The reaction conditions influence on sucrose acid hydrolysis studied by means of DSC method
Abstract The influence of the reaction conditions upon the sucrose acid hydrolysis to glucose/fructose equimolecular mixture was investigated, in heterogeneous and homogeneous system, by means of DSC method. The recorded DSC signal was used to evaluate the kinetic parameters and the afferent catalyt...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Chambré, Dorina [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2007 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC. 2007 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969, 88(2007), 3 vom: Juni, Seite 681-686 |
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| Übergeordnetes Werk: |
volume:88 ; year:2007 ; number:3 ; month:06 ; pages:681-686 |
| Links: |
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| DOI / URN: |
10.1007/s10973-006-8043-y |
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| Katalog-ID: |
SPR015292959 |
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| 100 | 1 | |a Chambré, Dorina |e verfasserin |4 aut | |
| 245 | 1 | 4 | |a The reaction conditions influence on sucrose acid hydrolysis studied by means of DSC method |
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| 500 | |a © Springer Science+Business Media, LLC. 2007 | ||
| 520 | |a Abstract The influence of the reaction conditions upon the sucrose acid hydrolysis to glucose/fructose equimolecular mixture was investigated, in heterogeneous and homogeneous system, by means of DSC method. The recorded DSC signal was used to evaluate the kinetic parameters and the afferent catalytic constant, kcat323 values. In homogeneous conditions the used catalyst was acetic acid while in heterogeneous systems a series of carboxylic resins was used as catalysts. The results show a dependence of the kinetic parameters on homogeneous/heterogeneous catalyst nature and on resins experimental properties (cross-linking degree, granulation, porous nature of polymeric matrix, swelling time). | ||
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| 650 | 4 | |a catalytic kinetic parameters |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a DSC |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a homogeneous/heterogeneous acid catalysis |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a sucrose cationite hydrolysis |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Idiţoiu, Cornelia |4 aut | |
| 700 | 1 | |a Szabo, Maria-Raluca |4 aut | |
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10.1007/s10973-006-8043-y doi (DE-627)SPR015292959 (SPR)s10973-006-8043-y-e DE-627 ger DE-627 rakwb eng Chambré, Dorina verfasserin aut The reaction conditions influence on sucrose acid hydrolysis studied by means of DSC method 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media, LLC. 2007 Abstract The influence of the reaction conditions upon the sucrose acid hydrolysis to glucose/fructose equimolecular mixture was investigated, in heterogeneous and homogeneous system, by means of DSC method. The recorded DSC signal was used to evaluate the kinetic parameters and the afferent catalytic constant, kcat323 values. In homogeneous conditions the used catalyst was acetic acid while in heterogeneous systems a series of carboxylic resins was used as catalysts. The results show a dependence of the kinetic parameters on homogeneous/heterogeneous catalyst nature and on resins experimental properties (cross-linking degree, granulation, porous nature of polymeric matrix, swelling time). carboxylic resins catalysts (dpeaa)DE-He213 catalytic kinetic parameters (dpeaa)DE-He213 DSC (dpeaa)DE-He213 homogeneous/heterogeneous acid catalysis (dpeaa)DE-He213 sucrose cationite hydrolysis (dpeaa)DE-He213 Idiţoiu, Cornelia aut Szabo, Maria-Raluca aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 88(2007), 3 vom: Juni, Seite 681-686 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:88 year:2007 number:3 month:06 pages:681-686 https://dx.doi.org/10.1007/s10973-006-8043-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 88 2007 3 06 681-686 |
| spelling |
