Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals
Abstract The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of $ Na^{+} $, $ K^{+...
Ausführliche Beschreibung
Autor*in: |
Novikov, G. V. [verfasserIn] Yashina, S. V. [verfasserIn] Mel’nikov, M. E. [verfasserIn] Vikent’ev, I. V. [verfasserIn] Bogdanova, O. Yu. [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2014 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Lithology and mineral resources - Moscow : MAIK Nauka/Interperiodica Publ., 2000, 49(2014), 2 vom: März, Seite 138-164 |
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Übergeordnetes Werk: |
volume:49 ; year:2014 ; number:2 ; month:03 ; pages:138-164 |
Links: |
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DOI / URN: |
10.1134/S0024490214020072 |
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Katalog-ID: |
SPR01537890X |
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245 | 1 | 0 | |a Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals |
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520 | |a Abstract The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of $ Na^{+} $, $ K^{+} $, and $ Ca^{2+} $ cations, whereas minimum activity is recorded for cations $ Pb^{2+} $ and $ Co^{2+} $. The exchange complex of ore minerals in crusts is composed of $ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mg^{2+} $, and $ Mn^{2+} $ cations. The exchange capacity of manganese minerals increases from the alkali metal cations to rare and heavy metal cations. Peculiarities of the affiliation of $ Co^{2+} $, $ Mn^{2+} $, and $ Mg^{2+} $ cations in manganese minerals of crusts are discussed. In manganese minerals, Co occurs as $ Co^{2+} $ and $ Co^{3+} $ cations. Metal cations in manganese minerals occur in different chemical forms: sorbed ($ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mn^{2+} $, $ Co^{2+} $, $ Cu^{2+} $, $ Zn^{2+} $, $ Cd^{2+} $, and $ Pb^{2+} $); sorbed and chemically bound ($ Mg^{2+} $, $ Ni^{2+} $, $ Y^{3+} $, $ La^{3+} $, and $ Mo^{6+} $); and only chemically bound ($ Co^{3+} $). It is shown that the age of crust, its preservation time in the air-dry state, and type of host substrate do not affect the ion exchange indicators of manganese minerals. It has been established that alkali metal cations are characterized by completely reversible equivalent sorption, whereas heavy metal cations are sorbed by a complex mechanism: equivalent ion exchange for all metal cations; superequivalent, partly reversible sorption for $ Ba^{2+} $, $ Pb^{2+} $, $ Co^{2+} $, and $ Cu^{2+} $ cations, relative to exchange cations of manganese minerals. The obtained results refine the role of ion exchange processes during the hydrogenic formation of Co-bearing ferromanganese crusts. | ||
650 | 4 | |a Metal Cation |7 (dpeaa)DE-He213 | |
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650 | 4 | |a Ferromanganese Crust |7 (dpeaa)DE-He213 | |
700 | 1 | |a Yashina, S. V. |e verfasserin |4 aut | |
700 | 1 | |a Mel’nikov, M. E. |e verfasserin |4 aut | |
700 | 1 | |a Vikent’ev, I. V. |e verfasserin |4 aut | |
700 | 1 | |a Bogdanova, O. Yu. |e verfasserin |4 aut | |
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10.1134/S0024490214020072 doi (DE-627)SPR01537890X (SPR)S0024490214020072-e DE-627 ger DE-627 rakwb eng 550 ASE 38.25 bkl 38.50 bkl Novikov, G. V. verfasserin aut Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of $ Na^{+} $, $ K^{+} $, and $ Ca^{2+} $ cations, whereas minimum activity is recorded for cations $ Pb^{2+} $ and $ Co^{2+} $. The exchange complex of ore minerals in crusts is composed of $ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mg^{2+} $, and $ Mn^{2+} $ cations. The exchange capacity of manganese minerals increases from