Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques

Abstract $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{x} $ perovskites system with n = 2, 2.5, and 4 synthesized through glassy precursor route by melt quenching. It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by ener...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Kannan, T. [verfasserIn] Predeep, P. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2013

Schlagwörter:	Melt quenching Avrami index Crystallization kinetics Activation energy PBSCCO

Übergeordnetes Werk:	Enthalten in: Journal of thermal analysis and calorimetry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969, 114(2013), 2 vom: 08. Feb., Seite 635-641
Übergeordnetes Werk:	volume:114 ; year:2013 ; number:2 ; day:08 ; month:02 ; pages:635-641

Links:	Volltext

DOI / URN:	10.1007/s10973-012-2845-x

Katalog-ID:	SPR015468178

Internformat


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245	1	0	\|a Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques
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520			\|a Abstract $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{x} $ perovskites system with n = 2, 2.5, and 4 synthesized through glassy precursor route by melt quenching. It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by energy dispersive X-ray showed an increase of elemental ratio of Bi in all compositions. Activation energies of crystallization of various compositions are evaluated using thermal analysis and it is found that the activation energy plays a critical role in superconducting transition of these compounds. Structural analysis of the perovskites by XRD revealed a strikingly similar structure for all the compositions irrespective of their superconducting nature, while Raman and SEM revealed slight traces of impurity modes in all the compositions. However the impurity observed thus are minima in the lone composition that exhibited superconducting transition. Here an effort has been made to investigate the reasons for the only one composition of the series exhibiting superconducting transition irrespective of their near uniformity in the structure. It has been found that the presence of residual glass, plumbates and poor inter-grain connectivity formed the detrimental factors that made the two compositions devoid of their superconducting transition.
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650		4	\|a Crystallization kinetics \|7 (dpeaa)DE-He213
650		4	\|a Activation energy \|7 (dpeaa)DE-He213
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700	1		\|a Predeep, P. \|e verfasserin \|4 aut
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912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
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912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_206
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
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912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
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912			\|a GBV_ILN_4328
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4336
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
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matchkey_str	article:15728943:2013----::netgtoitteuecnutntrsodfi1p_4r2anc_o2425prvktsyteiebgaspeusrot
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allfields	10.1007/s10973-012-2845-x doi (DE-627)SPR015468178 (SPR)s10973-012-2845-x-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Kannan, T. verfasserin aut Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{x} $ perovskites system with n = 2, 2.5, and 4 synthesized through glassy precursor route by melt quenching. It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by energy dispersive X-ray showed an increase of elemental ratio of Bi in all compositions. Activation energies of crystallization of various compositions are evaluated using thermal analysis and it is found that the activation energy plays a critical role in superconducting transition of these compounds. Structural analysis of the perovskites by XRD revealed a strikingly similar structure for all the compositions irrespective of their superconducting nature, while Raman and SEM revealed slight traces of impurity modes in all the compositions. However the impurity observed thus are minima in the lone composition that exhibited superconducting transition. Here an effort has been made to investigate the reasons for the only one composition of the series exhibiting superconducting transition irrespective of their near uniformity in the structure. It has been found that the presence of residual glass, plumbates and poor inter-grain connectivity formed the detrimental factors that made the two compositions devoid of their superconducting transition. Melt quenching (dpeaa)DE-He213 Avrami index (dpeaa)DE-He213 Crystallization kinetics (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 PBSCCO (dpeaa)DE-He213 Predeep, P. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 114(2013), 2 vom: 08. Feb., Seite 635-641 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:114 year:2013 number:2 day:08 month:02 pages:635-641 https://dx.doi.org/10.1007/s10973-012-2845-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 114 2013 2 08 02 635-641
