Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells

Abstract It is stated that one-dimensional conductivity in amorphous microporous carbon material (AMCM) samples is associated with the considerable imperfection of graphene fragments in the carbon material rather than the presence of unshared electrons. It is likely that the graphene fragments are f...
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Autor*in:	Barnakov, Ch. N. [verfasserIn] Kozlov, A. P. [verfasserIn] Romanenko, A. I. [verfasserIn] Vasenin, N. T. [verfasserIn] Anufrienko, V. F. [verfasserIn] Ismagilov, Z. R. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2010

Schlagwörter:	Carbonization Temperature Carbyne Dimensional Conductivity Graphene Fragment Carbyne Chain

Übergeordnetes Werk:	Enthalten in: Kinetics and catalysis - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960, 51(2010), 2 vom: März, Seite 312-317
Übergeordnetes Werk:	volume:51 ; year:2010 ; number:2 ; month:03 ; pages:312-317

Links:	Volltext

DOI / URN:	10.1134/S0023158410020217

Katalog-ID:	SPR015313891

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520			\|a Abstract It is stated that one-dimensional conductivity in amorphous microporous carbon material (AMCM) samples is associated with the considerable imperfection of graphene fragments in the carbon material rather than the presence of unshared electrons. It is likely that the graphene fragments are formed upon the carbonization of a carbon precursor accompanied by the partial or complete removal of precursor heteroatoms. It is hypothesized that the presence of localized unpaired electrons, which give EPR spectra, is due to the formation of local defects in carbene fragments. Thus, the effects of the value of conductivity and the concentration of unpaired electrons on the power output of a fuel cell cannot be distinguished based on the experimental data with the use of an AMCM as a catalyst support. The interaction of localized paramagnetic centers with electron gas can be interpreted in terms of the C-S relaxation model.
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700	1		\|a Kozlov, A. P. \|e verfasserin \|4 aut
700	1		\|a Romanenko, A. I. \|e verfasserin \|4 aut
700	1		\|a Vasenin, N. T. \|e verfasserin \|4 aut
700	1		\|a Anufrienko, V. F. \|e verfasserin \|4 aut
700	1		\|a Ismagilov, Z. R. \|e verfasserin \|4 aut
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912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_206
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
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author_variant	c n b cn cnb a p k ap apk a i r ai air n t v nt ntv v f a vf vfa z r i zr zri
matchkey_str	article:16083210:2010----::yteiadrprisfmcooosabnaeilsctls
hierarchy_sort_str	2010
bklnumber	35.17 35.13
publishDate	2010
allfields	10.1134/S0023158410020217 doi (DE-627)SPR015313891 (SPR)S0023158410020217-e DE-627 ger DE-627 rakwb eng 540 ASE 35.17 bkl 35.13 bkl Barnakov, Ch. N. verfasserin aut Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract It is stated that one-dimensional conductivity in amorphous microporous carbon material (AMCM) samples is associated with the considerable imperfection of graphene fragments in the carbon material rather than the presence of unshared electrons. It is likely that the graphene fragments are formed upon the carbonization of a carbon precursor accompanied by the partial or complete removal of precursor heteroatoms. It is hypothesized that the presence of localized unpaired electrons, which give EPR spectra, is due to the formation of local defects in carbene fragments. Thus, the effects of the value of conductivity and the concentration of unpaired electrons on the power output of a fuel cell cannot be distinguished based on the experimental data with the use of an AMCM as a catalyst support. The interaction of localized paramagnetic centers with electron gas can be interpreted in terms of the C-S relaxation model. Carbonization Temperature (dpeaa)DE-He213 Carbyne (dpeaa)DE-He213 Dimensional Conductivity (dpeaa)DE-He213 Graphene Fragment (dpeaa)DE-He213 Carbyne Chain (dpeaa)DE-He213 Kozlov, A. P. verfasserin aut Romanenko, A. I. verfasserin aut Vasenin, N. T. verfasserin aut Anufrienko, V. F. verfasserin aut Ismagilov, Z. R. verfasserin aut Enthalten in Kinetics and catalysis Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960 51(2010), 2 vom: März, Seite 312-317 (DE-627)334375800 (DE-600)2057716-3 1608-3210 nnns volume:51 year:2010 number:2 month:03 pages:312-317 https://dx.doi.org/10.1134/S0023158410020217 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE 35.13 ASE AR 51 2010 2 03 312-317
