | |a Hubert, A. |4 aut | |
| 700 | 1 | |a Baglan, N. |4 aut | |
| 700 | 1 | |a Hémet, P. |4 aut | |
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10.1007/s10967-008-0534-9 doi (DE-627)SPR01515713X (SPR)s10967-008-0534-9-e DE-627 ger DE-627 rakwb eng Pointurier, F. verfasserin aut Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media, LLC. 2007 Abstract We compare the analytical performance of a modern quadrupole-based ICP-MS (“X-Series”, Thermo-Electron, Winsford, UK) with a single-collector double-focusing sector-field ICP-MS (“Axiom”, VG Elemental, Winsford, UK) for uranium isotopic measurements in environmental samples. We focus on the precision and accuracy obtained with both instruments for the 235U/238U isotopic ratios and on the abundance sensitivity that is a key parameter for low 236U/238U isotopic ratios measurements. We observe that isotopic measurements are more precise accurate with the “X-Series” than with the “Axiom”. Besides, we demonstrate that the “Axiom’s” higher abundance sensitivity limits its capability to measure 236U/238U ratio below a few ppm. Isotopic Ratio (dpeaa)DE-He213 Relative Standard Deviation (dpeaa)DE-He213 Mass Bias (dpeaa)DE-He213 Isotopic Ratio Measurement (dpeaa)DE-He213 Isotopic Standard (dpeaa)DE-He213 Hubert, A. aut Baglan, N. aut Hémet, P. aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 276(2008), 2 vom: Mai, Seite 505-511 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:276 year:2008 number:2 month:05 pages:505-511 https://dx.doi.org/10.1007/s10967-008-0534-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 276 2008 2 05 505-511 |
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10.1007/s10967-008-0534-9 doi (DE-627)SPR01515713X (SPR)s10967-008-0534-9-e DE-627 ger DE-627 rakwb eng Pointurier, F. verfasserin aut Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media, LLC. 2007 Abstract We compare the analytical performance of a modern quadrupole-based ICP-MS (“X-Series”, Thermo-Electron, Winsford, UK) with a single-collector double-focusing sector-field ICP-MS (“Axiom”, VG Elemental, Winsford, UK) for uranium isotopic measurements in environmental samples. We focus on the precision and accuracy obtained with both instruments for the 235U/238U isotopic ratios and on the abundance sensitivity that is a key parameter for low 236U/238U isotopic ratios measurements. We observe that isotopic measurements are more precise accurate with the “X-Series” than with the “Axiom”. Besides, we demonstrate that the “Axiom’s” higher abundance sensitivity limits its capability to measure 236U/238U ratio below a few ppm. Isotopic Ratio (dpeaa)DE-He213 Relative Standard Deviation (dpeaa)DE-He213 Mass Bias (dpeaa)DE-He213 Isotopic Ratio Measurement (dpeaa)DE-He213 Isotopic Standard (dpeaa)DE-He213 Hubert, A. aut Baglan, N. aut Hémet, P. aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 276(2008), 2 vom: Mai, Seite 505-511 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:276 year:2008 number:2 month:05 pages:505-511 https://dx.doi.org/10.1007/s10967-008-0534-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 276 2008 2 05 505-511 |
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10.1007/s10967-008-0534-9 doi (DE-627)SPR01515713X (SPR)s10967-008-0534-9-e DE-627 ger DE-627 rakwb eng Pointurier, F. verfasserin aut Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media, LLC. 2007 Abstract We compare the analytical performance of a modern quadrupole-based ICP-MS (“X-Series”, Thermo-Electron, Winsford, UK) with a single-collector double-focusing sector-field ICP-MS (“Axiom”, VG Elemental, Winsford, UK) for uranium isotopic measurements in environmental samples. We focus on the precision and accuracy obtained with both instruments for the 235U/238U isotopic ratios and on the abundance sensitivity that is a key parameter for low 236U/238U isotopic ratios measurements. We observe that isotopic measurements are more precise accurate with the “X-Series” than with the “Axiom”. Besides, we demonstrate that the “Axiom’s” higher abundance sensitivity limits its capability to measure 236U/238U ratio below a few ppm. Isotopic Ratio (dpeaa)DE-He213 Relative Standard Deviation (dpeaa)DE-He213 Mass Bias (dpeaa)DE-He213 Isotopic Ratio Measurement (dpeaa)DE-He213 Isotopic Standard (dpeaa)DE-He213 Hubert, A. aut Baglan, N. aut Hémet, P. aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 276(2008), 2 vom: Mai, Seite 505-511 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:276 year:2008 number:2 month:05 pages:505-511 https://dx.doi.org/10.1007/s10967-008-0534-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 276 2008 2 05 505-511 |
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10.1007/s10967-008-0534-9 doi (DE-627)SPR01515713X (SPR)s10967-008-0534-9-e DE-627 ger DE-627 rakwb eng Pointurier, F. verfasserin aut Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media, LLC. 2007 Abstract We compare the analytical performance of a modern quadrupole-based ICP-MS (“X-Series”, Thermo-Electron, Winsford, UK) with a single-collector double-focusing sector-field ICP-MS (“Axiom”, VG Elemental, Winsford, UK) for uranium isotopic measurements in environmental samples. We focus on the precision and accuracy obtained with both instruments for the 235U/238U isotopic ratios and on the abundance sensitivity that is a key parameter for low 236U/238U isotopic ratios measurements. We observe that isotopic measurements are more precise accurate with the “X-Series” than with the “Axiom”. Besides, we demonstrate that the “Axiom’s” higher abundance sensitivity limits its capability to measure 236U/238U ratio below a few ppm. Isotopic Ratio (dpeaa)DE-He213 Relative Standard Deviation (dpeaa)DE-He213 Mass Bias (dpeaa)DE-He213 Isotopic Ratio Measurement (dpeaa)DE-He213 Isotopic Standard (dpeaa)DE-He213 Hubert, A. aut Baglan, N. aut Hémet, P. aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 276(2008), 2 vom: Mai, Seite 505-511 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:276 year:2008 number:2 month:05 pages:505-511 https://dx.doi.org/10.1007/s10967-008-0534-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 276 2008 2 05 505-511 |