10.1007/s10973-006-8043-y doi (DE-627)SPR015292959 (SPR)s10973-006-8043-y-e DE-627 ger DE-627 rakwb eng Chambré, Dorina verfasserin aut The reaction conditions influence on sucrose acid hydrolysis studied by means of DSC method 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media, LLC. 2007 Abstract The influence of the reaction conditions upon the sucrose acid hydrolysis to glucose/fructose equimolecular mixture was investigated, in heterogeneous and homogeneous system, by means of DSC method. The recorded DSC signal was used to evaluate the kinetic parameters and the afferent catalytic constant, kcat323 values. In homogeneous conditions the used catalyst was acetic acid while in heterogeneous systems a series of carboxylic resins was used as catalysts. The results show a dependence of the kinetic parameters on homogeneous/heterogeneous catalyst nature and on resins experimental properties (cross-linking degree, granulation, porous nature of polymeric matrix, swelling time). carboxylic resins catalysts (dpeaa)DE-He213 catalytic kinetic parameters (dpeaa)DE-He213 DSC (dpeaa)DE-He213 homogeneous/heterogeneous acid catalysis (dpeaa)DE-He213 sucrose cationite hydrolysis (dpeaa)DE-He213 Idiţoiu, Cornelia aut Szabo, Maria-Raluca aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 88(2007), 3 vom: Juni, Seite 681-686 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:88 year:2007 number:3 month:06 pages:681-686 https://dx.doi.org/10.1007/s10973-006-8043-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 88 2007 3 06 681-686 |
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10.1007/s10973-006-8043-y doi (DE-627)SPR015292959 (SPR)s10973-006-8043-y-e DE-627 ger DE-627 rakwb eng Chambré, Dorina verfasserin aut The reaction conditions influence on sucrose acid hydrolysis studied by means of DSC method 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media, LLC. 2007 Abstract The influence of the reaction conditions upon the sucrose acid hydrolysis to glucose/fructose equimolecular mixture was investigated, in heterogeneous and homogeneous system, by means of DSC method. The recorded DSC signal was used to evaluate the kinetic parameters and the afferent catalytic constant, kcat323 values. In homogeneous conditions the used catalyst was acetic acid while in heterogeneous systems a series of carboxylic resins was used as catalysts. The results show a dependence of the kinetic parameters on homogeneous/heterogeneous catalyst nature and on resins experimental properties (cross-linking degree, granulation, porous nature of polymeric matrix, swelling time). carboxylic resins catalysts (dpeaa)DE-He213 catalytic kinetic parameters (dpeaa)DE-He213 DSC (dpeaa)DE-He213 homogeneous/heterogeneous acid catalysis (dpeaa)DE-He213 sucrose cationite hydrolysis (dpeaa)DE-He213 Idiţoiu, Cornelia aut Szabo, Maria-Raluca aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 88(2007), 3 vom: Juni, Seite 681-686 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:88 year:2007 number:3 month:06 pages:681-686 https://dx.doi.org/10.1007/s10973-006-8043-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 88 2007 3 06 681-686 |
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10.1007/s10973-006-8043-y doi (DE-627)SPR015292959 (SPR)s10973-006-8043-y-e DE-627 ger DE-627 rakwb eng Chambré, Dorina verfasserin aut The reaction conditions influence on sucrose acid hydrolysis studied by means of DSC method 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media, LLC. 2007 Abstract The influence of the reaction conditions upon the sucrose acid hydrolysis to glucose/fructose equimolecular mixture was investigated, in heterogeneous and homogeneous system, by means of DSC method. The recorded DSC signal was used to evaluate the kinetic parameters and the afferent catalytic constant, kcat323 values. In homogeneous conditions the used catalyst was acetic acid while in heterogeneous systems a series of carboxylic resins was used as catalysts. The results show a dependence of the kinetic parameters on homogeneous/heterogeneous catalyst nature and on resins experimental properties (cross-linking degree, granulation, porous nature of polymeric matrix, swelling time). carboxylic resins catalysts (dpeaa)DE-He213 catalytic kinetic parameters (dpeaa)DE-He213 DSC (dpeaa)DE-He213 homogeneous/heterogeneous acid catalysis (dpeaa)DE-He213 sucrose cationite hydrolysis (dpeaa)DE-He213 Idiţoiu, Cornelia aut Szabo, Maria-Raluca aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 88(2007), 3 vom: Juni, Seite 681-686 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:88 year:2007 number:3 month:06 pages:681-686 https://dx.doi.org/10.1007/s10973-006-8043-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 88 2007 3 06 681-686 |
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10.1007/s10973-006-8043-y doi (DE-627)SPR015292959 (SPR)s10973-006-8043-y-e DE-627 ger DE-627 rakwb eng Chambré, Dorina verfasserin aut The reaction conditions influence on sucrose acid hydrolysis studied by means of DSC method 2007 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media, LLC. 2007 Abstract The influence of the reaction conditions upon the sucrose acid hydrolysis to glucose/fructose equimolecular mixture was investigated, in heterogeneous and homogeneous system, by means of DSC method. The recorded DSC signal was used to evaluate the kinetic parameters and the afferent catalytic constant, kcat323 values. In homogeneous conditions the used catalyst was acetic acid while in