the alkali metal cations to rare and heavy metal cations. Peculiarities of the affiliation of $ Co^{2+} $, $ Mn^{2+} $, and $ Mg^{2+} $ cations in manganese minerals of crusts are discussed. In manganese minerals, Co occurs as $ Co^{2+} $ and $ Co^{3+} $ cations. Metal cations in manganese minerals occur in different chemical forms: sorbed ($ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mn^{2+} $, $ Co^{2+} $, $ Cu^{2+} $, $ Zn^{2+} $, $ Cd^{2+} $, and $ Pb^{2+} $); sorbed and chemically bound ($ Mg^{2+} $, $ Ni^{2+} $, $ Y^{3+} $, $ La^{3+} $, and $ Mo^{6+} $); and only chemically bound ($ Co^{3+} $). It is shown that the age of crust, its preservation time in the air-dry state, and type of host substrate do not affect the ion exchange indicators of manganese minerals. It has been established that alkali metal cations are characterized by completely reversible equivalent sorption, whereas heavy metal cations are sorbed by a complex mechanism: equivalent ion exchange for all metal cations; superequivalent, partly reversible sorption for $ Ba^{2+} $, $ Pb^{2+} $, $ Co^{2+} $, and $ Cu^{2+} $ cations, relative to exchange cations of manganese minerals. The obtained results refine the role of ion exchange processes during the hydrogenic formation of Co-bearing ferromanganese crusts. Metal Cation (dpeaa)DE-He213 Alkali Metal Cation (dpeaa)DE-He213 Crustal Layer (dpeaa)DE-He213 Heavy Metal Cation (dpeaa)DE-He213 Ferromanganese Crust (dpeaa)DE-He213 Yashina, S. V. verfasserin aut Mel’nikov, M. E. verfasserin aut Vikent’ev, I. V. verfasserin aut Bogdanova, O. Yu. verfasserin aut Enthalten in Lithology and mineral resources Moscow : MAIK Nauka/Interperiodica Publ., 2000 49(2014), 2 vom: März, Seite 138-164 (DE-627)334711576 (DE-600)2058091-5 1608-3229 nnns volume:49 year:2014 number:2 month:03 pages:138-164 https://dx.doi.org/10.1134/S0024490214020072 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.25 ASE 38.50 ASE AR 49 2014 2 03 138-164 |
spelling |
10.1134/S0024490214020072 doi (DE-627)SPR01537890X (SPR)S0024490214020072-e DE-627 ger DE-627 rakwb eng 550 ASE 38.25 bkl 38.50 bkl Novikov, G. V. verfasserin aut Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of $ Na^{+} $, $ K^{+} $, and $ Ca^{2+} $ cations, whereas minimum activity is recorded for cations $ Pb^{2+} $ and $ Co^{2+} $. The exchange complex of ore minerals in crusts is composed of $ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mg^{2+} $, and $ Mn^{2+} $ cations. The exchange capacity of manganese minerals increases from the alkali metal cations to rare and heavy metal cations. Peculiarities of the affiliation of $ Co^{2+} $, $ Mn^{2+} $, and $ Mg^{2+} $ cations in manganese minerals of crusts are discussed. In manganese minerals, Co occurs as $ Co^{2+} $ and $ Co^{3+} $ cations. Metal cations in manganese minerals occur in different chemical forms: sorbed ($ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mn^{2+} $, $ Co^{2+} $, $ Cu^{2+} $, $ Zn^{2+} $, $ Cd^{2+} $, and $ Pb^{2+} $); sorbed and chemically bound ($ Mg^{2+} $, $ Ni^{2+} $, $ Y^{3+} $, $ La^{3+} $, and $ Mo^{6+} $); and only chemically bound ($ Co^{3+} $). It is shown that the age of crust, its preservation time in the air-dry state, and type of host substrate do not affect the ion exchange indicators of manganese minerals. It has been established that alkali metal cations are characterized by completely reversible equivalent sorption, whereas heavy metal cations are sorbed by a complex mechanism: equivalent ion exchange for all metal cations; superequivalent, partly reversible sorption for $ Ba^{2+} $, $ Pb^{2+} $, $ Co^{2+} $, and $ Cu^{2+} $ cations, relative to exchange cations of manganese minerals. The obtained results refine the role of ion exchange