Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation
Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addit...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Bykov, V. I. [verfasserIn] Khmarin, E. M. [verfasserIn] Belyaev, B. A. [verfasserIn] Butenko, T. A. [verfasserIn] Finkel’shtein, E. Sh. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2008 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Kinetics and catalysis - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960, 49(2008), 1 vom: Jan., Seite 11-17 |
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| Übergeordnetes Werk: |
volume:49 ; year:2008 ; number:1 ; month:01 ; pages:11-17 |
| Links: |
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| DOI / URN: |
10.1134/S0023158408010023 |
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| Katalog-ID: |
SPR015310701 |
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| 100 | 1 | |a Bykov, V. I. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation |
| 264 | 1 | |c 2008 | |
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| 520 | |a Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addition of a third component (silicon tetrachloride or germanium tetrachloride in combination with tetramethyltin) to a partially deactivated catalyst. The number of active centers was determined (5–6% of the amount of Mo), and the mechanisms of formation, deactivation, and reactivation were proposed for the binary and ternary catalytic systems. The roles of the individual components of the catalytic systems were revealed. | ||
| 650 | 4 | |a Metathesis |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Metathesis Reaction |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Silicon Tetrachloride |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Carbene Center |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Germanium Tetrachloride |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Khmarin, E. M. |e verfasserin |4 aut | |
| 700 | 1 | |a Belyaev, B. A. |e verfasserin |4 aut | |
| 700 | 1 | |a Butenko, T. A. |e verfasserin |4 aut | |
| 700 | 1 | |a Finkel’shtein, E. Sh. |e verfasserin |4 aut | |
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10.1134/S0023158408010023 doi (DE-627)SPR015310701 (SPR)S0023158408010023-e DE-627 ger DE-627 rakwb eng 540 ASE 35.17 bkl 35.13 bkl Bykov, V. I. verfasserin aut Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addition of a third component (silicon tetrachloride or germanium tetrachloride in combination with tetramethyltin) to a partially deactivated catalyst. The number of active centers was determined (5–6% of the amount of Mo), and the mechanisms of formation, deactivation, and reactivation were proposed for the binary and ternary catalytic systems. The roles of the individual components of the catalytic systems were revealed. Metathesis (dpeaa)DE-He213 Metathesis Reaction (dpeaa)DE-He213 Silicon Tetrachloride (dpeaa)DE-He213 Carbene Center (dpeaa)DE-He213 Germanium Tetrachloride (dpeaa)DE-He213 Khmarin, E. M. verfasserin aut Belyaev, B. A. verfasserin aut Butenko, T. A. verfasserin aut Finkel’shtein, E. Sh. verfasserin aut Enthalten in Kinetics and catalysis Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960 49(2008), 1 vom: Jan., Seite 11-17 (DE-627)334375800 (DE-600)2057716-3 1608-3210 nnns volume:49 year:2008 number:1 month:01 pages:11-17 https://dx.doi.org/10.1134/S0023158408010023 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE 35.13 ASE AR 49 2008 1 01 11-17 |
| spelling |
10.1134/S0023158408010023 doi (DE-627)SPR015310701 (SPR)S0023158408010023-e DE-627 ger DE-627 rakwb eng 540 ASE 35.17 bkl 35.13 bkl Bykov, V. I. verfasserin aut Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addition of a third component (silicon tetrachloride or germanium tetrachloride in combination with tetramethyltin) to a partially deactivated catalyst. The number of active centers was determined (5–6% of the amount of Mo), and the mechanisms of formation, deactivation, and reactivation were proposed for the binary and ternary catalytic systems. The roles of the individual components of the catalytic systems were revealed. Metathesis (dpeaa)DE-He213 Metathesis Reaction (dpeaa)DE-He213 Silicon Tetrachloride (dpeaa)DE-He213 Carbene Center (dpeaa)DE-He213 Germanium Tetrachloride (dpeaa)DE-He213 Khmarin, E. M. verfasserin aut Belyaev, B. A. verfasserin aut Butenko, T. A. verfasserin aut Finkel’shtein, E. Sh. verfasserin aut Enthalten in Kinetics and catalysis Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960 49(2008), 1 vom: Jan., Seite 11-17 (DE-627)334375800 (DE-600)2057716-3 1608-3210 nnns volume:49 year:2008 number:1 month:01 pages:11-17 https://dx.doi.org/10.1134/S0023158408010023 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE 35.13 ASE AR 49 2008 1 01 11-17 |
