Kinetics of α-olefin metathesis on binary and ternary catalytic systems based on $ MoCl_{5} $/$ SiO_{2} $: Determination of the number of active centers and the mechanisms of their formation, deactivation, and reactivation

Abstract The kinetics of α-olefin metathesis in the presence of binary ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn) and ternary catalytic systems ($ MoCl_{5} $/$ SiO_{2} $-$ Me_{4} $Sn-$ ECl_{4} $, E = Si or Ge) was studied. It was found that reactivation in the course of metathesis occurred on the addit...
Ausführliche Beschreibung

Gespeichert in:
Autor*in:

Bykov, V. I. [verfasserIn]

Khmarin, E. M. [verfasserIn]

Belyaev, B. A. [verfasserIn]

Butenko, T. A. [verfasserIn]

Finkel’shtein, E. Sh. [verfasserIn]

Format:

E-Artikel

Sprache:

Englisch

Erschienen:

2008

Schlagwörter:

Metathesis

Metathesis Reaction

Silicon Tetrachloride

Carbene Center

Germanium Tetrachloride

Übergeordnetes Werk:

Enthalten in: Kinetics and catalysis - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960, 49(2008), 1 vom: Jan., Seite 11-17

Übergeordnetes Werk:

volume:49 ; year:2008 ; number:1 ; month:01 ; pages:11-17

Links:

Volltext

DOI / URN:

10.1134/S0023158408010023

Katalog-ID:

SPR015310701

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