Effects of silane precursors on curing behavior of UV-curable hybrid coatings
Abstract This study demonstrates the effect of some commonly used silane precursors on curing behavior and photopolymerization kinetics of UV-curable hybrid coatings. Tetraethoxyorthosilane (TEOS), vinyltrimethoxysilane (VTMS), and 3-methacryloxypropyltrimethoxysilane (MPS) were polymerized under ac...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Mohseni, Majid [verfasserIn] Bastani, Saeed [verfasserIn] Jannesari, Ali [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969, 119(2014), 1 vom: 04. Sept., Seite 515-526 |
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| Übergeordnetes Werk: |
volume:119 ; year:2014 ; number:1 ; day:04 ; month:09 ; pages:515-526 |
| Links: |
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| DOI / URN: |
10.1007/s10973-014-4071-1 |
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| Katalog-ID: |
SPR015497372 |
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| 520 | |a Abstract This study demonstrates the effect of some commonly used silane precursors on curing behavior and photopolymerization kinetics of UV-curable hybrid coatings. Tetraethoxyorthosilane (TEOS), vinyltrimethoxysilane (VTMS), and 3-methacryloxypropyltrimethoxysilane (MPS) were polymerized under acidic conditions by the sol–gel method. The resulting structure of the tested siloxane oligomers was characterized using 29Si-NMR and 1H-NMR spectroscopy. Photo-DSC was used to evaluate photocuring enthalpy. A fully integrated model was applied to investigate propagation rate coefficients and to identify the most effective termination mechanism (monomolecular, bimolecular, or mixed). Results showed that oligomers containing MPS effectively promoted total heat of the polymerization process and consequently affected the maximum rate of polymerization and final double bond conversion. Enthalpy rating for samples containing MPS was higher than that of those containing VTMS, showing that MPS was more compatible with the acrylate systems. In addition, evaluations for photopolymerization kinetic constants proved that non-functional oligomers containing TEOS caused radical trapping and increased activity of the monomolecular termination mechanism. Graphical Abstract | ||
| 650 | 4 | |a UV-curable |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Hybrid coating |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Photocuring kinetic |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Photo-DSC |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Silane precursor |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Bastani, Saeed |e verfasserin |4 aut | |
| 700 | 1 | |a Jannesari, Ali |e verfasserin |4 aut | |
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10.1007/s10973-014-4071-1 doi (DE-627)SPR015497372 (SPR)s10973-014-4071-1-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Mohseni, Majid verfasserin aut Effects of silane precursors on curing behavior of UV-curable hybrid coatings 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract This study demonstrates the effect of some commonly used silane precursors on curing behavior and photopolymerization kinetics of UV-curable hybrid coatings. Tetraethoxyorthosilane (TEOS), vinyltrimethoxysilane (VTMS), and 3-methacryloxypropyltrimethoxysilane (MPS) were polymerized under acidic conditions by the sol–gel method. The resulting structure of the tested siloxane oligomers was characterized using 29Si-NMR and 1H-NMR spectroscopy. Photo-DSC was used to evaluate photocuring enthalpy. A fully integrated model was applied to investigate propagation rate coefficients and to identify the most effective termination mechanism (monomolecular, bimolecular, or mixed). Results showed that oligomers containing MPS effectively promoted total heat of the polymerization process and consequently affected the maximum rate of polymerization and final double bond conversion. Enthalpy rating for samples containing MPS was higher than that of those containing VTMS, showing that MPS was more compatible with the acrylate systems. In addition, evaluations for photopolymerization kinetic constants proved that non-functional oligomers containing TEOS caused radical trapping and increased activity of the monomolecular termination mechanism. Graphical Abstract UV-curable (dpeaa)DE-He213 Hybrid coating (dpeaa)DE-He213 Photocuring kinetic (dpeaa)DE-He213 Photo-DSC (dpeaa)DE-He213 Silane precursor (dpeaa)DE-He213 Bastani, Saeed verfasserin aut Jannesari, Ali verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 119(2014), 1 vom: 04. Sept., Seite 515-526 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:119 year:2014 number:1 day:04 month:09 pages:515-526 https://dx.doi.org/10.1007/s10973-014-4071-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 119 2014 1 04 09 515-526 |
| spelling |