processes during the hydrogenic formation of Co-bearing ferromanganese crusts. Metal Cation (dpeaa)DE-He213 Alkali Metal Cation (dpeaa)DE-He213 Crustal Layer (dpeaa)DE-He213 Heavy Metal Cation (dpeaa)DE-He213 Ferromanganese Crust (dpeaa)DE-He213 Yashina, S. V. verfasserin aut Mel’nikov, M. E. verfasserin aut Vikent’ev, I. V. verfasserin aut Bogdanova, O. Yu. verfasserin aut Enthalten in Lithology and mineral resources Moscow : MAIK Nauka/Interperiodica Publ., 2000 49(2014), 2 vom: März, Seite 138-164 (DE-627)334711576 (DE-600)2058091-5 1608-3229 nnns volume:49 year:2014 number:2 month:03 pages:138-164 https://dx.doi.org/10.1134/S0024490214020072 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.25 ASE 38.50 ASE AR 49 2014 2 03 138-164 |
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10.1134/S0024490214020072 doi (DE-627)SPR01537890X (SPR)S0024490214020072-e DE-627 ger DE-627 rakwb eng 550 ASE 38.25 bkl 38.50 bkl Novikov, G. V. verfasserin aut Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of $ Na^{+} $, $ K^{+} $, and $ Ca^{2+} $ cations, whereas minimum activity is recorded for cations $ Pb^{2+} $ and $ Co^{2+} $. The exchange complex of ore minerals in crusts is composed of $ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mg^{2+} $, and $ Mn^{2+} $ cations. The exchange capacity of manganese minerals increases from the alkali metal cations to rare and heavy metal cations. Peculiarities of the affiliation of $ Co^{2+} $, $ Mn^{2+} $, and $ Mg^{2+} $ cations in manganese minerals of crusts are discussed. In manganese minerals, Co occurs as $ Co^{2+} $ and $ Co^{3+} $ cations. Metal cations in manganese minerals occur in different chemical forms: sorbed ($ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mn^{2+} $, $ Co^{2+} $, $ Cu^{2+} $, $ Zn^{2+} $, $ Cd^{2+} $, and $ Pb^{2+} $); sorbed and chemically bound ($ Mg^{2+} $, $ Ni^{2+} $, $ Y^{3+} $, $ La^{3+} $, and $ Mo^{6+} $); and only chemically bound ($ Co^{3+} $). It is shown that the age of crust, its preservation time in the air-dry state, and type of host substrate do not affect the ion exchange indicators of manganese minerals. It has been established that alkali metal cations are characterized by completely reversible equivalent sorption, whereas heavy metal cations are sorbed by a complex mechanism: equivalent ion exchange for all metal cations; superequivalent, partly reversible sorption for $ Ba^{2+} $, $ Pb^{2+} $, $ Co^{2+} $, and $ Cu^{2+} $ cations, relative to exchange cations of manganese minerals. The obtained results refine the role of ion exchange processes during the hydrogenic formation of Co-bearing ferromanganese crusts. Metal Cation (dpeaa)DE-He213 Alkali Metal Cation (dpeaa)DE-He213 Crustal Layer (dpeaa)DE-He213 Heavy Metal Cation (dpeaa)DE-He213 Ferromanganese Crust (dpeaa)DE-He213 Yashina, S. V. verfasserin aut Mel’nikov, M. E. verfasserin aut Vikent’ev, I. V. verfasserin aut Bogdanova, O. Yu. verfasserin aut Enthalten in Lithology and mineral resources Moscow : MAIK Nauka/Interperiodica Publ., 2000 49(2014), 2 vom: März, Seite 138-164 (DE-627)334711576 (DE-600)2058091-5 1608-3229 nnns volume:49 year:2014 number:2 month:03 pages:138-164 https://dx.doi.org/10.1134/S0024490214020072 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.25 ASE 38.50 ASE AR 49 2014 2 03 138-164 |