spelling	10.1007/s10973-012-2845-x doi (DE-627)SPR015468178 (SPR)s10973-012-2845-x-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Kannan, T. verfasserin aut Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{x} $ perovskites system with n = 2, 2.5, and 4 synthesized through glassy precursor route by melt quenching. It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by energy dispersive X-ray showed an increase of elemental ratio of Bi in all compositions. Activation energies of crystallization of various compositions are evaluated using thermal analysis and it is found that the activation energy plays a critical role in superconducting transition of these compounds. Structural analysis of the perovskites by XRD revealed a strikingly similar structure for all the compositions irrespective of their superconducting nature, while Raman and SEM revealed slight traces of impurity modes in all the compositions. However the impurity observed thus are minima in the lone composition that exhibited superconducting transition. Here an effort has been made to investigate the reasons for the only one composition of the series exhibiting superconducting transition irrespective of their near uniformity in the structure. It has been found that the presence of residual glass, plumbates and poor inter-grain connectivity formed the detrimental factors that made the two compositions devoid of their superconducting transition. Melt quenching (dpeaa)DE-He213 Avrami index (dpeaa)DE-He213 Crystallization kinetics (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 PBSCCO (dpeaa)DE-He213 Predeep, P. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 114(2013), 2 vom: 08. Feb., Seite 635-641 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:114 year:2013 number:2 day:08 month:02 pages:635-641 https://dx.doi.org/10.1007/s10973-012-2845-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 114 2013 2 08 02 635-641
allfields_unstemmed	10.1007/s10973-012-2845-x doi (DE-627)SPR015468178 (SPR)s10973-012-2845-x-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Kannan, T. verfasserin aut Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{x} $ perovskites system with n = 2, 2.5, and 4 synthesized through glassy precursor route by melt quenching. It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by energy dispersive X-ray showed an increase of elemental ratio of Bi in all compositions. Activation energies of crystallization of various compositions are evaluated using thermal analysis and it is found that the activation energy plays a critical role in superconducting transition of these compounds. Structural analysis of the perovskites by XRD revealed a strikingly similar structure for all the compositions irrespective of their superconducting nature, while Raman and SEM revealed slight traces of impurity modes in all the compositions. However the impurity observed thus are minima in the lone composition that exhibited superconducting transition. Here an effort has been made to investigate the reasons for the only one composition of the series exhibiting superconducting transition irrespective of their near uniformity in the structure. It has been found that the presence of residual glass, plumbates and poor inter-grain connectivity formed the detrimental factors that made the two compositions devoid of their superconducting transition. Melt quenching (dpeaa)DE-He213 Avrami index (dpeaa)DE-He213 Crystallization kinetics (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 PBSCCO (dpeaa)DE-He213 Predeep, P. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 114(2013), 2 vom: 08. Feb., Seite 635-641 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:114 year:2013 number:2 day:08 month:02 pages:635-641 https://dx.doi.org/10.1007/s10973-012-2845-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 114 2013 2 08 02 635-641
allfieldsGer	10.1007/s10973-012-2845-x doi (DE-627)SPR015468178 (SPR)s10973-012-2845-x-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Kannan, T. verfasserin aut Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{x} $ perovskites system with n = 2, 2.5, and 4 synthesized through glassy precursor route by melt quenching. It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by energy dispersive X-ray showed an increase of elemental ratio of Bi in all compositions. Activation energies of crystallization of various compositions are evaluated using thermal analysis and it is found that the activation energy plays a critical role in superconducting transition of these compounds. Structural analysis of the perovskites by XRD revealed a strikingly similar structure for all the compositions irrespective of their superconducting nature, while Raman and SEM revealed slight traces of impurity modes in all the compositions. However the impurity observed thus are minima in the lone composition that exhibited superconducting transition. Here an effort has been made to investigate the reasons for the only one composition of the series exhibiting superconducting transition irrespective of their near uniformity in the structure. It has been found that the presence of residual glass, plumbates and poor inter-grain connectivity formed the detrimental factors that made the two compositions devoid of their superconducting transition. Melt quenching (dpeaa)DE-He213 Avrami index (dpeaa)DE-He213 Crystallization kinetics (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 PBSCCO (dpeaa)DE-He213 Predeep, P. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 114(2013), 2 vom: 08. Feb., Seite 635-641 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:114 year:2013 number:2 day:08 month:02 pages:635-641 https://dx.doi.org/10.1007/s10973-012-2845-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 114 2013 2 08 02 635-641