10.1007/s10973-014-4071-1 doi (DE-627)SPR015497372 (SPR)s10973-014-4071-1-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Mohseni, Majid verfasserin aut Effects of silane precursors on curing behavior of UV-curable hybrid coatings 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract This study demonstrates the effect of some commonly used silane precursors on curing behavior and photopolymerization kinetics of UV-curable hybrid coatings. Tetraethoxyorthosilane (TEOS), vinyltrimethoxysilane (VTMS), and 3-methacryloxypropyltrimethoxysilane (MPS) were polymerized under acidic conditions by the sol–gel method. The resulting structure of the tested siloxane oligomers was characterized using 29Si-NMR and 1H-NMR spectroscopy. Photo-DSC was used to evaluate photocuring enthalpy. A fully integrated model was applied to investigate propagation rate coefficients and to identify the most effective termination mechanism (monomolecular, bimolecular, or mixed). Results showed that oligomers containing MPS effectively promoted total heat of the polymerization process and consequently affected the maximum rate of polymerization and final double bond conversion. Enthalpy rating for samples containing MPS was higher than that of those containing VTMS, showing that MPS was more compatible with the acrylate systems. In addition, evaluations for photopolymerization kinetic constants proved that non-functional oligomers containing TEOS caused radical trapping and increased activity of the monomolecular termination mechanism. Graphical Abstract UV-curable (dpeaa)DE-He213 Hybrid coating (dpeaa)DE-He213 Photocuring kinetic (dpeaa)DE-He213 Photo-DSC (dpeaa)DE-He213 Silane precursor (dpeaa)DE-He213 Bastani, Saeed verfasserin aut Jannesari, Ali verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 119(2014), 1 vom: 04. Sept., Seite 515-526 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:119 year:2014 number:1 day:04 month:09 pages:515-526 https://dx.doi.org/10.1007/s10973-014-4071-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 119 2014 1 04 09 515-526 |
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10.1007/s10973-014-4071-1 doi (DE-627)SPR015497372 (SPR)s10973-014-4071-1-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Mohseni, Majid verfasserin aut Effects of silane precursors on curing behavior of UV-curable hybrid coatings 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract This study demonstrates the effect of some commonly used silane precursors on curing behavior and photopolymerization kinetics of UV-curable hybrid coatings. Tetraethoxyorthosilane (TEOS), vinyltrimethoxysilane (VTMS), and 3-methacryloxypropyltrimethoxysilane (MPS) were polymerized under acidic conditions by the sol–gel method. The resulting structure of the tested siloxane oligomers was characterized using 29Si-NMR and 1H-NMR spectroscopy. Photo-DSC was used to evaluate photocuring enthalpy. A fully integrated model was applied to investigate propagation rate coefficients and to identify the most effective termination mechanism (monomolecular, bimolecular, or mixed). Results showed that oligomers containing MPS effectively promoted total heat of the polymerization process and consequently affected the maximum rate of polymerization and final double bond conversion. Enthalpy rating for samples containing MPS was higher than that of those containing VTMS, showing that MPS was more compatible with the acrylate systems. In addition, evaluations for photopolymerization kinetic constants proved that non-functional oligomers containing TEOS caused radical trapping and increased activity of the monomolecular termination mechanism. Graphical Abstract UV-curable (dpeaa)DE-He213 Hybrid coating (dpeaa)DE-He213 Photocuring kinetic (dpeaa)DE-He213 Photo-DSC (dpeaa)DE-He213 Silane precursor (dpeaa)DE-He213 Bastani, Saeed verfasserin aut Jannesari, Ali verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 119(2014), 1 vom: 04. Sept., Seite 515-526 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:119 year:2014 number:1 day:04 month:09 pages:515-526 https://dx.doi.org/10.1007/s10973-014-4071-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 119 2014 1 04 09 515-526 |
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10.1007/s10973-014-4071-1 doi (DE-627)SPR015497372 (SPR)s10973-014-4071-1-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Mohseni, Majid verfasserin aut Effects of silane precursors on curing behavior of UV-curable hybrid coatings 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract This study demonstrates the effect of some commonly used silane precursors on curing behavior and photopolymerization kinetics of UV-curable hybrid coatings. Tetraethoxyorthosilane (TEOS), vinyltrimethoxysilane (VTMS), and 3-methacryloxypropyltrimethoxysilane (MPS) were polymerized under acidic conditions by the sol–gel method. The resulting structure of the tested siloxane oligomers was characterized using 29Si-NMR and 1H-NMR spectroscopy. Photo-DSC was used to evaluate photocuring enthalpy. A fully integrated model was applied to investigate propagation rate coefficients and to identify the most effective termination mechanism (monomolecular, bimolecular, or mixed). Results showed that oligomers containing MPS effectively promoted total heat of the polymerization process and consequently affected the maximum rate of polymerization and final double bond conversion. Enthalpy rating for samples containing MPS was higher than that of those containing VTMS, showing that MPS was more compatible with the acrylate systems. In addition, evaluations for photopolymerization kinetic constants proved that non-functional oligomers containing TEOS caused radical trapping and increased activity of the monomolecular termination mechanism. Graphical Abstract UV-curable (dpeaa)DE-He213 Hybrid coating (dpeaa)DE-He213 Photocuring kinetic (dpeaa)DE-He213 Photo-DSC (dpeaa)DE-He213 Silane precursor (dpeaa)DE-He213 Bastani, Saeed verfasserin aut Jannesari, Ali verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 119(2014), 1 vom: 04. Sept., Seite 515-526 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:119 year:2014 number:1 day:04 month:09 pages:515-526 https://dx.doi.org/10.1007/s10973-014-4071-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 119 2014 1 04 09 515-526 |