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10.1134/S0023158408010023 doi (DE-627)SPR015310701 (SPR)S0023158408010023-e DE-627 ger DE-627 rakwb eng 540 ASE 35.17 bkl 35.13 bkl Bykov, V. I. verfasserin aut Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addition of a third component (silicon tetrachloride or germanium tetrachloride in combination with tetramethyltin) to a partially deactivated catalyst. The number of active centers was determined (5–6% of the amount of Mo), and the mechanisms of formation, deactivation, and reactivation were proposed for the binary and ternary catalytic systems. The roles of the individual components of the catalytic systems were revealed. Metathesis (dpeaa)DE-He213 Metathesis Reaction (dpeaa)DE-He213 Silicon Tetrachloride (dpeaa)DE-He213 Carbene Center (dpeaa)DE-He213 Germanium Tetrachloride (dpeaa)DE-He213 Khmarin, E. M. verfasserin aut Belyaev, B. A. verfasserin aut Butenko, T. A. verfasserin aut Finkel’shtein, E. Sh. verfasserin aut Enthalten in Kinetics and catalysis Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960 49(2008), 1 vom: Jan., Seite 11-17 (DE-627)334375800 (DE-600)2057716-3 1608-3210 nnns volume:49 year:2008 number:1 month:01 pages:11-17 https://dx.doi.org/10.1134/S0023158408010023 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE 35.13 ASE AR 49 2008 1 01 11-17 |
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10.1134/S0023158408010023 doi (DE-627)SPR015310701 (SPR)S0023158408010023-e DE-627 ger DE-627 rakwb eng 540 ASE 35.17 bkl 35.13 bkl Bykov, V. I. verfasserin aut Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addition of a third component (silicon tetrachloride or germanium tetrachloride in combination with tetramethyltin) to a partially deactivated catalyst. The number of active centers was determined (5–6% of the amount of Mo), and the mechanisms of formation, deactivation, and reactivation were proposed for the binary and ternary catalytic systems. The roles of the individual components of the catalytic systems were revealed. Metathesis (dpeaa)DE-He213 Metathesis Reaction (dpeaa)DE-He213 Silicon Tetrachloride (dpeaa)DE-He213 Carbene Center (dpeaa)DE-He213 Germanium Tetrachloride (dpeaa)DE-He213 Khmarin, E. M. verfasserin aut Belyaev, B. A. verfasserin aut Butenko, T. A. verfasserin aut Finkel’shtein, E. Sh. verfasserin aut Enthalten in Kinetics and catalysis Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960 49(2008), 1 vom: Jan., Seite 11-17 (DE-627)334375800 (DE-600)2057716-3 1608-3210 nnns volume:49 year:2008 number:1 month:01 pages:11-17 https://dx.doi.org/10.1134/S0023158408010023 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE 35.13 ASE AR 49 2008 1 01 11-17 |
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10.1134/S0023158408010023 doi (DE-627)SPR015310701 (SPR)S0023158408010023-e DE-627 ger DE-627 rakwb eng 540 ASE 35.17 bkl 35.13 bkl Bykov, V. I. verfasserin aut Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addition of a third component (silicon tetrachloride or germanium tetrachloride in combination with tetramethyltin) to a partially deactivated catalyst. The number of active centers was determined (5–6% of the amount of Mo), and the mechanisms of formation, deactivation, and reactivation were proposed for the binary and ternary catalytic systems. The roles of the individual components of the catalytic systems were revealed. Metathesis (dpeaa)DE-He213 Metathesis Reaction (dpeaa)DE-He213 Silicon Tetrachloride (dpeaa)DE-He213 Carbene Center (dpeaa)DE-He213 Germanium Tetrachloride (dpeaa)DE-He213 Khmarin, E. M. verfasserin aut Belyaev, B. A. verfasserin aut Butenko, T. A. verfasserin aut Finkel’shtein, E. Sh. verfasserin aut Enthalten in Kinetics and catalysis Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960 49(2008), 1 vom: Jan., Seite 11-17 (DE-627)334375800 (DE-600)2057716-3 1608-3210 nnns volume:49 year:2008 number:1 month:01 pages:11-17 https://dx.doi.org/10.1134/S0023158408010023 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE 35.13 ASE AR 49 2008 1 01 11-17 |
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Enthalten in Kinetics and catalysis 49(2008), 1 vom: Jan., Seite 11-17 volume:49 year:2008 number:1 month:01 pages:11-17 |
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Enthalten in Kinetics and catalysis 49(2008), 1 vom: Jan., Seite 11-17 volume:49 year:2008 number:1 month:01 pages:11-17 |
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Bykov, V. I. @@aut@@ Khmarin, E. M. @@aut@@ Belyaev, B. A. @@aut@@ Butenko, T. A. @@aut@@ Finkel’shtein, E. Sh. @@aut@@ |
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I.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2008</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addition of a third component (silicon tetrachloride or germanium tetrachloride in combination with tetramethyltin) to a partially deactivated catalyst. The number of active centers was determined (5–6% of the amount of Mo), and the mechanisms of formation, deactivation, and reactivation were proposed for the binary and ternary catalytic systems. The roles of the individual components of the catalytic systems were revealed.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Metathesis</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Metathesis Reaction</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Silicon Tetrachloride</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Carbene Center</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Germanium Tetrachloride</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Khmarin, E. 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|