spelling	10.1134/S0023158410020217 doi (DE-627)SPR015313891 (SPR)S0023158410020217-e DE-627 ger DE-627 rakwb eng 540 ASE 35.17 bkl 35.13 bkl Barnakov, Ch. N. verfasserin aut Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract It is stated that one-dimensional conductivity in amorphous microporous carbon material (AMCM) samples is associated with the considerable imperfection of graphene fragments in the carbon material rather than the presence of unshared electrons. It is likely that the graphene fragments are formed upon the carbonization of a carbon precursor accompanied by the partial or complete removal of precursor heteroatoms. It is hypothesized that the presence of localized unpaired electrons, which give EPR spectra, is due to the formation of local defects in carbene fragments. Thus, the effects of the value of conductivity and the concentration of unpaired electrons on the power output of a fuel cell cannot be distinguished based on the experimental data with the use of an AMCM as a catalyst support. The interaction of localized paramagnetic centers with electron gas can be interpreted in terms of the C-S relaxation model. Carbonization Temperature (dpeaa)DE-He213 Carbyne (dpeaa)DE-He213 Dimensional Conductivity (dpeaa)DE-He213 Graphene Fragment (dpeaa)DE-He213 Carbyne Chain (dpeaa)DE-He213 Kozlov, A. P. verfasserin aut Romanenko, A. I. verfasserin aut Vasenin, N. T. verfasserin aut Anufrienko, V. F. verfasserin aut Ismagilov, Z. R. verfasserin aut Enthalten in Kinetics and catalysis Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960 51(2010), 2 vom: März, Seite 312-317 (DE-627)334375800 (DE-600)2057716-3 1608-3210 nnns volume:51 year:2010 number:2 month:03 pages:312-317 https://dx.doi.org/10.1134/S0023158410020217 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE 35.13 ASE AR 51 2010 2 03 312-317
allfields_unstemmed	10.1134/S0023158410020217 doi (DE-627)SPR015313891 (SPR)S0023158410020217-e DE-627 ger DE-627 rakwb eng 540 ASE 35.17 bkl 35.13 bkl Barnakov, Ch. N. verfasserin aut Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract It is stated that one-dimensional conductivity in amorphous microporous carbon material (AMCM) samples is associated with the considerable imperfection of graphene fragments in the carbon material rather than the presence of unshared electrons. It is likely that the graphene fragments are formed upon the carbonization of a carbon precursor accompanied by the partial or complete removal of precursor heteroatoms. It is hypothesized that the presence of localized unpaired electrons, which give EPR spectra, is due to the formation of local defects in carbene fragments. Thus, the effects of the value of conductivity and the concentration of unpaired electrons on the power output of a fuel cell cannot be distinguished based on the experimental data with the use of an AMCM as a catalyst support. The interaction of localized paramagnetic centers with electron gas can be interpreted in terms of the C-S relaxation model. Carbonization Temperature (dpeaa)DE-He213 Carbyne (dpeaa)DE-He213 Dimensional Conductivity (dpeaa)DE-He213 Graphene Fragment (dpeaa)DE-He213 Carbyne Chain (dpeaa)DE-He213 Kozlov, A. P. verfasserin aut Romanenko, A. I. verfasserin aut Vasenin, N. T. verfasserin aut Anufrienko, V. F. verfasserin aut Ismagilov, Z. R. verfasserin aut Enthalten in Kinetics and catalysis Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960 51(2010), 2 vom: März, Seite 312-317 (DE-627)334375800 (DE-600)2057716-3 1608-3210 nnns volume:51 year:2010 number:2 month:03 pages:312-317 https://dx.doi.org/10.1134/S0023158410020217 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE 35.13 ASE AR 51 2010 2 03 312-317
allfieldsGer	10.1134/S0023158410020217 doi (DE-627)SPR015313891 (SPR)S0023158410020217-e DE-627 ger DE-627 rakwb eng 540 ASE 35.17 bkl 35.13 bkl Barnakov, Ch. N. verfasserin aut Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract It is stated that one-dimensional conductivity in amorphous microporous carbon material (AMCM) samples is associated with the considerable imperfection of graphene fragments in the carbon material rather than the presence of unshared electrons. It is likely that the graphene fragments are formed upon the carbonization of a carbon precursor accompanied by the partial or complete removal of precursor heteroatoms. It is hypothesized that the presence of localized unpaired electrons, which give EPR spectra, is due to the formation of local defects in carbene fragments. Thus, the effects of the value of conductivity and the concentration of unpaired electrons on the power output of a fuel cell cannot be distinguished based on the experimental data with the use of