allfieldsSound	10.1007/s10973-012-2845-x doi (DE-627)SPR015468178 (SPR)s10973-012-2845-x-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Kannan, T. verfasserin aut Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{x} $ perovskites system with n = 2, 2.5, and 4 synthesized through glassy precursor route by melt quenching. It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by energy dispersive X-ray showed an increase of elemental ratio of Bi in all compositions. Activation energies of crystallization of various compositions are evaluated using thermal analysis and it is found that the activation energy plays a critical role in superconducting transition of these compounds. Structural analysis of the perovskites by XRD revealed a strikingly similar structure for all the compositions irrespective of their superconducting nature, while Raman and SEM revealed slight traces of impurity modes in all the compositions. However the impurity observed thus are minima in the lone composition that exhibited superconducting transition. Here an effort has been made to investigate the reasons for the only one composition of the series exhibiting superconducting transition irrespective of their near uniformity in the structure. It has been found that the presence of residual glass, plumbates and poor inter-grain connectivity formed the detrimental factors that made the two compositions devoid of their superconducting transition. Melt quenching (dpeaa)DE-He213 Avrami index (dpeaa)DE-He213 Crystallization kinetics (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 PBSCCO (dpeaa)DE-He213 Predeep, P. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 114(2013), 2 vom: 08. Feb., Seite 635-641 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:114 year:2013 number:2 day:08 month:02 pages:635-641 https://dx.doi.org/10.1007/s10973-012-2845-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 114 2013 2 08 02 635-641
language	English
source	Enthalten in Journal of thermal analysis and calorimetry 114(2013), 2 vom: 08. Feb., Seite 635-641 volume:114 year:2013 number:2 day:08 month:02 pages:635-641
sourceStr	Enthalten in Journal of thermal analysis and calorimetry 114(2013), 2 vom: 08. Feb., Seite 635-641 volume:114 year:2013 number:2 day:08 month:02 pages:635-641
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Melt quenching Avrami index Crystallization kinetics Activation energy PBSCCO
dewey-raw	660
isfreeaccess_bool	false
container_title	Journal of thermal analysis and calorimetry
authorswithroles_txt_mv	Kannan, T. @@aut@@ Predeep, P. @@aut@@
publishDateDaySort_date	2013-02-08T00:00:00Z
hierarchy_top_id	315295422
dewey-sort	3660
id	SPR015468178
language_de	englisch
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It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by energy dispersive X-ray showed an increase of elemental ratio of Bi in all compositions. Activation energies of crystallization of various compositions are evaluated using thermal analysis and it is found that the activation energy plays a critical role in superconducting transition of these compounds. Structural analysis of the perovskites by XRD revealed a strikingly similar structure for all the compositions irrespective of their superconducting nature, while Raman and SEM revealed slight traces of impurity modes in all the compositions. However the impurity observed thus are minima in the lone composition that exhibited superconducting transition. Here an effort has been made to investigate the reasons for the only one composition of the series exhibiting superconducting transition irrespective of their near uniformity in the structure. 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author	Kannan, T.
spellingShingle	Kannan, T. ddc 660 bkl 35.00 misc Melt quenching misc Avrami index misc Crystallization kinetics misc Activation energy misc PBSCCO Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques
authorStr	Kannan, T.
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issn	1572-8943
topic_title	660 ASE 35.00 bkl Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques Melt quenching (dpeaa)DE-He213 Avrami index (dpeaa)DE-He213 Crystallization kinetics (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 PBSCCO (dpeaa)DE-He213
topic	ddc 660 bkl 35.00 misc Melt quenching misc Avrami index misc Crystallization kinetics misc Activation energy misc PBSCCO
topic_unstemmed	ddc 660 bkl 35.00 misc Melt quenching misc Avrami index misc Crystallization kinetics misc Activation energy misc PBSCCO
topic_browse	ddc 660 bkl 35.00 misc Melt quenching misc Avrami index misc Crystallization kinetics misc Activation energy misc PBSCCO
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
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hierarchy_parent_title	Journal of thermal analysis and calorimetry
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title	Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques
ctrlnum	(DE-627)SPR015468178 (SPR)s10973-012-2845-x-e
title_full	Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques
author_sort	Kannan, T.
journal	Journal of thermal analysis and calorimetry
journalStr	Journal of thermal analysis and calorimetry
lang_code	eng
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container_start_page	635
author_browse	Kannan, T. Predeep, P.
container_volume	114
class	660 ASE 35.00 bkl
format_se	Elektronische Aufsätze
author-letter	Kannan, T.
doi_str_mv	10.1007/s10973-012-2845-x
dewey-full	660
author2-role	verfasserin
title_sort	investigation into the superconducting threshold of $ bi_{1.6} %$ pb_{0.4} %$ sr_{2} %$ ca_{n−1} %$ cu_{n} %$ o_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with thermal and raman spectroscopic techniques