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10.1134/S0024490214020072 doi (DE-627)SPR01537890X (SPR)S0024490214020072-e DE-627 ger DE-627 rakwb eng 550 ASE 38.25 bkl 38.50 bkl Novikov, G. V. verfasserin aut Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of $ Na^{+} $, $ K^{+} $, and $ Ca^{2+} $ cations, whereas minimum activity is recorded for cations $ Pb^{2+} $ and $ Co^{2+} $. The exchange complex of ore minerals in crusts is composed of $ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mg^{2+} $, and $ Mn^{2+} $ cations. The exchange capacity of manganese minerals increases from the alkali metal cations to rare and heavy metal cations. Peculiarities of the affiliation of $ Co^{2+} $, $ Mn^{2+} $, and $ Mg^{2+} $ cations in manganese minerals of crusts are discussed. In manganese minerals, Co occurs as $ Co^{2+} $ and $ Co^{3+} $ cations. Metal cations in manganese minerals occur in different chemical forms: sorbed ($ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mn^{2+} $, $ Co^{2+} $, $ Cu^{2+} $, $ Zn^{2+} $, $ Cd^{2+} $, and $ Pb^{2+} $); sorbed and chemically bound ($ Mg^{2+} $, $ Ni^{2+} $, $ Y^{3+} $, $ La^{3+} $, and $ Mo^{6+} $); and only chemically bound ($ Co^{3+} $). It is shown that the age of crust, its preservation time in the air-dry state, and type of host substrate do not affect the ion exchange indicators of manganese minerals. It has been established that alkali metal cations are characterized by completely reversible equivalent sorption, whereas heavy metal cations are sorbed by a complex mechanism: equivalent ion exchange for all metal cations; superequivalent, partly reversible sorption for $ Ba^{2+} $, $ Pb^{2+} $, $ Co^{2+} $, and $ Cu^{2+} $ cations, relative to exchange cations of manganese minerals. The obtained results refine the role of ion exchange processes during the hydrogenic formation of Co-bearing ferromanganese crusts. Metal Cation (dpeaa)DE-He213 Alkali Metal Cation (dpeaa)DE-He213 Crustal Layer (dpeaa)DE-He213 Heavy Metal Cation (dpeaa)DE-He213 Ferromanganese Crust (dpeaa)DE-He213 Yashina, S. V. verfasserin aut Mel’nikov, M. E. verfasserin aut Vikent’ev, I. V. verfasserin aut Bogdanova, O. Yu. verfasserin aut Enthalten in Lithology and mineral resources Moscow : MAIK Nauka/Interperiodica Publ., 2000 49(2014), 2 vom: März, Seite 138-164 (DE-627)334711576 (DE-600)2058091-5 1608-3229 nnns volume:49 year:2014 number:2 month:03 pages:138-164 https://dx.doi.org/10.1134/S0024490214020072 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.25 ASE 38.50 ASE AR 49 2014 2 03 138-164 |
allfieldsSound |
10.1134/S0024490214020072 doi (DE-627)SPR01537890X (SPR)S0024490214020072-e DE-627 ger DE-627 rakwb eng 550 ASE 38.25 bkl 38.50 bkl Novikov, G. V. verfasserin aut Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of $ Na^{+} $, $ K^{+} $, and $ Ca^{2+} $ cations, whereas minimum activity is recorded for cations $ Pb^{2+} $ and $ Co^{2+} $. The exchange complex of ore minerals in crusts is composed of $ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mg^{2+} $, and $ Mn^{2+} $ cations. The exchange capacity of manganese minerals increases from the alkali metal cations to rare and heavy metal cations. Peculiarities of the affiliation of $ Co^{2+} $, $ Mn^{2+} $, and $ Mg^{2+} $ cations in manganese minerals of crusts are discussed. In manganese minerals, Co occurs as $ Co^{2+} $ and $ Co^{3+} $ cations. Metal cations in manganese minerals occur in different chemical forms: sorbed ($ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mn^{2+} $, $ Co^{2+} $, $ Cu^{2+} $, $ Zn^{2+} $, $ Cd^{2+} $, and $ Pb^{2+} $); sorbed and chemically bound ($ Mg^{2+} $, $ Ni^{2+} $, $ Y^{3+} $, $ La^{3+} $, and $ Mo^{6+} $); and only chemically bound ($ Co^{3+} $). It is shown that the age of crust, its preservation time in the air-dry state, and type of host substrate do not affect the ion exchange indicators of manganese minerals. It has been established that alkali metal cations are characterized by completely reversible equivalent sorption, whereas heavy metal cations are sorbed by a complex mechanism: equivalent ion exchange for all metal cations; superequivalent, partly reversible