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10.1007/s10967-008-0534-9 doi (DE-627)SPR01515713X (SPR)s10967-008-0534-9-e DE-627 ger DE-627 rakwb eng Pointurier, F. verfasserin aut Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media, LLC. 2007 Abstract We compare the analytical performance of a modern quadrupole-based ICP-MS (“X-Series”, Thermo-Electron, Winsford, UK) with a single-collector double-focusing sector-field ICP-MS (“Axiom”, VG Elemental, Winsford, UK) for uranium isotopic measurements in environmental samples. We focus on the precision and accuracy obtained with both instruments for the 235U/238U isotopic ratios and on the abundance sensitivity that is a key parameter for low 236U/238U isotopic ratios measurements. We observe that isotopic measurements are more precise accurate with the “X-Series” than with the “Axiom”. Besides, we demonstrate that the “Axiom’s” higher abundance sensitivity limits its capability to measure 236U/238U ratio below a few ppm. Isotopic Ratio (dpeaa)DE-He213 Relative Standard Deviation (dpeaa)DE-He213 Mass Bias (dpeaa)DE-He213 Isotopic Ratio Measurement (dpeaa)DE-He213 Isotopic Standard (dpeaa)DE-He213 Hubert, A. aut Baglan, N. aut Hémet, P. aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 276(2008), 2 vom: Mai, Seite 505-511 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:276 year:2008 number:2 month:05 pages:505-511 https://dx.doi.org/10.1007/s10967-008-0534-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 276 2008 2 05 505-511 |
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Pointurier, F. |
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Pointurier, F. misc Isotopic Ratio misc Relative Standard Deviation misc Mass Bias misc Isotopic Ratio Measurement misc Isotopic Standard Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples |
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Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples Isotopic Ratio (dpeaa)DE-He213 Relative Standard Deviation (dpeaa)DE-He213 Mass Bias (dpeaa)DE-He213 Isotopic Ratio Measurement (dpeaa)DE-He213 Isotopic Standard (dpeaa)DE-He213 |
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misc Isotopic Ratio misc Relative Standard Deviation misc Mass Bias misc Isotopic Ratio Measurement misc Isotopic Standard |
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misc Isotopic Ratio misc Relative Standard Deviation misc Mass Bias misc Isotopic Ratio Measurement misc Isotopic Standard |
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Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples |
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Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples |
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Pointurier, F. |
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10.1007/s10967-008-0534-9 |
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evaluation of a new generation quadrupole-based icp-ms for uranium isotopic measurements in environmental samples |
| title_auth |
Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples |
| abstract |
Abstract We compare the analytical performance of a modern quadrupole-based ICP-MS (“X-Series”, Thermo-Electron, Winsford, UK) with a single-collector double-focusing sector-field ICP-MS (“Axiom”, VG Elemental, Winsford, UK) for uranium isotopic measurements in environmental samples. We focus on the precision and accuracy obtained with both instruments for the 235U/238U isotopic ratios and on the abundance sensitivity that is a key parameter for low 236U/238U isotopic ratios measurements. We observe that isotopic measurements are more precise accurate with the “X-Series” than with the “Axiom”. Besides, we demonstrate that the “Axiom’s” higher abundance sensitivity limits its capability to measure 236U/238U ratio below a few ppm. © Springer Science+Business Media, LLC. 2007 |
| abstractGer |
Abstract We compare the analytical performance of a modern quadrupole-based ICP-MS (“X-Series”, Thermo-Electron, Winsford, UK) with a single-collector double-focusing sector-field ICP-MS (“Axiom”, VG Elemental, Winsford, UK) for uranium isotopic measurements in environmental samples. We focus on the precision and accuracy obtained with both instruments for the 235U/238U isotopic ratios and on the abundance sensitivity that is a key parameter for low 236U/238U isotopic ratios measurements. We observe that isotopic measurements are more precise accurate with the “X-Series” than with the “Axiom”. Besides, we demonstrate that the “Axiom’s” higher abundance sensitivity limits its capability to measure 236U/238U ratio below a few ppm. © Springer Science+Business Media, LLC. 2007 |
| abstract_unstemmed |
Abstract We compare the analytical performance of a modern quadrupole-based ICP-MS (“X-Series”, Thermo-Electron, Winsford, UK) with a single-collector double-focusing sector-field ICP-MS (“Axiom”, VG Elemental, Winsford, UK) for uranium isotopic measurements in environmental samples. We focus on the precision and accuracy obtained with both instruments for the 235U/238U isotopic ratios and on the abundance sensitivity that is a key parameter for low 236U/238U isotopic ratios measurements. We observe that isotopic measurements are more precise accurate with the “X-Series” than with the “Axiom”. Besides, we demonstrate that the “Axiom’s” higher abundance sensitivity limits its capability to measure 236U/238U ratio below a few ppm. © Springer Science+Business Media, LLC. 2007 |
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Evaluation of a new generation quadrupole-based ICP-MS for uranium isotopic measurements in environmental samples |
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https://dx.doi.org/10.1007/s10967-008-0534-9 |
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Hubert, A. Baglan, N. Hémet, P. |
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10.1007/s10967-008-0534-9 |
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2024-07-03T14:18:02.026Z |
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| score |
7.398837 |