an AMCM as a catalyst support. The interaction of localized paramagnetic centers with electron gas can be interpreted in terms of the C-S relaxation model. Carbonization Temperature (dpeaa)DE-He213 Carbyne (dpeaa)DE-He213 Dimensional Conductivity (dpeaa)DE-He213 Graphene Fragment (dpeaa)DE-He213 Carbyne Chain (dpeaa)DE-He213 Kozlov, A. P. verfasserin aut Romanenko, A. I. verfasserin aut Vasenin, N. T. verfasserin aut Anufrienko, V. F. verfasserin aut Ismagilov, Z. R. verfasserin aut Enthalten in Kinetics and catalysis Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960 51(2010), 2 vom: März, Seite 312-317 (DE-627)334375800 (DE-600)2057716-3 1608-3210 nnns volume:51 year:2010 number:2 month:03 pages:312-317 https://dx.doi.org/10.1134/S0023158410020217 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE 35.13 ASE AR 51 2010 2 03 312-317
allfieldsSound	10.1134/S0023158410020217 doi (DE-627)SPR015313891 (SPR)S0023158410020217-e DE-627 ger DE-627 rakwb eng 540 ASE 35.17 bkl 35.13 bkl Barnakov, Ch. N. verfasserin aut Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract It is stated that one-dimensional conductivity in amorphous microporous carbon material (AMCM) samples is associated with the considerable imperfection of graphene fragments in the carbon material rather than the presence of unshared electrons. It is likely that the graphene fragments are formed upon the carbonization of a carbon precursor accompanied by the partial or complete removal of precursor heteroatoms. It is hypothesized that the presence of localized unpaired electrons, which give EPR spectra, is due to the formation of local defects in carbene fragments. Thus, the effects of the value of conductivity and the concentration of unpaired electrons on the power output of a fuel cell cannot be distinguished based on the experimental data with the use of an AMCM as a catalyst support. The interaction of localized paramagnetic centers with electron gas can be interpreted in terms of the C-S relaxation model. Carbonization Temperature (dpeaa)DE-He213 Carbyne (dpeaa)DE-He213 Dimensional Conductivity (dpeaa)DE-He213 Graphene Fragment (dpeaa)DE-He213 Carbyne Chain (dpeaa)DE-He213 Kozlov, A. P. verfasserin aut Romanenko, A. I. verfasserin aut Vasenin, N. T. verfasserin aut Anufrienko, V. F. verfasserin aut Ismagilov, Z. R. verfasserin aut Enthalten in Kinetics and catalysis Dordrecht [u.a.] : Springer Science + Business Media B.V, 1960 51(2010), 2 vom: März, Seite 312-317 (DE-627)334375800 (DE-600)2057716-3 1608-3210 nnns volume:51 year:2010 number:2 month:03 pages:312-317 https://dx.doi.org/10.1134/S0023158410020217 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE 35.13 ASE AR 51 2010 2 03 312-317
language	English
source	Enthalten in Kinetics and catalysis 51(2010), 2 vom: März, Seite 312-317 volume:51 year:2010 number:2 month:03 pages:312-317
sourceStr	Enthalten in Kinetics and catalysis 51(2010), 2 vom: März, Seite 312-317 volume:51 year:2010 number:2 month:03 pages:312-317
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Carbonization Temperature Carbyne Dimensional Conductivity Graphene Fragment Carbyne Chain
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container_title	Kinetics and catalysis
authorswithroles_txt_mv	Barnakov, Ch. N. @@aut@@ Kozlov, A. P. @@aut@@ Romanenko, A. I. @@aut@@ Vasenin, N. T. @@aut@@ Anufrienko, V. F. @@aut@@ Ismagilov, Z. R. @@aut@@
publishDateDaySort_date	2010-03-01T00:00:00Z
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N.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2010</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract It is stated that one-dimensional conductivity in amorphous microporous carbon material (AMCM) samples is associated with the considerable imperfection of graphene fragments in the carbon material rather than the presence of unshared electrons. It is likely that the graphene fragments are formed upon the carbonization of a carbon precursor accompanied by the partial or complete removal of precursor heteroatoms. It is hypothesized that the presence of localized unpaired electrons, which give EPR spectra, is due to the formation of local defects in carbene fragments. Thus, the effects of the value of conductivity and the concentration of unpaired electrons on the power output of a fuel cell cannot be distinguished based on the experimental data with the use of an AMCM as a catalyst support. 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author	Barnakov, Ch. N.
spellingShingle	Barnakov, Ch. N. ddc 540 bkl 35.17 bkl 35.13 misc Carbonization Temperature misc Carbyne misc Dimensional Conductivity misc Graphene Fragment misc Carbyne Chain Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells