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10.1007/s10973-014-4071-1 doi (DE-627)SPR015497372 (SPR)s10973-014-4071-1-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Mohseni, Majid verfasserin aut Effects of silane precursors on curing behavior of UV-curable hybrid coatings 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract This study demonstrates the effect of some commonly used silane precursors on curing behavior and photopolymerization kinetics of UV-curable hybrid coatings. Tetraethoxyorthosilane (TEOS), vinyltrimethoxysilane (VTMS), and 3-methacryloxypropyltrimethoxysilane (MPS) were polymerized under acidic conditions by the sol–gel method. The resulting structure of the tested siloxane oligomers was characterized using 29Si-NMR and 1H-NMR spectroscopy. Photo-DSC was used to evaluate photocuring enthalpy. A fully integrated model was applied to investigate propagation rate coefficients and to identify the most effective termination mechanism (monomolecular, bimolecular, or mixed). Results showed that oligomers containing MPS effectively promoted total heat of the polymerization process and consequently affected the maximum rate of polymerization and final double bond conversion. Enthalpy rating for samples containing MPS was higher than that of those containing VTMS, showing that MPS was more compatible with the acrylate systems. In addition, evaluations for photopolymerization kinetic constants proved that non-functional oligomers containing TEOS caused radical trapping and increased activity of the monomolecular termination mechanism. Graphical Abstract UV-curable (dpeaa)DE-He213 Hybrid coating (dpeaa)DE-He213 Photocuring kinetic (dpeaa)DE-He213 Photo-DSC (dpeaa)DE-He213 Silane precursor (dpeaa)DE-He213 Bastani, Saeed verfasserin aut Jannesari, Ali verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 119(2014), 1 vom: 04. Sept., Seite 515-526 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:119 year:2014 number:1 day:04 month:09 pages:515-526 https://dx.doi.org/10.1007/s10973-014-4071-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 119 2014 1 04 09 515-526 |
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Enthalten in Journal of thermal analysis and calorimetry 119(2014), 1 vom: 04. Sept., Seite 515-526 volume:119 year:2014 number:1 day:04 month:09 pages:515-526 |
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Enthalten in Journal of thermal analysis and calorimetry 119(2014), 1 vom: 04. Sept., Seite 515-526 volume:119 year:2014 number:1 day:04 month:09 pages:515-526 |
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UV-curable Hybrid coating Photocuring kinetic Photo-DSC Silane precursor |
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Journal of thermal analysis and calorimetry |
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Mohseni, Majid @@aut@@ Bastani, Saeed @@aut@@ Jannesari, Ali @@aut@@ |
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Tetraethoxyorthosilane (TEOS), vinyltrimethoxysilane (VTMS), and 3-methacryloxypropyltrimethoxysilane (MPS) were polymerized under acidic conditions by the sol–gel method. The resulting structure of the tested siloxane oligomers was characterized using 29Si-NMR and 1H-NMR spectroscopy. Photo-DSC was used to evaluate photocuring enthalpy. A fully integrated model was applied to investigate propagation rate coefficients and to identify the most effective termination mechanism (monomolecular, bimolecular, or mixed). Results showed that oligomers containing MPS effectively promoted total heat of the polymerization process and consequently affected the maximum rate of polymerization and final double bond conversion. Enthalpy rating for samples containing MPS was higher than that of those containing VTMS, showing that MPS was more compatible with the acrylate systems. In addition, evaluations for photopolymerization kinetic constants proved that non-functional oligomers containing TEOS caused radical trapping and increased activity of the monomolecular termination mechanism. 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Mohseni, Majid |
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Mohseni, Majid ddc 660 bkl 35.00 misc UV-curable misc Hybrid coating misc Photocuring kinetic misc Photo-DSC misc Silane precursor Effects of silane precursors on curing behavior of UV-curable hybrid coatings |
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660 ASE 35.00 bkl Effects of silane precursors on curing behavior of UV-curable hybrid coatings UV-curable (dpeaa)DE-He213 Hybrid coating (dpeaa)DE-He213 Photocuring kinetic (dpeaa)DE-He213 Photo-DSC (dpeaa)DE-He213 Silane precursor (dpeaa)DE-He213 |
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ddc 660 bkl 35.00 misc UV-curable misc Hybrid coating misc Photocuring kinetic misc Photo-DSC misc Silane precursor |
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ddc 660 bkl 35.00 misc UV-curable misc Hybrid coating misc Photocuring kinetic misc Photo-DSC misc Silane precursor |