title_auth	Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques
abstract	Abstract $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{x} $ perovskites system with n = 2, 2.5, and 4 synthesized through glassy precursor route by melt quenching. It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by energy dispersive X-ray showed an increase of elemental ratio of Bi in all compositions. Activation energies of crystallization of various compositions are evaluated using thermal analysis and it is found that the activation energy plays a critical role in superconducting transition of these compounds. Structural analysis of the perovskites by XRD revealed a strikingly similar structure for all the compositions irrespective of their superconducting nature, while Raman and SEM revealed slight traces of impurity modes in all the compositions. However the impurity observed thus are minima in the lone composition that exhibited superconducting transition. Here an effort has been made to investigate the reasons for the only one composition of the series exhibiting superconducting transition irrespective of their near uniformity in the structure. It has been found that the presence of residual glass, plumbates and poor inter-grain connectivity formed the detrimental factors that made the two compositions devoid of their superconducting transition.
abstractGer	Abstract $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{x} $ perovskites system with n = 2, 2.5, and 4 synthesized through glassy precursor route by melt quenching. It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by energy dispersive X-ray showed an increase of elemental ratio of Bi in all compositions. Activation energies of crystallization of various compositions are evaluated using thermal analysis and it is found that the activation energy plays a critical role in superconducting transition of these compounds. Structural analysis of the perovskites by XRD revealed a strikingly similar structure for all the compositions irrespective of their superconducting nature, while Raman and SEM revealed slight traces of impurity modes in all the compositions. However the impurity observed thus are minima in the lone composition that exhibited superconducting transition. Here an effort has been made to investigate the reasons for the only one composition of the series exhibiting superconducting transition irrespective of their near uniformity in the structure. It has been found that the presence of residual glass, plumbates and poor inter-grain connectivity formed the detrimental factors that made the two compositions devoid of their superconducting transition.
abstract_unstemmed	Abstract $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{x} $ perovskites system with n = 2, 2.5, and 4 synthesized through glassy precursor route by melt quenching. It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by energy dispersive X-ray showed an increase of elemental ratio of Bi in all compositions. Activation energies of crystallization of various compositions are evaluated using thermal analysis and it is found that the activation energy plays a critical role in superconducting transition of these compounds. Structural analysis of the perovskites by XRD revealed a strikingly similar structure for all the compositions irrespective of their superconducting nature, while Raman and SEM revealed slight traces of impurity modes in all the compositions. However the impurity observed thus are minima in the lone composition that exhibited superconducting transition. Here an effort has been made to investigate the reasons for the only one composition of the series exhibiting superconducting transition irrespective of their near uniformity in the structure. It has been found that the presence of residual glass, plumbates and poor inter-grain connectivity formed the detrimental factors that made the two compositions devoid of their superconducting transition.
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title_short	Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques
url	https://dx.doi.org/10.1007/s10973-012-2845-x
remote_bool	true
author2	Predeep, P.
author2Str	Predeep, P.
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doi_str	10.1007/s10973-012-2845-x
up_date	2024-07-03T16:26:28.082Z
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It has been found that only one composition of the series (n = 4), exhibited superconducting transition. Analysis by energy dispersive X-ray showed an increase of elemental ratio of Bi in all compositions. Activation energies of crystallization of various compositions are evaluated using thermal analysis and it is found that the activation energy plays a critical role in superconducting transition of these compounds. Structural analysis of the perovskites by XRD revealed a strikingly similar structure for all the compositions irrespective of their superconducting nature, while Raman and SEM revealed slight traces of impurity modes in all the compositions. However the impurity observed thus are minima in the lone composition that exhibited superconducting transition. Here an effort has been made to investigate the reasons for the only one composition of the series exhibiting superconducting transition irrespective of their near uniformity in the structure. 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Investigation into the superconducting threshold of $ Bi_{1.6} %$ Pb_{0.4} %$ Sr_{2} %$ Ca_{n−1} %$ Cu_{n} %$ O_{2n+4+δ} $, n = 2, 2.5, 4 perovskites synthesized by glassy precursor route with Thermal and Raman spectroscopic techniques

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