heterogeneous systems a series of carboxylic resins was used as catalysts. The results show a dependence of the kinetic parameters on homogeneous/heterogeneous catalyst nature and on resins experimental properties (cross-linking degree, granulation, porous nature of polymeric matrix, swelling time). carboxylic resins catalysts (dpeaa)DE-He213 catalytic kinetic parameters (dpeaa)DE-He213 DSC (dpeaa)DE-He213 homogeneous/heterogeneous acid catalysis (dpeaa)DE-He213 sucrose cationite hydrolysis (dpeaa)DE-He213 Idiţoiu, Cornelia aut Szabo, Maria-Raluca aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 88(2007), 3 vom: Juni, Seite 681-686 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:88 year:2007 number:3 month:06 pages:681-686 https://dx.doi.org/10.1007/s10973-006-8043-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 88 2007 3 06 681-686 |
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Enthalten in Journal of thermal analysis and calorimetry 88(2007), 3 vom: Juni, Seite 681-686 volume:88 year:2007 number:3 month:06 pages:681-686 |
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Enthalten in Journal of thermal analysis and calorimetry 88(2007), 3 vom: Juni, Seite 681-686 volume:88 year:2007 number:3 month:06 pages:681-686 |
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Chambré, Dorina @@aut@@ Idiţoiu, Cornelia @@aut@@ Szabo, Maria-Raluca @@aut@@ |
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Chambré, Dorina |
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Chambré, Dorina misc carboxylic resins catalysts misc catalytic kinetic parameters misc DSC misc homogeneous/heterogeneous acid catalysis misc sucrose cationite hydrolysis The reaction conditions influence on sucrose acid hydrolysis studied by means of DSC method |
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The reaction conditions influence on sucrose acid hydrolysis studied by means of DSC method carboxylic resins catalysts (dpeaa)DE-He213 catalytic kinetic parameters (dpeaa)DE-He213 DSC (dpeaa)DE-He213 homogeneous/heterogeneous acid catalysis (dpeaa)DE-He213 sucrose cationite hydrolysis (dpeaa)DE-He213 |
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reaction conditions influence on sucrose acid hydrolysis studied by means of dsc method |
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The reaction conditions influence on sucrose acid hydrolysis studied by means of DSC method |
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Abstract The influence of the reaction conditions upon the sucrose acid hydrolysis to glucose/fructose equimolecular mixture was investigated, in heterogeneous and homogeneous system, by means of DSC method. The recorded DSC signal was used to evaluate the kinetic parameters and the afferent catalytic constant, kcat323 values. In homogeneous conditions the used catalyst was acetic acid while in heterogeneous systems a series of carboxylic resins was used as catalysts. The results show a dependence of the kinetic parameters on homogeneous/heterogeneous catalyst nature and on resins experimental properties (cross-linking degree, granulation, porous nature of polymeric matrix, swelling time). © Springer Science+Business Media, LLC. 2007 |
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Abstract The influence of the reaction conditions upon the sucrose acid hydrolysis to glucose/fructose equimolecular mixture was investigated, in heterogeneous and homogeneous system, by means of DSC method. The recorded DSC signal was used to evaluate the kinetic parameters and the afferent catalytic constant, kcat323 values. In homogeneous conditions the used catalyst was acetic acid while in heterogeneous systems a series of carboxylic resins was used as catalysts. The results show a dependence of the kinetic parameters on homogeneous/heterogeneous catalyst nature and on resins experimental properties (cross-linking degree, granulation, porous nature of polymeric matrix, swelling time). © Springer Science+Business Media, LLC. 2007 |
| abstract_unstemmed |
Abstract The influence of the reaction conditions upon the sucrose acid hydrolysis to glucose/fructose equimolecular mixture was investigated, in heterogeneous and homogeneous system, by means of DSC method. The recorded DSC signal was used to evaluate the kinetic parameters and the afferent catalytic constant, kcat323 values. In homogeneous conditions the used catalyst was acetic acid while in heterogeneous systems a series of carboxylic resins was used as catalysts. The results show a dependence of the kinetic parameters on homogeneous/heterogeneous catalyst nature and on resins experimental properties (cross-linking degree, granulation, porous nature of polymeric matrix, swelling time). © Springer Science+Business Media, LLC. 2007 |
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