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Effects of silane precursors on curing behavior of UV-curable hybrid coatings |
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Effects of silane precursors on curing behavior of UV-curable hybrid coatings |
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Mohseni, Majid |
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Journal of thermal analysis and calorimetry |
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Mohseni, Majid Bastani, Saeed Jannesari, Ali |
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Mohseni, Majid |
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verfasserin |
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effects of silane precursors on curing behavior of uv-curable hybrid coatings |
| title_auth |
Effects of silane precursors on curing behavior of UV-curable hybrid coatings |
| abstract |
Abstract This study demonstrates the effect of some commonly used silane precursors on curing behavior and photopolymerization kinetics of UV-curable hybrid coatings. Tetraethoxyorthosilane (TEOS), vinyltrimethoxysilane (VTMS), and 3-methacryloxypropyltrimethoxysilane (MPS) were polymerized under acidic conditions by the sol–gel method. The resulting structure of the tested siloxane oligomers was characterized using 29Si-NMR and 1H-NMR spectroscopy. Photo-DSC was used to evaluate photocuring enthalpy. A fully integrated model was applied to investigate propagation rate coefficients and to identify the most effective termination mechanism (monomolecular, bimolecular, or mixed). Results showed that oligomers containing MPS effectively promoted total heat of the polymerization process and consequently affected the maximum rate of polymerization and final double bond conversion. Enthalpy rating for samples containing MPS was higher than that of those containing VTMS, showing that MPS was more compatible with the acrylate systems. In addition, evaluations for photopolymerization kinetic constants proved that non-functional oligomers containing TEOS caused radical trapping and increased activity of the monomolecular termination mechanism. Graphical Abstract |
| abstractGer |
Abstract This study demonstrates the effect of some commonly used silane precursors on curing behavior and photopolymerization kinetics of UV-curable hybrid coatings. Tetraethoxyorthosilane (TEOS), vinyltrimethoxysilane (VTMS), and 3-methacryloxypropyltrimethoxysilane (MPS) were polymerized under acidic conditions by the sol–gel method. The resulting structure of the tested siloxane oligomers was characterized using 29Si-NMR and 1H-NMR spectroscopy. Photo-DSC was used to evaluate photocuring enthalpy. A fully integrated model was applied to investigate propagation rate coefficients and to identify the most effective termination mechanism (monomolecular, bimolecular, or mixed). Results showed that oligomers containing MPS effectively promoted total heat of the polymerization process and consequently affected the maximum rate of polymerization and final double bond conversion. Enthalpy rating for samples containing MPS was higher than that of those containing VTMS, showing that MPS was more compatible with the acrylate systems. In addition, evaluations for photopolymerization kinetic constants proved that non-functional oligomers containing TEOS caused radical trapping and increased activity of the monomolecular termination mechanism. Graphical Abstract |
| abstract_unstemmed |
Abstract This study demonstrates the effect of some commonly used silane precursors on curing behavior and photopolymerization kinetics of UV-curable hybrid coatings. Tetraethoxyorthosilane (TEOS), vinyltrimethoxysilane (VTMS), and 3-methacryloxypropyltrimethoxysilane (MPS) were polymerized under acidic conditions by the sol–gel method. The resulting structure of the tested siloxane oligomers was characterized using 29Si-NMR and 1H-NMR spectroscopy. Photo-DSC was used to evaluate photocuring enthalpy. A fully integrated model was applied to investigate propagation rate coefficients and to identify the most effective termination mechanism (monomolecular, bimolecular, or mixed). Results showed that oligomers containing MPS effectively promoted total heat of the polymerization process and consequently affected the maximum rate of polymerization and final double bond conversion. Enthalpy rating for samples containing MPS was higher than that of those containing VTMS, showing that MPS was more compatible with the acrylate systems. In addition, evaluations for photopolymerization kinetic constants proved that non-functional oligomers containing TEOS caused radical trapping and increased activity of the monomolecular termination mechanism. Graphical Abstract |
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1 |
| title_short |
Effects of silane precursors on curing behavior of UV-curable hybrid coatings |
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https://dx.doi.org/10.1007/s10973-014-4071-1 |
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| author2 |
Bastani, Saeed Jannesari, Ali |
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Bastani, Saeed Jannesari, Ali |
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| doi_str |
10.1007/s10973-014-4071-1 |
| up_date |
2024-07-03T16:38:40.554Z |
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| score |
7.400157 |