sorption for $ Ba^{2+} $, $ Pb^{2+} $, $ Co^{2+} $, and $ Cu^{2+} $ cations, relative to exchange cations of manganese minerals. The obtained results refine the role of ion exchange processes during the hydrogenic formation of Co-bearing ferromanganese crusts. Metal Cation (dpeaa)DE-He213 Alkali Metal Cation (dpeaa)DE-He213 Crustal Layer (dpeaa)DE-He213 Heavy Metal Cation (dpeaa)DE-He213 Ferromanganese Crust (dpeaa)DE-He213 Yashina, S. V. verfasserin aut Mel’nikov, M. E. verfasserin aut Vikent’ev, I. V. verfasserin aut Bogdanova, O. Yu. verfasserin aut Enthalten in Lithology and mineral resources Moscow : MAIK Nauka/Interperiodica Publ., 2000 49(2014), 2 vom: März, Seite 138-164 (DE-627)334711576 (DE-600)2058091-5 1608-3229 nnns volume:49 year:2014 number:2 month:03 pages:138-164 https://dx.doi.org/10.1134/S0024490214020072 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.25 ASE 38.50 ASE AR 49 2014 2 03 138-164 |
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English |
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Enthalten in Lithology and mineral resources 49(2014), 2 vom: März, Seite 138-164 volume:49 year:2014 number:2 month:03 pages:138-164 |
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Enthalten in Lithology and mineral resources 49(2014), 2 vom: März, Seite 138-164 volume:49 year:2014 number:2 month:03 pages:138-164 |
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Metal Cation Alkali Metal Cation Crustal Layer Heavy Metal Cation Ferromanganese Crust |
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Lithology and mineral resources |
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Novikov, G. V. @@aut@@ Yashina, S. V. @@aut@@ Mel’nikov, M. E. @@aut@@ Vikent’ev, I. V. @@aut@@ Bogdanova, O. Yu. @@aut@@ |
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2014-03-01T00:00:00Z |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR01537890X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20220111021543.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2014 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1134/S0024490214020072</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR01537890X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)S0024490214020072-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">550</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">38.25</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">38.50</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Novikov, G. V.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2014</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of $ Na^{+} $, $ K^{+} $, and $ Ca^{2+} $ cations, whereas minimum activity is recorded for cations $ Pb^{2+} $ and $ Co^{2+} $. The exchange complex of ore minerals in crusts is composed of $ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mg^{2+} $, and $ Mn^{2+} $ cations. The exchange capacity of manganese minerals increases from the alkali metal cations to rare and heavy metal cations. Peculiarities of the affiliation of $ Co^{2+} $, $ Mn^{2+} $, and $ Mg^{2+} $ cations in manganese minerals of crusts are discussed. In manganese minerals, Co occurs as $ Co^{2+} $ and $ Co^{3+} $ cations. Metal cations in manganese minerals occur in different chemical forms: sorbed ($ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mn^{2+} $, $ Co^{2+} $, $ Cu^{2+} $, $ Zn^{2+} $, $ Cd^{2+} $, and $ Pb^{2+} $); sorbed and chemically bound ($ Mg^{2+} $, $ Ni^{2+} $, $ Y^{3+} $, $ La^{3+} $, and $ Mo^{6+} $); and only chemically bound ($ Co^{3+} $). It is shown that the age of crust, its preservation time in the air-dry state, and type of host substrate do not affect the ion exchange indicators of manganese minerals. It has been established that alkali metal cations are characterized by completely reversible equivalent sorption, whereas heavy metal cations are sorbed by a complex mechanism: equivalent ion exchange for all metal cations; superequivalent, partly reversible sorption for $ Ba^{2+} $, $ Pb^{2+} $, $ Co^{2+} $, and $ Cu^{2+} $ cations, relative to exchange cations of manganese minerals. 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author |