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topic_title	540 ASE 35.17 bkl 35.13 bkl Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells Carbonization Temperature (dpeaa)DE-He213 Carbyne (dpeaa)DE-He213 Dimensional Conductivity (dpeaa)DE-He213 Graphene Fragment (dpeaa)DE-He213 Carbyne Chain (dpeaa)DE-He213
topic	ddc 540 bkl 35.17 bkl 35.13 misc Carbonization Temperature misc Carbyne misc Dimensional Conductivity misc Graphene Fragment misc Carbyne Chain
topic_unstemmed	ddc 540 bkl 35.17 bkl 35.13 misc Carbonization Temperature misc Carbyne misc Dimensional Conductivity misc Graphene Fragment misc Carbyne Chain
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title	Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells
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title_full	Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells
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title_sort	synthesis and properties of a microporous carbon material as a catalyst support for fuel cells
title_auth	Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells
abstract	Abstract It is stated that one-dimensional conductivity in amorphous microporous carbon material (AMCM) samples is associated with the considerable imperfection of graphene fragments in the carbon material rather than the presence of unshared electrons. It is likely that the graphene fragments are formed upon the carbonization of a carbon precursor accompanied by the partial or complete removal of precursor heteroatoms. It is hypothesized that the presence of localized unpaired electrons, which give EPR spectra, is due to the formation of local defects in carbene fragments. Thus, the effects of the value of conductivity and the concentration of unpaired electrons on the power output of a fuel cell cannot be distinguished based on the experimental data with the use of an AMCM as a catalyst support. The interaction of localized paramagnetic centers with electron gas can be interpreted in terms of the C-S relaxation model.
abstractGer	Abstract It is stated that one-dimensional conductivity in amorphous microporous carbon material (AMCM) samples is associated with the considerable imperfection of graphene fragments in the carbon material rather than the presence of unshared electrons. It is likely that the graphene fragments are formed upon the carbonization of a carbon precursor accompanied by the partial or complete removal of precursor heteroatoms. It is hypothesized that the presence of localized unpaired electrons, which give EPR spectra, is due to the formation of local defects in carbene fragments. Thus, the effects of the value of conductivity and the concentration of unpaired electrons on the power output of a fuel cell cannot be distinguished based on the experimental data with the use of an AMCM as a catalyst support. The interaction of localized paramagnetic centers with electron gas can be interpreted in terms of the C-S relaxation model.
abstract_unstemmed	Abstract It is stated that one-dimensional conductivity in amorphous microporous carbon material (AMCM) samples is associated with the considerable imperfection of graphene fragments in the carbon material rather than the presence of unshared electrons. It is likely that the graphene fragments are formed upon the carbonization of a carbon precursor accompanied by the partial or complete removal of precursor heteroatoms. It is hypothesized that the presence of localized unpaired electrons, which give EPR spectra, is due to the formation of local defects in carbene fragments. Thus, the effects of the value of conductivity and the concentration of unpaired electrons on the power output of a fuel cell cannot be distinguished based on the experimental data with the use of an AMCM as a catalyst support. The interaction of localized paramagnetic centers with electron gas can be interpreted in terms of the C-S relaxation model.
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title_short	Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells
url	https://dx.doi.org/10.1134/S0023158410020217
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author2	Kozlov, A. P. Romanenko, A. I. Vasenin, N. T. Anufrienko, V. F. Ismagilov, Z. R.
author2Str	Kozlov, A. P. Romanenko, A. I. Vasenin, N. T. Anufrienko, V. F. Ismagilov, Z. R.
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doi_str	10.1134/S0023158410020217
up_date	2024-07-03T15:23:53.722Z
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Synthesis and properties of a microporous carbon material as a catalyst support for fuel cells

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