| author |
Bykov, V. I. |
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Bykov, V. I. ddc 540 bkl 35.17 bkl 35.13 misc Metathesis misc Metathesis Reaction misc Silicon Tetrachloride misc Carbene Center misc Germanium Tetrachloride Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation |
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540 - Chemistry & allied sciences |
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1608-3210 |
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540 ASE 35.17 bkl 35.13 bkl Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation Metathesis (dpeaa)DE-He213 Metathesis Reaction (dpeaa)DE-He213 Silicon Tetrachloride (dpeaa)DE-He213 Carbene Center (dpeaa)DE-He213 Germanium Tetrachloride (dpeaa)DE-He213 |
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ddc 540 bkl 35.17 bkl 35.13 misc Metathesis misc Metathesis Reaction misc Silicon Tetrachloride misc Carbene Center misc Germanium Tetrachloride |
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ddc 540 bkl 35.17 bkl 35.13 misc Metathesis misc Metathesis Reaction misc Silicon Tetrachloride misc Carbene Center misc Germanium Tetrachloride |
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ddc 540 bkl 35.17 bkl 35.13 misc Metathesis misc Metathesis Reaction misc Silicon Tetrachloride misc Carbene Center misc Germanium Tetrachloride |
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Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation |
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(DE-627)SPR015310701 (SPR)S0023158408010023-e |
| title_full |
Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation |
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Bykov, V. I. |
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Kinetics and catalysis |
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Kinetics and catalysis |
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eng |
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500 - Science |
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2008 |
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Bykov, V. I. Khmarin, E. M. Belyaev, B. A. Butenko, T. A. Finkel’shtein, E. Sh. |
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49 |
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540 ASE 35.17 bkl 35.13 bkl |
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Elektronische Aufsätze |
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Bykov, V. I. |
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10.1134/S0023158408010023 |
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540 |
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verfasserin |
| title_sort |
kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ mocl_{5} $/$ sio_{2} $: determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation |
| title_auth |
Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation |
| abstract |
Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addition of a third component (silicon tetrachloride or germanium tetrachloride in combination with tetramethyltin) to a partially deactivated catalyst. The number of active centers was determined (5–6% of the amount of Mo), and the mechanisms of formation, deactivation, and reactivation were proposed for the binary and ternary catalytic systems. The roles of the individual components of the catalytic systems were revealed. |
| abstractGer |
Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addition of a third component (silicon tetrachloride or germanium tetrachloride in combination with tetramethyltin) to a partially deactivated catalyst. The number of active centers was determined (5–6% of the amount of Mo), and the mechanisms of formation, deactivation, and reactivation were proposed for the binary and ternary catalytic systems. The roles of the individual components of the catalytic systems were revealed. |
| abstract_unstemmed |
Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addition of a third component (silicon tetrachloride or germanium tetrachloride in combination with tetramethyltin) to a partially deactivated catalyst. The number of active centers was determined (5–6% of the amount of Mo), and the mechanisms of formation, deactivation, and reactivation were proposed for the binary and ternary catalytic systems. The roles of the individual components of the catalytic systems were revealed. |
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1 |
| title_short |
Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation |
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https://dx.doi.org/10.1134/S0023158408010023 |
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Khmarin, E. M. Belyaev, B. A. Butenko, T. A. Finkel’shtein, E. Sh |
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Khmarin, E. M. Belyaev, B. A. Butenko, T. A. Finkel’shtein, E. Sh |
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10.1134/S0023158408010023 |
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2024-07-03T15:22:32.561Z |
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| score |
7.4004374 |