Novikov, G. V. |
spellingShingle |
Novikov, G. V. ddc 550 bkl 38.25 bkl 38.50 misc Metal Cation misc Alkali Metal Cation misc Crustal Layer misc Heavy Metal Cation misc Ferromanganese Crust Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals |
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550 ASE 38.25 bkl 38.50 bkl Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals Metal Cation (dpeaa)DE-He213 Alkali Metal Cation (dpeaa)DE-He213 Crustal Layer (dpeaa)DE-He213 Heavy Metal Cation (dpeaa)DE-He213 Ferromanganese Crust (dpeaa)DE-He213 |
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ddc 550 bkl 38.25 bkl 38.50 misc Metal Cation misc Alkali Metal Cation misc Crustal Layer misc Heavy Metal Cation misc Ferromanganese Crust |
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ddc 550 bkl 38.25 bkl 38.50 misc Metal Cation misc Alkali Metal Cation misc Crustal Layer misc Heavy Metal Cation misc Ferromanganese Crust |
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ddc 550 bkl 38.25 bkl 38.50 misc Metal Cation misc Alkali Metal Cation misc Crustal Layer misc Heavy Metal Cation misc Ferromanganese Crust |
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Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals |
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Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals |
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Novikov, G. V. Yashina, S. V. Mel’nikov, M. E. Vikent’ev, I. V. Bogdanova, O. Yu. |
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nature of co-bearing ferromanganese crusts of the magellan seamounts (pacific ocean): communication 2. ion exchange properties of ore minerals |
title_auth |
Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals |
abstract |
Abstract The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of $ Na^{+} $, $ K^{+} $, and $ Ca^{2+} $ cations, whereas minimum activity is recorded for cations $ Pb^{2+} $ and $ Co^{2+} $. The exchange complex of ore minerals in crusts is composed of $ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mg^{2+} $, and $ Mn^{2+} $ cations. The exchange capacity of manganese minerals increases from the alkali metal cations to rare and heavy metal cations. Peculiarities of the affiliation of $ Co^{2+} $, $ Mn^{2+} $, and $ Mg^{2+} $ cations in manganese minerals of crusts are discussed. In manganese minerals, Co occurs as $ Co^{2+} $ and $ Co^{3+} $ cations. Metal cations in manganese minerals occur in different chemical forms: sorbed ($ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mn^{2+} $, $ Co^{2+} $, $ Cu^{2+} $, $ Zn^{2+} $, $ Cd^{2+} $, and $ Pb^{2+} $); sorbed and chemically bound ($ Mg^{2+} $, $ Ni^{2+} $, $ Y^{3+} $, $ La^{3+} $, and $ Mo^{6+} $); and only chemically bound ($ Co^{3+} $). It is shown that the age of crust, its preservation time in the air-dry state, and type of host substrate do not affect the ion exchange indicators of manganese minerals. It has been established that alkali metal cations are characterized by completely reversible equivalent sorption, whereas heavy metal cations are sorbed by a complex mechanism: equivalent ion exchange for all metal cations; superequivalent, partly reversible sorption for $ Ba^{2+} $, $ Pb^{2+} $, $ Co^{2+} $, and $ Cu^{2+} $ cations, relative to exchange cations of manganese minerals. The obtained results refine the role of ion exchange processes during the hydrogenic formation of Co-bearing ferromanganese crusts. |
abstractGer |
Abstract The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of $ Na^{+} $, $ K^{+} $, and $ Ca^{2+} $ cations, whereas minimum activity is recorded for cations $ Pb^{2+} $ and $ Co^{2+} $. The exchange complex of ore minerals in crusts is composed of $ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mg^{2+} $, and $ Mn^{2+} $ cations. The exchange capacity of manganese minerals increases from the alkali metal cations to rare and heavy metal cations. Peculiarities of the affiliation of $ Co^{2+} $, $ Mn^{2+} $, and $ Mg^{2+} $ cations in manganese minerals of crusts are discussed. In manganese minerals, Co occurs as $ Co^{2+} $ and $ Co^{3+} $ cations. Metal cations in manganese minerals occur in different chemical forms: sorbed ($ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mn^{2+} $, $ Co^{2+} $, $ Cu^{2+} $, $ Zn^{2+} $, $ Cd^{2+} $, and $ Pb^{2+} $); sorbed and chemically bound ($ Mg^{2+} $, $ Ni^{2+} $, $ Y^{3+} $, $ La^{3+} $, and $ Mo^{6+} $); and only chemically bound ($ Co^{3+} $). It is shown that the age of crust, its preservation time in the air-dry state, and type of host substrate do not affect the ion exchange indicators of manganese minerals. It has been established that alkali metal cations are characterized by completely reversible equivalent sorption, whereas heavy metal cations are sorbed by a complex mechanism: equivalent ion exchange for all metal cations; superequivalent, partly reversible sorption for $ Ba^{2+} $, $ Pb^{2+} $, $ Co^{2+} $, and $ Cu^{2+} $ cations, relative to exchange cations of manganese minerals. The obtained results refine the role of ion exchange processes during the hydrogenic formation of Co-bearing ferromanganese crusts. |
abstract_unstemmed |
Abstract The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of $ Na^{+} $, $ K^{+} $, and $ Ca^{2+} $ cations, whereas minimum activity is recorded for cations $ Pb^{2+} $ and $ Co^{2+} $. The exchange complex of ore minerals in crusts is composed of $ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mg^{2+} $, and $ Mn^{2+} $ cations. The exchange capacity of manganese minerals increases from the alkali metal cations to rare and heavy metal cations. Peculiarities of the affiliation of $ Co^{2+} $, $ Mn^{2+} $, and $ Mg^{2+} $ cations in manganese minerals of crusts are discussed. In manganese minerals, Co occurs as $ Co^{2+} $ and $ Co^{3+} $ cations. Metal cations in manganese minerals occur in different chemical forms: sorbed ($ Na^{+} $, $ K^{+} $, $ Ca^{2+} $, $ Mn^{2+} $, $ Co^{2+} $, $ Cu^{2+} $, $ Zn^{2+} $, $ Cd^{2+} $, and $ Pb^{2+} $); sorbed and chemically bound ($ Mg^{2+} $, $ Ni^{2+} $, $ Y^{3+} $, $ La^{3+} $, and $ Mo^{6+} $); and only chemically bound ($ Co^{3+} $). It is shown that the age of crust, its preservation time in the air-dry state, and type of host substrate do not affect the ion exchange indicators of manganese minerals. It has been established that alkali metal cations are characterized by completely reversible equivalent sorption, whereas heavy metal cations are sorbed by a complex mechanism: equivalent ion exchange for all metal cations; superequivalent, partly reversible sorption for $ Ba^{2+} $, $ Pb^{2+} $, $ Co^{2+} $, and $ Cu^{2+} $ cations, relative to exchange cations of manganese minerals. The obtained results refine the role of ion exchange processes during the hydrogenic formation of Co-bearing ferromanganese crusts. |
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Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals |
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|
score |
7.399351 |